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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,189 records · Page 66
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Effect of ion sputtering on interface chemistry and electrical properties of Au GaAs(100) Schottky contacts

The effects of sputtering n-type (100)GaAs with 1 to 5 keV argon ions have been studied in ultrahigh vacuum. Auger electron and X-ray photoelectron spectroscopies have been used to characterize the surface before and after sputtering. Gold Schottky contacts were prepared in situ to avoid contamination at the metal/semiconductor interface. The data show that sputtering depletes the surface in As, and the extent of depletion increased as the ion energy was increased. However, angular-resolved photoelectron data showed As was enriched on the outer atom layer by 5 keV but depleted by 1 keV Ar(+) sputtering. Current and capacitance versus voltage data showed that sputtering always lowered the Schottky barrier height and generally increased the ideality factor. However, the barrier height after 3 keV sputtering was higher than after 1 keV sputtering. Those effects are explained based on a combined effective work function model and creation of a donorlike surface damage layer. The donor layer was correlated with As depletion by sputtering. Deep level trap formation and annealing of sputtering effects were studied.

Wang, Y.-X.↗
NASA NTRS1986

The physical basis for spectral variations in thermal infrared emittance of silicates and application to remote sensing

The use of infrared spectroscopy for the remote characterization of planetary surfaces has received attention due to efforts in the investigation of these bodies from space. In the 8 to 14 micron region, a depression in the emittance spectra of rocks (sometimes called reststrahlen) is related to the fundamental stretching vibrations of Si-O bonds and shifts in the locations of this feature are ascribed to variations in rock composition. Thus, it should be possible to investigate, quantify, and model the relationships of reststrahlen spectral band location through silicate mineralogical composition to rock classification. This concept will be tested first through the use of laboratory-acquired data on the infrared spectra and mineralogy of selected mineral and rock samples. As a suitable classification model is developed, it will be tested through overflights of appropriate rock outcrops using the Thermal Infrared Multispectral Scanner (TIMS).

Walter, Louis S.↗
NASA NTRS1988

Direct control and characterization of a Schottky barrier by scanning tunneling microscopy

Scanning tunneling microscopy (STM) methods are used to directly control the barrier height of a metal tunnel tip-semiconductor tunnel junction. Barrier behavior is measured by tunnel current-voltage spectroscopy and compared to theory. A unique surface preparation method is used to prepare a low surface state density Si surface. Control of band bending with this method enables STM investigation of semiconductor subsurface properties.

Bell, L. D.↗
NASA NTRS1990

Velocity mapping and models of the elliptical galaxies NGC 720, NGC 1052, and NGC 4697

CCD surface photometry and extensive long-slit spectroscopy are used to construct detailed models of the flattened ellipticals NGC 720, 1052, and 4697. The models are combined with the Jeans equations to yield predicted fields of line-of-sight velocity dispersion and streaming velocity. By comparing these fields with observed velocities, it is concluded that none of these systems can have isotropic velocity dispersion tensors, and diminishing the assumed inclination of any given galaxy tends to decrease the line-of-sight velocity dispersion and, counterintuitively, to increase the line-of-sight rotation speeds. The ratio of the line-of-sight velocity dispersion along the minor axis to that along the major axis is found to be a sensitive diagnostic of the importance of a third integral for the galaxy's structure.

Binney, J. J.↗
NASA NTRS1991

Study of balloon and thermal control material degradation aboard LDEF

The initial results of analysis performed on a number of polymeric materials which were exposed aboard the Long Duration Exposure Facility (LDEF) are discussed. These materials include two typical high altitude balloon films (a polyester and a polyethylene) and silver-backed Teflon from thermal control blanket samples. The techniques used for characterizing changes in mechanical properties, chemical structure and surface morphology include Fourier Transform Infrared (FTIR) spectroscopy, scanning electron microscopy, and dynamic mechanical analysis.

Letton, Alan↗
NASA NTRS1993

EUVE survey observations of the moon

Preliminary survey images of the moon obtained by the Extreme Ultraviolet Explorer and results of data analysis are presented. The preliminary results indicate that the brightness of the moon varies little from observation to observation. Early results also show that the lunar albedo closely matches the relative reflectivity of mineral found on the moon's surface. Further studies are conducted during the spectroscopy phase of the EUVE mission to confirm current results regarding the presence of X-ray fluorescence in the data.

Mcdonald, J. S.↗
NASA NTRS1992

A Backscatter Moessbauer Spectrometer (BaMS) for use on Mars

The use of Moessbauer spectroscopy for in situ analysis on the surface of Mars was proposed and the design and implementation of a backscatter Moessbauer spectrometer (BaMS) instrument suitable for planetary missions to the surfaces of Mars (MESUR), the Moon (Artemis and lunar outpost), asteroids, or other solid solar system objects is discussed. The BaMS instrument is designed to be capable of analysis of a sample for the mineralogy of its iron-bearing phases without any sample preparation. A requirement of lander missions to Mars is instrumentation for in situ mineralogical analyses. Such analyses provide data needed for primary characterization as to the type of surface materials present and by inference the processes that formed and subsequently modified them. For purposes of providing diagnostic information about naturally occurring materials, the element iron is particularly important because it is abundant and multivalent (primarily 0, +2, and +3 oxidation states). Knowledge of the oxidation state of iron and its distribution among iron-bearing mineralogies tightly constrains the types of materials present. The pivotal role of iron was already recognized in 1978 by COMPLEX, who recommended development of flight instruments that would identify mineralogy and the oxidation state of iron in planetary surface materials. The near-term U.S. strategy for the exploration of Mars is the MESUR (Mars Environmental SURvey) program, which entails emplacement of a network of small, long-lived surface landers. For the Moon, BaMS was recommended as part of a three-instrument landed payload for the Artemis missions, targeted for 1997. BaMS would prospect for ilmenite, an oxygen resource material, and provide data to assess the maturity of lunar soil. Because instrumental characteristics are low mass, low volume, and low power consumption, BaMS is suitable for implementation on even small landers and rovers, as are being envisioned in MESUR and Artemis concepts. In addition to providing highly diagnostic data, a BaMS analyzer is inherently simple and, as is highly desirable for remote operation, no sample preparation is required.

Agresti, D. G.↗
NASA NTRS1994

Simulations of Terrestrial in-situ Cosmogenic-Nuclide Production

Targets of silicon and silicon dioxide were irradiated with spallation neutrons to simulate the production of long-lived radionuclides in the surface of the Earth. Gamma-ray spectroscopy was used to measure Be-7 and Na-22, and accelerator mass spectrometry was used to measure Be-10, C-14, and Al-26. The measured ratios of these nuclides are compared with calculated ratios and with ratios from other simulations and agree well with ratios inferred from terrestrial samples.

Reedy, R. C.↗
NASA NTRS1998

Mineral Mapping Using AVIRIS Data at Ray Mine, AZ

Imaging Spectroscopy enables the identification and mapping of surface mineralogy over large areas. This study focused on assessing the utility of Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data for environmental impact analysis over the Environmental Protection Agency's (EPA) high priority Superfund site Ray Mine, AZ. Using the Spectral Angle Mapper (SAM) algorithm to analyze AVIRIS data makes it possible to map surface materials that are indicative of acid generating minerals. The improved performance of the AVIRIS sensor since 1996 provides data with sufficient signal to noise ratio to characterize up to 8 image endmembers. Specifically we employed SAM to map minerals associated with mine generated acid waste, namely jarositc, goethite, and hematite, in the presence of a complex mineralogical background.

McCubbin, Ian↗
NASA NTRS2004

Lunar and Planetary Science XXXV: Venus

The session "Venus" included the following reports:Preliminary Study of Laser-induced Breakdown Spectroscopy (LIBS) for a Venus Mission; Venus Surface Investigation Using VIRTIS Onboard the ESA/Venus Express Mission; Use of Magellan Images for Venus Landing Safety Assessment; Volatile Element Geochemistry in the Lower Atmosphere of Venus; Resurfacing Styles and Rates on Venus: Assessment of 18 Venusian Quadrangles; Stereo Imaging of Impact Craters in the Beta-Atla-Themis (BAT) Region, Venus; Depths of Extended Crater-related Deposits on Venus ; Potential Pyroclastic Deposit in the Nemesis Tessera (V14) Quadrangle of Venus; Relationship Between Coronae, Regional Plains and Rift Zones on Venus, Preliminary Results; Coronae of Parga Chasma, Venus; The Evolution of Four Volcano/Corona Hybrids on Venus; Calderas on Venus and Earth: Comparison and Models of Formation; Venus Festoon Deposits: Analysis of Characteristics and Modes of Emplacement; Topographic and Structural Analysis of Devana Chasma, Venus: A Propagating Rift System; Anomalous Radial Structures at Irnini Mons, Venus: A Parametric Study of Stresses on a Pressurized Hole; Analysis of Gravity and Topography Signals in Atalanta-Vinmara and Lavinia Planitiae Canali are Lava, Not River, Channels; and Formation of Venusian Channels in a Shield Paint Substrate.

Source record↗
NASA NTRS2009

Reflectance Spectra Comparison of Orbital Debris, Intact Spacecraft, and Intact Rocket Bodies in the GEO Regime

A key objective of NASA s Orbital Debris program office at Johnson Space Center (JSC) is to characterize the debris environment by way of assessing the physical properties (type, mass, density, and size) of objects in orbit. Knowledge of the geosynchronous orbit (GEO) debris environment in particular can be used to determine the hazard probability at specific GEO altitudes and aid predictions of the future environment. To calculate an optical size from an intensity measurement of an object in the GEO regime, a 0.175 albedo is assumed currently. However, identification of specific material type or types could improve albedo accuracy and yield a more accurate size estimate for the debris piece. Using spectroscopy, it is possible to determine the surface materials of space objects. The study described herein used the NASA Infrared Telescope Facility (IRTF) to record spectral data in the 0.6 to 2.5 micron regime on eight catalogued space objects. For comparison, all of the objects observed were in GEO or near-GEO. The eight objects consisted of two intact spacecraft, three rocket bodies, and three catalogued debris pieces. Two of the debris pieces stemmed from Titan 3C transtage breakup and the third is from COSMOS 2054. The reflectance spectra of the Titan 3C pieces share similar slopes (increasing with wavelength) and lack any strong absorption features. The COSMOS debris spectra is flat and has no absorption features. In contrast, the intact spacecraft show classic absorption features due to solar panels with a strong band gap feature near 1 micron. The two spacecraft are spin-stabilized objects and therefore have solar panels surrounding the outer surface. Two of the three rocket bodies are inertial upper stage (IUS) rocket bodies and have similar looking spectra. The slopes flatten out near 1.5 microns with absorption features in the near-infrared that are similar to that of white paint. The third rocket body has a similar flattening of slope but with fewer features of white paint - indicating that the surface paint on the SL-12 may be different than the IUS. This study shows that the surface materials of debris appear different spectrally than intact rocket bodies and spacecraft and therefore are not believed to be solar panel material or pristine white paint. Further investigation is necessary in order to eliminate materials as possible choices for the debris pieces.

Barker, Ed↗
NASA NTRS2012

Overview of Vesta Mineralogy Diversity

4 Vesta is known to have a surface of basaltic material through visible/near-infrared reflectance spectroscopy (1). Vesta s spectrum has strong absorption features centered near 0.9 and 1.9 m, indicative of Fe-bearing pyroxenes. The spectra of HED (howardite, eucrite and diogenite) meteorites have similar features (1). This led to the hypothesis that Vesta was the parent body of the HED clan (2,3) and the discovery of a dynamical Vesta family of asteroids (Vestoids) provides a further link between Vesta and HEDs (4). Data from the Dawn VIR (Visible InfraRed mapping Spectrometer) (5) characterize and map the mineral distribution on Vesta, strengthen the Vesta - HED linkage and provide new insights into Vesta s formation and evolution.

DeSanctis, M. C.↗
DOE OSTI2023

Origin of surface and subband states at the InAs(111)A surface

The atomic structure of surfaces and interfaces plays a vital role in the electronic quality and properties of quantum devices. The interplay between the surface and confined bulk subband states in terms of their susceptibility has been investigated in relation to crystal defects on an InAs(111)A-(2×2) reconstructed surface, using low-temperature scanning tunneling microscopy and spectroscopy. We measure the two-dimensional quantized subband states arising from the confined potential imposed by downward bending of the conduction band edge. Furthermore, we show evidence of the existence of surface Bloch states within the confined bulk band gap projected on the surface spectrum which have originated from the surface reconstruction. As expected, larger confined bulk band gaps at the surface and conduction band offset are measured to be 0.58 and 0.31 eV, respectively. Here we further show the scattering of these quantum states at different surface defects and demonstrate that surface states are more susceptible to the defect potential when compared with the corresponding subband states. This apparent contrast follows from the length scale at which these defect potentials actively interact on or near the surface. Our observed experimental results are supported by empirical tight-binding simulations for the subband states and first-principles density functional theory simulations for the surface states present on the surface.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2020

Surface modification of bamboo fiber with sodium hydroxide and graphene oxide in epoxy composites

Bamboo fibers (BFs) have high mechanical properties and are candidate reinforcement for epoxy matrix composites. However, to improve performance, good fiber-matrix interaction is required. In this work, unidirectional long BF reinforced epoxy composites at fiber volume content of 22%, 40%, and 50% were made by compression molding. The 40 v% untreated BF reinforced composites exhibited 107% and 439% increase for flexural strength and modulus, respectively, compared to neat epoxy. Sodium hydroxide (NaOH) treatment was used to modify the surface of the BFs, and then the NaOH modified BFs were coated with graphene oxide (GO). The 40 v% NaOH modified BF composites showed an improvement from 259.9 to 327.5 MPa for flexural strength and from 16.7 to 21.5 GPa for flexural modulus, compared to 40 v% untreated BF composites. Slight improvement in properties up to 334.6 MPa for flexural strength and up to 23.8 GPa for flexural modulus was achieved for composites made of 40 v% NaOH/GO modified BF. Surface modification of BF after the NaOH and NaOH/GO treatment was confirmed by X-ray photoelectron spectroscopy and by scanning electron microscopy, which showed differences on the fiber surface morphology and on the composite fracture surface. This BF surface modification approach with GO has potential to impart other properties beyond mechanical to produce multifunctional composite and lead to the use of sustainable plant fibers as alternatives to synthetic fibers.

36 MATERIALS SCIENCE↗
NASA NTRS1995

Concerning Apparent Similarity of Structures of Fluoropolymer Surfaces Exposed to an Argon Plasma or Argon Ion Beam

X-ray photoelectron spectroscopy (XPS) C(sub 1s) spectra of fluoropolymers exposed to either an argon plasma or argon ion beam show remarkable similarity, implying that the surface-modification reactions for these two processes likely proceed through comparable mechanisms, revolving predominantly ion-surface interactions. The importance of working with a monochromatized x-ray source for XPS analysis of the surface-modified fluoropolymers is once again emphasized.

Golub, Morton A.↗
DOE OSTI2022

Unveiling the High-valence Oxygen Degradation Across the Delithiated Cathode Surface

Charge compensation on anionic redox reaction (ARR) has been promising to realize extra capacity beyond transition metal redox in battery cathodes. The practical development of ARR capacity has been hindered by high-valence oxygen instability, particularly at cathode surfaces. However, the direct probe of surface oxygen behavior has been challenging. Here, the electronic states of surface oxygen are investigated by combining mapping of resonant Auger electronic spectroscopy (mRAS) and ambient pressure X-ray photoelectron spectroscopy (APXPS) on a model LiCoO 2 cathode. The mRAS verified that no high-valence oxygen can sustain at cathode surfaces, while APXPS proves that cathode electrolyte interphase (CEI) layer evolves and oxidizes upon oxygen gas contact. In conclusion, this work provides valuable insights into the high-valence oxygen degradation mode across the interface. Oxygen stabilization from surface architecture is proven a prerequisite to the practical development of ARR active cathodes.

25 ENERGY STORAGE↗