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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,207 records · Page 67
All sourcesNASA NTRSDOE OSTI
NASA NTRS2021

Severity of Drought and Heatwave Crop Losses Tripled Over the Last Five Decades in Europe

Extreme weather disasters (EWDs) can jeopardize domestic food supply and disrupt commodity markets. However, historical impacts on European crop production associated with droughts, heatwaves, floods, and cold waves are not well understood—especially in view of potential adverse trends in the severity of impacts due to climate change. Here, we combine observational agricultural data (FAOSTAT) with an extreme weather disaster database (EM-DAT) between 1961 and 2018 to evaluate European crop production responses to EWD. Using a compositing approach (superposed epoch analysis), we show that historical droughts and heatwaves reduced European cereal yields on average by 9% and 7.3%, respectively, associated with a wide range of responses (inter-quartile range +2% to −23%; +2% to −17%). Non-cereal yields declined by 3.8% and 3.1% during the same set of events. Cold waves led to cereal and non-cereal yield declines by 1.3% and 2.6%, while flood impacts were marginal and not statistically significant. Production losses are largely driven by yield declines, with no significant changes in harvested area. While all four event frequencies significantly increased over time, the severity of heatwave and drought impacts on crop production roughly tripled over the last 50 years, from −2.2% (1964–1990) to −7.3% (1991–2015). Drought-related cereal production losses are shown to intensify by more than 3% yr−1. Both the trend in frequency and severity can possibly be explained by changes in the vulnerability of the exposed system and underlying climate change impacts.

Extreme weather disasters↗
NASA NTRS2023

Performance, Inflow, and Tip Loss Characteristics of Rotors with Discontinuous Steps in Twist and Lift at the Blade-Tips

This paper examines the inflow and tip-loss characteristics of rotors incorporating indexed blade-tips that have discontinuous steps in twist or lift distribution. An extension of the classic two-dimensional Prandtl tip loss analysis is derived for indexed-tip rotors and proprotors. Additionally, parametric analysis of tip span and indexed-tip twist-steps was performed using computational fluid dynamics for hover and high-speed axial-flow conditions for proprotors. The intent of this work is to define a new class of active-rotor-twist-control designs for proprotors that avoids unnecessary aeroperformance compromises for rotor twist distributions for proprotors in all phases of flight.

rotors↗
DOE OSTI2017

A Study of IR Loss Correction Methodologies for Commercially Available Pyranometers

This presentation provides a high-level overview of a study of IR Loss Connection Methodologies for Commercially Available Pyranometers. The IR Loss Corrections Study is investigating how various correction methodologies work for several makes and models of commercially available pyranometers in common use, both when operated in ventilators with DC fans and without ventilators, as when they are typically calibrated.

14 SOLAR ENERGY↗
DOE OSTI2019

Bifacial PV System Mismatch Loss Estimation

Nonuniform rear-irradiance on bifacial PV systems can cause additional mismatch loss, which may not be appropriately captured in PV energy production estimates and software. A simplified empirical relationship is presented that links the spatial variation of irradiance (to the resulting mismatch loss factor).

14 SOLAR ENERGY↗
DOE OSTI2014

Modification of the loss cone for energetic particles

Abstract The optimal pitch angle which maximizes the penetration distance, along the magnetic field, of relativistic charged particles injected from the midplane of an axisymmetric field is investigated analytically and numerically. Higher‐order terms of the magnetic moment invariant are necessary to correctly determine the mirror point of trapped energetic particles, and therefore the loss cone. The modified loss cone resulting from the inclusion of higher‐order terms is no longer entirely defined by the pitch angle but also by the phase angle of the particle at the point of injection. The optimal orientation of the injection has a nonzero component perpendicular to the magnetic field line, and is in the plane tangential to the flux surface. Numerical integration of particle orbits were carried out for a relativistic electron in a dipole field, showing agreement with analytic expressions. The results are relevant to experiments, which are concerned with injection of relativistic beams into the atmosphere from aboard a spacecraft in the magnetosphere.

Porazik, Peter↗
DOE OSTI2015

Acceleration and loss of relativistic electrons during small geomagnetic storms

We report that past studies of radiation belt relativistic electrons have favored active storm time periods, while the effects of small geomagnetic storms (Dst >₋50 nT) have not been statistically characterized. In this timely study, given the current weak solar cycle, we identify 342 small storms from 1989 through 2000 and quantify the corresponding change in relativistic electron flux at geosynchronous orbit. Surprisingly, small storms can be equally as effective as large storms at enhancing and depleting fluxes. Slight differences exist, as small storms are 10% less likely to result in flux enhancement and 10% more likely to result in flux depletion than large storms. Nevertheless, it is clear that neither acceleration nor loss mechanisms scale with storm drivers as would be expected. Small geomagnetic storms play a significant role in radiation belt relativistic electron dynamics and provide opportunities to gain new insights into the complex balance of acceleration and loss processes.

58 GEOSCIENCES↗
DOE OSTI2016

Highly relativistic radiation belt electron acceleration, transport, and loss: Large solar storm events of March and June 2015

Two of the largest geomagnetic storms of the last decade were witnessed in 2015. On 17 March 2015, a coronal mass ejection-driven event occurred with a Dst (storm time ring current index) value reaching –223 nT. On 22 June 2015 another strong storm (Dst reaching –204 nT) was recorded. These two storms each produced almost total loss of radiation belt high-energy (E ≳ 1 MeV) electron fluxes. Following the dropouts of radiation belt fluxes there were complex and rather remarkable recoveries of the electrons extending up to nearly 10 MeV in kinetic energy. The energized outer zone electrons showed a rich variety of pitch angle features including strong “butterfly” distributions with deep minima in flux at α = 90°. However, despite strong driving of outer zone earthward radial diffusion in these storms, the previously reported “impenetrable barrier” at L ≈ 2.8 was pushed inward, but not significantly breached, and no E ≳ 2.0 MeV electrons were seen to pass through the radiation belt slot region to reach the inner Van Allen zone. Altogether, these intense storms show a wealth of novel features of acceleration, transport, and loss that are demonstrated in the present detailed analysis.

58 GEOSCIENCES↗
DOE OSTI2022

Effect of the Selective Halogenation of Small Molecule Acceptors on the Blend Morphology and Voltage Loss of High-Performance Solar Cells

Herein, the impacts of the selective halogenation at two different positions of dicyanomethylene-3-indanone (IC) end groups and inner side chains of small molecular acceptors (SMAs) on the P D :SMA interfacial interactions, blend morphology, and resulting photovoltaic properties are described. In this study, four different SMAs (A1, A2, A3, and A4) with the same molecular backbone, but with different degrees of halogenation, are synthesized. The IC end groups on the backbones of the A1 and A3, and A2 and A4 SMAs are chlorinated and fluorinated, respectively; in addition, 6-phenoxyhexyl inner side chains of the A3 and A4 are chlorinated. The SMAs are paired with a chlorinated PBDT-Cl PD to construct organic solar cells (OSCs). The PBDT-Cl:A4-based OSC exhibits the highest power conversion efficiency of 17.2%, outperforming the PBDT-Cl:A1-(13.3%), PBDT-Cl:A2-(15.6%), and PBDT-Cl:A3-based OSC (16.5%). The Cl atoms on the side chains in the A3 and A4 SMAs enhance the molecular/energetic interactions at the P D :SMA interfaces and improve the blend morphology in terms of domain purity and spacing. These effects lead to the improved fill factors and reduced voltage loss of the PBDT-Cl:A3- and PBDT-Cl:A4-based OSCs. This study demonstrates the importance of appropriate halogenation of SMAs in optimizing the blend morphology, reducing voltage loss, and improving OSC performance.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Low‐Loss Far‐Infrared Surface Phonon Polaritons in Suspended SrTiO 3 Nanomembranes

Phonon polaritons (PhPs), excitations arising from the coupling of light with lattice vibrations, enable light confinement and local field enhancement, which is essential for various photonic and thermal applications. To date, PhPs with high confinement and low loss are mainly observed in the mid-infrared regime and mostly in manually exfoliated flakes of van der Waals (vdW) materials. In this work, the existence of low-loss, thickness-tunable phonon polaritons in the far-infrared regime within transferable freestanding SrTiO 3 membranes synthesized through a scalable approach, achieving high figures of merit is demonstrated, which are comparable to the previous record values from the vdW materials. Leveraging atomic precision in thickness control, large dimensions, and compatibility with mature oxide electronics, functional oxide membranes present a promising large-scale 2D platform alternative to vdW materials for on-chip polaritonic technologies in the infrared regime.

functional oxide membranes↗
DOE OSTI2015

Electric and magnetic response in dielectric dark states for low loss subwavelength optical meta atoms

Artificially created surfaces or metasurfaces, composed of appropriately shaped subwavelength structures, namely, meta-atoms, control light at subwavelength scales. Historically, metasurfaces have used radiating metallic resonators as subwavelength inclusions. However, while resonant optical metasurfaces made from metal have been sufficiently subwavelength in the propagation direction, they are too lossy for many applications. Metasurfaces made out of radiating dielectric resonators have been proposed to solve the loss problem, but are marginally subwavelength at optical frequencies. We designed subwavelength resonators made out of nonradiating dielectrics. The resonators are decorated with appropriately placed scatterers, resulting in a meta-atom with an engineered electromagnetic response. A metasurface that yields an electric response is fabricated, experimentally characterized, and a method to obtain a magnetic response at optical frequencies is theoretically demonstrated. In conclusion, this design methodology paves the way for metasurfaces that are simultaneously subwavelength and low loss.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Incorporating Electrochemical Halide Oxidation into Drift-Diffusion Models to Explain Performance Losses in Perovskite Solar Cells under Prolonged Reverse Bias

Partial shading of a solar module can induce a set of cells within the module to operate under reverse bias. Studies have shown that metal halide perovskite solar cells with a wide variety of compositions and contacts exhibit interesting behavior in reverse bias that includes both reversible performance loss and non-reversible degradation. In this paper, an advanced drift-diffusion approach incorporating an electrochemical term to explain the short-circuit, open circuit and fill factor losses that are experimentally measured after prolonged reverse bias is used. It is shown that holes can tunnel into the perovskite due to sharp band bending near the contact, accumulate within the bulk of the perovskite absorber, and trigger the oxidation of halides to form neutral halogens. The density of neutral halogens is much higher in reverse bias because there are hardly any electrons available to reduce the iodine. The resulting halogens act as bulk recombination centers. While the interstitial halogen density does decay when the cell is operated in forward bias, permanent degradation can occur if the iodine diffuses out of the perovskite layer. Finally, the ways in which changing parameters such as the mobile ion density or the series resistance at the contact can influence device performance and stability are discussed.

degradation↗
DOE OSTI2025

Heterogeneity of the Dominant Causes of Performance Loss in End-of-Life Cathodes and Their Consequences for Direct Recycling

Recycling Li-ion batteries from electric vehicles is critical for reducing costs and supporting the development of a domestic battery supply chain. Direct recycling of cathodes, like LiNixMnyCozO2 (NMC), is attractive due to its low cost, energy use, and emissions compared to traditional recycling techniques. However, a comprehensive understanding of the active material properties at end-of-life is needed to guide direct recycling processes and the performance-dependent reuse applications. Here, NMC material from an end-of-life commercial pouch cell is characterized and bench-marked against pristine non-cycled counterparts with respect to capacity, impedance, crystallography, morphology, and microstructure to identify major degradation modes and understand variability in the end-of-life material. The spatial heterogeneity of each property throughout the cell is also quantified. While the degraded material demonstrated similar capacity as the pristine, its impedance and rate capability are severely diminished. Furthermore, samples from the periphery of the electrode layers showed more severe performance loss compared to samples extracted from central regions. The dominant culprit of performance loss is the material microstructure, where the magnitude of particle cracking showed the strongest correlation to the impedance components that are most unfavorably impacted. This work suggests severe cracks in cathode active materials are the primary challenge that direct recycling methods must overcome.

25 ENERGY STORAGE↗
DOE OSTI2020

Cxcl12 Deletion in Mesenchymal Cells Increases Bone Turnover and Attenuates the Loss of Cortical Bone Caused by Estrogen Deficiency in Mice

ABSTRACT CXCL12 is abundantly expressed in reticular cells associated with the perivascular niches of the bone marrow (BM) and is indispensable for B lymphopoiesis. Cxcl12 promotes osteoclastogenesis and has been implicated in pathologic bone resorption. We had shown earlier that estrogen receptor α deletion in osteoprogenitors and estrogen deficiency in mice increase Cxcl12 mRNA and protein levels in the BM plasma, respectively. We have now generated female and male mice with conditional deletion of a Cxcl12 allele in Prrx1 targeted cells (Cxcl12∆Prrx1) and show herein that they have a 90% decrease in B lymphocytes but increased erythrocytes and adipocytes in the marrow. Ovariectomy increased the expression of Cxcl12 and B-cell number in the Cxcl12f/f control mice, but these effects were abrogated in the Cxcl12∆Prrx1 mice. Cortical bone mass was not affected in Cxcl12∆Prrx1 mice. Albeit, the cortical bone loss caused by ovariectomy was greatly attenuated. Most unexpectedly, the rate of bone turnover in sex steroid–sufficient female or male Cxcl12∆Prrx1 mice was dramatically increased, as evidenced by a more than twofold increase in several osteoblast- and osteoclast-specific mRNAs, as well as increased mineral apposition and bone formation rate and increased osteoclast number in the endosteal surface. The magnitude of the Cxcl12∆Prrx1-induced changes were much greater than those caused by ovariectomy or orchidectomy in the Cxcl12f/f mice. These results strengthen the evidence that CXCL12 contributes to the loss of cortical bone mass caused by estrogen deficiency. Moreover, they reveal for the first time that in addition to its effects on hematopoiesis, CXCL12 restrains bone turnover—without changing the balance between resorption and formation—by suppressing osteoblastogenesis and the osteoclastogenesis support provided by cells of the osteoblast lineage. © 2020 American Society for Bone and Mineral Research.

Ponte, Filipa (ORCID:0000000197133640)↗
DOE OSTI2023

Quantifying optical loss of high-voltage degradation modes in photovoltaic modules using spectral analysis

The direct current bias for photovoltaic (PV) modules interconnected in series-strings may include both high voltage negative (“HV-”) and positive (“HV+”) polarity with respect to the electrical ground. Multiple degradation modes, resulting in quantifiable optical loss, were found to occur during HV-/HV+ sequential stress, including corrosion of the external glass surface, encapsulant delamination (at its interfaces with the glass and the PV cell), internal haze formation (resulting from a chemical interaction between the glass and the encapsulant), corrosion and migration of the gridlines, and corrosion of the silicon nitride (Si x N y ) antireflective coating on the cell. The effects of these separate modes were examined using monolithic (e.g., glass or PV cell) and laminated-coupon (glass/encapsulant/glass or glass/encapsulant/cell/encapsulant/backsheet) specimens. Characterizations during and after unbiased accelerated testing at 85°C/85% relative humidity included spectrophotometry, optical microscopy, electron microscopy, and ellipsometry. For some module components (i.e., the glass and the Si x N y coating), the optical performance was determined through iterative analysis of empirical measurements. Concentrating on just their spectral effect, a novel model was then developed to estimate the transfer of light to the PV cell and the return of light from the PV module with simultaneous degradation mechanisms, which was compared with a mini-module previously subjected to HV-/HV+ stress. Here the model suggests that one third of the current loss observed for the mini-module can be attributed to the optical degradation of the packaging materials. The dominant degradation modes include encapsulant delamination and corrosion of the Si x N y coating. Recommendations are given so that the optical model may be improved relative to accelerated testing and validated relative to field aging.

14 SOLAR ENERGY↗
DOE OSTI2026

Interfacial and Kinetic Origins of Voltage Loss in Neutral Zinc‐Air Batteries

Rechargeable zinc-air batteries are promising candidates for grid-scale energy storage; however, their practical deployment is limited by oxygen electrocatalysis inefficiencies and interfacial instabilities, particularly outside conventional alkaline electrolytes. Here, in this work, zinc-air batteries operating under neutral electrolyte conditions using ZnCl 2 soaked KC-PAA-PAM gel polymer electrolytes and electrochemically synthesized Ni/Fe layered double hydroxide electrocatalysts is investigated. Ni/Fe-LDH is intentionally employed as an OER-biased benchmark catalyst to diagnose electrolyte and interface driven limitations rather than as a bifunctional ORR/OER solution. Full cells exhibit highly stable cycling over hundreds of hours, yet operate at substantially suppressed charge and discharge voltages relative to the thermodynamic value. Electrochemical impedance analysis shows that ohmic losses contribute only minimally to this voltage suppression. Post-mortem X-ray photoelectron spectroscopy reveals metallic zinc accumulation on the air cathode and chloride-containing species on the anode, indicating parasitic interfacial processes. Synchrotron-based soft X-ray absorption spectroscopy confirms stable Ni 2+ and Fe 3+ oxidation states during cycling, consistent with OER-biased catalytic behavior, while neutral-electrolyte oxygen evolution measurements demonstrate strong electrolyte-induced suppression of oxygen kinetics. Together, these results show that electrolyte chemistry and cathode-side parasitic processes, rather than catalyst identity alone, dominate voltage losses in neutral zinc-air batteries, providing mechanistic insight into the fundamental challenges associated with neutral electrolyte operation.

Long duration energy storage↗
DOE OSTI2023

Information loss, mixing and emergent type III 1 factors

A manifestation of the black hole information loss problem is that the two-point function of probe operators in a large Anti-de Sitter black hole decays in time, whereas, on the boundary CFT, it is expected to be an almost periodic function of time. We point out that the decay of the two-point function (clustering in time) holds important clues to the nature of observable algebras, states, and dynamics in quantum gravity. We call operators that cluster in time “mixing” and explore the necessary and sufficient conditions for mixing. The information loss problem is a special case of the statement that in type I algebras, there exists no mixing operators. We prove that, in a thermofield double state (KMS state), if mixing operators form an algebra (close under multiplication), the resulting algebra must be a von Neumann type III 1 factor. In other words, the physically intuitive requirement that all nonconserved operators should exponentially mix is so strong that it fixes the observable algebra to be an exotic algebra called a type III1 factor. More generally, for an arbitrary out-of-equilibrium state of a general quantum system (von Neumann algebra), we show that if the set of operators that mix under modular flow forms an algebra, it is a type III1 von Neumann factor.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2020

Fully coherent energy loss effects on light hadron production in pA collisions

We single out the role of fully coherent induced gluon radiation on light hadron production in pA collisions. The effect has the same general features as for quarkonium production, however with a richer color structure as the induced radiation depends on the global color charge of the partonic subprocess final state. Baseline predictions for light hadron nuclear suppression in pPb collisions at the LHC are provided, taking into account only the effect of fully coherent energy loss, which proves to be of the same order of magnitude as gluon shadowing or saturation. This underlines the need to include fully coherent energy loss in phenomenological studies of hadron production in pA collisions.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2020

Coral loss alters guarding and farming behavior of a Caribbean damselfish

Coral loss is a major element of global ecological change in the oceans that may shape the behavior of keystone species such as habitat-attached animals. Farming damselfishes cultivate and aggressively protect algal garden within their territory, thereby shaping local fish assemblages and macro-algae diversity. Following the widespread loss of live branching coral throughout Florida and the Caribbean Sea, dusky damselfish (Stegastes adustus) have modified their territorial behavior. We compared antagonistic behavior, and size and algal species composition of territories of dusky damselfish on dead branching coral rubble and live boulder coral in the Dry Tortugas National Park, USA. Even though similar numbers of “intruders” entered each habitat type, dusky damselfish on rubble territories chased out significantly more fishes, had larger territories and more species of algae were present in their gardens. This study shows that dusky damselfish successfully occupy living and dead coral areas; however, there are potential trade-offs between defending a larger territory and cultivating fewer algal species.

59 BASIC BIOLOGICAL SCIENCES↗