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NASA NTRS1976

Differences in the production of noncharacteristic radiation in gaseous and solid targets

Bell et al. (1975) found that the observed yield of noncharacteristic radiation (NCR) for a beam of S atoms hitting Al and Ne targets is of approximately equal magnitude for gaseous and solid targets under similar collision conditions. They concluded that NCR is produced predominantly in single collisions for 55-MeV S atoms on an Al target. This conclusion is tested in a similar collision system by comparing the NCR yields obtained with a 40-MeV Si(6+) ion beam on SiH4 (gaseous target) and on Al (solid target). Corrected X-ray spectra recorded in both cases clearly indicate a difference in the NCR yield for gaseous and solid targets. The results suggest that double collisions dominate the NCR production and that a single-collision production contribution of 15% to 20% is an upper limit for the projectile-target system used.

Laubert, R.↗

NASA NTRS1977

Thermal degradation of the tensile strength of unidirectional boron/aluminum composites

The variation of ultimate tensile strength with thermal treatment of B-Al composite materials and of boron fibers chemically removed from these composites in an attempt to determine the mechanism of the resulting strength degradation was studied. Findings indicate that thermally cycling B-Al represents a more severe condition than equivalent time at temperature. Degradation of composite tensile strength from about 1.3 GN/m squared to as low as 0.34 GN/m squared was observed after 3,000 cycles to 420 C for 203 micrometers B-1100 Al composite. In general, the 1100 Al matrix composites degraded somewhat more than the 6061 matrix material studied. Measurement of fiber strengths confirmed a composite strength loss due to the degradation of fiber strength. Microscopy indicated a highly flawed fiber surface.

Grimes, H. H.↗

NASA NTRS1977

Reply in response to comment by E. W. Hones

Hones 1977 points out the marked disagreement between the plasma flow measurements reported by Frank et al. 1976 and those obtained with the LASL plasma analyzer. He suggests (1) that solar ultraviolet background rates may have been incorrectly accounted for in the computation of proton bulk flows in the magnetotail as reported by Frank et al. 1976 and (2) that bulk flows with substantial speeds, i.e., those speeds greater than 50 km per sec, are seldom encountered in the plasma sheet at geocentric radial distances approx. equal to 35 R sub E. It is demonstrated that such ultraviolet responses were carefully considered by Frank et al. 1976 and thus the conclusion is maintained that bulk flows greater than 50 km per sec frequently occur in the plasma sheet at these radial distances. Further, a direct comparison of the capabilities of the LASL plasma analyzer employed by Hones and of the LEPEDEA Frank et al., 1976 indicates that there are rather severe restrictions on which plasmas in the plasma sheet can be properly measured to gain proton temperatures, number densities and flow velocities with the LASL plasma analyzer.

Frank, L. A.↗

NASA NTRS1976

Chemical characterization of lunar core 60009

A total of 27 major, minor and trace element abundances in 27 fine fractions (smaller than 1 mm) of core 60009 were determined by instrumental neutron activation analysis. The core was divided into five chemically defined stratigraphic units. Unit 1, 0.5 to 11.5 cm, is characterized by low Ca and Al abundances which increase towards the base of the unit and high ferromagnesian element abundances. Unit 2, 11.5 to 19.8 cm, has higher abundances of Ca and Al and lower abundances of ferromagnesian elements than unit 1 and is much more uniform. Unit 3, 19.8 to 25.7 cm is very similar to unit 1 and may have been derived from the same source region. Unit 4, 25.7 to 29.6 cm, has the highest Ca and Al abundances of all the units defined and the lowest abundances of ferromagnesian elements. The ferromagnesian elements generally decrease in abundance towards the base of the unit. This unit exhibits a positive Eu anomaly. Unit 5, 29.6 to 31.5 cm, has the lowest Ca and Al abundances and highest ferromagnesian abundances of all the units. The unit boundaries correspond well with major unit boundaries characterized by Duke and Nagle (1974) on the basis of textural parameters, structure, composition and thickness of layers.

Ali, M. Z.↗

NASA NTRS1977

Formation and composition of the moon

Many of the properties of the Moon, including the enrichment in Ca, Al, Ti, U, Th, Ba, Sr, and the REE and the depletion in Fe, Rb, K, Na, and other volatiles can be understood if the Moon represents a high-temperature condensate from the solar nebula. Thermodynamic calculations show that Ca-, Al-, and Ti-rich compounds condense first in a cooling nebula. The initial high temperature mineralogy is gehlenite, spinel, perovskite, Ca-Al-rich pyroxenes, and anorthite. Inclusions in carbonaceous chondrites such as the Allende meteorite are composed primarily of these minerals and, in addition, are highly enriched in refractories such as REE relative to carbonaceous chondrites. These inclusions can yield basalt and anorthosite in the proportions required to eliminate the europium anomaly, leaving a residual spinel-melilite interior. A deep interior high in Ca-Al does not imply an unacceptable mean density or moment of inertia for the Moon. The inferred high-U content of the lunar interior, both from the Allende analog and the high heat flow, indicates a high-temperature interior. The model is consistent with extensive early melting, with shallow melting at 3 AE, and with presently high deep internal temperatures. It is predicted that the outer 250 km is rich in plagioclase and FeO. The low iron content of the interior in this model raises the interior temperatures estimated from electrical conductivity by some 800 C.

Anderson, D. L.↗

NASA NTRS1979

Electrostatic noise at the plasma frequency beyond the earth's bow shock

Scarf et al. (1971) and Dunckel (1974) have shown that there are, very frequently, intense electrostatic waves whose frequency is near the plasma frequency upstream of the earth's bow shock and that these waves are correlated with the presence of energetic electrons from the bow shock. Also, Fredericks et al. (1971) have postulated a two-stream instability. The paper investigates these phenomena further, by comparing electrostatic noise at or near the ambient solar wind plasma frequency with times when the interplanetary magnetic field probably connects to the shock. Evidence is presented that Scarf et al. and Fredericks et al. were correct in their explanation of the phenomenon, and that the double-humped distribution would be expected only in a region too small to be resolved by the plasma measurements made so far.

Filbert, P. C.↗

NASA NTRS1979

A correlative study of magnetic flux transfer in the magnetosphere

The applied magnetic flux of the southward component of the IMF in GSM coordinates (Bz-) which impinges upon the sunward magnetopause is compared to the time integral of the auroral AL index during 56 intervals within a 3-month period in 1969 when interplanetary records from Heos 1 and Explorer 35 were available. The periods of magnetic activity were those for which Bz was greater than 0 and AL was less than 20gamma at the beginning and end of the interval. It was found that for these intervals, the time integral of the AL index was proportional to the applied magnetic flux with a correlation coefficient of 0.94. In addition, the empirical relationships between magnetic flux transfer, applied southward flux, and the time integral of AL arrived at by Holzer and Slavin (1978) on the basis of expansion and contractions of the forward magnetosphere observed with OGO 5 are reexamined and improved.

Holzer, R. E.↗

NASA NTRS1980

Label Identification from Statistical Tabulation (LIST) temporal extendability study

The author has identified the following significant results. The most apparent contributors to the problem of poor temporal extension of LIST are the drastic changes in the brightness keys and an inadequate set of AI responses in Phase 3. The brightness trajectories change drastically from Phase 3 to the transition year (TY). Removing brightness channels from the discriminant does not completely correct the lack of extendability. Removing brightness increases the accuracy of the extension from Phase 3 to TY from 57.7 percent to 64.18 percent. The removal of the Al keys increases accuracy to 65.76 percent. Although the latter increase appears insignificant when compared to the first, the removal of only the Al keys increased accuracy to 63.58 percent. Proper weighting of the responses explains 73.8 percent of the ground truth labels but only 56.7 percent of the Al labels. By contrast, the TY responses which were weighted to explain the TY ground truth labels fared equally well, explaining 73.6 percent of those labels and 87.1 percent of the Al labels.

Dennis, T. B.↗

NASA NTRS1982

Method of protecting a surface with a silicon-slurry/aluminide coating

A low cost coating for protecting metallic base system substrates from high temperatures, high gas velocity oxidation, thermal fatigue and hot corrosion is described. The coating is particularly useful for protecting vanes and blades in aircraft and land based gas turbine engines. A lacquer slurry comprising cellulose nitrate containing high purity silicon powder is sprayed onto the superalloy substrates. The silicon layer is then aluminized to complete the coating. The Si-Al coating is less costly to produce than advanced aluminides and protects the substrate from oxidation and thermal fatigue for a much longer period of time than the conventional aluminide coatings. While more expensive Pt-Al coatings and physical vapor deposited MCrAlY coatings may last longer or provide equal protection on certain substrates, the Si-Al coating exceeded the performance of both types of coatings on certain superalloys in high gas velocity oxidation and thermal fatigue. Also, the Si-Al coating increased the resistance of certain superalloys to hot corrosion.

Deadmore, D. L.↗

NASA NTRS1982

The relative stress-corrosion-cracking susceptibility of candidate aluminum-lithium alloys for aerospace applications

Stress corrosion tests of Al-Li-Cu powder metallurgy alloys are described. Alloys investigated were Al-2.6% Li-1.4% and Al-2.6% Li-1.4% Cu-1.6% Mg. The base properties of the alloys were characterized. Process, heat treatment, and size/orientational effects on the tensile and fracture behavior were investigated. Metallurgical and electrochemical conditions are identified which provide reproducible and controlled parameters for stress corrosion evaluation. Preliminary stress corrosion test results are reported. Both Al-Li-Cu alloys appear more susceptible to stress corrosion crack initiation than 7075-T6 aluminum, with the magnesium bearing alloy being the most susceptible. Tests to determine the threshold stress intensity for the base and magnesium bearing alloys are underway. Twelve each, bolt loaded DCB type specimens are under test (120 days) and limited crack growth in these precracked specimens has been observed. General corrosion in the aqueous sodium chloride environment is thought to be obscuring results through crack tip blunting.

Pizzo, P. P.↗

NASA NTRS1981

Muon hyperfine fields in iron and its dilute alloys

The temperature dependence of the interstitial magnetic field, B, as determined by the rotation of the spin of the muon, has been measured for dilute polycrystalline iron alloys with Mo, Ti, and Nb additions over a temperature range of 240 to 633 K. In all cases the behaviors differ from one another and from the Fe(Al) alloys previously studied. B, which is negative with respect to the magnetization, is increased in magnitude by Al and Mo, and decreased greatly by Ti. The addition of Nb creates a two-phase alloy from which the role of heterogeneity and/or strain on B in iron can be assessed. If the temperature dependence of the hyperfine field extracted from B for Fe(Mo) alloys is interpreted on the model previously used to discuss the Fe(Al) data, then the muon must be attracted to the Mo atom while repelled by the Al atoms as the temperature decreases.

Stronach, C. E.↗

NASA NTRS1982

Transport processes on the lunar surface - Comparison of model calculations with radionuclides data

Descriptions are given of the experimental methods used in determining Al-26 and Mn-53 activities and of the possible improvements that can be expected in the near future. The results obtained for the seven lunar core sections where both Al-26 and Mn-53 are measured with good depth definition are discussed. It is then shown how meteoritic impacts and the secondary effects they induce modify the Al-26 and Mn-53 activities in a core. Using a Monte Carlo method, 150 possible depositional histories for a core are generated; from these the resulting activity profiles for both Al-26 and Mn-53 are computed, using several possible SCR energy spectra. These model-generated profiles are then compared with the experimental profiles in the seven cores, and plausible scenarios for the depositional history of each of the cores are tentatively inferred.

Langevin, Y.↗

NASA NTRS1983

The effects of metals and inhibitors on thermal oxidative degradation reactions of unbranched perfluoroalkylethers

Thermal oxidative degradation studies were performed on unbranched perfluoroalkylethers at 288 C in oxygen. Metals and alloys studied included Ti, Al, and Ti (4 Al, 4 Mn). The mechanism of degradation was by chain scission. Ti and Al promoted less degradation than Ti (4 Al, 4 Mn). The two inhibitors investigated (a perfluorophenyl phosphine and a phosphatriazine) reduced degradation rates by several orders of magnitude. Both inhibitors were effective for the same duration (75 to 100 hours). The phosphatriazine appeared to provide more surface protection.

Jones, W. R., Jr.↗

NASA NTRS1983

Solar wind control of the low-latitude asymmetric magnetic disturbance field

The extent to which the low latitude dawn-dusk magnetic asymmetry is controlled by the dawn-dusk solar wind motional electric field VBs and/or substorm processes measured by the westward auroral electrojet index AL is studied using the technique of empirical linear prediction filters. A new index, (ASYM), defined as the difference between dawn and dusk deviations in the X (geomagnetic Northward) magnetic field component, is used to measure the dawn-dusk asymmetry. Quantitative information which characterizes the coupling processes are provided by the empirically determined filters obtained from this analysis. Results indicate that some currents are directly driven by the solar wind-magnetosphere interaction and that their magnetic perturbations contribute to both the AL and ASYM indices. However, a portion of the AL index that is uncorrelated with VBs is correlated with ASYM which suggests that internal magnetospheric processes also contribute to AL and ASYM.

Clauer, C. R.↗

NASA NTRS1983

Barium from a mini r-process in supernovae

McCulloch and Wasserburg (1978) have reported nonlinear isotopic anomalies in barium for two Ca-Al-rich inclusions of the Allende carbonaceous chondrite, known as EK-1-4-1 and C-1. In an attempt to account for these anomalies, it has been proposed that Ba from an r-process of nucleosynthesis, containing Ba-135 and Ba-137, was injected into the primeval color system but was not totally homogenized. Questions arise in connection with the relations of Xe isotopes in carbonaceous chondrites. This has prompted Heymann and Dziczkaniec (1979, 1980, 1981) to study the formation of r-Xe, r-Kr, and r-Te by the mini r-process which is thought to occur in the O, Ne-rich shells of Type II supernovae. Lee et al. (1979) have studied the formation of r-Ba, r-Nd, and r-Sm by the same process. Certain differences regarding the approaches used by Lee et al. and by Heymann and Dziczkaniec make it necessary to restudy the work of Lee et al. Attention is given to the survival probabilities of nuclear species of interest, taking into accounts the elements Cs, Ba, I, and Xe.

Heymann, D.↗

NASA NTRS1983

Stress-corrosion behavior of aluminum-lithium alloys in aqueous environments

The stress corrosion susceptibility of two powder metallurgy (P/M) alloys, Al-Li-Cu and Al-Li-Cu-Mg two mechanically attrited (M/A) alloys, Al-Li-Cu and Al-Li-Mg; and two wrought, ingot alloys, X-2020 and AA7475, are compared. Time-dependent fracture in an aqueous sodium chloride environment under alternate immersion condition was found to vary significantly between alloys. The stress corrosion behavior of the two powder metallurgy processed alloys was studied in detail under conditions of crack initiation, static crack growth, and fatigue crack growth. A variety of stress corrosion tests were performed including smooth surface, time-to-failure tests; potentiostatic tests on smooth surfaces exposed to constant applied strain rates; and fracture mechanics-type tests under static and cyclic loads. Both alloys show surface pitting and subsequent intergranular corrosion. Pitting is more severe in the magnesium-bearing alloy and is associated with stringer particles strung along the extrusion direction as a result of P/M processing.

Pizzo, P. P.↗

NASA NTRS1984

Effects of alloy composition on cyclic flame hot-corrosion attack of cast nickel-base superalloys at 900 deg C

The effects of Cr, Al, Ti, Mo, Ta, Nb, and W content on the hot corrosion of nickel base alloys were investigated. The alloys were tested in a Mach 0.3 flame with 0.5 ppmw sodium at a temperature of 900 C. One nondestructive and three destructive tests were conducted. The best corrosion resistance was achieved when the Cr content was 12 wt %. However, some lower-Cr-content alloys ( 10 wt%) exhibited reasonable resistance provided that the Al content alloys ( 10 wt %) exhibited reasonable resistance provided that the Al content was 2.5 wt % and the Ti content was Aa wt %. The effect of W, Ta, Mo, and Nb contents on the hot-corrosion resistance varied depending on the Al and Ti contents. Several commercial alloy compositions were also tested and the corrosion attack was measured. Predicted attack was calculated for these alloys from derived regression equations and was in reasonable agreement with that experimentally measured. The regression equations were derived from measurements made on alloys in a one-quarter replicate of a 2(7) statistical design alloy composition experiment. These regression equations represent a simple linear model and are only a very preliminary analysis of the data needed to provide insights into the experimental method.

Deadmore, D. L.↗

NASA NTRS1983

Ancient crustal components in the Fra Mauro breccias

Texturally pristine clasts preserve primary petrographic relationships and mineral compositions, yielding insights into igneous processes of the early lunar crust that cannot be gained from highly shocked and brecciated 'chemically pristine' samples. The use of texture as a prime criterion allows for expansion of the data base derived solely from chemical criteria, and provides complementary data. Texturally pristine clasts from the Apollo 14 site studied here include anorthosite, troctolites, gabbronorites, and basalts. Alkali anorthosites are plagioclase orthocumulates and may form by flotation in Mg-suite plutons. Ferroan anorthosite was cataclastically deformed and metamorphosed to granulite facies. Troctolites include both 01 + Plg and 01 + En + Plg cumulates. Major and trace element analyses of two troctolites reveal 'eastern' geochemical affinities that contrast other 'western' troctolites. Gabbronorites are Pig + Plg + or - Sp cumulates whose parent magmas may range from high-Al to intermediate-Ti mare basalt. At least three varieties of mare basalt are found at Apollo 14: high-Al, low-Ti; low-Al, intermediate-Ti; and low-Al, Ti VHK basalt. VHK (Very High Potassium) basalt is a new variety indigenous to Apollo 14.

Shervais, J. W.↗