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At least 1,189 records · Page 66

Infrared Spectra and Optical Constants of Astronomical Ices: I. Amorphous and Crystalline Acetylene

Here we report recent measurements on acetylene (C2H2) ices at temperatures applicable to the outer Solar System and the interstellar medium. New near- and mid-infrared data, including optical constants (n, k), absorption coefficients (alpha), and absolute band strengths (A), are presented for both amorphous and crystalline phases of C2H2 that exist below 70 K. Comparisons are made to earlier work. Electronic versions of the data are made available, as is a computer routine to use our reported n and k values to simulate the observed IR spectra. Suggestions are given for the use of the data and a comparison to a spectrum of Makemake is made.

IR spectroscopy↗

Deep Learning and Natural Language Processing for Accelerated Inverse Design of Optical Metamaterials

Optical metamaterial device design has enjoyed a long track of success over the past 50 years leading to the manipulation of light over a wide range of wavelengths spanning the ultraviolet to the far infrared. The manipulation of light over such wavelengths has already led to many technological advancements such as the design of selective radiative absorbers for solar energy, daytime passive cooling using deep space, and optical invisibility cloaks for defense applications. Further disruptive advancements in energy, defense, computing, and biomedical fields could be enabled or enhanced by future optical metamaterial devices. These technologies could lead to increased energy efficiency and hence reduced national primary energy consumption, cheap long duration energy storage, and next generation solid-state heat engines. But historically the methods to invent and develop all of these devices have been time- consuming and based mostly on intuition and iteration. Finding an optimal design can take years.

36 MATERIALS SCIENCE↗

Deep Learning and Natural Language Processing for Accelerated Inverse Design of Optical Metamaterials

Optical metamaterial device design has enjoyed a long track of success over the past 50 years leading to the manipulation of light over a wide range of wavelengths spanning the ultraviolet to the far infrared. The manipulation of light over such wavelengths has already led to many technological advancements such as the design of selective radiative absorbers for solar energy, daytime passive cooling using deep space, and optical invisibility cloaks for defense applications. Further disruptive advancements in energy, defense, computing, and biomedical fields could be enabled or enhanced by future optical metamaterial devices. These technologies could lead to increased energy efficiency and hence reduced national primary energy consumption, cheap long duration energy storage, and next generation solid-state heat engines. But historically the methods to invent and develop all of these devices have been time- consuming and based mostly on intuition and iteration. Finding an optimal design can take years. In this project we developed a machine learning-based algorithm capable of automatically generating device designs to produce desired optical properties, reducing the design cycle life in certain situations to be almost instantaneous.

36 MATERIALS SCIENCE↗

MODELING AND METHOD FOR OPTICAL PERFORMANCE OF A RECEIVER COATING AND ITS DEGRADATION DUE TO OPERATION

The optical properties of the coating used on a concentrated solar power (CSP)’s receiver directly impact the performance of the power plant. Receiver coatings are designed to absorb as much heat as possible and transfer it to the circulating fluid. Over time, the absorptivity of the receiver coating degrades due to environmental and operational conditions. This project aims to (1) create a test apparatus that allows coatings to undergo accelerated lifetime testing under conditions that mimic what the coating will experience on-tower; and (2) develop a mathematical model that based on the test data predicts absorptivity over time. To create the mathematical model, samples of BrightSource Energy’s Gen1 and Gen2 coatings were tested first looking at individual failure modes (such as high temperature cycling) and then for combined failure modes in the newly developed apparatus. In addition to taking optical measurements, the samples were destroyed to allow for metalogical evaluation to understand what was happening on a microscopic level. Pre-existing models from the literature that describe accelerated testing as well as individual phenomena observed in the coating were then combined to create the model. Additionally, the Gen2 and Gen3 coatings are being testing at the Plataforma Solar de Almería (PSA) facility in Almeria, Spain to confirm that the apparatus test results are similar to those received on-sun. (PSA’s facility closely mimics on-tower conditions). The goal is to enable industry players to test coatings using the new apparatus, gather absorptivity measurements (without needing to destroy samples), and input the information into the model to determine how the coating will perform over time, thus allowing the optical performance of coatings to be compared even before they are used on-tower. The model will be publicly available by the end of the project (currently projected as December 2024).

14 SOLAR ENERGY↗

Optimal Heliostat Assignment Strategy for Multiple-Receiver Systems

Next-generation concentrating solar power concepts currently being developed under the U.S. Department of Energy's Gen3 program include several novel heliostat field and receiver arrangements. Among these concepts are solar fields utilizing multiple receivers or several distinct receiver flux control zones, and each of which has particular power or peak flux constraints. In this paper, we present a linear program that identifies optimal heliostat-to-receiver assignment strategies for multi-receiver or multi-zone solar fields based on detailed calculations made by an optics modeling package. Two distinct problems are addressed: namely, (1) a design problem that chooses the optimal set of heliostats to include in a final layout given receiver constraints and performance, and (2) an operations problem that assigns existing heliostats to a receiver, maximizing field power output while maintaining receiver power constraints. The optimization methodology is integrated into the concentrating solar power tower modeling package SolarPILOTTM, and results are presented showing that heliostat assignment strategies can impact both initial heliostat field layout characteristics and the cost of thermal energy produced by the field. The methodology succeeds in maintaining power requirements but at the expense of producing different flux profiles on each receiver surface. Consequently, the paper also discusses additional measures that are applied to ensure that desirable flux distribution properties are maintained, reducing local flux mean-absolute-deviation values from a baseline of 17% or greater to less than 5% compared to a desired reference flux profile.

41 EE - Solar Energy Technologies Office (EE-4S)↗

Direct glass bonded high specific power silicon solar cells for space applications

A lightweight, radiation hard, high performance, ultra-thin silicon solar cell is described that incorporates light trapping and a cover glass as an integral part of the device. The manufacturing feasibility of high specific power, radiation insensitive, thin silicon solar cells was demonstrated experimentally and with a model. Ultra-thin, light trapping structures were fabricated and the light trapping demonstrated experimentally. The design uses a micro-machined, grooved back surface to increase the optical path length by a factor of 20. This silicon solar cell will be highly tolerant to radiation because the base width is less than 25 microns making it insensitive to reduction in minority carrier lifetime. Since the silicon is bonded without silicone adhesives, this solar cell will also be insensitive to UV degradation. These solar cells are designed as a form, fit, and function replacement for existing state of the art silicon solar cells with the effect of simultaneously increasing specific power, power/area, and power supply life. Using a 3-mil thick cover glass and a 0.3 g/sq cm supporting Al honeycomb, a specific power for the solar cell plus cover glass and honeycomb of 80.2 W/Kg is projected. The development of this technology can result in a revolutionary improvement in high survivability silicon solar cell products for space with the potential to displace all existing solar cell technologies for single junction space applications.

Dinetta, L. C.↗

Thermospheric O I 844.6-nm emission in twilight

The thermospheric O I 844.6-nm column emission rate was measured over Toronto, a midlatitude station, in the autumn of 1991 using an imaging Fabry-Perot spectrometer. Twilight decay curves were measured on four clear evenings when the solar zenith angle was between 95 degs and 104 degs, giving corresponding column emission rates between 874 R and 130 R at 20 degs elevation angle in the azimuth of the Sun. The expected decay curves were calculated from the field line interhemisperic plasma model assuming only photoelectron impact excitation as the production mechanism with a cross section appropriate to an optically thin atmosphere. The agreement was good when the solar and geomagnetic activity levels were low to moderate, but the emission rate was overestimated during high activity periods. The comparison indicates that the photoelectron impact mechanism with a thin-atmosphere cross section is sufficient to explain the twilight decay of the thermospheric O I 844.6-nm emission.

Bahsoun-Hamade, F.↗

Fabrication of AlGaAs/GaAs cascade solar cell by LPE

Stacking two or more photovoltaic junctions in electrical and optical series results in higher conversion efficiency since each junction can be tailored to respond more efficiently to a smaller range of photon energies. An efficiency of about 30 percent was predicted for a two junction cascade cell having the optimum bandgap values. A number of III-V materials systems were considered for use in fabricating cascade solar cells. The Al-Ga-As system is attractive from a developmental standpoint since it employs a proven materials system that is closely lattice matched throughout its compositional range. This system employs a GaAs low bandgap cell and 1.9 eV AlGaAs high bandgap cell connected by an AlGaAs tunnel junction. Although this cell does not possess the optimum bandgap values, an efficiency of 25 percent was predicted at 300 K under AMO, 1 sun illumination.

Bedair, S. M.↗

Space Qualification of the Optical Filter Assemblies for the ICESat-2/ATLAS Instrument

The Advanced Topographic Laser Altimeter System (ATLAS) will be the only instrument on the Ice, Cloud, and Land Elevation Satellite -2 (ICESat-2). ICESat-2 is the 2nd-generation of the orbiting laser altimeter ICESat, which will continue polar ice topography measurements with improved precision laser-ranging techniques. In contrast to the original ICESat design, ICESat-2 will use a micro-pulse, multi-beam approach that provides dense cross-track sampling to help scientists determine a surface's slope with each pass of the satellite. The ATLAS laser will emit visible, green laser pulses at a wavelength of 532 nm and a rate of 10 kHz and will be split into 6 beams. A set of six identical, thermally tuned optical filter assemblies (OFA) will be used to remove background solar radiation from the collected signal while transmitting the laser light to the detectors. A seventh assembly will be used to monitor the laser center wavelength during the mission. In this paper, we present the design and optical performance measurements of the ATLAS OFA in air and in vacuum prior to their integration on the ATLAS instrument.

Etalons↗

Understanding and Overcoming Water-induced Interfacial Degradation in Si Modules (Final Technical Report)

Moisture ingress is an established issue for photovoltaic module durability. Durability studies probing moisture effects typically evaluate performance losses at the module level, attributing global power losses to the overall humidity condition of the test environment while leaving local module behavior unknown. This project successfully develops an in situ short-wave infrared probe of moisture content in PV modules with demonstrated detection limits better than 100 ppm in EVA-encapsulated Al-BSF and PERC architectures (66 µg/cm3) and applicability across the range of terrestrial conditions. Combining this optical moisture quantification method (water reflectometry detection, WaRD) with peel testing of interfaces, biased photoluminescence imaging of performance, and first principles computation, we correlate module moisture content and cell performance over the course of accelerated damp heat tests. By performing multi-level humidity and thermal accelerated testing over thousands of hours (0, 65 and 85% RH and 25, 65, and 85°C), we are able to attribute effects of individual environmental stresses and the dependence on module architecture. Using first-principles computational chemistry, we find that the decomposition of EVA to acetic acid (Norrish II) is thermodynamically preferred over a pathway to acetaldehyde (Norrish I), elucidating the underlying chemistry of encapsulant degradation. We also find it is likely that water segregates to the stable interfaces of the cell, especially the SiNx/EVA interface. We find that moisture is strongly correlated with reduction in adhesion at the interfaces of the cells, particularly at Ag fingers. We show uniquely that the peel strength required to delaminate the encapsulant from the front of the cell depends not only on the exposure to a high heat and humid environment, but also to the moisture content during the mechanical testing, indicating an important interaction between when mechanical stresses are faced in terms of the moisture content of the module and its durability. We find that the background sheet resistance (that is, the sheet resistance rise not attributable to finger interruptions or cracks) is substantially higher in the backsheet mini-modules vs glass-glass packages when humidity and temperature are faced. This increase in power loss due to the background resistance increase over time in damp heat in glass-backsheet modules resulted in ~3-4% larger decrease in relative PCE compared to glass-glass modules. In glass-backsheet modules, the effect of the moisture dose alone is comparable or greater than that of the combined temperature and water term, suggesting that glass-backsheet modules are overall more susceptible to moisture induced performance loss. Finally, we show that thin film PV modules are amenable to WaRD measurement, based on the ability to detect moisture in POE encapsulants or in the cell stack itself. The ease of WaRD measurement and its few requirements on the bill of materials should enable broad applicability of this technique for studying the effects of moisture in PV.

14 SOLAR ENERGY↗

The Use of MODIS Instrument on the EOS-Terra Satellite to Assess the Impact of Aerosol on Climate

Terra will derive the aerosol optical thickness and properties. The aerosol properties can be used to distinguish between natural and human-made aerosol. In the polar orbit Terra will measure aerosol only once a day, around 10:30 am. How will we use this information to study the global radiative impacts of aerosol on climate? We shall present a strategy to address this problem. It includes the following steps: 1) From the Terra aerosol optical thickness and size distribution model we derive the effect of aerosol on reflection of solar radiation at the top of the atmosphere. In a sensitivity study we show that the effect of aerosol on solar fluxes can be derived 10 times more accurately from the MODIS data than derivation of the optical thickness itself. Applications to data over several regions will be given. 2) Using 1/2 million AERONET global data of aerosol spectral optical thickness we show that the aerosol optical thickness and properties during the Terra 10:30 pass are equivalent to the daily average. Due to the aerosol lifetime of several days measurements at this time of the day are enough to assess the daily impact of aerosol on radiation. 3) Aerosol impact on the top of the atmosphere is only part of the climate question. The INDOEX experiment showed that addressing the impact of aerosol on climate, requires also measurements of the aerosol forcing at the surface. This can be done by a combination of measurements of MODIS and AERONET data.

Kaufman, Y.↗

Strategy to use the Terra Aerosol Information to Derive the Global Aerosol Radiative Forcing of Climate

Terra will derive the aerosol optical thickness and properties. The aerosol properties can be used to distinguish between natural and human-made aerosol. In the polar orbit Terra will measure aerosol only once a day, around 10:30 am. How will we use this information to study the global radiative impacts of aerosol on climate? We shall present a strategy to address this problem. It includes the following steps: - From the Terra aerosol optical thickness and size distribution model we derive the effect of aerosol on reflection of solar radiation at the top of the atmosphere. In a sensitivity study we show that the effect of aerosol on solar fluxes can be derived 10 times more accurately from the MODIS data than derivation of the optical thickness itself. Applications to data over several regions will be given. - Using 1/2 million AERONET global data of aerosol spectral optical thickness we show that the aerosol optical thickness and properties during the Terra 10:30 pass are equivalent to the daily average. Due to the aerosol lifetime of several days measurements at this time of the day are enough to assess the daily impact of aerosol on radiation. - Aerosol impact on the top of the atmosphere is only part of the climate question. The INDOEX experiment showed that addressing the impact of aerosol on climate, requires also measurements of the aerosol forcing at the surface. This can be done by a combination of measurements of MODIS and AERONET data.

Kaufman, Yoram J.↗

A V-grooved AlGaAs/GaAs passivated PN junction

A passivated, V-grooved GaAs solar cell offers important advantages in terms of improved optical coupling, higher short circuit current, and increased tolerance to particle radiation when compared to the planar cell configuration. An AlGaAs epilayer has been deposited on a p-type GaAs epilayer grown on an n-type V-grooved GaAs surface using MOCVD. A wet chemical etching process was used to produce a V-pattern with a 7.0 micron periodicity. Reflectivity measurements substantiate the expected decrease in solar reflectance. Scanning electron microscopy techniques were used to confirm the presence of the AlGaAs layer and verify the existence of a pn junction.

Bailey, Sheila G.↗

Lunar Polar Exploration with Beamed Powered Rovers

Use of a laser to transmit power to a photovoltaic array has been proposed many times, including significant work done at NASA Glenn during the 1990s, but until recently the technology has lagged behind the ambitious requirements. The current NASA objective of lunar polar exploration provides the need, and evolution of higher-power and more efficient lasers provides the opportunity. Exploration of the ice-bearing craters near the lunar poles, where complete absence of sunlight precludes solar power, have been identified as a significant technology challenge for NASA’s future exploration. An approach to solve this is to use a laser to send power from the illuminated crater rim to a photovoltaic receiver on a rover inside the permanently dark region. A conceptual design was done of a prototype laser power system to be included on a proposed flight demonstration of the Kilopower space reactor. For the design, the laser transmitter is mounted on a small rover capable of moving to a location in line of sight of the receiving rover, e.g., on a crater rim with a view into the permanently dark region to be explored. A 250-watt laser diode bar transmits power at 808 nm, using a 10.5 cm optical beam director. The beam is received by a GaAs solar array mounted on the exploring rover, where it is converted into electrical power at ~50% optical to electrical efficiency. For the flight demonstration, 50 meters of laser transmission was required. The design showed a total laser mass of 7.8 kg is capable of producing the beam needed, not including the thermal control system. The demonstration design demonstrates 50-m transmission, but it would be valuable to have longer point-to-point beaming on the moon. Long beam paths require higher coherence than the diode laser bars of the demonstration system. The development of high-efficiency diode-pumped fiber lasers meets this technology need: and diode-pumped fiber lasers using the Er/Yb system can be purchased commercially with overall conversion efficiency of greater than 50% at wavelength 1.06 micrometers. Two technologies for a photovoltaic converter for this wavelength are the InGaAs photovoltaic cell, using technology developed for multi-junction space solar cells, or newly-developed high-quantum efficiency silicon cells. The next step to mature the technology would be a lunar flight demonstration. In the future, this has the potential to enhance and enable future human exploration of the moon, harvesting and utilizing the ice resources of these permanently-shadowed craters.

Geoffrey A Landis↗

A V-grooved AlGaAs/GaAs passivated pn junction

A passivated, V-grooved GaAs solar cell offers important advantages in terms of improved optical coupling, higher short-circuit current, and increased tolerance to particle radiation when compared to the planar cell configuration. An AlGaAs epilayer has been deposited on a p-type GaAs epilayer grown on an n-type V-grooved GaAs surface using MOCVD. A wet chemical etching process was used to produce a V-pattern with a 7.0-micron periodicity. Reflectivity measurements substantiate the expected decrease in solar reflectance. Scanning electron microscopy techniques were used to confirm the presence of the AlGaAs layer and verify the existence of a pn junction.

Bailey, S. G.↗

The Extreme Ultraviolet Normal Incidence Spectrograph (EUNIS)

EUNIS (Extreme Ultraviolet Normal Incidence Spectrograph) is a high-efficiency extreme ultraviolet spectrometer that is expected to fly for the first time in 2004 as a sounding rocket payload. Using two independent optical systems, EUNIS will probe the structure and dynamics of the inner solar corona high spectral resolution in two wavelength regions: 17-21 nm with 3.5 pm resolution and 30-37 nm with 7 pm resolution. The long wavelength channel includes He II 30.4 nm and strong lines from Fe XI-XVI; the short wavelength channel includes strong lines of Fe IX-XIII. Angular resolution of 2 arcsec is maintained along a slit covering a full solar radius. EUNIS will have 100 times the throughput of the highly successful SERTS payloads that have preceded it. There are only two reflections in each optical channel, from the superpolished, off-axis paraboloidal primary and the toroidal grating. Each optical element is coated with a high-efficiency multilayer coating optimized for its spectral bandpass. The detector in each channel is a microchannel plate image intensifier fiber- coupled to three 1K x 1K active pixel sensors. EUNIS will obtain spectra with a cadence as short as 1 sec, allowing unprecedented studies of the physical properties of evolving and transient structures. Diagnostics of wave heating and reconnection wil be studied at heights above 2 solar radii, in the wind acceleration region. The broad spectral coverage and high spectral resolution will provide superior temperature and density diagnostics and will enable underflight calibration of several orbital instruments, including SOHO/CDS and EIT, TRACE, Solar-B/EIS, and STEREO/EUVI. EUNIS is supported by NASA through the Low Cost Access to Space Program in Solar and Heliospheric Physics.

Oegerle, William↗

High-Temperature Selective Emitter Design and Materials: Titanium Aluminum Nitride Alloys for Thermophotovoltaics

The efficiency of a thermophotovoltaic (TPV) system depends critically upon the spectral selectivity and stability of an emitter, which may operate most effectively at temperatures in excess of 1000 °C. Here, we computationally design and experimentally demonstrate a novel selective emitter design based on multilayer nanostructures, robust to off-normal emission angles. A computational search of the material and temperature compatibility space of simple emitter designs motivates new material classes and identifies several promising multilayer nanostructure designs for both TPV absorber and emitter applications. One such structure, comprising a thin (<100 nm) tunable Ti x Al 1-x N (TiAlN) absorber and refractory oxide Bragg reflector is grown on W metal foil. In agreement with simulations, the emitter achieves record spectral efficiency (43.4%) and power density (3.6 W/cm 2 ) for an emitter with at least 1 h of high temperature (>800 °C) operation.

36 MATERIALS SCIENCE↗

Photonic Crystal Waveguides for >90% Light Trapping Efficiency in Luminescent Solar Concentrators

Luminescent solar concentrators are currently limited in their potential concentration factor and solar conversion efficiency by the inherent escape cone losses present in conventional planar dielectric waveguides. Here, we demonstrate that photonic crystal slab waveguides tailored for luminescent solar concentrator applications can exhibit >90% light trapping efficiency. This is achieved by use of quantum dot luminophores embedded within the waveguide that absorb light at photon energies corresponding to photonic crystal leaky modes that couple to incoming sunlight. The luminophores then emit at lower photon energies into photonic crystal bound modes that enable highly efficient light trapping in slab waveguides of wavelength-scale thickness. Photonic crystal waveguides thus nearly eliminate escape cone losses, and overcome the performance limitations of previously proposed wavelength-selective dielectric multilayer filters. We describe designs for hole-array and rod-array photonic crystals comprised of hydrogenated amorphous silicon carbide using CdSe/CdS quantum dots. Our analysis suggests that photonic crystal waveguide luminescent solar concentrators using these materials these can achieve light trapping efficiency above 92% and a concentration factor as high as 100.

36 MATERIALS SCIENCE↗