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At least 1,189 records · Page 66

Water Quality Contamination Sources and Controls for the Exploration Extra-vehicular Mobility Unit (xEMU)

NASA has been developing a new spacesuit, called the Exploration Extravehicular Mobility Unit (xEMU) for over a decade. This spacesuit is underdevelopment to support missions to the International Space Station (ISS) and also to the Moon. The xEMU uses controlled evaporative cooling through a membrane to reject waste heat from the crewmember, avionics, and environmental in-leak during autonomous operation. Given the unique mass and volume constraints imposed by the spacesuit application and the opportunities presented by the selection of a given membrane, the xEMU does not possess a separate feedwater loop to feed the evaporation process, rather the feedwater for the evaporation process is fed directly from the transport loop which collects heat from the sources within the suit. This has many benefits including mass/volume reductions from a lower component count within the system but does pose some additional potential constraints on water quality within the system in order to provide a working fluid that can be pumped, filtered, and used in contact with the remainder of the system while both avoiding fouling of the membrane as well as other deleterious effects such as creating conditions for corrosion of wetted surfaces within the transport loop. The discussion will seek to address the main sources of contamination and the applied controls. Sources considered will include: self-generated via materials selection and processes applied, influent working fluid, contamination of the influent working fluid via Ground Support Equipment (GSE) or processing equipment, microbial activity, and environmental influences such as elevated ambient CO2.

Colin Campbell↗

Stress-Activated Positive Holes (O− in a Matrix of O2–) Cause DNA Damage in Surface-Dwelling Organisms: Unveiling Mutation-Induced Secrets of Nature

Peroxy defects consist of pairs of tightly bonded oxygen anions in the –1 valence state such as in O3X/OO\YO3 with X, Y = Si4+, Al3+ etc. They commonly occur in igneous, metamorphic and many sedimentary rocks. When such rocks are stressed by tectonic forces, peroxy defects break up, releasing highly mobile electronic charge carriers: defect electrons in the O2– sublattice, i.e. unbound O–, known as “positive holes”, h•. The h• can flow out of stressed rock volumes, spreading far and wide, causing electric currents and electrochemical reactions. This study explores how the h• impact the electron flow in the electron transport chain (ETC) of organisms on the surface of rocks such as gabbro and granite. We found that, by forming hydroxyl radicals and superoxide anions, the h• disrupt the in vivo coordination of reduction-oxidation reactions that are essential for the timing of the redox cycle. Our observations show that stress activation of h• delays the sprouting of certain plant seeds and impedes the growth of yeast cultures, Saccharomyces cerevisiae. The h• induce mutations and affect plant development as evidenced by reduced stem length and leaf size. At the same time, the h• serve as a source of abiotic oxidation, capable of forming various organic compounds in situ. Through the generation of radical species that create new carbon-carbon bonds the h• facilitate the abiotic synthesis of hydrocarbons and other organic molecules essential to life, including porphyrins. Our findings highlight the intricate interplay between positive holes, redox timing, and biological processes, revealing their significant role in influencing the growth and development of organisms in tectonically stressed crustal environments. Understanding these effects enhances our broader comprehension of redox biology and the influence of environmental factors on cellular development in natural settings.

astrobiology↗

A Break In the Size-Stellar Mass Relation: Evidence for Quenching and Feedback in Dwarf Galaxies

Mapping stars and gas in nearby galaxies is fundamental for understanding their growth and the impact of their environment. This issue is addressed by comparing the stellar ‘edges’ of galaxies D stellar, defined as the outermost diameter where in situ star formation significantly drops, with the gaseous distribution parameterized by the neutral atomic hydrogen diameter measured at 1M⊙/pc2,DHI. By sampling a broad HI mass range 105M⊙< MHI<1011M⊙, we find several dwarf galaxies withMHI<109M⊙from the field and Fornax Cluster which are distinguished by D stellar>> DHI. For the cluster dwarfs, the average HI surface density near D stellar is∼0.3M⊙/pc2, reflecting the impact of quenching and outside-in gas removal from ram pressure and tidal interactions. In comparison, D stellar/DHI ranges between 0.5–2 in dwarf field galaxies, consistent with the expectations from stellar feedback. Only more massive disk galaxies in the field can thus be characterized by the common assumption that D stellar≲DHI. We discover a break in the D stellar−M⋆relation atm break∼4×108M⊙that potentially differentiates the low mass regime where the influence of stellar feedback and environmental processes more prominently regulates the sizes of nearby galaxies. Our results highlight the importance of combining deep optical and HI imaging for understanding galaxy evolution.

Scaling relations↗

Investigation of Polyurethane and Fire-Retardant Foams as a Radiological Contamination Fixatives - 20202

Fixation of radiological contamination in decommissioning and deactivation can reduce worker risk, and mitigate potentially hazardous conditions; however, nearly every marketed contamination fixative has been found to be flammable, a significant concern in radiological facilities. Coupled with this, industry fixatives are normally used as a thin coating which can present problems when attempting to stabilize irregular void spaces or areas that are difficult to access and ensure full coverage. To this end, Savannah River National Laboratory (SRNL), in conjunction with Florida International University (FIU), have begun investigating the applicability of polyurethane based foaming materials, which will expand to fill a given asymmetric volume and provide fire retardancy to ensure no release of contamination in the event of a facility fire. Commercial foams undergo exothermic reactions resulting in gaseous release that subsequently causes the curing foam material to expand. Heat generation during curing can potentially compromise rubber parts of an enclosure, a significant concern in nuclear facilities. To mitigate large body heat generation, SRNL has also examined multiple layering of the material to ensure compatibility of the curing material with a previously cured body of the same material. Environmental studies were also completed in order to determine the influence on polyurethane based foams curing process. These studies showed that nearly half of the materials tested delaminated from a cured body of the same material, a property not discussed in commercially available documentation on the products. Of note was the compatibility of the foaming material with the substrate, depending on the type material that the foam was cured in/on, significant delamination could occur. Mechanical testing via tensile pull tester, dynamic mechanical analysis (DMA), and thermogravimetric analysis (TGA) was also performed. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Air Classification of Forestry Residues for Fast Pyrolysis

Understanding critical biomass attributes through efficient fractionation is crucial for advancing sustainable pyrolysis for renewable energy and chemical production. This study investigates the intricate relationship between biomass preprocessing and pyrolysis product yields, employing the air classification technique for the treatment of loblolly pine residues with varying moisture content. A comprehensive exploration of the physicochemical properties of air-classified loblolly pine informs a sophisticated pyrolysis simulation model. Given the complex and multifaceted nature of biomass pyrolysis, operating across diverse temporal and spatial scales, a pyrolysis kinetics-based CFD–DEM simulation method is employed to predict product yields. Results showed that the elevated moisture content amplifies particle adhesiveness, necessitating augmented air velocities for effective separation, thereby influencing the efficiency of the separation process. While carbon and hydrogen contents exhibit relative stability across diverse moisture contents and blower frequencies, the oxygen content undergoes noticeable changes. For example, the oxygen contents were measured as 29.2 and 38.6 wt% in the light fraction of 30% moisture content sample at blower frequencies of 10 and 20 Hz, respectively. An intriguing finding emerges from pyrolysis simulation, indicating that a lower blower frequency in air classification moderately enhances bio-oil yield and significantly improves its quality, particularly in terms of water content. For instance, the water content in the bio-oil was about 1.5% and 10% in the heavy and light fractions, respectively from 10% moisture sample under 15 Hz blower frequency.

09 - BIOMASS FUELS↗

Biogeochemical Cycles of Carbon and Sulfur

The elements carbon (C) and sulfur (S) interact with each other across a network of elemental reservoirs that are interconnected by an array of physical, chemical and biological processes. These networks are termed the biogeochemical C and S cycles. The compounds of C are highly important, not only as organic matter, but also as atmospheric greenhouse gases, pH buffers in seawater, oxidation-reduction buffers virtually everywhere, and key magmatic constituents affecting plutonism and volcanism. The element S assumes important roles as an oxidation-reduction partner with C and Fe in biological systems, as a key constituent in magmas and volcanic gases, and as a major influence upon pH in certain environments. This presentation describes the modern biogeochemical C and S cycles. Measurements are described whereby stable isotopes can help to infer the nature and quantitative significance of biological and geological processes involved in the C and S cycles. This lecture also summarizes the geological and climatologic aspects of the ancient C and S cycles, as well as the planetary and extraterrestrial processes that influenced their evolution over millions to billions of years.

DesMarais, David J.↗

Role of the Terrestrial Biosphere in Atmospheric Chemistry and Climate

The terrestrial biosphere–atmosphere interface provides a key chemical, biological, and physical lower boundary for the atmosphere. The presence of vegetation itself modifies the physical boundary, or the biogeophysical aspects of the system, by controlling important climate drivers such as soil moisture, light environment, and temperature. The leaf surface area of the terrestrial biosphere provides additional surface area for emissions, and it can be up to 55% of the total Earth’s surface area during the boreal summer. Vegetation also influences the biogeochemical aspects of the system by emitting a broad suite of reactive trace gases such as biogenic volatile organic compound (BVOC) emissions and climate-relevant primary biological aerosol particles (PBAP). Many of these emissions are a function of meteorological and climatological conditions at the surface, including temperature, light environment, soil moisture, and winds. Once emitted, they can be processed in the troposphere through a suite of chemical reactions. BVOC can contribute to the formation of ozone and secondary organic aerosols (SOA), and PBAP can rupture to form smaller particles with climatic relevance. These emissions and subsequent aerosol products can influence atmospheric processes that affect the surface climate, such as the attenuation of radiation, the formation of greenhouse gases such as ozone that can feedback to surface air temperature, and the alteration of clouds and subsequent precipitation. These atmospheric changes can then feedback to the land surface and emissions themselves, creating positive or negative feedback loops that can dampen or amplify the emission response. For the dominant BVOC isoprene, the feedback response to temperature can be positive or negative depending on ambient temperatures that drive isoprene emissions. The feedback response to soil moisture and precipitation can be positive, negative, or uncoupled depending on the moisture content of the soil and the total atmospheric aerosol loading. For light, the isoprene response can be positive or negative depending on the role of diffuse light. Overall, these feedbacks highlight the dynamical response of the biosphere to changing atmospheric conditions across a range of time scales, from minutes for trace gases and aerosols, to months for phenological changes, to years for land cover and land use change. Here, the dynamic aspect of this system requires us to understand, simulate, and predict the complex feedbacks between the biosphere and atmosphere and understand their role in the simulation and understanding of climate and global change. From the observational perspective, these feedbacks are challenging to identify in observations, and predictive modeling tools provide a crucial link for understanding how these feedbacks will change under warming climate scenarios.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Advancing the Understanding of Snow Accumulation, Melting, and Associated Thermal Insulation Using Spatially Dense Snow Depth and Temperature Time Series

Snow thermal insulation is a critical factor influencing ground thermal dynamics and associated biogeochemical processes. We analyzed the spatiotemporal variability of snow accumulation, melting, and thermal insulation dynamics using spatially dense, collocated snow depth and ground interface temperature time series over two consecutive years. We demonstrated that considering late‐winter snow depth alone was insufficient to fully capture the complexity in snow and insulation dynamics. The influence of vegetation and topography on snow depth distribution varied over the season, across sites and years. We found that deep snow with a long melting period had a substantial impact on thawing n‐factors. To better predict snow insulation effects, we proposed a new weighted snow depth metric that integrates mean daily snow depth and air temperature throughout the cold season. Our results provide insights for developing space‐time remote sensing products and evaluating the representation of snow and permafrost processes in Earth system models.

54 ENVIRONMENTAL SCIENCES↗

Carbide Particle Redistribution in U-10Mo Alloy during Hot and Cold Rolling Processes: Synthetic Microstructure-Based Finite-Element Approach

The influence of initial carbide particle distribution features on particle fracture and the evolution of stringer distribution within an alloy of uranium with 10 weight percent molybdenum during cold rolling was investigated in this study. This work will provide guidance to casting optimization work and identify actionable process changes to eliminate the surface features directly attributed to carbides. In a previous study, various synthetic microstructure-based finite-element (FE) models were generated with consideration of different parameters (i.e., particle shape, particle volume fraction, and particle distribution), and used to examine the effects of hot rolling on the microstructure evolution. In this study, microstructures after ~80% hot rolling were used as the initial microstructures for the subsequent cold rolling simulation. Plane-strain compression loading was employed in the FE models to simulate cold rolling with reductions from ~80% to ~94%. Stringer analyses with the consideration of particle fracture were then performed with the simulated cold rolling results. The results of void evolution analyses show that microstructures with elliptical particles incorporate a much larger (almost double) void volume fraction than those with circular particles, indicating that the elliptical particles are fractured more easily than the circular ones. The results from the fracture mode analyses show that, under the adopted simple compression loading assumption, almost all the particles (i.e., >99%) were fractured by tensile separation. The results of stringer analyses show that, during cold rolling, the stringer volume fractions increase substantially due to the particle fracture, especially for the microstructures with the elliptical particles, and that the stringer volume fractions from stringers comprising many particles tend to increase faster. The maximum stringer lengths for the microstructures with circular particles tend to remain constant or decrease during cold rolling, whereas those for elliptical particles tend to slightly increase after a slight decrease. The number of particles at the surface increases very rapidly due to particle fracture during cold rolling.

36 MATERIALS SCIENCE↗

De-Risking High-Recovery Brackish Water Desalination via Flow Reversal and Feed Flushing Using Techno-Economic Assessment

Novel desalination technologies have demonstrated enhanced performance and improved financial metrics over existing processes adopted by industry. Establishing quantitative performance targets is essential for achieving financial benefits over the current state of the art. Herein, we demonstrate how WaterTAP, a techno-economic assessment (TEA) tool, can be used to identify minimum performance metrics necessary to achieve financial benefit over using existing processes. This study evaluates the feasibility of increasing water recovery at the Chino Desalter I above 90 % through the addition of a third variable configuration reverse osmosis (VCRO) stage. Sensitivity analyses revealed flow reversal frequency, feed flushing volume (used as a cleaning step), and membrane lifespan are key factors influencing the financial viability of the VCRO process. The TEA analysis demonstrated that the system must achieve a recovery of 84 % and a 1-year membrane lifespan to have a breakeven LCOW, while achieving 90 % recovery can ultimately reduce the LCOW by 16 %. Notably, a trade-off between decreasing frictional losses and increased osmotic pressure across the recovery range, resulted in a stable specific energy consumption across the recovery range, enabling meaningful LCOW reductions without an energy penalty, a key finding that contrasts with conventional RO. This work demonstrates how TEA can guide system design by identifying key performance targets and exploring trade-offs, enabling data-driven decisions to de-risk innovative processes. These findings underscore the importance of leveraging TEA to evaluate scaling mitigation strategies and optimize inland desalination systems for sustainable and cost-effective operation.

14 SOLAR ENERGY↗

Shuttle Entry Imaging Using Infrared Thermography

During the Columbia Accident Investigation, imaging teams supporting debris shedding analysis were hampered by poor entry image quality and the general lack of information on optical signatures associated with a nominal Shuttle entry. After the accident, recommendations were made to NASA management to develop and maintain a state-of-the-art imagery database for Shuttle engineering performance assessments and to improve entry imaging capability to support anomaly and contingency analysis during a mission. As a result, the Space Shuttle Program sponsored an observation campaign to qualitatively characterize a nominal Shuttle entry over the widest possible Mach number range. The initial objectives focused on an assessment of capability to identify/resolve debris liberated from the Shuttle during entry, characterization of potential anomalous events associated with RCS jet firings and unusual phenomenon associated with the plasma trail. The aeroheating technical community viewed the Space Shuttle Program sponsored activity as an opportunity to influence the observation objectives and incrementally demonstrate key elements of a quantitative spatially resolved temperature measurement capability over a series of flights. One long-term desire of the Shuttle engineering community is to calibrate boundary layer transition prediction methodologies that are presently part of the Shuttle damage assessment process using flight data provided by a controlled Shuttle flight experiment. Quantitative global imaging may offer a complementary method of data collection to more traditional methods such as surface thermocouples. This paper reviews the process used by the engineering community to influence data collection methods and analysis of global infrared images of the Shuttle obtained during hypersonic entry. Emphasis is placed upon airborne imaging assets sponsored by the Shuttle program during Return to Flight. Visual and IR entry imagery were obtained with available airborne imaging platforms used within DoD along with agency assets developed and optimized for use during Shuttle ascent to demonstrate capability (i.e., tracking, acquisition of multispectral data, spatial resolution) and identify system limitations (i.e., radiance modeling, saturation) using state-of-the-art imaging instrumentation and communication systems. Global infrared intensity data have been transformed to temperature by comparison to Shuttle flight thermocouple data. Reasonable agreement is found between the flight thermography images and numerical prediction. A discussion of lessons learned and potential application to a potential Shuttle boundary layer transition flight test is presented.

Horvath, Thomas↗

Zeolite crystal growth in space - What has been learned

Three zeolite crystal growth experiments developed at WPI have been performed in space in last twelve months. One experiment, GAS-1, illustrated that to grow large, crystallographically uniform crystals in space, the precursor solutions should be mixed in microgravity. Another experiment evaluated the optimum mixing protocol for solutions that chemically interact ('gel') on contact. These results were utilized in setting the protocol for mixing nineteen zeolite solutions that were then processed and yielded zeolites A, X and mordenite. All solutions in which the nucleation event was influenced produced larger, more 'uniform' crystals than did identical solutions processed on earth.

Sacco, A., Jr.↗

Facet-dependent electron transfer induces distinct arsenic reallocations on hematite

The interfacial electron transfer (ET) between electron shuttling compounds and iron (Fe) oxyhydroxides plays a crucial role in the reductive dissolution of Fe minerals and the fate of surface-bound arsenic (As). However, the impact of exposed facets of highly crystalline hematite on reductive dissolution and As immobilization is poorly understood. In this study, we systematically investigated the interfacial processes of the electron shuttling compound cysteine (Cys) on various facets of hematite and the reallocations of surface-bound As(III) or As(V) on the respective surfaces. Our results demonstrate that the ET process between Cys and hematite generates Fe(II) and leads to reductive dissolution, with more Fe(II) generated on {001} facets of exposed hematite nanoplates (HNPs). Reductive dissolution of hematite leads to significantly enhanced As(V) reallocations on hematite. Nevertheless, upon the addition of Cys, a raipd release of As(III) can be halted by its prompt re-adsorption, leaving the extent of As(III) immobilization on hematite unchanged throughout the course of reductive dissolution. This is due to that Fe(II) can form new precipitates with As(V), a process that is facet-dependent and influenced by water chemistry. Electrochemical analysis reveals that HNPs exhibit higher conductivity and ET ability, which is beneficial for reductive dissolution and As reallocations on hematite. In conclusion, these findings highlight the facet-dependent reallocations of As(III) and As(V) facilitated by electron shuttling compounds and have implications for the biogeochemical processes of As in soil and subsurface environments.

54 ENVIRONMENTAL SCIENCES↗

Free convection in enclosures exposed to compressive heating

An experimental study of heat transfer in a vertical annulus and a three-dimensional gap used to establish the influence of compressive heating on the convective process in enclosures is presented. Test runs were made using helium gas with compressive rates of 6, 15, and 30 psi/min. Temperature and pressure histories were reduced to film coefficients based on nodal modeling of the test geometries. The data are correlated in terms of free convection parameters. The heat transfer correlations show virtually no influence of compression rate and only a slight dependence on geometry. The correlations will be applied to the design of a vented Galileo mission descent module parachuting into the Jupiter atmosphere.

Bobco, R. P.↗

A stochastic-dynamical approach to the study of the natural variability of the climate

A method, suggested by Leith (1975), which employed stochastic-dynamic forecasts obtained from a general circulation model in such a way as to satisfy the definition of climatic noise, was used to validate assumptions accounting for the effects of external influences in estimating the climatic noise. Two assumptions were investigated: (1) that the weather fluctuations can be represented as a Markov process, and (2) that changing external conditions do not influence the atmosphere's statistical properties on short time scales. The general circulation model's simulation of the daily weather fluctuations was generated by performing integrations with prescribed climatological boundary conditions for random initial atmospheric states, with resulting dynamical forecasts providing an ensemble of simulated data for the autoregressive modeling of weather fluctuations. To estimate the climatic noise from the observational data (consisting of hourly values of sea level pressure and surface temperature at 54 U.S. stations for the month of January for the years 1949-1975) use of the short time-scale assumption is made. The simulated and observed data were found not to be consistent with either white noise or a Markov process of weather fluctuations. Good agreement was found between the results of the hypothetical testing of the simulated and the observed surface temperatures; and only partial support was found for the short time-scale assumption, i.e., for sea level pressure.

Straus, D. M.↗

Low cost processes for fabricating silicon solar cells

Solar cell fabrication processes, in particular junction formation and metallization, are evaluated in terms of cell efficiencies, process yields, module packing factors, and energy cost effectiveness. It is shown that for junction formation, the diffusion processes provide a relatively low-cost approach. The costs per unit cell area can be further reduced by increased wafer area and mechanized wafer handling. The costs for a large number of metallization processes, excluding the costs of the metal, are roughly comparable. However, their varying influence on cell performance leads to a significant spread in the allowable process costs.

Goldman, H.↗

Mesoscale Convective Systems During SCSMEX: Simulations with a Regional Climate Model and a Cloud-Resolving Model

The South China Sea Monsoon Experiment (SCSMEX) was conducted in May-June 1998. One of its major objectives is to better understand the key physical processes for the onset and evolution of the summer monsoon over Southeast Asia and southern China (Lau et al. 2000). Multiple observation platforms (e.g., soundings, Doppler radar, ships, wind seafarers, radiometers, etc.) during SCSMEX provided a first attempt at investigating the detailed characteristics of convection and circulation changes, associated with monsoons over the South China Sea region. SCSMEX also provided precipitation derived from atmospheric budgets (Johnson and Ciesielski 2002) and comparison to those obtained from the Tropical Rainfall Measuring Mission (TRMM). In this paper, a regional climate model and a cloud-resolving model are used to perform multi-day integrations to understand the precipitation processes associated with the summer monsoon over Southeast Asia and southern China. The regional climate model is used to understand the soil - precipitation interaction and feedback associated with a flood event that occurred in and around China's Atlantic River during SCSMEX. Sensitivity tests on various land surface models, cumulus parameterization schemes (CASE), sea surface temperature (SST) variations and midlatitude influences are also performed to understand the processes associated with the onset of the monsoon over the S. China Sea during SCSMEX. Cloud-resolving models (CRMs) use more sophisticated and physically realistic parameterizations of cloud microphysical processes with very fine spatial and temporal resolution. One of the major characteristics of CRMs is an explicit interaction between clouds, radiation and the land/ocean surface. It is for this reason that GEWEX (Global Energy and Water Cycle Experiment) has formed the GCSS (GEWEX Cloud System Study) expressly for the purpose of improving the representation of the moist processes in large-scale models using CRMs. The Goddard Cumulus Ensemble (GCE) model is a CRM and is used to simulate convective systems associated with the onset of the South China Sea monsoon in 1998. The BRUCE model includes the same land surface model, cloud physics, and radiation scheme used in the regional climate model. A comparison between the results from the GCE model and regional climate model is performed.

Tao, W. K.↗

Deep-learning based artificial intelligence tool for melt pools and defect segmentation

Accelerating fabrication of additively manufactured components with precise microstructures is important for quality and qualification of built parts, as well as for a fundamental understanding of process improvement. Accomplishing this requires fast and robust characterization of melt pool geometries and structural defects in images. This paper proposes a pragmatic approach based on implementation of deep learning models and self-consistent workflow that enable systematic segmentation of defects and melt pools in optical images. Deep learning is based on an image-to-image translation–conditional generative adversarial neural network architecture. An artificial intelligence (AI) tool based on this deep learning model enables fast and incrementally more accurate predictions of the prevalent geometric features, including melt pool boundaries and printing-induced structural defects. We present statistical analysis of geometric features that is enabled by the AI tool, showing strong spatial correlation of defects and the melt pool boundaries. The correlations of widths and heights of melt pools with dataset processing parameters show the highest sensitivity to thermal influences resulting from laser passes in adjacent and subsequent layer passes. The presented models and tools are demonstrated on the aluminum alloy and datasets produced with different sets of processing parameters. However, they have universal quality and could easily be adapted to different material compositions. The method can be easily generalized to microstructural characterizations other than optical microscopy.

additive manufacturing↗