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At least 1,189 records · Page 66

Microphysics of Pyrocumulonimbus Clouds

The intense heat from forest fires can generate explosive deep convective cloud systems that inject pollutants to high altitudes. Both satellite and high-altitude aircraft measurements have documented cases in which these pyrocumulonimbus clouds inject large amounts of smoke well into the stratosphere (Fromm and Servranckx 2003; Jost et al. 2004). This smoke can remain in the stratosphere, be transported large distances, and affect lower stratospheric chemistry. In addition recent in situ measurements in pyrocumulus updrafts have shown that the high concentrations of smoke particles have significant impacts on cloud microphysical properties. Very high droplet number densities result in delayed precipitation and may enhance lightning (Andrew et al. 2004). Presumably, the smoke particles will also lead to changes in the properties of anvil cirrus produces by the deep convection, with resulting influences on cloud radiative forcing. In situ sampling near the tops of mature pyrocumulonimbus is difficult due to the high altitude and violence of the storms. In this study, we use large eddy simulations (LES) with size-resolved microphysics to elucidate physical processes in pyrocumulonimbus clouds.

Jensen, Eric↗

Shielded Heavy-Ion Environment Linear Detector (SHIELD): an experiment for the Radiation and Technology Demonstration (RTD) Mission

Radiological assessment of the many cosmic ion species of widely distributed energies requires the use of theoretical transport models to accurately describe diverse physical processes related to nuclear reactions in spacecraft structures, planetary atmospheres and surfaces, and tissues. Heavy-ion transport models that were designed to characterize shielded radiation fields have been validated through comparison with data from thick-target irradiation experiments at particle accelerators. With the RTD Mission comes a unique opportunity to validate existing radiation transport models and guide the development of tools for shield design. For the first time, transport properties will be measured in free-space to characterize the shielding effectiveness of materials that are likely to be aboard interplanetary space missions. Target materials composed of aluminum, advanced composite spacecraft structure and other shielding materials, helium (a propellant) and tissue equivalent matrices will be evaluated. Large solid state detectors will provide kinetic energy and charge identification for incident heavy-ions and for secondary ions created in the target material. Transport calculations using the HZETRN model suggest that 8 g cm -2 thick targets would be adequate to evaluate the shielding effectiveness during solar minimum activity conditions for a period of 30 days or more.

NASA Center LaRC↗

Laboratory comparisons of organic materials to interstellar dust and the Murchison meteorite

Spectra of objects which lie along several lines of sight through the diffuse interstellar medium (DISM) reveal an absorption feature near 3.4 micrometers, which has been attributed to saturated aliphatic hydrocarbons on interstellar grains. The similarity of the absorption bands near 3.4 micrometers (2950 cm-1) along different lines of sight indicates that the carrier of this band lies in the diffuse dust. Several materials have been proposed as "fits" to the 3.4 micrometers feature over the years. A comparison of these identifications is presented. These comparisons illustrate the need for high resolution, high signal-to-noise observational data as a means of distinguishing between laboratory organics as matches to the interstellar material. Although any material containing hydrocarbons will produce features in the 3.4 micrometers region, the proposed "matches" to the DISM do differ in detail. These differences may help in the analyses of the chemical composition and physical processes which led to the production of the DISM organics, although ISO Observations through the 5-8 micrometers spectral region are essential for a definitive identification. A remarkable similarity between the spectrum of the diffuse dust and an organic extract from the Murchison meteorite suggests that some of the interstellar organic material may be preserved in primitive solar system bodies. The 3.4 micrometers absorption feature (in the rest frame) has recently been detected in external galaxies, indicating the widespread availability of organic material for incorporation into planetary systems.

NASA Center ARC↗

The photophysics of monomeric bacteriochlorophylls c and d and their derivatives: properties of the triplet state and singlet oxygen photogeneration and quenching

Measurements of pigment triplet-triplet absorption, pigment phosphorescence and photosensitized singlet oxygen luminescence were carried out on solutions containing monomeric bacteriochlorophylls (Bchl) c and d, isolated from green photosynthetic bacteria, and their magnesium-free and farnesyl-free analogs. The energies of the pigment triplet states fell in the range 1.29-1.34 eV. The triplet lifetimes in aerobic solutions were 200-250 ns; they increased to 280 +/- 70 microseconds after nitrogen purging in liquid solutions and to 0.7-2.1 ms in a solid matrix at ambient or liquid nitrogen temperatures. Rate constants for quenching of the pigment triplet state by oxygen were (2.0-2.5) x 10(9) M-1 s-1, which is close to 1/9 of the rate constant for diffusion-controlled reactions. This quenching was accompanied by singlet oxygen formation. The quantum yields for the triplet state formation and singlet oxygen production were 55-75% in air-saturated solutions. Singlet oxygen quenching by ground-state pigment molecules was observed. Quenching was the most efficient for magnesium-containing pigments, kq = (0.31-1.2) x 10(9) M-1 s-1. It is caused mainly by a physical process of singlet oxygen (1O2) deactivation. Thus, Bchl c and d and their derivatives, as well as chlorophyll and Bchl a, combine a high efficiency of singlet oxygen production with the ability to protect photochemical and photobiological systems against damage by singlet oxygen.

NASA Discipline Number 52-30↗

Diploptene: an indicator of terrigenous organic carbon in Washington coastal sediments

The pentacyclic triterpene 17 beta(H),21 beta(H)-hop-22(29)-ene (diploptene) occurs in sediments throughout the Columbia River drainage basin and off the southern coast of Washington state in concentrations comparable to long-chain plantwax n-alkanes. The same relationship is evident for diploptene and long-chain n-alkanes in soils from the Willamette Valley. Microorganisms indigenous to soils and soil erosion are indicated as the biological source and physical process, respectively, for diploptene in coastal sediments. Similarity between the stable carbon isotopic composition (delta 13CPDB) of diploptene isolated from soil in the Willamette Valley (-31.2 +/- 0.3%) and from sediments deposited throughout the Washington coastal environment (-31.2 +/- 0.5%) supports this argument. Values of delta for diploptene in river sediments are variable and 8-17% lighter, indicating that an additional biological source such as methane-oxidizing bacteria makes a significant contribution to the diploptene record in river sediments. Selective biodegradation resulting from a difference in the physicochemical association within eroded particles can explain the absence of the more-13C-depleted form of diploptene in Washington coastal sediments, but this mechanism remains unproven.

Non-NASA Center↗

Aerothermodynamic Flight Simulation Capabilities for Aerospace Vehicles

Aerothermodynamics, encompassing aerodynamics, aeroheating, and fluid dynamics and physical processes, is the genesis for the design and development of advanced space transportation vehicles and provides crucial information to other disciplines such as structures, materials, propulsion, avionics, and guidance, navigation and control. Sources of aerothermodynamic information are ground-based facilities, Computational Fluid Dynamic (CFD) and engineering computer codes, and flight experiments. Utilization of this aerothermodynamic triad provides the optimum aerothermodynamic design to safely satisfy mission requirements while reducing design conservatism, risk and cost. The iterative aerothermodynamic process for initial screening/assessment of aerospace vehicle concepts, optimization of aerolines to achieve/exceed mission requirements, and benchmark studies for final design and establishment of the flight data book are reviewed. Aerothermodynamic methodology centered on synergism between ground-based testing and CFD predictions is discussed for various flow regimes encountered by a vehicle entering the Earth s atmosphere from low Earth orbit. An overview of the resources/infrastructure required to provide accurate/creditable aerothermodynamic information in a timely manner is presented. Impacts on Langley s aerothermodynamic capabilities due to recent programmatic changes such as Center reorganization, downsizing, outsourcing, industry (as opposed to NASA) led programs, and so forth are discussed. Sample applications of these capabilities to high Agency priority, fast-paced programs such as Reusable Launch Vehicle (RLV)/X-33 Phases I and 11, X-34, Hyper-X and X-38 are presented and lessons learned discussed. Lastly, enhancements in ground-based testing/CFD capabilities necessary to partially/fully satisfy future requirements are addressed.

Miller, Charles G.↗

Elemental Abundance Variations Observed in Solar Energetic Particle Events During Solar Cycle 23

We report on observations of the abundances of elements from Helium to Nickel in over 50 different solar energetic particle events using the Solar Isotope Spectrometer (SIS) on-board the Advanced Composition Explorer (ACE) spacecraft. It had originally been expected that the energy spectra of different elements would show spectral roll-overs at energies related to the Q/M ratio of each element. Due to the partial stripping of Fe and essentially complete stripping of O, it was expected that the Fe/O ratio would be observed to decrease with increasing energy. While many events show this pattern, others have Fe/O which is constant with energy, while for yet others Fe/O actually increases with energy. Events having constant Fe/O could simply have their spectral breaks outside of the observed energy range. However, events which show increasing Fe/O cannot be explained within the framework of spectral breaks. Possible explanations include injection of remnant heavy ions from earlier impulsive events, hybrid Events consisting of a combination of flare-accelerated and shock-accelerated particles from a single solar event, and some new physical process in shock acceleration. We will report on efforts to distinguish these possible explanations.

vonRosenvinge, T. T.↗

MGGPOD: a Monte Carlo Suite for Modeling Instrumental Line and Continuum Backgrounds in Gamma-Ray Astronomy

Intense and complex instrumental backgrounds, against which the much smaller signals from celestial sources have to be discerned, are a notorious problem for low and intermediate energy gamma-ray astronomy (approximately 50 keV - 10 MeV). Therefore a detailed qualitative and quantitative understanding of instrumental line and continuum backgrounds is crucial for most stages of gamma-ray astronomy missions, ranging from the design and development of new instrumentation through performance prediction to data reduction. We have developed MGGPOD, a user-friendly suite of Monte Carlo codes built around the widely used GEANT (Version 3.21) package, to simulate ab initio the physical processes relevant for the production of instrumental backgrounds. These include the build-up and delayed decay of radioactive isotopes as well as the prompt de-excitation of excited nuclei, both of which give rise to a plethora of instrumental gamma-ray background lines in addition t o continuum backgrounds. The MGGPOD package and documentation are publicly available for download. We demonstrate the capabilities of the MGGPOD suite by modeling high resolution gamma-ray spectra recorded by the Transient Gamma-Ray Spectrometer (TGRS) on board Wind during 1995. The TGRS is a Ge spectrometer operating in the 40 keV to 8 MeV range. Due to its fine energy resolution, these spectra reveal the complex instrumental background in formidable detail, particularly the many prompt and delayed gamma-ray lines. We evaluate the successes and failures of the MGGPOD package in reproducing TGRS data, and provide identifications for the numerous instrumental lines.

Weidenspointner, G.↗

Magnetosphere-Ionosphere Coupling in the Auroral Zone

The visual light display at high latitudes referred to as the aurora fascinates casual observers and researchers alike. The natural question is what causes the aurora? We know that energized electrons streaming along the Earth's ambient magnetic field and colliding with atmospheric particles produce aurora. We do not know for certain, however, how these electrons are accelerated to high energies primarily in the field-aligned direction toward the Earth, or what the drivers of this acceleration are. As such, the goal of this Guest Investigator research project was to examine the physical processes that can cause field-aligned acceleration of plasma particles in the auroral region.

Schriver, David↗

X-ray Probes of Magnetospheric Interactions with Jupiter's Auroral zones, the Galilean Satellites, and the Io Plasma Torus

Remote observations with the Chandra X-ray Observatory and the XMM-Newton Observatory have shown that the Jovian system is a source of x-rays with a rich and complicated structure. The planet's polar auroral zones and its disk are powerful sources of x-ray emission. Chandra observations revealed x-ray emission from the Io Plasma Torus and from the Galilean moons Io, Europa, and possibly Ganymede. The emission from these moons is certainly due to bombardment of their surfaces of highly energetic protons, oxygen and sulfur ions from the region near the Torus exciting atoms in their surfaces and leading to fluorescent x-ray emission lines. Although the x-ray emission from the Galilean moons is faint when observed fiom Earth orbit, an imaging x-ray spectrometer in orbit around these moons, operating at 200 eV and above with 150 eV energy resolution, would provide a detailed mapping (down to 40 m spatial resolution) of the elemental composition in their surfaces. Here we describe the physical processes leading to x-ray emission fiom the surfaces of Jupiter's moons and the instrumental properties, as well as energetic ion flux models or measurements, required to map the elemental composition of their surfaces. We discuss the proposed scenarios leading to possible surface compositions. For Europa, the two most extreme are (1) a patina produced by exogenic processes such as meteoroid bombardment and ion implantation, and (2) upwelling of material fiom the subsurface ocean. We also describe the characteristics of X - m , an imaging x-ray spectrometer under going a feasibility study for the JIM0 mission, with the ultimate goal of providing unprecedented x-ray studies of the elemental composition of the surfaces of Jupiter's icy moons and Io, as well as of Jupiter's auroral x-ray emission.

Elsner, R. F.↗

Condensation Front Migration in a Protoplanetary Nebula

Condensation front dynamics are investigated in the mid-solar nebula region. A quasi-steady model of the evolving nebula is combined with equilibrium vapor pressure curves to determine evolutionary condensation fronts for selected species. These fronts are found to migrate inwards from the far-nebula to final positions during a period of 10(exp 7) years. The physical process governing this movement is a combination of local viscous heating and luminescent heating from the central star. Two luminescent heating models are used and their effects on the ultimate radial position of the condensation front are discussed. At first the fronts move much faster than the nebular accretion velocity, but after a time the accreting gas and dust overtakes the slowing condensation front.

Davis, Sanford S.↗

The Global Distribution of Precipitation and Clouds

The water cycle is the key circuit moving water through the Earth's system. This large system, powered by energy from the sun, is a continuous exchange of moisture between the oceans, the atmosphere, and the land. Precipitation (including rain, snow, sleet, freezing rain, and hail), is the primary mechanism for transporting water from the atmosphere back to the Earth's surface and is the key physical process that links aspects of climate, weather, and the global water cycle. Global precipitation and associate cloud processes are critical for understanding the water cycle balance on a global scale and interactions with the Earth's climate system. However, unlike measurement of less dynamic and more homogenous meteorological fields such as pressure or even temperature, accurate assessment of global precipitation is particularly challenging due to its highly stochastic and rapidly changing nature. It is not uncommon to observe a broad spectrum of precipitation rates and distributions over very localized time scales. Furthermore, precipitating systems generally exhibit nonhomogeneous spatial distributions of rain rates over local to global domains.

Shepherd, J. Marshall↗

Spaceflight exposure effects on transcription, activity, and localization of alcohol dehydrogenase in the roots of Arabidopsis thaliana

Although considerable research and speculation have been directed toward understanding a plant's perception of gravity and the resulting gravitropic responses, little is known about the role of gravity-dependent physical processes in normal physiological function. These studies were conducted to determine whether the roots of plants exposed to spaceflight conditions may be experiencing hypoxia. Arabidopsis thaliana (L.) Heynh. plants were grown in agar medium during 6 or 11 d of spaceflight exposure on shuttle missions STS-54 (CHROMEX-03) and STS-68 (CHROMEX-05), respectively. The analysis included measurement of agar redox potential and root alcohol dehydrogenase (ADH) activity, localization, and expression. ADH activity increased by 89% as a result of spaceflight exposure for both CHROMEX-03 and -05 experiments, and ADH RNase protection assays revealed a 136% increase in ADH mRNA. The increase in ADH activity associated with the spaceflight roots was realized by a 28% decrease in oxygen availability in a ground-based study; however, no reduction in redox potential was observed in measurements of the spaceflight bulk agar. Spaceflight exposure appears to effect a hypoxic response in the roots of agar-grown plants that may be caused by changes in gravity-mediated fluid and/or gas behavior.

STS-68 Shuttle Project↗

Removing Spectral Diagnostics of Galactic and Stellar X-Ray Emission from Charged Exchange Recombination

Our research uses the electron beam ion trap (EBIT) at the Lawrence Livermore National Laboratory to study X-ray emission from the charge exchange (CX) of highly charged ions with neutral gases. The resulting data help to fill a void in existing experimental and theoretical understanding of this atomic physics process, and are needed to explain all or part of the observed X-ray emission from the soft X-ray background, stellar winds, the Galactic Center and Galactic Ridge, supernova ejecta, and photoionized nebulae. Appreciation of the astrophysical relevance of our work continues to grow with the publication of roughly a dozen papers in the past four years describing Chandra and XMM observations of geocoronal and heliospheric CX emission, the temporal variation of such emission and correlation with X-ray emission enhancements observed by ROSAT, the theoretical spatial distribution of that emission, and CX emission around other stars. A similar number of papers were also published during that time describing CX emission from planets and comets. We expect that the launch of ASTRSE2, with its second-generation XRS microcalo- (with 6-eV resolution), will reveal even more clearly the contributions of CX to astrophysical emission. In our EBIT work we collected CX spectra from such ions as H-like and He-like Ne, Ar, and Fe. Our early measurements were made with a high-purity Ge detector, but during the second year we began operation of the first-generation XRS microcalorimeter (a twin of the XRS on ASTRO-E) and greatly improved the resolution of our measurements from roughly 150 eV (FWHM) with the Ge detectors to 10 eV with the XRS. We found that saturation of the XRS counting apparatus, which we described in our proposal as a potential concern, is not a problem for studying CX. During the course of our research, we expanded the number of injection gases permitted by the LLNL safety team, purchased and eventually operated an atomic H source, and clearly demonstrated the feasibility of our longer-range plan. For example, we successfully injected He into EBIT (not a small feat because of the difficulty of maintaining a good vacuum with He and avoiding electrical breakdown) to collect a H-like oxygen CX spectrum. The highest energy CX spectrum recorded with the XRS to date is that of the Ar K-shell emission. These measurements provided the first observation of the relative intensity ratios of resolved He-like singlet and triplet n=2->1 lines. We also carried out measurements of He-like Ne as a function of collision energy (i.e., ion temperature). Significant differences in the resulting x-ray spectra were noted. In all cases, the intensity of high-n H-like Lyman lines is significantly higher than current theoretical CX models predict.

Wargelin, Brad↗

Measurements of HNO3, SO2 High Resolution Aerosol SO4 (sup 2-), and Selected Aerosol Species Aboard the NASA DC-8 Aircraft: During the Transport and Chemical Evolution Over the Pacific Airborne Mission (TRACE-P)

The UNH investigation during TRACE-P provided measurements of selected acidic gases and aerosol species aboard the NASA DC-8 research aircraft. Our investigation focused on measuring HNO3, SO2, and fine (less than 2 microns) aerosol SO4(sup 2-) with two minute time resolution in near-real-time. We also quantified mixing ratios of aerosol ionic species, and aerosol (210)Pb and (7)Be collected onto bulk filters at better than 10 minute resolution. This suite of measurements contributed extensively to achieving the principal objectives of TRACE-P. In the context of the full data set collected by experimental teams on the DC-8, our observations provide a solid basis for assessing decadal changes in the chemical composition and source strength of Asian continental outflow. This region of the Pacific should be impacted profoundly by Asian emissions at this time with significant degradation of air quality over the next few decades. Atmospheric measurements in the western Pacific region will provide a valuable time series to help quantify the impact of Asian anthropogenic activities. Our data also provide important insight into the chemical and physical processes transforming Asian outflow during transport over the Pacific, particularly uptake and reactions of soluble gases on aerosol particles. In addition, the TRACE-P data set provide strong constraints for assessing and improving the chemical fields simulated by chemical transport models.

Talbot, Robert W.↗

Exploring Diverse Data Sets and Developing New Theories and Ideas With Project Integration Architecture

The development of new ideas is the essence of scientific research. This is frequently done by developing models of physical processes and comparing model predictions with results from experiments. With models becoming ever more complex and data acquisition systems becoming more powerful, the researcher is burdened with wading through data ranging in volume up to a level of many terabytes and beyond. These data often come from multiple, heterogeneous sources and usually the methods for searching through it are at or near the manual level. In addition, current documentation methods are generally limited to researchers pen-and-paper style notebooks. Researchers may want to form constraint-based queries on a body of existing knowledge that is, itself, distributed over many different machines and environments and from the results of such queries then spawn additional queries, simulations, and data analyses in order to discover new insights into the problem being investigated. Currently, researchers are restricted to working within the boundaries of tools that are inefficient at probing current and legacy data to extend the knowledge of the problem at hand and reveal innovative and efficient solutions. A framework called the Project Integration Architecture is discussed that can address these desired functionalities.

Benyo, Theresa L.↗

Soot Formation in Purely-Curved Premixed Flames and Laminar Flame Speeds of Soot-Forming Flames

The research addressed here is a collaborative project between University of Delaware and Case Western Reserve University. There are two basic and related scientific objectives. First, we wish to demonstrate the suitability of spherical/cylindrical, laminar, premixed flames in the fundamental study of the chemical and physical processes of soot formation. Our reasoning is that the flame standoff distance in spherical/cylindrical flames under microgravity can be substantially larger than that in a flat burner-stabilized flame. Therefore the spherical/cylindrical flame is expected to give better spatial resolution to probe the soot inception and growth chemistry than flat flames. Second, we wish to examine the feasibility of determining the laminar flame speed of soot forming flames. Our basic assumption is that under the adiabatic condition (in the absence of conductive heat loss), the amount and dynamics of soot formed in the flame is unique for a given fuel/air mixture. The laminar flame speed can be rigorously defined as long as the radiative heat loss can be determined. This laminar flame speed characterizes the flame soot formation and dynamics in addition to the heat release rate. The research involves two integral parts: experiments of spherical and cylindrical sooting flames in microgravity (CWRU), and the computational counterpart (UD) that aims to simulate sooting laminar flames, and the sooting limits of near adiabatic flames. The computations work is described in this report, followed by a summary of the accomplishments achieved to date. Details of the microgra+ experiments will be discussed in a separate, final report prepared by the co-PI, Professor C-J. Sung of CWRU. Here only a brief discussion of these experiments will be given.

Buchanan, Thomas↗

It's a Sooty Problem: Black Carbon and Aerosols from Space

Our knowledge of atmospheric aerosols (smoke, pollution, dust or sea salt particles, small enough to be suspended in the air), their evolution, composition, variability in space and time and interaction with solar radiation, clouds and precipitation is lacking despite decades of research. Just recently we recognized that understanding the global aerosol system is fundamental for progress in climate change and hydrological cycle research. While a single instrument was used to demonstrate 50 yrs ago that the global CO2 levels are rising, posing thread to our climate, we need an may of satellites, surface networks of radiometers, elaborated laboratory and field experiments coupled with chemical transport models to understand the global aerosol system. This complexity of the aerosol problem results from their short lifetime (1 week), variability of the chemical composition and complex chemical and physical processes in the atmosphere. The result is a heterogeneous distribution of aerosol and their properties. The new generation of satellites and surface networks of radiometers provides exciting opportunities to measure the aerosol properties and their interaction with clouds and climate. However farther development in the satellite capability, aerosol chemical models and climate models is needed to fully decipher the aerosol secrets with accuracy required to predict future climates.

Kaufman, Yoram J.↗