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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,189 records · Page 66

Role of Polymer Architecture in CO 2 Capture from Air Using Supported Poly(alkylenimine)s: Linear vs Branched Polymers

Direct air capture (DAC) of CO 2 coupled with geologic storage is a promising climate change mitigation strategy, with some applications employing amines supported on porous solids as CO 2 sorbents. While branched poly(ethylenimine) (PEI) is the standard benchmark amine material, it suffers from limited oxidative stability. Poly(propylenimine) (PPI), as an alternative, has previously demonstrated improved resistance to degradation under harsh oxidative conditions. Linear and branched PEI are commercially available, though at different molecular weights, while PPI is not commercially available. For this reason, a comparative study of all four polymers (linear PEI, branched PEI, linear PPI, branched PPI) has not been reported for DAC. In this study, we synthesize and compare low-molecular-weight (∼800 g/mol) linear (L) and branched (B) PEI and PPI supported on a model support, SBA-15 silica. These materials are evaluated for CO 2 adsorption under dry, DAC-relevant conditions (400 ppm of CO 2 , 30 °C). LPPI exhibited the highest amine efficiency at all loadings, reaching a maximum of 0.14 mmol CO 2 /mmol N, outperforming BPEI, while LPEI consistently showed the lowest uptake capacity. Temperature-programmed desorption reveals that the structure of the amine polymer impacts the CO 2 binding strength, with branched polymers displaying higher desorption energies of 102−111 kJ/mol. In situ infrared spectroscopy experiments show that all sorbents preferentially capture CO 2 as ammonium carbamate. Isobaric CO 2 uptake studies further underscore the influence of polymer mobility and support pore crowding on performance, while demonstrating the sorbents’ performance at elevated temperatures and CO 2 concentrations. All materials demonstrated good stability over 25 adsorption−desorption cycles using thermal regeneration in an inert gas purge, with only BPPI displaying a 10−11% decrease in capacity/amine efficiency during cycling, possibly due to the loss of low molecular weight, oligomeric amines. This is the first side-by-side comparison of the CO 2 sorption properties of linear and branched PEI and PPI with similar molecular weights. These findings highlight the significant role of polymer architecture in CO 2 capture efficiency and inform future designs of durable, high-performance DAC sorbents.

adsorbents↗

Evaluation of a collisional radiative model for electron temperature determination in hydrogen plasma

A collisional-radiative (CR) model that extracts the electron temperature, T e , of hydrogen plasmas from Balmer-line-ratio measurements is examined for the plasma electron density, n e , and T e ranges of 10 10 –10 15 cm –3 and 5–500 eV, respectively. The CR code, developed and implemented in Python, has a forward component that computes the densities of excited states up to n = 15 as functions of T e , n e , and the molecular-to-atomic neutral ratio r(H 2 /H). The backward component provides ne and r(H 2 /H) as functions of the Balmer ratios to predict the T e . The model assumes Maxwellian electrons. Furthermore, the density profiles of the electrons and of the molecular and atomic hydrogen neutrals are shown to be of great importance, as is the accuracy of the line-ratio measurement method.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Adaptation to the dietary sugar D-tagatose via genome instability in polyploid Candida albicans cells

The opportunistic fungal pathogen Candida albicans undergoes an unusual parasexual cycle wherein diploid cells mate to form tetraploid cells that can generate genetically diverse progeny via a nonmeiotic program of chromosome loss. The genetic diversity afforded by parasex impacts clinically relevant features including drug resistance and virulence, and yet the factors influencing genome instability in C. albicans are not well defined. To understand how environmental cues impact genome instability, we monitored ploidy change following tetraploid cell growth in a panel of different carbon sources. We found that growth in one carbon source, D-tagatose, led to high levels of genomic instability and chromosome loss in tetraploid cells. This sugar is a stereoisomer of L-sorbose which was previously shown to promote karyotypic changes in C. albicans. However, while expression of the SOU1 gene enabled utilization of L-sorbose, overexpression of this gene did not promote growth in D-tagatose, indicating differences in assimilation of the two sugars. In addition, genome sequencing of multiple progenies recovered from D-tagatose cultures revealed increased relative copy numbers of chromosome 4, suggestive of chromosome-level regulation of D-tagatose metabolism. Together, these studies identify a novel environmental cue that induces genome instability in C. albicans, and further implicate chromosomal changes in supporting metabolic adaptation in this species.

59 BASIC BIOLOGICAL SCIENCES↗

Fiberboard Properties and Degradation Rates for Storage of 9975 Shipping Package in KAC (2020 Status Report)

Savannah River Site (SRS) stores plutonium materials within model 9975 shipping packages in the K-Area Complex (KAC). The 9975 shipping package consists of a 35 gallon stainless steel drum, Celotex fiberboard insulation, lead shield, and primary and secondary containment vessels. The 9975 shipping package design, performance, and analysis for safe transport of radioactive material are described in the Safety Analysis Report for Packaging (SARP). Celotex fiberboard provides three safety functions: thermal insulation to limit internal temperature during a fire, criticality control, and resistance to package crushing. The fiberboard material must retain its dimensions and density within certain ranges to provide the required impact resistance, criticality control, and fire resistance. The SRS Surveillance Program monitors material performance to establish a basis for service life and ensures the continued integrity of 9975 packages. Fiberboard samples, taken from multiple fiberboard assemblies fabricated from cane and softwood fiberboard, have been conditioning in elevated temperature environments since 2005. The samples are periodically examined to monitor thermal, mechanical, and physical properties, and assess degradation trends. Fiberboard properties of interest that are evaluated to demonstrate acceptable long-term performance include dimensional stability, density, compressive strength, thermal conductivity, and specific heat capacity. Duplicate samples from multiple package sources have been tested to identify the range of variability in fiberboard properties and degradation rates. Baseline and long-term testing of fiberboard material properties have been reported previously; reference 6 summarized experimental results of cane and softwood fiberboard through May 2019 and presented degradation models for the measured properties. This report presents the cumulative data collected through June 2020 and the corresponding updated aging models.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

DOE National Laboratories: Vital to U.S. science and technology [Slides]

DOE has extremely challenging and diverse missions, each born out of national need. The national labs serve as the science and technology engine for DOE missions. Each Lab stewards distinctive capabilities which DOE leverages through networks of labs address core missions, dynamic programs and rapid response needs. National lab networks have transformative impact.

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗

Accessible Training and Shared Capitalization Platforms for Low-Income Solar Finance

From March 2020 through November 2023, the University of New Hampshire Carsey Center for Impact Finance and its partners worked to create accessible training programs and shared capitalization platforms to enable community finance institutions – such as credit unions, community banks, and Community Development Financial Institutions (“CDFI”s) – to expand their engagement in solar finance in low-income communities.

14 SOLAR ENERGY↗

PCAST: Report to the President Review of the Networking and Information Technology Research and Development Program

The President’s Council of Advisors on Science and Technology (PCAST) is the sole body of advisors from outside the federal government charged with making science, technology, and innovation policy recommendations to the President and the White House. Established by Executive Order, it is an independent Federal Advisory Committee comprised of distinguished individuals from industry, academia, and non-profit organizations with a range of perspectives and expertise. On December 5, 2024, PCAST sent a report to the President with recommendations to strengthen and improve the NITRD program and its activities to provide an even greater positive impact for the Nation.

97 MATHEMATICS AND COMPUTING↗

Time Data Sequential Processor /TDSP/

Time Data Sequential Processor /TDSP/ computer program provides preflight predictions for lunar trajectories from injection to impact, and for planetary escape trajectories for up to 100 hours from launch. One of the major options TDSP performs is the determination of tracking station view periods.

Joseph, A. E.↗

Technology utilization in a non-urban region: Further impact and technique of the Technology Use Studies Center, 2

The clientele served by the Technology Use Studies Center (TUSC) is updated. Manufacturing leads the list of client firms. The standard industrial classification (SIC) range of these firms is broad. Substantial numbers of college and university faculties are using TUSC services. Field operations inherent in the functions of dissemination and assistance are reviewed. Increasing emphasis among clientele is on environmental concerns and management. A record is provided of the institutions contacted and the extent of TUSC involvement with them, as well as TUSC's cooperation with agencies and organizations. The impact of TUSC and the NASA-sponsored Technology Utilization Program on other public agencies is discussed.

Gold, H. C.↗

Multilayer high performance insulation materials

A number of tests are required to evaluate both multilayer high performance insulation samples and the materials that comprise them. Some of the techniques and tests being employed for these evaluations and some of the results obtained from thermal conductivity tests, outgassing studies, effect of pressure on layer density tests, hypervelocity impact tests, and a multilayer high performance insulation ambient storage program at the Kennedy Space Center are presented.

Stuckey, J. M.↗

Measuring projectile speed

Apparatus uses optoelectric detector to measure station-to-station time-of-flight of small spherical aluminum projectile down steel barrel. Instrument has been used to study impact resistance of composite materials used in aircraft structural research program.

Jordan, J. E.↗

A bibliography of space books and articles from non-aerospace journals, 1957-1977

This bibliography cites over 3,600 articles and books from the nonspecialized secondary literature relating to NASA and to aerospace-related themes. Entries are arranged alphabetically by author in the following categories: (1) space activity; (2) spaceflight: earliest times to the creation of NASA; (3) organization, administration, and management of NASA; (4) aeronautics; (5) boosters and rockets; (6) technology of spaceflight; (7) manned spaceflight; (8) space science; (9) applications; (10) space law; (11) international implications; (12) foreign space programs; (13) domestic public policy and opinion; and (14) economics: impact of NASA, analyses of aerospace industry, and patent policy.

Looney, J. J.↗

Aerospace mechanical reliability practice

The impact of mechanical-reliability practice on the Saturn/Apollo launch program is considered with reference to the interrelationship of analysts and designers with management. Rocket engine development, ground testing, and launch facilities in the Saturn/Apollo program are discussed, and the Saturn reliability approach is examined in regard to management style, decision making, human error control, and reliability analyses. It is noted that the use of conservative design philosophy contributed to achieved reliability.

Fedor, O. H.↗

Velocity visualization in gaseous flows

Techniques yielding simultaneous, multiple-point measurements of velocity in reacting or nonreacting flow fields have the potential to significantly impact basic and applied studies of fluid mechanics. This research program is aimed at investigating several candidate schemes which could provide such measurement capability. The concepts under study have in common the use of a laser source (to illuminate a column, a grid, a plane or a volume in the flow) and the collection of light at right angles (from Mie scattering, fluorescence, phosphorescence or chemiluminescence) using a multi-element solid-state camera (100 x 100 array of photodiodes). The work will include an overview and a status report of work in progress with particular emphasis on the method of Doppler-modulated absorption.

Hanson, R. K.↗

Effects of vibrational enhancement of N2 on the cooling rate of ionospheric thermal electrons

It is shown that the cooling rate of ionospheric thermal electrons by molecular nitrogen may be reduced by more than a factor of 3 as a result of the enhanced vibrational excitation of N2 from a number of chemical sources. Furthermore, under conditions of enhanced F region electron densities (greater than 10 to the 6 per cubic centimeter), N2 may act as a small net source rather than as a sink of electron thermal energy. The object of the study is to use results of the Atmospheric Explorer program and improved laboratory reaction rate measurements to evaluate the impact of N2 vibrational on the transfer of energy between N2 and thermal electrons.

Richards, P. G.↗

Experiences performing conceptual design optimization of transport aircraft

Optimum Preliminary Design of Transports (OPDOT) is a computer program developed at NASA Langley Research Center for evaluating the impact of new technologies upon transport aircraft. For example, it provides the capability to look at configurations which have been resized to take advantage of active controls and provide and indication of economic sensitivity to its use. Although this tool returns a conceptual design configuration as its output, it does not have the accuracy, in absolute terms, to yield satisfactory point designs for immediate use by aircraft manufacturers. However, the relative accuracy of comparing OPDOT-generated configurations while varying technological assumptions has been demonstrated to be highly reliable. Hence, OPDOT is a useful tool for ascertaining the synergistic benefits of active controls, composite structures, improved engine efficiencies and other advanced technological developments. The approach used by OPDOT is a direct numerical optimization of an economic performance index. A set of independent design variables is iterated, given a set of design constants and data. The design variables include wing geometry, tail geometry, fuselage size, and engine size. This iteration continues until the optimum performance index is found which satisfies all the constraint functions. The analyst interacts with OPDOT by varying the input parameters to either the constraint functions or the design constants. Note that the optimization of aircraft geometry parameters is equivalent to finding the ideal aircraft size, but with more degrees of freedom than classical design procedures will allow.

Arbuckle, P. D.↗

Liquid Rocket Booster (LRB) for the Space Transportation System (STS) systems study. Volume 2: Addendum 1

The potential of a common Liquid Rocket Booster (LRB) design was evaluated for use with both the Space Transportation System (STS) and the Advanced Launch System (ALS). A goal is to have a common Liquid Oxygen/Liquid Hydrogen (LO2/LH2) engine developed for both the ALS booster and the core stage. The LO2/LH2 option for the STS was evaluated to identify potential LRB program cost reductions. The objective was to identify the structural impacts to the external tank (ET), and to determine if any significant ET re-development costs are required as a result of the larger LO2/LH2 LRB. The potential ET impacts evaluated are presented.

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