Hydrothermal synthesis and thermal change in IR reflectance of Al/W co-doped VO2 powder
Highlights: • Al/W-doped VO{sub 2} powders were synthesized by a hydrothermally method. • The Al/W-doped VO{sub 2} underwent a phase transition at around room temperature. • The Al/W-doped VO{sub 2} had the larger IR reflectance compared with W-VO{sub 2}(M). - Abstract: Al/W co-doped VO{sub 2} with a monoclinic structure, space group P2{sub 1}/c, was synthesized (hereafter, Al/W-doped VO{sub 2}(M1)) and its thermochromic property was investigated. First, to prepare the precursor for Al/W-doped VO{sub 2}(M1), V{sub 2}O{sub 5}, (NH{sub 4}){sub 10}W{sub 12}O{sub 41}·5H{sub 2}O, and AlCl{sub 3}·H{sub 2}O were dispersed in a citric acid solution and then hydrothermally treated in an autoclave. Then, the Al/W-doped VO{sub 2}(M1) powders were synthesized by heating the obtained precursor at various temperatures under an Ar gas flow. The Al/W-doped VO{sub 2}(M1) has a monoclinic structure with space group P2{sub 1}/c, similar to undoped VO{sub 2}(M1) and W-doped VO{sub 2}(M1). The Al/W-doped VO{sub 2}(M1) indicated that the monoclinic to tetragonal transition temperature was lowered to approximately room temperature by the Al and W doping. The Al/W-doped VO{sub 2}(M1) had the lower optical band gap and showed a larger IR reflectance in the 800–2000 nm range, compared with W-doped VO{sub 2}(M1) and pure VO{sub 2}(M1).