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All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Robust In-Situ Strain Measurements to Monitor CO 2 Storage

The goal of this project was to develop and demonstrate robust instrumentation to monitor the in-situ strain tensor in order to improve the reliability and security of CO 2 storage in geologic formations. We met the original goals of the project and the major overarching accomplishment is the advancement of strain tensor monitoring from an intriguing concept to a commercially available technology with a solid foundation of novel instruments supported by theoretical analyses and validation experiments. The main accomplishments of the project are summarized below. We designed, built and evaluated nine new optical fiber strainmeters and tiltmeters using Michelson interferometers to measure deformation with ultra-high resolution at both shallow and deep point locations in the subsurface. These are the robust strainmeters that motivated the title of the project. We designed, built and evaluated a novel method of measuring distributed strain in optical fibers with nanostrain resolution, and cm-scale location, and sampling into the seismic band. The new method is called Coherence-length-gated Microwave Photonics Interfereometry (CMPI). CMPI technology has advantages over existing commercial DAS and DSS methods. We developed and demonstrated capabilities to deploy instruments in the field and used them to measure strain caused by ambient signals like barometric pressure and tides, as well as induced signals like surface loading and pore pressure changes from pumping tests. We deployed a working strainmeter at 1,700 ft depth, slightly above an active reservoir. This is to our knowledge the greatest depth a strainmeter has been deployed and the techniques we used can readily be extended to greater depths. Optical fiber borehole tensor strainmeter techology was advanced from a TRL 4 at the start, to a TRL of 7 at the conclusion of the project. The project included advances in simulations and theoretical analyses. We developed and demonstrated a computational workflow that uses machine learning to reduce the computational requirements and make it practical to use Bayesian inversion to solve large numerical poroelastic analyses needed to interpret strain tensor field data. We evaluated the strain tensor fields and time series that would be caused by leaks of CO 2 or other fluids from reservoirs. These simulations demonstrated that signals from leaks could be measured with instruments developed for the project, opening a potentially new method for ensuring storage security. We showed that strains in caprock can be used to estimate pressure in a reservoir. This avoids the need to drill monitoring wells into the reservoir, and it expands the capabilities of monitoring in the caprock. The project includes a derivation and application of a novel analytical solution to the strains in the vicinity of a pressurized poroelastic inclusion. This solution explains field data measured during injeciton tests at the North Avant Field, and it will simplify future interpretation of strain tensor data. The project included a broad range of experiments, and of the most significant is the characterization of the strain tensor at an array three strainmeters during six injection tests at the North Avant Field, Oklahoma. This demonstrated repeatability of the strain signal measured by the new instruments developed for the project, and it showed similarities between the strain signal at shallow depths and pressure in the underlying reservoir. We also demonstrated that useful strain data can be measured at reservoir depths. This confirms that strain tensor data can be measured throughout the caprock over a reservoir. The project demonstrated the feasibility of using the strain tensor and distributed strain measured in caprock during a variety of different well tests where the pumping rate was constant, sinusoidal and positive, or a periodic square wave with zero net rate. This further strengthens the validity of using strain data to characterize reservoirs and aquifers. We also demonstrated that strain caused be fluctuations of air pressure and water pressure in the vadose zone can be measured and interpreted, suggesting that high resolution distributed strain measurements hold promise for monitoring the vadose zone. The project partially supported nine graduate students in the Environmental Engineering, Hydrogeology, Electrical Engineering programs at Clemson University. The research was described in nine journal papers, 23 talks and conference abstracts. Additional journal papers are in preparation. A new company called Tensora was started to provide strainmeter technology for commercial applications.

01 COAL, LIGNITE, AND PEAT↗
NASA NTRS2001

Optical metrology for testing an all-composite 2-meter diameter mirror

The Herschel Space Observatory (formerly known as FIRST) consists of a 3.5 m space telescope designed for use in the long IR and sub-milimeter wavebands. To demonstrate the viability of a carbon fiber composite telescope for this application, Composite Optics Incorporated (COI) manufactured a fast (f/1), large (2 m), lightweight (10.1 kg/m squared) demonstration mirror. A key challenge in demonstrating the performance of this novel mirror was to characterize the surface accuracy at cryogenic (70 K) temperatures. A wide variety of optical metrology techniques were investigated and a brief survey of empirical test results and limitations of the various techniques will be presented in this paper. Two complementary infrared (IR)techniques operating at a wavelength of 10.6 microns were chosen for further development: (1) IR Twyman-Green Phase Shifting Interferometry (IR PSI) and (2) IR Shack-Hartmann (IR SH) Wavefront Sensing. Innovative design modifications made to an existing IR PSI to achieve high-resolution, scannable, infrared measurements of the composite mirror are described. The modified interferometer was capable of measuring surface gradients larger than 350 microradians. The design and results of measurements made with a custom-built IR SH Wavefrong Sensor operating at 10.6 microns are also presented. A compact experimental setup permitting simultaneous operation of both the IR PSI and IR SH tools is shown. The advantages and the limitations of the two key IR metrology tools are discussed.

IR metrology phase shifting interferometry Shack-H↗
NASA NTRS1994

Fabric geometry distortion during composites processing

Waviness and tow misalignment are often cited as possible causes of data scatter and lower compression stiffness and strength in textile composites. Strength differences of as much as 40 percent have been seen in composites that appear to have the same basic material and structural properties -- i.e., yarn orientation, yarn size, interlacing geometry. Fabric geometry distortion has been suggested as a possible reason for this discrepancy, but little quantitative data or substantial evidence exists. The focus of this research is to contribute to the present understanding of the causes and effects of geometric distortion in textile composites. The initial part of the study was an attempt to gather qualitative information on a variety of textile structures. Existing and new samples confirmed that structures with a significant direction presence would be more susceptible to distortion due to the compaction process. Thus, uniweaves (fiber vol frac: 54-72 percent) biaxial braids (vf: 34-58 percent) demonstrated very little fabric geometry distortion. In stitched panels, only slight buckling of z-direction stitches was observed, primarily near the surface. In contrast, for structures with high compaction ratios -- e.g., large cylindrical yarns (2.5:1) orpowder towpreg (4:1) -- there were visible distortions where previously smooth and periodic undulations were transformed to abrupt changes in direction. A controlled study of the effect of forming pressure on distortion was conducted on type 162 glass plain weave fabrics. Panels (6 x 6 in) were produced via a resin infusion type setup, but with an EPON 815 epoxy resin. Pressures ranging from hand layup to 200 psi were used (vf: 34-54 percent). Photomicrographs indicated that at pressures up to 50 psi, large changes in thickness were due primarily to resin squeeze out. At higher pressures, when intimate contact was made between the layers, there was some tow flattening and in-plane shifting to optimize nesting. However, even at 200 psi the period and amplitude of the tow undulation remained constant, suggesting that for this relatively fine fabric, distortions from compaction were not a problem. Because of the interest in using larger tows (to reduce cost) and more complex structures, tests were also run on 2D triaxial glass braid (113 yd/lb at 0, 225 yd/lb at +/- 45). Forming pressures of 20, 50, 200, and 500 psi were used, and short block compression tests were run. The 500 psi specimen had a 10 percent decrease in modulus and an almost 50 percent decrease in strength (vs. 20 psi). Because the total fiber wgt/panel was kept constant, the thickness varied from 0.32 to 0.22 in (49-70 percent vf). Yet, the strength value is clearly below what would be expected, even with the decrease in thickness. Photomicrographs of these samples will be taken to determine if more fabric distortion exists in the 500 psi specimens. Finally, because the ultimate goal is to be able to predict and control distortion in a variety of textile structures, a model compaction test was developed to directly measure the deformation of the tows during compaction. Layers of dry glass fabric were placed in a mold with a clear plexiglass window. The yarn amplitude and period was then calculated using image analysis of the videotaped deformation. Preliminary tests demonstrated the feasibility of this technique for simple fabrics with large tows.

Chen, Julie↗
DOE OSTI2022

Carbon Electrodes from Powder River Basin Coal Development of Competitive Supercapacitor Electrodes of Diverse Compositions from Coal Extract

Recent demand for coal as a thermal energy source has decreased significantly and will likely continue to decrease as renewable sources of energy become more available and environmental concern and cost from burning coal makes it more costly than renewables. Given that Powder River Basin (PRB) coal in Wyoming has relatively low thermal energy, it is critical for Wyoming to employ coal in other capacities at the current energy transition period in history. Among many potential non-thermal applications, PRB coal can be utilized for membrane and electrode applications through the formation of carbon fibers. Coal-derived membranes can become low-cost, conductive membranes for use in electrodialysis separation processes. Carbon fiber derived electrodes have been shown be a cost-effective alternative to typical electrode materials that can meet or exceed the performance of current carbon electrode materials. In this talk, we demonstrate the manufacture of supercapacitor electrodes from Powder River Basin (PRB) coal-derived precursors. Specifically, PRB coal was treated in cheap solvents, partitioned into liquid extract and solid residue. An electropinning process has been developed that can convert either the liquid extract or the solid residue into carbon fiber mats. The electrospinning process is versatile with many tunable process parameters to achieve desirable physiochemical properties. For example, the coal residue can be manipulated by additional heat treatment, or by adding binders, salts, or surfactants to create a solution that can be electrospun into advanced carbon electrodes with desirable structural and surface properties. Similarly, some of the liquid extract (tar fraction) can be subsequently reacted with toluene diisocyanate to create resinous coal-derived polyurethane (PUs) as a spinnable ink. Carbon nanofiber mats made from our proprietary electrospinning process were further carbonized at temperature ranging from 700°C to 900°C before they are used as electrodes in supercapacitors. Galvanostatic charge-discharge (GCD) results show that the best performing PU fiber mats can deliver a specific capacitance of 604 F g -1 at the current density of 1 A g -1 . A carbon fiber mat from a different solvent extraction residue also delivered the specific capacitance of 508 F g -1 . These specific capacitance values are comparable to or better than commercial activated carbons, demonstrating the viability of manufacturing carbon nanofiber electrodes from coal without the use of a commercial polymer as binder in the spinning ink.

Cincotta, Robert↗
NASA NTRS1981

Rub energetics of compressor blade tip seals

The rub mechanics of aircraft gas turbine engine compressor abradable blade tip seals was studied at simulated engine conditions. In 12 statistically planned, instrumented rub tests using single titanium blades and fiber-metal rubstrips the rub velocity, incursion rate, incursion depth, blade thickness, and abradable strength were varied to determine the effects on rub energy, heat split between the blade, rubstrip surface and rub debris, and blade and seal wear. The rub energies were found to be most significantly affected by the incursion rate while rub velocity and blade thickness were of secondary importance. In five additional rub tests using single nickel alloy blades and multiple titanium alloy blades, rub energy and wear effects were found to be similar for titanium and nickel alloy blades while rub energies increased for multiple blades relative to single blade test results.

Laverty, W. F.↗
NASA NTRS2005

Electrospinning of Polyvinylidene Fluoride and Polyetherimide From Mixed Solvents

Polyvinylidene fluoride and Ultem(TradeMark) polyetherimide were dissolved in 50/50 acetone/N,N dimethylformamide (DMF) and 80/20 tetrahydrofuran/DMF, respectively, and electrospun. Polymer solution concentrations and molecular weights were changed while other spinning parameters (voltage, distance, solution feed rate) were held constant. Fiber diameters in the resulting electrospun mats varied from 0.25 to 4.4 microns, increasing with polymer concentration and molecular weight; trends in diameter were compared with trends in viscosities and surface tensions of the spinning solutions.

Morgret, Leslie D.↗
NASA NTRS2005

Fabrication and Deployment Testing of Solar Sail Quadrants for a 20-Meter Solar Sail Ground Test System Demonstration

A 20-meter Scalable Square Solar Sail (S(sup 4)) System was produced and successfully completed functional vacuum testing in NASA Glenn's Space Power Facility at Plum Brook Station Ohio in May 2005. The S(sup 4) system was designed and developed by ATK Space Systems, and the design and production of the Solar Sails for this system was carried out by SRS Technologies. The S(sup 4) system consists of a central structure with four deployable carbon fiber masts that support four triangular sails. SRS has developed an effective and efficient design for triangular sail quadrants that are supported at three points and provide a flat reflective surface with a high fill factor. This sail design is robust enough for deployments in a one atmosphere, one gravity environment and incorporates several advanced features including adhesiveless seaming of membrane strips, compliant edge borders to allow for film membrane cord strain mismatch without causing wrinkling and low mass (3% of total sail mass) ripstop. This paper will outline some of the sail design and fabrication processes and the mature production, packaging and deployment processes that have been developed. This paper will also detail the successful ambient and vacuum testing of the sails and the ATK spacecraft structure. Based on recent experience and testing, SRS is confidant that high Technology Readiness Level (TRL) 5-6 solar sails in the 40-120-meter size range with areal density in the 4-5 grams per square meters (sail minus structure) range can be produced with existing technology. Additional film production research will lead to further reductions in film thickness to less than 1 micron enabling production of sails with areal densities as low as 2.0 grams per square meters using the current design, resulting in a system areal densities as low as 5.3 grams per square meters (sail and structure). These areal densities are low enough to allow nearly all of the Solar Sail missions that have been proposed by the scientific community. The fundamental technologies required to produce these systems has been demonstrated on the 20-meter S(sup 4) sails that have recently completed ground testing demonstrating a mature and technology suitable for incorporation into future flight validation and future mission. Solar Sails can support NASA's Vision for Space Exploration by allowing communication satellite orbits that can maintain continuous communication with the polar regions of the Moon and Mars and to support solar weather monitoring to provide early warning of solar flares and storms that could threaten the safety of astronauts and other spacecraft.

Laue, Greg↗
NASA NTRS2017

In-Situ Observations of Longitudinal Compression Damage in Carbon-Epoxy Cross Ply Laminates Using Fast Synchrotron Radiation Computed Tomography

The role of longitudinal compressive failure mechanisms in notched cross-ply laminates is studied experimentally with in-situ synchrotron radiation based computed tomography. Carbon/epoxy specimens loaded monotonically in uniaxial compression exhibited a quasi-stable failure process, which was captured with computed tomography scans recorded continuously with a temporal resolutions of 2.4 seconds and a spatial resolution of 1.1 microns per voxel. A detailed chronology of the initiation and propagation of longitudinal matrix splitting cracks, in-plane and out-of-plane kink bands, shear-driven fiber failure, delamination, and transverse matrix cracks is provided with a focus on kink bands as the dominant failure mechanism. An automatic segmentation procedure is developed to identify the boundary surfaces of a kink band. The segmentation procedure enables 3-dimensional visualization of the kink band and conveys the orientation, inclination, and spatial variation of the kink band. The kink band inclination and length are examined using the segmented data revealing tunneling and spatial variations not apparent from studying the 2-dimensional section data.

Bergan, Andrew C.↗
NASA NTRSDate not supplied

Development and Airborne Demonstration of the Concurrent Artificially-Intelligent Spectrometry and Adaptive Lidar System: Advancing Lidar Capabilities for the STV Observing System

We report on the design, build and planned airborne demonstration of a spaceflight-prototype Concurrent Artificially-intelligent Spectrometry and Adaptive Lidar System (CASALS). The CASALS lidar is an Adaptive Wavelength Scanning Lidar (AWSL) operating in push broom mode. The demonstration has three major goals: advance the Technical Readiness Level of the AWSL hardware, validate its measurement performance and mature algorithms and methods needed for the Surface Topography and Vegetation (STV) observing system. AWSL acquires parallel tracks of surface heights by rapidly steering a laser beam across a swath. A 1040nm-centered laser is tuned across 30nm and carved into 2-ns pulses, the pulse energy is fiber amplified and the pulses are dispersed cross-track using a non-mechanical wavelength-to-angle grating. For the spaceflight system the beam will be pointable to 1200 10m footprints across a 7km swath. For the airborne demonstration there will be 256 0.7m footprints across a 110m swath. In both cases the footprints overlap across- and along-track for uniform target illumination. For the airborne demonstration a steering mirror will increase the accessible swath width to 4km. At the receiver, solar radiation is filtered with a narrow-slit grating-spectrometer and the footprints are imaged onto a linear-mode, photon-sensitive HgCdTe APD-array. The received pulses are time-division-multiplexed to a few high-speed analog-to-digital converters to record waveforms. Spaceflight and airborne CASALS are designed to nominally detect 20 photons per pulse and, by averaging 27 overlapping footprints, achieve 2cm flat target range precision and high-quality vegetation structure waveforms The AWSL will be flown in the summer of 2024, along with a Headwall VNIR-SWIR hyperspectral sensor imaging a 4km wide swath, at NEON eddy covariance flux towers in the U.S. mid-Atlantic where high resolution hyperspectral and lidar data, acquired annually, are available for validation.

Guangning Yang↗
NASA NTRSDate not supplied

Production and Characterization of Additively Manufactured Radiator Panels with Integral Branching Heat Pipes for High-Temperature Heat Rejection

Emerging concepts for fission surface power and nuclear electric propulsion necessitate lightweight, mechanically robust, and thermally efficient heat rejection radiators. State-of-the-art intermediate-temperature (~400 K) composite radiator assemblies have been developed based on titanium-water heat pipes bonded to metal, graphite, and carbon-fiber-based panels. NASA has identified a need for new radiator concepts that can operate at even higher temperatures (500 – 600 K), minimize thermal resistances and thermal stress failures at bond interfaces, and approach areal densities of 2 – 3 kg m -2 . To meet these needs, our team is developing additively manufactured (AM) radiator panels with integral branching wicking heat pipe networks. Water is selected as the working fluid for this temperature range. Based on simulations and thermal vacuum experiments, these branching embedded heat pipe networks can efficiently distribute heat over panels for finned surface efficiencies of η f >70% at T H = 500 K input heat. This paper first presents laser powder-bed fusion AM strategies to produce embedded porous structures for wicking heat pipes in Inconel 718 and titanium alloys (commercially pure and Ti-6Al-4V alloys). Post-build chemical and thermal treatments are described that yield hydrophilic wicking surfaces for operation with water. Transient rate-of-rise experiments with water and acetone are reported that yield estimates for AM wick porosity (ϵ), permeability (K), and effective pore radius (r pore ). Based on the wick characterization results, small prototype radiator panels (75 × 125 mm) with integrated heat pipe networks were manufactured. Heat rejection performance data are presented from cold thermal vacuum testing, with heat input temperatures up to ~510 K. Future efforts will focus on improving heat pipe performance, optimizing radiator mass, and evaluating larger panels to assess scalability.

thermal management↗
NASA NTRS2024

Production and Characterization of Additively Manufactured Radiator Panels With Integral Branching Heat Pipes for High-Temperature Heat Rejection

Emerging concepts for fission surface power and nuclear electric propulsion necessitate lightweight, mechanically robust, and thermally efficient heat rejection radiators. State-of-the-art intermediate-temperature (~400 K) composite radiator assemblies have been developed based on titanium-water heat pipes bonded to metal, graphite, and carbon-fiber-based panels. NASA has identified a need for new radiator concepts that can operate at even higher temperatures (500 – 600 K), minimize thermal resistances and thermal stress failures at bond interfaces, and approach areal densities of 2 – 3 kg m -2 . To meet these needs, our team is developing additively manufactured (AM) radiator panels with integral branching wicking heat pipe networks. Water is selected as the working fluid for this temperature range. Based on simulations and thermal vacuum experiments, these branching embedded heat pipe networks can efficiently distribute heat over panels for finned surface efficiencies of η f >70% at T H = 500 K input heat. This paper first presents laser powder-bed fusion AM strategies to produce embedded porous structures for wicking heat pipes in Inconel 718 and titanium alloys (commercially pure and Ti-6Al-4V alloys). Post-build chemical and thermal treatments are described that yield hydrophilic wicking surfaces for operation with water. Transient rate-of-rise experiments with water and acetone are reported that yield estimates for AM wick porosity (ϵ), permeability (K), and effective pore radius ( r pore ). Based on the wick characterization results, small prototype radiator panels (75 × 125 mm) with integrated heat pipe networks were manufactured. Heat rejection performance data are presented from cold thermal vacuum testing, with heat input temperatures up to ~510 K. Future efforts will focus on improving heat pipe performance, optimizing radiator mass, and evaluating larger panels to assess scalability.

nuclear electric propulsion↗
NASA NTRS1973

Ablative system

A carrier liquid containing ablative material bodies is connected to a plenum chamber wall with openings to a high temperature environment. The liquid and bodies pass through the openings of the wall to form a self replacing ablative surface. The wall is composed of honeycomb layers, spheres containing ablative whiskers or wads, and a hardening catalyst for the carrier liquid. The wall also has woven wicks of ablative material fibers that extend through the wall openings and into plenum chamber which contains the liquid.

Gray, V. H.↗
NASA NTRS1974

Method of repairing discontinuity in fiberglass structures

Damaged fiberglass structures are repaired by substantially filling the irregular surfaced damaged area with a liquid, self-curing resin, preferably an epoxy resin mixed with chopped fiberglass, and then applying to the resin surface the first of several woven fiberglass swatches which has stitching in a zig-zag pattern parallel to each of its edges and a fringe of warp and fill glass fibers about the edges outward of the stitching. The method is especially applicable to repair of fiberglass rocket engine casings and is particularly advantageous since it restores the repaired fiberglass structure to substantially its original strength without any significant changes in the geometry or mass of the structure.

Gelb, L. L.↗
NASA NTRS1999

Pyrometric Gas and Surface Temperature Measurements

A multiwavelength pyrometer possessing advantages over the one- and two-wavelength designs is described. Results of its application to surface temperature measurements of ceramics is presented. Also described is a probe suitable for gas temperature measurements to temperatures > 2600 K. The design of the probe includes a multiwavelength pyrometer with fiber optic input.

Fralick, Gustave↗
NASA NTRS2009

Improved Fabrication of Ceramic Matrix Composite/Foam Core Integrated Structures

The use of hybridized carbon/silicon carbide (C/SiC) fabric to reinforce ceramic matrix composite face sheets and the integration of such face sheets with a foam core creates a sandwich structure capable of withstanding high-heatflux environments (150 W/cm2) in which the core provides a temperature drop of 1,000 C between the surface and the back face without cracking or delamination of the structure. The composite face sheet exhibits a bilinear response, which results from the SiC matrix not being cracked on fabrication. In addition, the structure exhibits damage tolerance under impact with projectiles, showing no penetration to the back face sheet. These attributes make the composite ideal for leading edge structures and control surfaces in aerospace vehicles, as well as for acreage thermal protection systems and in high-temperature, lightweight stiffened structures. By tailoring the coefficient of thermal expansion (CTE) of a carbon fiber containing ceramic matrix composite (CMC) face sheet to match that of a ceramic foam core, the face sheet and the core can be integrally fabricated without any delamination. Carbon and SiC are woven together in the reinforcing fabric. Integral densification of the CMC and the foam core is accomplished with chemical vapor deposition, eliminating the need for bond-line adhesive. This means there is no need to separately fabricate the core and the face sheet, or to bond the two elements together, risking edge delamination during use. Fibers of two or more types are woven together on a loom. The carbon and ceramic fibers are pulled into the same pick location during the weaving process. Tow spacing may be varied to accommodate the increased volume of the combined fiber tows while maintaining a target fiber volume fraction in the composite. Foam pore size, strut thickness, and ratio of face sheet to core thickness can be used to tailor thermal and mechanical properties. The anticipated CTE for the hybridized composite is managed by the choice of constituents, varying fiber tow sizes and constituent part ratios. This structural concept provides high strength and stiffness at low density 1.06 g/cm3 in panels tested. Varieties of face sheet constructions are possible, including variations in fiber type and weave geometry. The integrated structures possible with this composite could eliminate the need for non-load-bearing thermal protection systems on top of a structural component. The back sheet can readily be integrated to substructures through the incorporation of ribs. This would eliminate weight and cost for aerospace missions.

Hurwitz, Frances I.↗
NASA NTRS2009

Inert Welding/Brazing Gas Filters and Dryers

The use of hybridized carbon/silicon carbide (C/SiC) fabric to reinforce ceramic matrix composite face sheets and the integration of such face sheets with a foam core creates a sandwich structure capable of withstanding high-heat-flux environments (150 W/sq cm) in which the core provides a temperature drop of 1,000 C between the surface and the back face without cracking or delamination of the structure. The composite face sheet exhibits a bilinear response, which results from the SiC matrix not being cracked on fabrication. In addition, the structure exhibits damage tolerance under impact with projectiles, showing no penetration to the back face sheet. These attributes make the composite ideal for leading-edge structures and control surfaces in aerospace vehicles, as well as for acreage thermal protection systems and in high-temperature, lightweight stiffened structures. By tailoring the coefficient of thermal expansion (CTE) of a carbon fiber containing ceramic matrix composite (CMC) face sheet to match that of a ceramic foam core, the face sheet and the core can be integrally fabricated without any delamination. Carbon and SiC are woven together in the reinforcing fabric. Integral densification of the CMC and the foam core is accomplished with chemical vapor deposition, eliminating the need for bond-line adhesive. This means there is no need to separately fabricate the core and the face sheet, or to bond the two elements together, risking edge delamination during use. Fibers of two or more types are woven together on a loom. The carbon and ceramic fibers are pulled into the same "pick" location during the weaving process. Tow spacing may be varied to accommodate the increased volume of the combined fiber tows while maintaining a target fiber volume fraction in the composite. Foam pore size, strut thickness, and ratio of face sheet to core thickness can be used to tailor thermal and mechanical properties. The anticipated CTE for the hybridized composite is managed by the choice of constituents, varying fiber tow sizes and constituent part ratios. This structural concept provides high strength and stiffness at low density 1.06 g/cu cm in panels tested. Varieties of face sheet constructions are possible, including variations in fiber type and weave geometry. The integrated structures possible with this composite could eliminate the need for non-load-bearing thermal protection systems on top of a structural component. The back sheet can readily be integrated to substructures through the incorporation of ribs. This would eliminate weight and cost for aerospace missions.

Goudy, Jerry↗
NASA NTRS2004

Composite-Material Tanks with Chemically Resistant Liners

Lightweight composite-material tanks with chemically resistant liners have been developed for storage of chemically reactive and/or unstable fluids . especially hydrogen peroxide. These tanks are similar, in some respects, to the ones described in gLightweight Composite-Material Tanks for Cryogenic Liquids h (MFS-31379), NASA Tech Briefs, Vol. 25, No. 1 (January, 2001), page 58; however, the present tanks are fabricated by a different procedure and they do not incorporate insulation that would be needed to prevent boil-off of cryogenic fluids. The manufacture of a tank of this type begins with the fabrication of a reusable multisegmented aluminum mandrel in the shape and size of the desired interior volume. One or more segments of the mandrel can be aluminum bosses that will be incorporated into the tank as end fittings. The mandrel is coated with a mold-release material. The mandrel is then heated to a temperature of about 400 F (approximately equal to 200 C) and coated with a thermoplastic liner material to the desired thickness [typically approxiamtely equal to 15 mils (approximately equal to 0.38 mm)] by thermal spraying. In the thermal-spraying process, the liner material in powder form is sprayed and heated to the melting temperature by a propane torch and the molten particles land on the mandrel. The sprayed liner and mandrel are allowed to cool, then the outer surface of the liner is chemically and/or mechanically etched to enhance bonding of a composite overwrap. The etched liner is wrapped with multiple layers of an epoxy resin reinforced with graphite fibers; the wrapping can be done either by manual application of epoxy-impregnated graphite cloth or by winding of epoxy-impregnated filaments. The entire assembly is heated in an autoclave to cure the epoxy. After the curing process, the multisegmented mandrel is disassembled and removed from inside, leaving the finished tank. If the tank is to be used for storing hydrogen peroxide, then the liner material should be fluorinated ethylene/propylene (FEP), and one or more FEP O ring(s) should be used in the aluminum end fitting(s). This choice of materials is dictated by experimental observations that pure aluminum and FEP are the only materials suitable for long-term storage of hydrogen peroxide and that other materials tend to catalyze the decomposition of hydrogen peroxide to oxygen and water. Other thermoplastic liner materials that are suitable for some applications include nylon 6 and polyethylene. The processing temperatures for nylon 6 are lower than those for FEP. Nylon 6 is compatible with propane, natural gas, and other petroleum-based fuels. Polyethylene is compatible with petroleum- based products and can be used for short-term storage of hydrogen peroxide.

DeLay, Thomas K.↗