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At least 1,207 records · Page 67

Cometary dust: A thermal criterion to identify cometary samples among the collected interplanetary dust

The relative proportions of the cometary and the asteroidal contributions to the interplanetary dust have not yet been definitively established. These proportions may vary with time as a result of major catastrophic disruptions in the main belt or the appearance of fresh, active comets. Dermott et al. and Reach suggest the debris from catastrophic collisions in the main belt can account for most of the zodiacal cloud particles. Earth collection of these asteroidal particles is strongly favored by near-Earth gravitational enhancement. However, comets are observed to produce interplanetary dust particles (IDP's), and the identification of cometary IDP's would allow inferences of the compositions, mineralogies, and physical properties of the comets. The peak temperatures reached by IDP's on atmospheric entry indicate the distribution of IDP velocities. Each IDP contains many internal thermometers: minerals that transform above certain temperatures, volatile elements that are lost sequentially with increasing temperatures, solar flare tracks that anneal at different temperatures in different minerals, and solar-implanted noble gases that outgas progressively with temperature. Thus, limits on the peak temperature reached by each IDP on Earth atmospheric entry can be set. Other aspects of this investigation are covered.

Flynn, George J.↗

Magnetospheric Response to the Arrival of the Shock Wave in Front of the Magnetic Cloud Event of January 10,1997

We are studying the magnetic cloud event of January 6-11, 1997. Specifically, we have investigated the response of the magnetosphere to the shock wave in front of the magnetic cloud on January 10, 1997 using data from WIND, GEOTAIL and POLAR spacecraft as well as ground magnetometer data. The WIND spacecraft, which was located at about 100 Re upstream from the Earth, observed the arrival of the shock wave front at 005OUT. Geotail was located at the equatorial magnetopause (approx. 8.7 Re), while POLAR was located in the northern dawn sector at 8.4 Re, 6.1 MLT and 61.1 MLAT. A magnetic signature was nearly simultaneously observed at about 0104 UT at the POLAR and Geotail spacecraft. Particle density increases were observed on WIND and Geotail, but not on POLAR. The UV aurora shows an asymmetrical dawn-dusk intensification and presubstorm activity. The significance of these findings will be discussed.

Wuest, M.↗

Purification of the small mechanosensitive channel of Escherichia coli (MscS): the subunit structure, conduction, and gating characteristics in liposomes

The small mechanosensitive channel, MscS, is a part of the turgor-driven solute efflux system that protects bacteria from lysis in the event of osmotic downshift. It has been identified in Escherichia coli as a product of the orphan yggB gene, now called mscS (Levina et al., 1999, EMBO J. 18:1730). Here I show that that the isolated 31-kDa MscS protein is sufficient to form a functional mechanosensitive channel gated directly by tension in the lipid bilayer. MscS-6His complexes purified in the presence of octylglucoside and lipids migrate in a high-resolution gel-filtration column as particles of approximately 200 kDa. Consistent with that, the protein cross-linking patterns predict a hexamer. The channel reconstituted in soybean asolectin liposomes was activated by pressures of 20-60 mm Hg and displayed the same asymmetric I-V curve and slight anionic preference as in situ. At the same time, the single-channel conductance is proportional to the buffer conductivity in a wide range of salt concentrations. The rate of channel activation in response to increasing pressure gradient across the patch was slower than the rate of closure in response to decreasing steps of pressure gradient. Therefore, the open probability curves were recorded with descending series of pressures. Determination of the curvature of patches by video imaging permitted measurements of the channel activity as a function of membrane tension (gamma). Po(gamma) curves had the midpoint at 5.5 +/- 0.1 dyne/cm and gave estimates for the energy of opening DeltaG = 11.4 +/- 0.5 kT, and the transition-related area change DeltaA = 8.4 +/- 0.4 nm(2) when fitted with a two-state Boltzmann model. The correspondence between channel properties in the native and reconstituted systems is discussed.

NASA Discipline Cell Biology↗

Overview of Results from the Cassini Magnetospheric Imaging Instrument (MIMI) During the First Year of Operations

The MIMI investigation comprises three sensors covering the indicated energy ranges: the Ion and Neutral Camera (INCA) -- 7 keV/nuc 3 Mev) and protons (1.6 < E < 160 Mev) from the back end of the dual field-of-view telescope. The Saturn observation sequences began in January, 2004 and culminated in Saturn Orbit Insertion on July 1, 2004. The MIMI sensors observed substantial activity in interplanetary space for several months prior to SOI, including several interplanetary shocks associated with corotating interaction regions, numerous increases most likely originating from particle streams in the vicinity of the Saturnian bow shock and energetic neutral atoms (ENA) emanating from Saturn s magnetosphere. Results following SOI revealed: a dynamical magnetosphere with a day-night asymmetry and an 11-hour periodicity; several water-product ions (O+, OH+, H2O+), but little N+; inferred quantities of neutral gas sufficient to cause major losses in the trapped ions and electrons in the middle and inner magnetosphere; a Titan exosphere that is a copious source of ENA; INCA imaging through ENA has also revealed a previously unknown radiation belt residing inward of the D-ring that is most likely the result of double charge-exchange between the main radiation belt and the upper layers of Saturn s exosphere. Finally, there is ample evidence for the presence of substorm-like injections of plasma that subsequently corotates for a number of days before dissipating on the night-side magnetotail. The observations will be presented and discussed in the context of current theoretical models.

Krimigis, S. M.↗

A Multifunctional Coating for Autonomous Corrosion Control

This slide presentation reviews the effects of corrosion on various structures at the Kennedy Space Center, and the work to discover a corrosion control coating that will be autonomous and will indicate corrosion at an early point in the process. Kennedy Space Center has many environmental conditions that are corrosive: ocean salt spray, heat, humidity, sunlight and acidic exhaust from the Solid Rocket Boosters (SRBs). Presented is a chart which shows the corrosion rates of carbon steel at various locations. KSC has the highest corrosion rates with 42.0 mils/yr, leading the next highest Galeta Point Beach, in the Panama Canal Zone with 27 mils/yr corrosion. A chart shows the changes in corrosion rate with the distance from the ocean. The three types of corrosion protective coatings are described: barrier (passive), Barrier plus active corrosion inhibiting components, and smart. A smart coating will detect and respond actively to changes in its environment in a functional and predictable manner and is capable of adapting its properties dynamically. The smart coating uses microcapsules, particles or liquid drops coated in polymers, that can detect and control the corrosion caused by the environment. The mechanism for a pH sensitive microcapsule and the hydrophobic core microcapsule are demonstrated and the chemistry is reviewed. When corrosion begins, the microcapsule will release the contents of the core (indicator, inhibitor, and self healing agent) in close proximity to the corrosion. The response to a pH increase is demonstrated by a series of pictures that show the breakdown of the microcapsule and the contents release. An example of bolt corrosion is used, as an example of corrosion in places that are difficult to ascertain. A comparison of various coating systems is shown.

Calle, L. M.↗

What Reliability Engineers Should Know about Space Radiation Effects

Space radiation in space systems present unique failure modes and considerations for reliability engineers. Radiation effects is not a one size fits all field. Threat conditions that must be addressed for a given mission depend on the mission orbital profile, the technologies of parts used in critical functions and on application considerations, such as supply voltages, temperature, duty cycle, and redundancy. In general, the threats that must be addressed are of two types-the cumulative degradation mechanisms of total ionizing dose (TID) and displacement damage (DD). and the prompt responses of components to ionizing particles (protons and heavy ions) falling under the heading of single-event effects. Generally degradation mechanisms behave like wear-out mechanisms on any active components in a system: Total Ionizing Dose (TID) and Displacement Damage: (1) TID affects all active devices over time. Devices can fail either because of parametric shifts that prevent the device from fulfilling its application or due to device failures where the device stops functioning altogether. Since this failure mode varies from part to part and lot to lot, lot qualification testing with sufficient statistics is vital. Displacement damage failures are caused by the displacement of semiconductor atoms from their lattice positions. As with TID, failures can be either parametric or catastrophic, although parametric degradation is more common for displacement damage. Lot testing is critical not just to assure proper device fi.mctionality throughout the mission. It can also suggest remediation strategies when a device fails. This paper will look at these effects on a variety of devices in a variety of applications. This paper will look at these effects on a variety of devices in a variety of applications. (2) On the NEAR mission a functional failure was traced to a PIN diode failure caused by TID induced high leakage currents. NEAR was able to recover from the failure by reversing the current of a nearby Thermal Electric Cooler (turning the TEC into a heater). The elevated temperature caused the PIN diode to anneal and the device to recover. It was by lot qualification testing that NEAR knew the diode would recover when annealed. This paper will look at these effects on a variety of devices in a variety of applications. Single Event Effects (SEE): (1) In contrast to TID and displacement damage, Single Event Effects (SEE) resemble random failures. SEE modes can range from changes in device logic (single-event upset, or SEU). temporary disturbances (single-event transient) to catastrophic effects such as the destructive SEE modes, single-event latchup (SEL). single-event gate rupture (SEGR) and single-event burnout (SEB) (2) The consequences of nondestructive SEE modes such as SEU and SET depend critically on their application--and may range from trivial nuisance errors to catastrophic loss of mission. It is critical not just to ensure that potentially susceptible devices are well characterized for their susceptibility, but also to work with design engineers to understand the implications of each error mode. -For destructive SEE, the predominant risk mitigation strategy is to avoid susceptible parts, or if that is not possible. to avoid conditions under which the part may be susceptible. Destructive SEE mechanisms are often not well understood, and testing is slow and expensive, making rate prediction very challenging. (3) Because the consequences of radiation failure and degradation modes depend so critically on the application as well as the component technology, it is essential that radiation, component. design and system engineers work togetherpreferably starting early in the program to ensure critical applications are addressed in time to optimize the probability of mission success.

DiBari, Rebecca↗

Techniques for Measuring Surface Potentials in Space

Materials exposed to the space plasma environment charge to a net potential relative to the ambient plasma. The charging process is due to differential currents to the material surface that results in a net surface charge density. While this process is termed "spacecraft surface charging" when applied to aerospace hardware, it also applies to the surfaces of astronomical objects in direct contact with the space plasma environment including a number of planetary bodies, asteroids, and dust particles. The ability to measure surface potentials is important to many techniques used in conducting fundamental heliospheric science, spacecraft engineering operations, and space technology development activities. This presentation provides a survey of current technologies used to measure surface potentials of spacecraft and planetary bodies with examples of their application to space science and technology programs.

Minow, Joseph I.↗

Properties of DH Type II Radio Bursts and Their Space Weather Implications

We report on the properties of type II radio bursts observed by the Radio and Plasma Wave Experiment (WAVES) onboard the Wind spacecraft over the past two solar cycles. We confirm that the associated coronal mass ejections (CMEs) are fast and wide, more than half the CMEs being halos. About half of the type II bursts extend down to 0.5M hertz, corresponding to a heliocentric distance of tens of solar radii. The DH (Decametric-Hectometric) type II bursts are mostly confined to the active region belt and their occurrence rate follows the solar activity cycle. Type II bursts occurring on the western hemisphere of the Sun and extending to lower frequencies are good indicators of a solar energetic particle event.

Gopalswamy, N.↗

Elemental and isotopic composition of solar energetic particles - Preliminary results from the Phoenix I telescope

The Phoenix I instrument on the S81-1 mission was designed to resolve isotopes in the charge range He to Ni. Analysis of four periods of moderate flare activity shows no strong evidence for mass dependent acceleration in the range C to Si; indeed, the mass abundance ratios are consistent with 'solar system' composition. However, the average Ne-22/Ne-20 ratio for these periods is 0.060 (+0.045, -0.023), i.e. about one standard deviation below ratios reported earlier for solar energetic neon.

Simpson, J. A.↗

Monthly Variability in Upper Ocean Biogeochemistry Due to Mesoscale Eddy Activity in the Sargasso Sea

A comparison of monthly biogeochemical measurements made from 1993 to 1995, combined with hydrography and satellite altimetry, was used to observe the impacts of nine eddy events on primary productivity and particle flux in the Sargasso Sea. Measurements of primary production, thorium-234 flux, nitrate+nitrite, and photosynthetic pigments made at the US JGOFS Bermuda Atlantic Time-Series Study (BATS) site were used. During the three years of this study, four out of six high thorium-234 flux events over 1000 dpm/sq m/d occurred during the passage of an eddy. Primary production nearly as high as the spring bloom maximum was observed in two mode-water eddies (May 1993 and July 1995). The 1994 spring bloom at BATS was suppressed by the passage of an anticyclone. Distinct phytoplankton community shifts were observed in mode-water eddies, which had an increased percentage diatoms and dinoflagelletes, and in cyclones, which had an increased percentage cyanobacteria (excluding Prochlorococcus). The difference in the observations of mode-water eddies and cyclones may result from the age of the eddy, which was very important to the biological response. In general, eddies that were one to two months old elicited a large biological response; eddies that were three months old may show a biological response and were accompanied by high thorium flux measurements; eddies that were four months old or older did not show a biological response or high thorium flux. Our conceptual model depicting the importance of temporal changes during eddy upwelling and decay fit the observations well in all seven upwelling eddies. Additional information is needed to determine the importance of deeper mixed layers and winter mixing to the magnitude of the eddy impacts. Also, sampling generally captured only the beginning, end, and/or edge of an eddy due to the monthly to semi-monthly frequency of the measurements made at BATS. Lagrangian studies, higher resolution time-series, and/or more spatial coverage is needed to provide additional information for improved C and N budgets in the Sargasso Sea and to complete our understanding of the temporal changes that occur in an eddy.

Sweeney, Erin N.↗

Monthly Variability in Upper Ocean Biogeochemistry due to Mesoscale Eddy Activity in the Sargasso Sea

A comparison of monthly biogeochemical measurements made from 1993 to 1995, combined with hydrography and satellite altimetry, was used to observe the impacts of nine eddy events on primary productivity and particle flux in the Sargasso Sea. Measurements of primary production, thorium-234 flux, nitrate+nitrite, and photosynthetic pigments made at the US JGOFS Bermuda Atlantic Time-series Study (BATS) site were used. During the three years of this study, four out of six high thorium-234 flux events over 1000 dpm/sq m/d occurred during the passage of an eddy. Primary production nearly as high as the spring bloom maximum was observed in two modewater eddies (May 1993 and July 1995). The 1994 spring bloom at BATS was suppressed by the passage of an anticyclone. Distinct phytoplankton community shifts were observed in mode-water eddies, which had an increased percentage diatoms and dinoflagelletes, and in cyclones, which had an increased percentage cyanobacteria (excluding Prochlorococcus). The difference in the observations of mode-water eddies and cyclones may result from the age of the eddy, which was very important to the biological response. In general, eddies that were one to two months old elicited a large biological response; eddies that were three months old may show a biological response and were accompanied by high thorium flux measurements, eddies that were four months old or older did not show a biological response or high thorium flux. Our conceptual model depicting the importance of temporal changes during eddy upwelling and decay fit the observations well in all 7 upwelling eddies. Additional information is needed to determine the importance of deeper mixed layers and winter mixing to the magnitude of the eddy impacts. Also, sampling generally captured only the beginning, end, and /or edge of an eddy due to the monthly to semi-monthly frequency of the measurements made at BATS. Lagrangian studies, higher resolution time-series, and/or more spatial coverage is needed to provide additional information for improved C and N budgets in the Sargasso Sea and to complete our understanding of the temporal changes that occur in an eddy.

Sweeney, Erin N.↗

Plasma wave measurements in the magnetosphere of Uranus

As Voyager 2 traversed the magnetosphere of Uranus, the plasma-wave instrument detected very significant phenomena related to local wave-particle interactions, radio emissions, and dust impacts. Here the region between the inbound and outbound bow shock traversals (covering a distance of more than 250 Uranus radii) is considered, and it is demonstrated that intense plasma-wave activity developed only in the inner magnetosphere (r less than 12 Uranus radii); this result is similar to that found at Saturn, but it is in marked contrast with the Jupiter case, where very strong wave activity was detected out to distances of 250 Jupiter radii. The Uranus plasma-wave observations in the inner magnetosphere are compared with corresponding results from the Jupiter and Saturn encounters, and it is shown that the Uranus wave measurements are unique in several significant ways. These new aspects include: (1) the detection of a marked inbound-outbound asymmetry and (2) the detection of whistler-mode waves that yield the strongest wave-particle interactions found in outer planet magnetospheres.

Scarf, F. L.↗

Charged Particle lunar Environment Experiment (CPLEE)

Research development in the Charged Particle Lunar Environment Experiment (CPLEE) is reported. The CPLEE is ion-electron spectrometer placed on the lunar surface for the purpose of measuring charged particle fluxes impacting the moon from a variety of regions and to study the interactions between space plasmas and the lunar surface. The principal accomplishments reported include: (1) furnishing design specifications for construction of the CPLEE instruments; (2) development of an advanced computer-controlled facility for automated instrument calibration; (3) active participation in the deployment and past-deployment operational phases with regard to data verification and operational mode selection; and (4) publication of research papers, including a study of lunar photoelectrons, a study of plasmas resulting from man-made lunar impart events, a study of magnetotail and magnetosheath particle populations, and a study of solar-flare interplanetary particles.

Reasoner, D. L.↗

Numerical and experimental studies of particle flow in a high-pressure boundary-layer wind tunnel

The approach was to simulate the surface environment of Venus as closely as practicable and to conduct experiments to determine threshold wind speeds, particle flux, particle velocities, and the characteristics of various aeolian bedforms. The Venus Wind Tunnel (VWT) is described and the experimental procedures that were developed to make the high-pressure wind tunnel measurements are presented. In terrestrial simulations of aeolian activity, it is possible to conduct experiments under pressures and temperatures found in natural environments. Because of the high pressures and temperatures, Venusian simulations are difficult to achieve in this regard. Consequently, extrapolation of results to Venue potentially involves unknown factors. The experimental rationale was developed in the following way: The VWT enables the density of the Venusian atmosphere to be reproduced. Density is the principal atmospheric property for governing saltation threshold, particle flux, and the ballistics of airborne particles (equivalent density maintains dynamic similarity of gas flow). When operated at or near Earth's ambient temperature, VWT achieves Venusian atmospheric density at pressures of about 30 bar, or about one third less than those on Venus, although still maintaining dynamic similarity to Venus.

White, B. R.↗

The computation of C-C and N-N bond dissociation energies for singly, doubly, and triply bonded systems

The bond dissociation energies (D sub e) of C2H2, C2H4, C2H6, N2, N2H2, and N2H4 are studied at various levels of correlation treatment. The convergence of D sub e with respect to the one particle basis is studied at the single reference modified coupled-pair functional (MCPF) level. At all levels of correlation treatment, the errors in the bond dissociation energies increase with the degree of multiple bond character. The multireference configuration interaction (MRCI) D sub e values, corrected for an estimate of higher excitations, are in excellent agreement with those determined using the size extensive averaged coupled pair functional (ACPF) method. It was found that the full valence complete active space self consistent field (CASSCF)/MRCI calculations are reproduced very well by MRCI calculations based on a CASSCF calculation that includes in the active space only those electrons involved in the C-C or N-N bonds. To achieve chemical accuracy (1 kcal/mole) for the D sub e values of the doubly bonded species C2H4 and N2H2 requires one particle basis sets including up through h angular momentum functions (l = 5) and a multireference treatment of electron correlation: still higher levels of calculation are required to achieve chemical accuracy for the triply bonded species C2H2 and N2.

Langhoff, Stephen R.↗

Fischer-Tropsch Cobalt Catalyst Improvements with the Presence of TiO2, La2O3, and ZrO2 on an Alumina Support

The objective of this study was to evaluate the effect of titanium oxide, lanthanum oxide, and zirconium oxide on alumina supported cobalt catalysts. The hypothesis was that the presence of lanthanum oxide, titanium oxide, and zirconium oxide would reduce the interaction between cobalt and the alumina support. This was of interest because an optimized weakened interaction could lead to the most advantageous cobalt dispersion, particle size, and reducibility. The presence of these oxides on the support were investigated using a wide range of characterization techniques such as SEM, nitrogen adsorption, x-ray diffraction (XRD), temperature programmed reduction (TPR), temperature programmed reduction after reduction (TPR-AR), and hydrogen chemisorptions/pulse reoxidation. Results indicated that both La2O3 and TiO2 doped supports facilitated the reduction of cobalt oxide species in reference to pure alumina supported cobalt catalysts, however further investigation is needed to determine the effect of ZrO2 on the reduction profile. Results showed an increased corrected cluster size for all three doped supported catalysts in comparison to their reference catalysts. The increase in reduction and an increase in the cluster size led to the conclusion that the support-metal interaction weakened by the addition of TiO2 and La2O3. It is also likely that the interaction decreased upon presence of ZrO2 on the alumina, but further research is necessary. Preliminary results have indicated that the alumina-supported catalysts with titanium oxide and lanthanum oxide present are of interest because of the weakened cobalt support interaction. These catalysts showed an increased extent of reduction, therefore more metallic cobalt is present on the support. However, whether or not there is more cobalt available to participate in the Fischer-Tropsch synthesis reaction (cobalt surface atoms) depends also on the cluster size. On one hand, increasing cluster size alone tends to decrease the active site density; on the other hand, by increasing the size of the cobalt clusters, there is less likelihood of forming oxidized cobalt complexes (cobalt aluminate) during Fischer-Tropsch synthesis. Thus, from the standpoint of stability, improving the extent of reduction while increasing the particle size slightly may be beneficial for maintaining the sites, even if there is a slight decrease in overall initial active site density.

Klettlinger, Jennifer Lindsey Suder↗

Intensity profiles of dust near extended sources on Comet Halley

The dust particle intensity decreases proportional to 1/R from the Comet Halley, as expected for free outflow. Flattening of the profile is evident within several tens of km from the nucleus. It is shown here that these phenomena can be explained by a model that considers the extended size and nonunifomity of the active region on the surface of the cometary nucleus. A critical scale length, defined by the opening angle of a jetlike feature and the size of the source, can be introduced to describe the flattening. The model is consistent with the observations and provides the basis for studying other mechanisms such as particle fragmentation.

Thomas, N.↗