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At least 1,207 records · Page 67
All sourcesNASA NTRSDOE OSTI
NASA NTRS1977

Mechanical properties of several nickel alloys in hydrogen at elevated temperatures

Tests were performed to determine low cycle fatigue and crack growth rate properties of one iron-base and two forms of one cast nickel-base alloy. The alloys were tested in various forms and/or heat-treat conditions that are proposed for use in a high-pressure hydrogen or a hydrogen-water vapor environment. Some general conclusions can be made comparing the results of tests in a hydrogen environment with those in a hydrogen-water vapor environment. The hydrogen-water vapor environment caused a 50 percent average reduction in fatigue life, indicating extreme degradation when compared with tests conducted in air, for Incoloy 903 at 1033 K (1400 F). Crack growth rates increased significantly for all materials with increasing test temperature. A very significant increase (three orders of magnitude) in crack growth rate occurred for Incoloy 903 tested in the hydrogen-water vapor environment when compared with testing done in hydrogen along at 922 K (1200 F).

Warren, J. R.↗
NASA NTRS1977

Review of electrochemical impregnation for nickel cadmium cells

A method of loading active material within the electrodes of nickel cadmium cells is examined. The basic process of electrochemical impregnation of these electrodes is detailed, citing the principle that when current is applied reactions occur which remove hydrogen ions from solution, making the interior of the plaque less acidic. Electrodes result which are superior in energy density, stability, and life. The technology is reviewed and illustrated with typical performance data. Recommendations are made for additional research and development.

Gross, S.↗
NASA NTRS1976

X-ray topographic observations of magnetic domains in Czochralski-grown nickel single crystals in anomalous transmission geometry

The anomalous transmission effect has been observed in nickel single crystals grown by the Czochralski technique. Sample crystals prepared for X-ray topography are 1.5 to 2.5 cm in diameter and thicker than 0.4 mm; the product of the ordinary linear absorption coefficient and thickness ranges from 17 to 45 for Cu K-alpha radiation. Topographs taken with an asymmetric-crystal-topographic (ACT) camera have revealed extremely straight line images and rectangular arrangements of short line-segment images, along with the images of crystal imperfections. The line images change their arrangement upon application of magnetic fields. These images are attributed to magnetic domains in the interior of crystals. The formation of domain walls near the crystal surface is also observed and distinguished clearly from magnetic domains in the bulk with the use of the ACT camera.

Kuriyama, M.↗
NASA NTRS1977

Coordinated NASA nickel-cadmium battery technology program

This paper describes the NASA nickel-cadmium (Ni-Cd) battery technology program which is being coordinated by JPL to provide NASA and other users with lighter and/or longer-lived Ni-Cd cells for low-earth-orbit, geosynchronous-orbit, and planetary spacecraft missions in the 1980s. The goal is to double the energy density and/or life of the system. Failure modes and mechanisms are differentiated and discussed to point out the critical design variables which affect Ni-Cd cell life. Cell component weights are listed, approaches for reducing weight are discussed, and program tasks and schedules are presented. The nine major tasks being worked on by various organizations are described. Progress has been made in weight reduction, understanding of life reliability mechanisms, and development of a process for manufacturing more stable electrodes. An accelerated and predictive life test program is approximately 30% complete. It appears feasible to double the life and/or usable energy density of the Ni-Cd cell.

Bogner, R. S.↗
NASA NTRS1977

Improved black nickel coatings for flat plate solar collectors

A new black nickel formula was developed which had a solar absorptance of 0.92 and an infrared emittance (at 100 C) of less than 0.10 after 14 days at 38 C and 95 percent relative humidity. The electroplating bath and conditions were changed to obtain the more stable coating configuration. The effect of bath composition, temperature, pH, and plating current density and time on the coating composition, optical properties and durability were investigated.

Lin, J. H.↗
NASA NTRS1977

Mechanism of beneficial effect of tantalum in hot corrosion of nickel-base superalloys

X-ray diffraction and electron microprobe analyses were used to examine a prominent NaTaO3 pattern formed in a number of nickel-base superalloys. It is found that a beneficial effect of tantalum with respect to hot corrosion attack arises from the ability of Ta2O5 to tie up Na2O and prevent the formation of a molten Na2MoO4 phase.

Fryburg, G. C.↗
NASA NTRS1977

Molecular cluster theory of CO chemisorption on a nickel /100/ surface

Self-consistent Hartree-Fock-Slater molecular cluster models for the chemisorption of carbon monoxide on a (100) transition metal surface are presented. Energy levels and charge distribution for the CO:Ni5 cluster in C sub 4v symmetry are obtained, and the variation of binding energies with height of the CO molecule above the surface of nickel is studied in detail. Comparison is made with experimental binding energy spectra and with the multiple-scattering results of Batra and Bagus. The redistribution in energy of free-atom valence levels is studied by means of local-densities-of-states diagrams.

Ellis, D. E.↗
NASA NTRS1976

Hot corrosion studies of four nickel-base superalloys - B-1900, NASA-TRW VIA, 713C and IN738

The susceptibility to hot corrosion of four nickel-base superalloys has been studied at 900 and 1000 C in one atmosphere of slowly flowing oxygen. Hot corrosion was induced by coating the samples with known doses of Na2SO4 and oxidizing the coated samples isothermally on a sensitive microbalance. In order of decending susceptibility to hot corrosion, these alloys were ranked: B-1900, 713C, NASA-TRW VIA, IN738. This order corresponds to the order of decreasing molybdenum content of the alloys. Chemical evidence for B-1900 indicates that hot corrosion is instigated by acid fluxing of the protective Al2O3 coating by MoO3.

Fryburg, G. C.↗
NASA NTRS1977

Correlation between nickel and sulfur abundances in Orgueil phyllosilicates

Sympathetic variations in nickel and sulfur abundances, on a scale of micrometers, in Orgueil phyllosilicates apparently reproduce similar correlations among matrices of different carbonaceous chondrites. In Orgueil this effect probably results from aqueous alteration of a Ni-Si-bearing phase on the parent body.

Kerridge, J. F.↗
NASA NTRS1976

Nickel-free Fe-12Mn-0.2Ti alloy steel for cryogenic applications

A nickel-free Fe-12Mn-0.2Ti alloy steel was investigated for cryogenic applications. The systematic control of the grain size and the microstructural distribution of the retained gamma phase was made through alpha plus gamma heat treatments in combination with mechanical working. Substantial improvements of important low temperature mechanical properties were obtained by these processings.

Hwang, S.↗
NASA NTRS1977

Hot corrosion resistance of nickel-chromium-aluminum alloys

The hot corrosion resistance of nickel-chromium-aluminum alloys was examined by cyclically oxidizing sodium sulfate-coated specimens in still air at 900, 1000, and 1100 C. The compositions tested were within the ternary region: Ni, Ni-50 at.% Cr, and Ni-50 at.% Al. At each temperature the corrosion data were statistically fitted to a third order regression equation as a function of chromium and aluminum contents. From these equations corrosion isopleths were prepared. Compositional regions with the best hot corrosion resistance were identified.

Santoro, G. J.↗
NASA NTRS1978

Hydrogen embrittlement of nickel

Report describes comprehensive study of hydrogen embrittlement in high purity single-crystal and polycrystalline nickel at temperatures from -130 degrees C to 20 degrees C.

Kamdar, M. H.↗
NASA NTRS1978

Kinetics of pack aluminization of nickel

The kinetics of pack aluminization of unalloyed nickel in packs of varying aluminum activity with various halide activators were studied. Surface compositions of the coatings as functions of time, temperature, and pack composition were obtained in order to establish the boundary conditions for diffusion in the system. The structure of the packs was also examined in order to clarify the mechanism of aluminum transport. The results indicate that the kinetics of pack aluminization are controlled jointly by gas diffusion in the pack and solid diffusion in the coating. Levine and Caves' model for gas diffusion was combined with calculations of rates of diffusion in the solid to formulate a more complete theory for the kinetics of pack aluminization.

Seigle, L. L.↗
NASA NTRS1977

Evaluation Program for Secondary Spacecraft Cells: Synchronous Orbit Testing of Sealed Nickel Cadmium Cells

Performance data concerning sealed nickel-cadmium cells operating under a synchronous orbit regime are presented. A space satellite maintaining a position over a fixed point on earth as the earth rotates on its axis and revolves about the sun was simulated. Results include: (1) exposure to synchronous orbit testing at a temperature of 40 C yields less than 6 years of life; (2) performance at -20 C presents a low capacity problem; (3) the capacity check, performed at the middle of each show period, provides a temporary red reconditioning effect on the cells in that the end-of-discharge voltages are higher, for approximately 7 to 10 days, following the capacity check than they were 7 to 10 days prior to the capacity check; (4) all the test packs at -20 C and 40 C have either failed or were discontinued because of low capacity; and (5) test packs at temperatures of 0 C and 10 C have delivered the best capacity during life and packs tested at 20 C showed better life capability than packs tested at -20 C and 40 C.

Harkness, J. D.↗
NASA NTRS1977

Effects of silicon on the oxidation, hot-corrosion, and mechanical behavior of two cast nickel-base superalloys

Cast specimens of nickel-base superalloys 713C and Mar-M200 with nominal additions of 0, 0.5, and 1 wt% Si were evaluated for oxidation and corrosion resistance, tensile and stress-rupture properties, microstructure, and phase relations. Results are compared with those of an earlier study of the effects of Si in B-1900. Si had similar effects on all three superalloys. It improves oxidation resistance but the improvement in 713C and Mar-M200 was considerably less than in B-1900. Hot-corrosion resistance is also improved somewhat. Si is, however, detrimental to mechanical properties, in particular, rupture strength and tensile ductility. Si has two obvious microstructural effects. It increases the amount of gamma-prime precipitated in eutectic nodules and promotes a Mo(Ni,Si)2 Laves phase in the alloys containing Mo. These microstructural effects do not appear responsible for the degradation of mechanical properties, however.

Miner, R. V., Jr.↗
NASA NTRS1978

Static and dynamic cyclic oxidation of 12 nickel-, cobalt-, and iron-base high-temperature alloys

Twelve typical high-temperature nickel-, cobalt-, and iron-base alloys were tested by 1 hr cyclic exposures at 1038, 1093, and 1149 C and 0.05 hr exposures at 1093 C. The alloys were tested in both a dynamic burner rig at Mach 0.3 gas flow and in static air furnace for times up to 100 hr. The alloys were evaluated in terms of specific weight loss as a function of time, and X-ray diffraction analysis and metallographic examination of the posttest specimens. A method previously developed was used to estimate specific metal weight loss from the specific weight change of the sample. The alloys were then ranked on this basis. The burner-rig test was more severe than a comparable furnace test and resulted in an increased tendency for oxide spalling due to volatility of Cr in the protective scale and the more drastic cooling due to the air-blast quench of the samples. Increased cycle frequency also increased the tendency to spall for a given test exposure. The behavior of the alloys in both types of tests was related to their composition and their tendency to form scales. The alloys with the best overall behavior formed alpha-Al2O3 aluminate spinels.

Barrett, C. A.↗
NASA NTRS1978

Strainrange partitioning behavior of the nickel-base superalloys, Rene 80 and IN-100

A study was made to assess the ability of the method of strainrange partitioning (SRP) to both correlate and predict high temperature, low cycle fatigue lives of nickel-base superalloys for gas turbine applications. Baseline data from strain-controlled, low cycle fatigue tests were expressed in terms of the PP, PC, CP, and CC partitioned inelastic strainrange versus life relationships for coated and uncoated Rene' 80 at 1000 C, Gatorized (creep-formed)IN 100 at 760 C, and cast IN 100 at 925 C. The SRP is shown to correlate the cyclic lives of the baseline tests to within factors of nearly two. The partitioned strainrange versus life relationships for uncoated Rene' 80 and cast IN 100 were also determined from the ductility normalized-strainrange partitioning equations. These were used to predict the cyclic lives of the baseline tests. Predicted and observed cyclic lives agreed to within factors of nearly three.

Halford, G. R.↗