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At least 1,189 records · Page 66

Integrated Reference Electrodes in Anion-Exchange-Membrane Electrolyzers: Impact of Stainless-Steel Gas-Diffusion Layers and Internal Mechanical Pressure

Alkaline-membrane electrolyzers operating in pure water might provide scalable low-cost H 2 production but currently lag in performance and durability compared to commercial technologies. Typically, membrane–electrode assemblies (MEAs) are optimized in electrolyzers by changing one parameter at a time and assessing the resulting system performance via two-electrode polarization and impedance measurements. These approaches are limited in their ability to assign performance changes and durability to specific electrodes or processes. We integrate a reference electrode with the MEA to separate anode and cathode responses in both polarization and impedance measurements. Here we illustrate the power of the approach by showing how the fiber diameter of stainless-steel gas-diffusion layers (GDLs) affects performance solely at the anode, while changing the thickness of the cathode GDL simultaneously affects the performance of the anode and cathode due to changes in internal pressure from mechanical compression. This finding was obscured in conventional two-electrode measurements. The work thus guides both high-performance alkaline-membrane water-electrolyzer development and illustrates a useful strategy to study structure–activity relationships in the MEA.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Symmetric fielding of the largest diamond capsule implosions on the NIF

We present results for the largest diamond capsule implosions driven symmetrically on the National Ignition Facility (NIF) (inner radius of ~1050 μm) without the use of cross beam transfer in cylindrical Hohlraums. We show that the methodology of designing Hohlraum parameters in a semi-empirical way using an extensive database resulted in a round implosion. In addition, we show that the radiation flux symmetry is well controlled during the foot of the pulse and that swings in P2 symmetry between the inflight dense shell and hot spot are within ±4 μm and that swings around peak compression are also within the symmetry specification of ±4 μm. We observed a stronger dependence of symmetry on the capsule scale than previously observed and also observed enhanced inner beam propagation for experiments using a gas fill density of 0.3 mg/cm 3 and 1000 μm inner radius capsules. We have observed sufficient symmetry and mass remaining at near full NIF power and energy, up to 480 TW and 1.9 MJ, with little laser–plasma interactions (low laser backscattered light) and predict that this design could support extended NIF energy of up to 2.1 MJ.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Assessment of Materials-Based Options for On-Board Hydrogen Storage for Rail Applications

The objective of this project was to evaluate material- and chemical-based solutions for hydrogen storage in rail applications as an alternative to high-pressure hydrogen gas and liquid hydrogen. Three use cases were assessed: yard switchers, long-haul locomotives, and tenders. Four storage options were considered: metal hydrides, nanoporous sorbents, liquid organic hydrogen carriers, and ammonia, using 700 bar compressed hydrogen as a benchmark. The results suggest that metal hydrides, currently the most mature of these options, have the highest potential. Storage in tenders is the most likely use case to be successful, with long-haul locomotives the least likely due to the required storage capacities and weight and volume constraints. Overall, the results are relevant for high-impact regions, such as the South Coast Air Quality Management District, for which an economical vehicular hydrogen storage system with minimal impact on cargo capacity could accelerate adoption of fuel cell electric locomotives. The results obtained here will contribute to the development of technical storage targets for rail applications that can guide future research. Moreover, the knowledge generated by this project will assist in development of material-based storage for stationary applications such as microgrids and backup power for data centers.

08 HYDROGEN↗

A two-dimensional numerical study of the flow inside the combustion chambers of a motored rotary engine

A numerical study was performed to investigate the unsteady, multidimensional flow inside the combustion chambers of an idealized, two-dimensional, rotary engine under motored conditions. The numerical study was based on the time-dependent, two-dimensional, density-weighted, ensemble-averaged conservation equations of mass, species, momentum, and total energy valid for two-component ideal gas mixtures. The ensemble-averaged conservation equations were closed by a K-epsilon model of turbulence. This K-epsilon model of turbulence was modified to account for some of the effects of compressibility, streamline curvature, low-Reynolds number, and preferential stress dissipation. Numerical solutions to the conservation equations were obtained by the highly efficient implicit-factored method of Beam and Warming. The grid system needed to obtain solutions were generated by an algebraic grid generation technique based on transfinite interpolation. Results of the numerical study are presented in graphical form illustrating the flow patterns during intake, compression, gaseous fuel injection, expansion, and exhaust.

Shih, T. I. P.↗

A two-dimensional numerical study of the flow inside the combustion chamber of a motored rotary engine

A numerical study was performed to investigate the unsteady, multidimensional flow inside the combustion chambers of an idealized, two-dimensional, rotary engine under motored conditions. The numerical study was based on the time-dependent, two-dimensional, density-weighted, ensemble-averaged conservation equations of mass, species, momentum, and total energy valid for two-component ideal gas mixtures. The ensemble-averaged conservation equations were closed by a K-epsilon model of turbulence. This K-epsilon model of turbulence was modified to account for some of the effects of compressibility, streamline curvature, low-Reynolds number, and preferential stress dissipation. Numerical solutions to the conservation equations were obtained by the highly efficient implicit-factored method of Beam and Warming. The grid system needed to obtain solutions were generated by an algebraic grid generation technique based on transfinite interpolation. Results of the numerical study are presented in graphical form illustrating the flow patterns during intake, compression, gaseous fuel injection, expansion, and exhaust.

Shih, T. I-P.↗

Automata network models of galaxy evolution

Two ideas appear frequently in theories of star formation and galaxy evolution: (1) star formation is nonlocally excitatory, stimulating star formation in neighboring regions by propagation of a dense fragmenting shell or the compression of preexisting clouds; and (2) star formation is nonlocally inhibitory, making H2 regions and explosions which can create low-density and/or high temperature regions and increase the macroscopic velocity dispersion of the cloudy gas. Since it is not possible, given the present state of hydrodynamic modeling, to estimate whether one of these effects greatly dominates the other, it is of interest to investigate the predicted spatial pattern of star formation and its temporal behavior in simple models which incorporate both effects in a controlled manner. The present work presents preliminary results of such a study which is based on lattice galaxy models with various types of nonlocal inhibitory and excitatory couplings of the local SFR to the gas density, temperature, and velocity field meant to model a number of theoretical suggestions.

Chappell, David↗

Advanced Multi-Phase Flow CFD Model Development for Solid Rocket Motor Flowfield Analysis

It is known that the simulations of solid rocket motor internal flow field with AL-based propellants require complex multi-phase turbulent flow model. The objective of this study is to develop an advanced particulate multi-phase flow model which includes the effects of particle dynamics, chemical reaction and hot gas flow turbulence. The inclusion of particle agglomeration, particle/gas reaction and mass transfer, particle collision, coalescence and breakup mechanisms in modeling the particle dynamics will allow the proposed model to realistically simulate the flowfield inside a solid rocket motor. The Finite Difference Navier-Stokes numerical code FDNS is used to simulate the steady-state multi-phase particulate flow field for a 3-zone 2-D axisymmetric ASRM model and a 6-zone 3-D ASRM model at launch conditions. The 2-D model includes aft-end cavity and submerged nozzle. The 3-D model represents the whole ASRM geometry, including additional grain port area in the gas cavity and two inhibitors. FDNS is a pressure based finite difference Navier-Stokes flow solver with time-accurate adaptive second-order upwind schemes, standard and extended k-epsilon models with compressibility corrections, multi zone body-fitted formulations, and turbulence particle interaction model. Eulerian/Lagrangian multi-phase solution method is applied for multi-zone mesh. To simulate the chemical reaction, penalty function corrected efficient finite-rate chemistry integration method is used in FDNS. For the AL particle combustion rate, the Hermsen correlation is employed. To simulate the turbulent dispersion of particles, the Gaussian probability distribution with standard deviation equal to (2k/3)(exp 1/2) is used for the random turbulent velocity components. The computational results reveal that the flow field near the juncture of aft-end cavity and the submerged nozzle is very complex. The effects of the turbulent particles affect the flow field significantly and provide better prediction of the ASRM performance. The multi-phase flow analysis using the FDNS code in the present research can be used as a design tool for solid rocket motor applications.

Liaw, Paul↗

Laminar Heating Validation of the OVERFLOW Code

OVERFLOW, a structured finite difference code, was applied to the solution of hypersonic laminar flow over several configurations assuming perfect gas chemistry. By testing OVERFLOW's capabilities over several configurations encompassing a variety of flow physics a validated laminar heating was produced. Configurations tested were a flat plate at 0 degrees incidence, a sphere, a compression ramp, and the X-38 re-entry vehicle. This variety of test cases shows the ability of the code to predict boundary layer flow, stagnation heating, laminar separation with re-attachment heating, and complex flow over a three-dimensional body. In addition, grid resolutions studies were done to give recommendations for the correct number of off-body points to be applied to generic problems and for wall-spacing values to capture heat transfer and skin friction. Numerical results show good comparison to the test data for all the configurations.

Lillard, Randolph P.↗

Wet biofuel compression ignition

A compression ignition engine system allows use of hydrous fuels, in particular hydrous biofuels, with high water content (e.g., 20-85% water). The hydrous fuel is pressurized, and also preferably heated via the engine's exhaust gas, to increase its enthalpy, and is then directly injected into the engine cylinder(s) near top dead center. The system provides brake thermal efficiency increases of 20% or more versus a comparable system using conventional diesel fuel, while allowing the use of inexpensive undistilled or lightly distilled biofuels.

Wickman, David Darin↗

Experimental observations of shock-wave-induced bubble collapse and hot-spot formation in nitromethane liquid explosive

We studied the collapse of individual helium gas bubbles in the homogeneous explosive nitromethane (NM) to investigate effects of hot-spot formation on the detonation process. A bubble was injected into a NM sample, and a shock wave from an explosive detonator compressed the bubble, creating a localized hot spot. We measured shock and detonation wave speeds with optical velocimetry, and we used a high-speed camera to image the shock propagation and the pre- and post-bubble collapse processes. An infrared camera image showed the residual radiance temperature distribution after the bubble collapse, and an optical fiber pyrometer measured the time-resolved thermal radiance. We measured the optical spectra of light emitted from detonating NM without a bubble and from a collapsing bubble in shocked, undetonated NM. We estimated temperatures of the detonation fronts and of the hot spots formed by bubble collapse. To study the incipient detonation process, we performed all bubble collapse experiments at pressures below the threshold for creating a sustained detonation. Where the bubble collapsed, we observed an opaque, thermally emissive region believed to be chemical reaction products. Chemical reactions in NM can be produced with lower shock pressures (~1 GPa) when a helium bubble is present than without a bubble (~10 GPa). We used hydrodynamic modeling to predict shock wave propagation, extent of chemical reaction, and subsequent temperature rise from the collapsing bubble. Simulations using a temperature-dependent Arrhenius burn model gave much better results than reactive burn models that depend only on pressure and density.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Constrained model calibration of grain structure dependent spall dynamics in shock-loaded tantalum

Here, we perform a gas gun experiment by shock loading tantalum samples of varying grain structures to assess the suitability of a numerical model for simulating spall behavior. The observed differences in spall strength, as well spallation and re-compression history, are not captured in uncalibrated hydrodynamic simulations. An optimization is performed on the Johnson spall model to determine the best parameters that fit the observed trends. Linear stability analysis is employed to motivate bounds on those parameters. Herein, optimized simulations agree well with the experimental results, reproducing pullback depth and recompression timescales across the different samples tested. Further, the observed pullback time of the single crystal sample was found to imply, via the stability analysis, a percolation threshold in good agreement with the theoretical value for a body centered cubic lattice. Therefore, the combined linear stability and percolation analysis shows promise and may be applied to other materials with diverse microstructures. Collectively, the findings demonstrate that the model is suitable for reproducing spall-induced free surface behavior across various microstructures, but also points to caution in using model coefficients for uncalibrated microstructures.

58 GEOSCIENCES↗

On High-Order/Low-Order and Micro-Macro Methods for Implicit Time-Stepping of the BGK Model

In this paper, a high-order/low-order (HOLO) method is combined with a micro-macro (MM) decomposition to accelerate iterative solvers in fully implicit time-stepping of the Bhatnagar–Gross–Krook (BGK) equation for gas dynamics. The MM formulation represents a kinetic distribution as the sum of a local Maxwellian and a perturbation. In highly collisional regimes, the perturbation away from initial and boundary layers is small and can be compressed to reduce the overall storage cost of the distribution. The convergence behavior of the MM methods, the usual HOLO method, and the standard source iteration method is analyzed on a linear BGK model. Both the HOLO and MM methods are implemented using a discontinuous Galerkin (DG) discretization in phase space, which naturally preserves the consistency between high- and low-order models required by the HOLO approach. Furthermore, the accuracy and performance of these methods are compared on the Sod shock tube problem and a sudden wall heating boundary layer problem. Overall, the results demonstrate the robustness of the MM and HOLO approaches and illustrate the compression benefits enabled by the MM formulation when the kinetic distribution is near equilibrium.

BGK model↗

Achieving Unprecedented CO 2 Utilization InCO 2 Concrete™: System Design, Product Development and Process Demonstration

Anthropogenic sources of carbon dioxide are generated from a number of sources, but the key among these are ordinary Portland cement (OPC) production and combustion of fossil fuels. Cement production is the largest global CO 2 source from the mineral decomposition of carbonates. This is due to the clinkering process whereby limestone (mainly consisting of CaCO 3 ) is decomposed into CaO and CO 2 , and combined with silica rich clays at high temperatures to form clinkers (i.e. the four key minerals that comprise cement). The high temperature range of 1400 – 1550°C required for this process accounts for up to 60% of the generated CO 2 from cement production. Combination of the limestone decomposition and thermal requirements of the clinkering process causes cement production to contribute 8-9% of annual global CO 2 emissions. Combustion of fossil fuels (coal, oil and gas) was shown to contribute a much larger portion of global CO 2 emissions. As of 2018, combustion of fossil fuels accounted for 65% of global CO 2 , where 41% was derived from stationary sources for electricity and heat generation and the other 24% was related to transport. To reduce these contributions, key steps forward in CO 2 utilization technologies are required. Therefore, a CO 2 mineralization technology (CO 2 mineralization concrete) to reduce the OPC content in concrete, while utilizing flue gas emissions from fossil fuel combustion has been developed to address both areas simultaneously. This Reversa™ technology utilizes low-carbon cementation agents produced by in situ CO 2 mineralization (“mineral carbonation reactions”) to offer a promising alternative to OPC. CO 2 mineralization relies upon the reaction of dissolved CO 2 with inorganic alkaline reactants to precipitate mineral carbonates (e.g., CaCO 3 ), which bind proximate particles and achieve cementation. Herein, a concrete green body, which is composed of a mixture of binder, water, and mineral aggregates, is exposed to CO 2 borne in industrial flue gas streams. This manner of CO 2 mineralization allows the production of construction components that feature equivalent engineering attributes as their OPC-based counterparts while featuring a much smaller embodied carbon intensity (eCI). The purpose of this project is to demonstrate the feasibility of the Reversa process evolving from a TRL-3 technology at the bench-scale up to TRL-6 technology at the pilot-scale. The reliability of the Reversa technology was tested to prove the effective production of three standard industrial concrete products selected during the course of the project. The results detailed herein will demonstrate the evolution of this technology to the industrial scale. The culmination of this work resulted in 9 production runs completed at the National Carbon Capture Center (NCCC), Wilsonville, AL, using natural gas (NG) flue gas as the CO 2 source. Over the course of the production runs at NCCC, the CO 2 utilization as a function of time, 24-h CO 2 uptake, electricity usage, and 28-d net area compressive strength recorded for each run. Collection of this data will be used to determine the success of the demonstration goals: (1) achieving in excess of 0.2gCO 2 /g reactant , (2) achieving greater than 50% reduction in global warming potential compared to standard produced units, and (3) ensuring compliance of carbonated concrete with industry standard specifications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Progress Update on the In Situ Load Retention Aging Vessel

To improve upon our conventional thermally accelerated aging study methods which require periodic interruption of aging to perform load testing in an Instron machine, a new aging system is being developed to: (1) automate/facilitate data acquisition/analysis, (2) improve data quality, and (3) enable uninterrupted aging conditions (compression, temperature, atmosphere) which represents the service condition. In FY24, a thermal aging vessel instrumented with load cells was fabricated and tested. That unit demonstrated the primary function of the vessel: to continuously monitor the in situ load retention of up to three compressed polymer coupons undergoing thermally accelerated aging under nitrogen. A secondary objective, not realized in the unit due to inadequate sealing, was to enable a single initial nitrogen backfill (as opposed to a continuous purge) and gas sampling of the vessel headspace during thermal aging. Heating of the vessel was achieved using a custom heater jacket.

36 MATERIALS SCIENCE↗

Resource Adequacy and Capital Cost Considerations Pertaining to Large Electric Grids Powered by Wind, Solar, Storage, Gas, and Nuclear

The capacity and generation of wind, solar, storage, nuclear, and gas are estimated for large, idealized copper-plate electric grids. Wind and solar penetrations of 30% to 80% are considered together with different storage systems such as vanadium and lithium-ion batteries, pumped hydroelectric, compressed air, and hydrogen. In addition to a baseline dispatchable fleet without wind/solar, two bounding cases with wind/solar are analyzed: one without storage and one where the whole wind/solar fleet is connected to the storage system, hence providing a buffer between the wind/solar fleet and the grid. The reality will likely be somewhere between these bounding cases. The viability of a power grid with a large wind/solar penetration and no storage is not guaranteed but was nonetheless considered to provide a lower-bound capital cost estimate. Overall, the options that rely strongly on wind, solar, and storage could be significantly more capital-intensive than those that rely strongly on nuclear, depending on the amount of storage necessary to ensure grid stability. This is especially true in the long run because wind, solar, and storage assets have shorter lifetimes than nuclear plants and, consequently, need to be replaced more frequently. More analyses (e.g., grid stability and public acceptance) are necessary to determine which option is most likely to provide the path of least resistance to powering a clean, affordable, and reliable grid in a timely manner. Depending on the priorities, the path of least resistance may not necessarily be the one that is less capital intensive.

adequacy↗

New mixing-length model for turbulent high-speed flows

A modification of Prandtl's mixing-length model is presented which takes into account the effects of compressibility on turbulence for high speed flows. A parameter is introduced into the turbulent transport formula which acts like an effective turbulent Schmidt number for mixtures of gases or a turbulent Prandtl number for a homogeneous gas. Results presented for such cases as high Mach number turbulent boundary layer flows over a flat surface, tangential slot injection problems, and shock/turbulent shear-layer and boundary-layer interactions agree well with experimental data.

Situ, M.↗

Sealing Out-Of-Round Tubes With O-Rings

Glass or ceramic tubes out-of-round sealed effectively by ordinary O-rings in caps of modified hydraulic fittings. In typical connection, O-ring squeezed between two surfaces having inward-opening slants of 5 degrees or 10 degrees. Slanted surfaces force ring inward, compressing it around tube. Connector metal fitting, tightened by hand around O-ring, seals O-ring against tube as much as 1/16 in. out of round. Modified connectors seal glass or ceramic tubes against gas or vacuum leakage in furnaces, vacuum systems, and tubes for glassblowing equipment.

Shlichta, Paul J.↗

Impact properties of three-dimensional braided graphite/epoxy composites

An experimental study of the response and damage of three-dimensional braided graphite/epoxy composite due to sub-perforation velocity impact was carried out in this research. Simply supported square plates were impacted with an instrumented impact pendulum and also a projectile fired by a gas gun. Hemispherical nose impactors of two different diameters, 12.7 mm and 25.4 mm, were used in the pendulum tests. In addition, static flexure tests were performed. Impact damage was assessed using X-radiography, and compression after impact tests. Damages involved in impacted braided panel are matrix cracking in resin pockets, separation of fiber tows, and fiber two breakage, mostly in fiber bundle crimp areas. A quasi-isotropic laminate was impact tested with pendulum for comparison of impact tolerance between the two composite systems.

Gong, J. C.↗