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All sourcesNASA NTRSDOE OSTI
NASA NTRS1976

Orbit selection for the 1978 Pioneer Venus mission

The Pioneer Venus Orbiter will be launched by NASA in the spring of 1978. Selection of the orbit in July, 1975, resulted from scientific, mission, spacecraft, and operational considerations summarized by this paper. The orbit will be inclined 105 deg to the ecliptic, and its periapsis will lie between 16 and 28 deg north celestial latitude. Its periapsis altitude will be maintained between 150 and 260 km above the solid surface, and its period will be kept near 24 hr. This orbit and the spinning spacecraft's ecliptic-normal attitude permit the scientific coverage geometry of Venus, which also is summarized here.

Cowley, J. R., Jr.↗
NASA NTRS1978

The analysis of temporal variations in regional models of the Sargasso Sea from GEOS-3 altimetry

The dense coverage of short pulse mode GEOS-3 altimeter data in the western North Atlantic provides a basis for studying time variations in the sea surface heights in the Sargasso Sea. Two techniques are utilized: the method of regional models, and the analysis of overlapping passes. An 88 percent correlation is obtained between the location of cyclonic eddies obtained from infrared imagery and sea surface height minima in the altimeter models. This figure drops to 59 percent in the case of correlations with maxima and minima of surface temperature fields. The analysis of overlapping passes provides a better picture of instantaneous sea state through wavelengths greater than 30 km. The variability of the Sargasso Sea through wavelengths between 150 km and 5000 km is estimated at + or - 28 cm. This value is in reasonable agreement with oceanographic estimates and is compatible with the eddy kinetic energy of a wind driven circulation.

Mather, R. S.↗
NASA NTRS1995

Partitioning of ocean and land uptake of CO2 as inferred by delta C-13 measurements from the NOAA Climate Monitoring and Diagnostics Laboratory Global Air Sampling Network

Using delta C-13 measurements in atmospheric CO2 from a cooperative global air sampling network, we determined the partitioning of the net uptake of CO2 between ocean and land as a function of latitude and time. The majority of delta C-13 measurements were made at the Institute of Arctic and Alpine Research (INSTAAR) of the University of Colorado. We perform an inverse deconvolution of both CO2 and delta C-13 observations, using a two-dimensional model of atmospheric transport. Also, the discrimination against C-13 by plant photosynthesis, as a function of latitude and time, is calculated from global runs of the simple biosphere (SiB) model. Uncertainty due to the longitudinal structure of the data, which is not represented by the model, is studied through a bootstrap analysis by adding and omitting measurement sites. The resulting error estimates for our inferred sources and sinks are of the order of 1 GTC (1 GTC = 10(exp 15) gC). Such error bars do not reflect potential systematic errors arising from our estimates of the isotopic disequilibria between the atmosphere and the oceans and biosphere, which are estimated in a separate sensitivity analysis. With respect to global totals for 1992 we found that 3.2 GTC of carbon dissolved into the ocean and that 1.5 GTC were sequestered by land ecosystems. Northern hemisphere ocean gyres north of 15 deg N absorbed 2.7 GTC. The equatorial oceans between 10 deg S and 10 deg N were a net source to the atmosphere of 0.9 GTC. We obtained a sink of 1.6 GTC in southern ocean gyres south of 20 deg S, although the deconvolution is poorly constrained by sparse data coverage at high southern latitudes. The seasonal uptake of CO2 in the northern gyres appears to be correlated with a bloom of phytoplankton in surface waters. On land, northern temperate and boreal ecosystems between 35 deg N and 65 deg N were found to be a major sink of CO2 in 1992, as large as 3.5 GTC. Northern tropical ecosystems (equator-30 deg N) appear to be a net source to the source to the atmosphere of 2 GTC which could reflect biomass burning. A small sink, 0.3 GTC, was inferred for southern tropical ecosystems (30 deg S-equator).

Ciais, Philippe↗
NASA NTRS2002

New Insights on Hydro-Climate Feedback Processes over the Tropical Ocean from TRMM

In this paper, we study hydro-climate feedback processes over the tropical oceans, by examining the relationships among large scale circulation and Tropical Rainfall Measuring Mission Microwave Imager-Sea Surface Temperature (TMI-SST), and a range of TRMM rain products including rain rate, cloud liquid water, precipitable water, cloud types and areal coverage, and precipitation efficiency. Results show that for a warm event (1998), the 28C threshold of convective precipitation is quite well defined over the tropical oceans. However, for a cold event (1999), the SST threshold is less well defined, especially over the central and eastern Pacific cold tongue, where stratiform rain occurs at much lower than 28 C. Precipitation rates and cloud liquid water are found to be more closely related to the large scale vertical motion than to the underlying SST. While total columnar water vapor is more strongly dependent on SST. For a large domain, over the eastern Pacific, we find that the areal extent of the cloudy region tends to shrink as the SST increases. Examination of the relationship between cloud liquid water and rain rate suggests that the residence time of cloud liquid water tends to be shorter, associated with higher precipitation efficiency in a warmer climate. It is hypothesized that the reduction in cloudy area may be influenced both by the shift in large scale cloud patterns in response to changes in large scale forcings, and possible increase in the cloud liquid water conversion to rain water in a warmer environment. Results of numerical experiments with the Goddard cloud resolving model to test the hypothesis will be discussed.

Lau, William K. M.↗
NASA NTRS2021

Assessment of the Advanced Very High Resolution Radiometer (AVHRR) for Snowfall Retrieval in High Latitudes Using CloudSat and Machine Learning

Precipitation retrieval is a challenging topic, especially in high latitudes (HL), and current precipitation products face ample challenges over these regions. This study investigates the potential of the Advanced Very High Resolution Radiometer (AVHRR) for snowfall retrieval in HL using CloudSat radar information and machine learning (ML). With all the known limitations, AVHRR observations should be considered for HL snowfall retrieval because 1) AVHRR data have been continuously collected for about four decades on multiple platforms with global coverage, and similar observations will likely continue in the future; 2) current passive microwave satellite precipitation products have several issues over snow and ice surfaces; and 3) good coincident observations between AVHRR and CloudSat are available for training ML algorithms. Using ML, snowfall rate was retrieved from AVHRR’s brightness temperature and cloud probability, as well as auxiliary information provided by numerical reanalysis. The results indicate that the ML-based retrieval algorithm is capable of detection and estimation of snowfall with comparable or better statistical scores than those obtained from the Atmospheric Infrared Sounder (AIRS) and two passive microwave sensors contributing to the Global Precipitation Measurement (GPM) mission constellation. The outcomes also suggest that AVHRR-based snowfall retrievals are spatially and temporally reasonable and can be considered as a quantitatively useful input to the merged precipitation products that require frequent sampling or long-term records.

Mohammad Reza↗
NASA NTRS1990

Calorimetry, activity, and micro-FTIR analysis of CO chemisorption, titration, and oxidation on supported Pt

The value of in situ analysis on CO chemisorption, titration and oxidation over supported Pt catalysts using calorimetry, catalytic and micro-FTIR methods is illustrated using silica- and titania-supported samples. Isothermal CO-O and O2-CO titrations have not been widely used on metal surfaces and may be complicated if some oxide supports are reduced by CO titrant. However, they can illuminate the kinetics of CO oxidation on metal/oxide catalysts since during such titrations all O and CO coverages are scanned as a function of time. There are clear advantages in following the rates of the catalyzed CO oxidation via calorimetry and gc-ms simultaneously. At lower temperatures the evidence they provide is complementary. CO oxidation and its catalysis of CO oxidation have been extensively studied with hysteresis and oscillations apparent, and the present results suggest the benefits of a combined approach. Silica support porosity may be important in defining activity-temperature hysteresis. FTIR microspectroscopy reveals the chemical heterogeneity of the catalytic surfaces used; it is interesting that the evidence with regard to the dominant CO surface species and their reactivities with regard to surface oxygen for present oxide-supported Pt are different from those seen on graphite-supported Pt.

Sermon, Paul A.↗
DOE OSTI2020

Enhanced Nanostructure Dynamics on Au(111) with Adsorbed Sulfur due to Au–S Complex Formation

Chemisorbed species can enhance the fluxional dynamics of nanostructured metal surfaces which has implications for applications such as catalysis. Scanning tunneling microscopy studies at room temperature reveal that the presence of adsorbed sulfur (S) greatly enhances the decay rate of 2D Au islands in the vicinity of extended step edges on Au(111). This enhancement is already significant at S coverages, θS, of a few hundredths of a monolayer (ML), and is most pronounced for 0.1–0.3 ML where the decay rate is increased by a factor of around 30. For θ S close to saturation at about 0.6 ML, sulfur induces pitting and reconstruction of the entire surface, and Au islands are stabilized. Enhanced coarsening at lower θS is attributed to the formation and diffusion across terraces of Au–S complexes, particularly AuS 2 and Au4S 4 , with some lesser contribution from Au3S4. This picture is supported by density functional theory analysis of complex formation energies and diffusion barriers.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Kinetics and selectivity of methane oxidation on an IrO 2 (110) film

Undercoordinated, bridging O-atoms (O br ) are highly active as H-acceptors in alkane dehydrogenation on IrO 2 (110) surfaces but transform to HO br groups that are inactive toward hydrocarbons. The low C–H activity and high stability of the HO br groups cause the kinetics and product selectivity during CH 4 oxidation on IrO 2 (110) to depend sensitively on the availability of O br atoms prior to the onset of product desorption. From temperature programmed reaction spectroscopy (TPRS) and kinetic simulations, we identified two O br -coverage regimes that distinguish the kinetics and product formation during CH 4 oxidation on IrO 2 (110). Under excess O br conditions, when the initial O br coverage is greater than that needed to oxidize all the CH 4 to CO 2 and HO br groups, complete CH 4 oxidation is dominant and produces CO 2 in a single TPRS peak between 450 and 500 K. However, under O br -limited conditions, nearly all the initial O br atoms are deactivated by conversion to HO br or abstracted after only a fraction of the initially adsorbed CH 4 oxidizes to CO 2 and CO below 500 K. Thereafter, some of the excess CH x groups abstract H and desorb as CH 4 above ~500 K while the remainder oxidize to CO 2 and CO at a rate that is controlled by the rate at which Obr atoms are regenerated from HObr during the formation of CH 4 and H 2 O products. We also show that chemisorbed O-atoms ('on-top O') on IrO 2 (110) enhance CO 2 production below 500 K by efficiently abstracting H from Obr atoms and thereby increasing the coverage of O br atoms available to completely oxidize CH x groups at low temperature. Furthermore, our results provide new insights for understanding factors which govern the kinetics and selectivity during CH 4 oxidation on IrO 2 (110) surfaces.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS2004

Libration Point Navigation Concepts Supporting Exploration Vision

Farquhar described several libration point navigation concepts that would appear to support NASA s current exploration vision. One concept is a Lunar Relay Satellite operating in the vicinity of Earth-Moon L2, providing Earth-to-lunar far-side and long- range surface-to-surface navigation and communications capability. Reference [ 1] lists several advantages of such a system in comparison to a lunar orbiting relay satellite constellation. Among these are one or two vs. many satellites for coverage, simplified acquisition and tracking due to very low relative motion, much longer contact times, and simpler antenna pointing. An obvious additional advantage of such a system is that uninterrupted links to Earth avoid performing critical maneuvers "in the blind." Another concept described is the use of Earth-Moon L1 for lunar orbit rendezvous, rather than low lunar orbit as was done for Apollo. This rendezvous technique would avoid large plane change and high fuel cost associated with high latitude landing sites and long stay times. Earth-Moon L1 also offers unconstrained launch windows from the lunar surface. Farquhar claims this technique requires only slightly higher fuel cost than low lunar orbit rendezvous for short-stay equatorial landings. Farquhar also describes an Interplanetary Transportation System that would use libration points as terminals for an interplanetary shuttle. This approach would offer increased operational flexibility in terms of launch windows, rendezvous, aborts, etc. in comparison to elliptical orbit transfers. More recently, other works including Folta[3] and Howell[4] have shown that patching together unstable trajectories departing Earth-Moon libration points with stable trajectories approaching planetary libration points may also offer lower overall fuel costs than elliptical orbit transfers. Another concept Farquhar described was a Deep Space Relay at Earth-Moon IA and/or L5 that would serve as a high data rate optical navigation and communications relay satellite. The advantages in comparison to a geosynchronous relay are minimal Earth occultation, distance from large noise sources on Earth, easier pointing due to smaller relative velocity, and a large baseline for interferometry if both L4 and L5 are used.

Carpenter, J. Russell↗
NASA NTRS2013

Radial Internal Material Handling System (RIMS) for Circular Habitat Volumes

On planetary surfaces, pressurized human habitable volumes will require a means to carry equipment around within the volume of the habitat, regardless of the partial gravity (Earth, Moon, Mars, etc.). On the NASA Habitat Demonstration Unit (HDU), a vertical cylindrical volume, it was determined that a variety of heavy items would need to be carried back and forth from deployed locations to the General Maintenance Work Station (GMWS) when in need of repair, and other equipment may need to be carried inside for repairs, such as rover parts and other external equipment. The vertical cylindrical volume of the HDU lent itself to a circular overhead track and hoist system that allows lifting of heavy objects from anywhere in the habitat to any other point in the habitat interior. In addition, the system is able to hand-off lifted items to other material handling systems through the side hatches, such as through an airlock. The overhead system consists of two concentric circle tracks that have a movable beam between them. The beam has a hoist carriage that can move back and forth on the beam. Therefore, the entire system acts like a bridge crane curved around to meet itself in a circle. The novelty of the system is in its configuration, and how it interfaces with the volume of the HDU habitat. Similar to how a bridge crane allows coverage for an entire rectangular volume, the RIMS system covers a circular volume. The RIMS system is the first generation of what may be applied to future planetary surface vertical cylinder habitats on the Moon or on Mars.

Howe, Alan S.↗
NASA NTRS1993

Lunar rover navigation concepts

With regard to the navigation of mobile lunar vehicles on the surface, candidate techniques are reviewed and progress of simulations and experiments made up to now are described. Progress that can be made through precursor investigations on Earth is considered. In the early seventies the problem was examined in a series of relevant tests made in the California desert. Meanwhile, Apollo rovers made short exploratory sorties and robotic Lunokhods traveled over modest distances on the Moon. In these early missions some of the required methods were demonstrated. The navigation problem for a lunar traverse can be viewed in three parts: to determine the starting point with enough accuracy to enable the desired mission; to determine the event sequence required to reach the site of each traverse objective; and to redetermine actual positions enroute. The navigator's first tool is a map made from overhead imagery. The Moon was almost completely photographed at moderate resolution by spacecraft launched in the sixties, but that data set provides imprecise topographic and selenodetic information. Therefore, more advanced orbital missions are now proposed as part of a resumed lunar exploration program. With the mapping coverage expected from such orbiters, it will be possible to use a combination of visual landmark navigation and external radio and optical references (Earth and Sun) to achieve accurate surface navigation almost everywhere on the near side of the Moon. On the far side and in permanently dark polar areas, there are interesting exploration targets where additional techniques will have to be used.

Burke, James D.↗
NASA NTRS1973

The International Planetary Patrol Program - An assessment of the first three years.

Day-to-day and hour-to-hour changes in the large-scale atmospheric and surface features of the planets can now be studied more effectively than previously possible. Since 1969 a network of observatories has obtained almost uninterrupted photographic coverage during all apparitions of Jupiter and Mars, plus some of Venus. Patrol films and catalogs are available to the scientific community. Recent or current analyses include the distribution and motion of clouds on Mars, the development and decay of Martian dust storms, the seasonal, diurnal, and random fluctuations in contrast between adjacent light and dark regions on Mars, the detection of vertical shear in the Jovian atmosphere, the longitudinal oscillation of the Red Spot, the dependence of rotation period on xenographic latitude and on time, the eruption and spread of south equatorial belt disturbances, and the retrograde circulation of the Venus cloud deck.

Baum, W. A.↗
NASA NTRS1979

Multispectral Resource Sampler - An experimental satellite sensor for the mid-1980s

An experimental pushbroom scan sensor, the Multispectral Resource Sampler (MRS), being developed by NASA for a future earth orbiting flight is presented. This sensor will provide new earth survey capabilities beyond those of current sensor systems, with a ground resolution of 15 m over a swath width of 15 km in four bands. The four arrays are aligned on a common focal surface requiring no beamsplitters, thus causing a spatial separation on the ground which requires computer processing to register the bands. Along track pointing permits stereo coverage at variable base/height ratios and atmospheric correction experiments, while across track pointing will provide repeat coverage, from a Landsat-type orbit, of every 1 to 3 days. The MRS can be used for experiments in crop discrimination and status, rock discrimination, land use classification, and forestry.

Schnetzler, C. C.↗
NASA NTRS1991

Satellite orbit considerations for a global change technology architecture trade study

A study was conducted to determine satellite orbits for earth observation missions aimed at obtaining data for assessing data global climate change. A multisatellite system is required to meet the scientific requirements for temporal coverage over the globe. The best system consists of four sun-synchronous satellites equally spaced in local time of equatorial crossing. This system can obtain data every three hours for all regions. Several other satellite systems consisting of combinations of sun-synchronous orbits and either the Space Station Freedom or a mid-altitude equatorial satellite can provide three to six hour temporal coverage, which is sufficient for measuring many of the parameters required for the global change monitoring mission. Geosynchronous satellites are required to study atmospheric and surface processes involving variations on the order of a few minutes to an hour. One or two geosynchronous satellites can be relocated in longitude to study processes over selected regions of earth.

Harrison, Edwin F.↗
NASA NTRS1991

Satellite orbit considerations for a global change technology architecture trade study

A study was conducted to determine satellite orbits for Earth observation missions aimed at obtaining data for assessing global climate change. A multisatellite system is required to meet the scientific requirements for temporal coverage over the globe. The best system consists of four Sun-synchronous satellites equally spaced in local time of equatorial crossing. This system can obtain data every three hours for all regions. Several other satellite systems consisting of combinations of Sun-synchronous orbits and either the Space Station Freedom or a mid-latitude equatorial satellite can provide three to six hour temporal coverage, which is sufficient for measuring many of the parameters required for the global change monitoring mission. Geosynchronous satellites are required to study atmospheric and surface processes involving variations on the order of a few minutes to an hour. Two or more geosynchronous satellites can be relocated in longitude to study processes over selected regions of Earth.

Harrison, Edwin F.↗
NASA NTRS1998

Prototype Local Data Integration System and Central Florida Data Deficiency

This report describes the Applied Meteorology Unit's (AMU) task on the Local Data Integration System (LDIS) and central Florida data deficiency. The objectives of the task are to identify all existing meteorological data sources within 250 km of the Kennedy Space Center (KSC) and the Eastern Range at Cape Canaveral Air Station (CCAS), identify and configure an appropriate LDIS to integrate these data, and implement a working prototype to be used for limited case studies and data non-incorporation (DNI) experiments. The ultimate goal for running LDIS is to generate products that may enhance weather nowcasts and short-range (less than 6 h) forecasts issued in support of the 45th Weather Squadron (45 WS), Spaceflight Meteorology Group (SMG), and the Melbourne National Weather Service (NWS MLB) operational requirements. The LDIS has the potential to provide added value for nowcasts and short term forecasts for two reasons. First, it incorporates all data operationally available in east central Florida. Second, it is run at finer spatial and temporal resolutions than current national-scale operational models. In combination with a suitable visualization tool, LDIS may provide users with a more complete and comprehensive understanding of evolving fine-scale weather features than could be developed by individually examining the disparate data sets over the same area and time. The utility of LDIS depends largely on the reliability and availability of observational data. Therefore, it is important to document all existing meteorological data sources around central Florida that can be incorporated by it. Several factors contribute to the data density and coverage over east central Florida including the level in the atmosphere, distance from KSC/CCAS, time, and prevailing weather. The central Florida mesonet consists of existing surface meteorological and hydrological data available from the Tampa NWS and data servers at Miami and Jacksonville. However the utility of these data for operational use is limited, mainly because there are relatively few additional meteorological observations within 50 km of KSC/CCAS to supplement existing METAR and KSC/CCAS tower reports.

Manobianco, John↗
NASA NTRS2011

Thermodynamics of the Solar Corona and Evolution of the Solar Magnetic Field as Inferred from the Total Solar Eclipse Observations of 11 July 2010

We report on multi-wavelength observations of the corona taken simultaneously in broadband white light, and in seven spectral lines, H-alpha 656.3 nm, Fe IX 435.9 nm, Fe X 637.4 nm, Fe XI 789.2 nm, Fe XIII 1074.7 nm, Fe XIV 530.3 nm and Ni XV 670.2 nm. The observations were made during the total solar eclipse of 11 July 2010 from the atoll of Tatakoto in French Polynesia. Simultaneous imaging with narrow bandpass filters in each of these spectral lines and in their corresponding underlying continua maximized the observing time during less than ideal observing conditions and yielded outstanding quality data. The application of two complementary image processing techniques revealed the finest details of coronal structures at 1" resolution in white light, and 6.5" in each of the spectral lines. This comprehensive wavelength coverage confirmed earlier eclipse findings that the solar corona has a clear two-temperature structure: The open field lines, expanding outwards from the solar surface, are characterized by electron temperatures near 1 X 10(exp 6) K, while the hottest plasma around 2X 10(exp 6) K resides in loop-like structures forming the bulges of streamers. The first images of the corona in the forbidden lines of Fe IX and Ni XV, showed that there was very little coronal plasma at temperatures below 5 X 10(exp 5) K and above 2.5X 10(exp 6) K. The data also enabled temperature differentiations as low as 0:2 X 10(exp 6) K in different density structures. These observations showed how the passage of CMEs through the corona, prior to totality, produced large scale ripples and very sharp streaks, which could be identified with distinct temperatures for the first time. The ripples were most prominent in emission from spectral lines associated with temperatures around 10(exp 6) K. The most prominent streak was associated with a conical-shaped void in the emission from the coolest line of Fe IX and from the hottest line of Ni XV. A prominence, which erupted prior to totality, appeared in the shape of a hook in the cooler lines of Fe X and Fe XI, spanning 0.5 R(solar) in extent starting at a heliocentric distance of 1.3 R(solar), with a complex trail of hot and cool twisted structures connecting it to the solar surface. Simultaneous Fe X 17.4 nm observations from space by Proba2/SWAP provided an ideal opportunity for comparing emission from a coronal forbidden line, namely Fe X 637.4 nm, with a space-based EUV allowed line. Comparison of the Fe X 17.4 nm and 637.4 nm emission provided the first textbook example of the role of radiative excitation in extending the detectability of coronal emission to much larger heliocentric distances than its collisionally excited component. These eclipse observations demonstrate the unique capabilities of coronal forbidden lines for exploring the evolution of the coronal magnetic field in the heliocentric distance range of 1 - 3 R(solar), which is currently inaccessible to any space-borne or ground-based observatory.

Habbal, Shadia Rifai↗
NASA NTRS2012

Monitoring Ocean CO2 Fluxes from Space: GOSAT and OCO-2

The ocean is a major component of the global carbon cycle, emitting over 330 billion tons of carbon dioxide (CO2) into the atmosphere each year, or about 10 times that emitted fossil fuel combustion and all other human activities [1, 2]. The ocean reabsorbs a comparable amount of CO2 each year, along with ~25% of the CO2 emitted by these human activities. The nature and geographic distribution of the processes controlling these ocean CO2 fluxes are still poorly constrained by observations. A better understanding of these processes is essential to predict how this important CO2 sink may evolve as the climate changes.While in situ measurements of ocean CO2 fluxes can be very precise, the sampling density is far too sparse to quantify ocean CO2 sources and sinks over much of the globe. One way to improve the spatial resolution, coverage, and sampling frequency is to make observations of the column averaged CO2 dry air mole fraction, XCO2, from space [4, 5, 6]. Such measurements could provide global coverage at high resolution (< 100 km) on monthly time scales. High precision (< 1 part per million, ppm) is essential to resolve the small, near-surface CO2 variations associated with ocean fluxes and to better constrain the CO2 transport over the ocean. The Japanese Greenhouse gases Observing Satellite (GOSAT) and the NASA Orbiting Carbon Observatory (OCO) were first two space based sensors designed specifically for this task. GOSAT was successfully launched on January 23, 2009, and has been returning measurements of XCO2 since April 2009. The OCO mission was lost in February 2009, when its launch vehicle malfunctioned and failed to reach orbit. In early 2010, NASA authorized a re-flight of OCO, called OCO-2, which is currently under development.

GOSAT↗