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At least 1,189 records · Page 66
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Clusters of Regional Precipitation Seasonality Change in the Community Earth System Model, Version 2

Abstract The likely changes to precipitation seasonality with warming are both impactful and not well understood. This work aims to describe areas that experience similar changes to seasonal precipitation irrespective of the original underlying precipitation seasonality. We train a self-organizing map on the difference between the seasonal cycle of precipitation in the past and in a high-warming future climate as represented by the Community Earth System Model, version 2, to create regions with similar changes in precipitation seasonality. This method is applied separately over land and ocean surfaces because of the differing processes leading to precipitation over each. This method indicates that future changes in seasonal precipitation are most varied in the tropics because of a southward shift in the intertropical convergence zone. The seasonal shifts found over midlatitude oceans indicate a poleward shift in atmospheric river activity. We find a correspondence between certain land-based precipitation changes and Köppen climate classification. The seasonality of large-scale and convective precipitation is examined for each region. The relationship between the seasonal changes to precipitation and associated atmospheric processes is discussed. These processes include atmospheric rivers, the intertropical convergence zone, tropical cyclones, and monsoons.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2012

One Step Biomass Gas Reforming-Shift Separation Membrane Reactor

GTI developed a plan where efforts were concentrated in 4 major areas: membrane material development, membrane module development, membrane process development, and membrane gasifier scale-up. GTI assembled a team of researchers to work in each area. Task 1.1 Ceramic Membrane Synthesis and Testing was conducted by Arizona State University (ASU), Task 1.2 Metallic Membrane Synthesis and Testing was conducted by the U.S. National Energy Technology Laboratory (NETL), Task 1.3 was conducted by SCHOTT, and GTI was to test all membranes that showed potential. The initial focus of the project was concentrated on membrane material development Metallic and glass-based membranes were identified as hydrogen selective membranes under the conditions of the biomass gasification, temperatures above 700C and pressures up to 30 atmospheres Membranes were synthesized by arc-rolling for metallic type membranes and incorporating Pd into a glass matrix for glass membranes.

08 HYDROGEN↗
NASA NTRS1993

Cognitive factors associated with immersion in virtual environments

Immersion into the dataspace provided by a computer, and the feeling of really being there or 'presence', are commonly acknowledged as the uniquely important features of virtual reality environments. How immersed one feels appears to be determined by a complex set of physical components and affordances of the environment, and as yet poorly understood psychological processes. Pimentel and Teixeira say that the experience of being immersed in a computer-generated world involves the same mental shift of 'suspending your disbelief for a period of time' as 'when you get wrapped up in a good novel or become absorbed in playing a computer game'. That sounds as if it could be right, but it would be good to get some evidence for these important conclusions. It might be even better to try to connect these statements with theoretical positions that try to do justice to complex cognitive processes. The basic precondition for understanding Virtual Reality (VR) is understanding the spatial representation systems that localize our bodies or egocenters in space. The effort to understand these cognitive processes is being driven with new energy by the pragmatic demands of successful virtual reality environments, but the literature is largely sparse and anecdotal.

Psotka, Joseph↗
NASA NTRS2009

Parallel-Processing CMOS Circuitry for M-QAM and 8PSK TCM

There has been some additional development of parts reported in "Multi-Modulator for Bandwidth-Efficient Communication" (NPO-40807), NASA Tech Briefs, Vol. 32, No. 6 (June 2009), page 34. The focus was on 1) The generation of M-order quadrature amplitude modulation (M-QAM) and octonary-phase-shift-keying, trellis-coded modulation (8PSK TCM), 2) The use of square-root raised-cosine pulse-shaping filters, 3) A parallel-processing architecture that enables low-speed [complementary metal oxide/semiconductor (CMOS)] circuitry to perform the coding, modulation, and pulse-shaping computations at a high rate; and 4) Implementation of the architecture in a CMOS field-programmable gate array.

Gray, Andrew↗
DOE OSTI2022

An energetics assessment of benzo[ a ]tetracene and benzo[ a ]pyrene as triplet–triplet annihilation emitters

Optical upconversion (UC) of low energy photons into high energy photons enables solar cells to harvest photons with energies below the band gap of the absorber, reducing the transmission loss. UC based on triplet–triplet annihilation (TTA) in organic chromophores can upconvert photons from sunlight, albeit with low conversion efficiency. We utilize three energy-based criteria to assess the UC potential of TTA emitters in terms of the quantum yield (QY) and the anti-Stokes shift. The energy loss in the singlet pathway of an emitter encounter complex, where a high energy photon is emitted, determines whether a chromophore may undergo TTA. The energy loss in the triplet pathway, which is the main competing process, impacts the TTA QY. The energy difference between the lowest singlet and triplet excitation states in TTA emitters sets an upper bound for the anti-Stokes shift of TTA-UC. Using the energetic criteria evaluated by time-dependent density functional theory (TDDFT) calculations, we find that benzo[a]tetracene, benzo[a]pyrene, and their derivatives are promising TTA emitters. The energetics assessment and computer simulations could be used to efficiently discover and design more candidate high-performance TTA emitters.

36 MATERIALS SCIENCE↗
DOE OSTI2025

A Unique Case of the “Goldilocks Rule” in Solid-State Electrolytes: Two Are Good, Four Are Too Many

We report the syntheses of two new series of methacrylate monomers with different backbones: ureidopyrimidinone (PU) and boron-substituted urea pyrimidine (U), which enhance both the mechanical and electrochemical properties of the solid-state electrolyte (SSE) while improving the cycle life of lithium iron phosphate (LiFePO 4 , LFP) cathodes. The PU backbone is characterized by four hydrogen bonds (H-bonds), while the U backbone bears only two. Importantly, our research reveals that two H-bonds in these monomers are optimal; in contrast, four are excessive. The exceptional mechanical properties and processability of the SSE with the U series additives, resulting from the optimal H-bonds, were unexpectedly achieved. This leads to the establishment of a “Goldilocks rule” for additive design. The key strategies include: 1) reducing hydrogen-bonding (H-bonding) sites by changing pyrimidinone to pyrimidine and 2) shifting from intermolecular to intramolecular H-bonding and π−π bonding. Furthermore, this reduction in H-bonding also offers significant advantages in processability. The advancement can be extended to electrode fabrication, making the manufacturing of all-solid-state batteries more practical and efficient.

hydrogen bonding↗
DOE OSTI2014

Cosmic muon flux measurements at the Kimballton Underground Research Facility

In this article, the results from a series of muon flux measurements conducted at the Kimballton Underground Research Facility (KURF), Virginia, United States, are presented. The detector employed for these investigations, is made of plastic scintillator bars readout by wavelength shifting fibers and multianode photomultiplier tubes. Data was taken at several locations inside KURF, spanning rock overburden values from ~ 200 to 1450 m.w.e. From the extracted muon rates an empirical formula was devised, that estimates the muon flux inside the mine as a function of the overburden. Furthermore, the results are in good agreement with muon flux calculations based on analytical models and MUSIC.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2012

Analysis of moire fringes by Wiener filtering: An extension to the Fourier method

In X-ray Talbot interferometry, tilting the phase grating with respect to the absorption grating results in the formation of spatial fringes. The analysis of this moire pattern, classically performed by the Fourier method, allows the extraction of the sample phase shift information from a single image. In this context, an extension to the Fourier method is proposed. The filter used to extract the fringe information is chosen optimally in the least-squares sense, given models for the zeroth and first order modes, noise and the modulation transfer function. The latter is obtained by measuring the detector response to moire fringes with increasing frequencies. The obtained Wiener filter allows a better reconstruction of the phase information at all fringe frequencies, compared to the usual box or gaussian filters. This is demonstrated quantitatively by experiments using synchrotron radiation.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2026

Dataset for Cruz-O'Byrne et al (2026): "Divergent biogeochemical responses in upland coastal forest soils to repeated flooding and shifts in water chemistry"

Hydrologic disturbances from accelerated sea-level rise and the increasing frequency and intensity of storms and tidal flooding are altering biogeochemical processes in upland coastal forests, transforming these ecosystems into wetlands. However, the initial effects of flooding on belowground biogeochemistry and the mechanisms driving greenhouse gas dynamics and soil organic matter stability during the early stages of this transition remain poorly understood. This dataset presents the results of a mesocosm experiment conducted in a controlled, highly instrumented laboratory environment, in which freshwater and brackish water pulses were applied to intact soil monoliths from a temperate upland coastal forest to examine how floodwater chemistry influences soil biogeochemistry and organo-mineral interactions. All data files are plain-text CSV (comma-separated value), and no special software is required to read them. Details about the content of each file are available in the document “Dataset_readme”. The dataset consists of the following data: • rcruzobyrne_moisture: Soil volumetric water content (VWC) • rcruzobyrne_GHG: Headspace greenhouse gas (GHG) concentration and fluxes • rcruzobyrne_methane_isotopes: Headspace methane isotope signature • rcruzobyrne_porewater: Porewater chemistry • rcruzobyrne_CDOM: Porewater colored dissolved organic matter (CDOM) • rcruzobyrne_FTIR: Soil Fourier-transform infrared (FTIR) spectroscopy Details of the experimental setup, data collection, and data analysis are provided in the manuscript by Cruz-O’Byrne et al (2026) Divergent biogeochemical responses in upland coastal forest soils to repeated flooding and shifts in water chemistry. Biogeochemistry. https://doi.org/10.1007/s10533-026-01340-0

EARTH SCIENCE > ATMOSPHERE > GREENHOUSE GAS↗
DOE OSTI2022

Waste to worth: A high-temperature water-gas shift magnetite catalyst with encapsulated core-shell structure from coal fly ash

In this paper, we demonstrate the synthesis of magnetite-based, encapsulated catalyst with a core-shell structure from coal fly ash, an industrial solid waste, and its application to industrially important high temperature water-gas shift reaction (HT-WGSR). The catalyst precursor was first synthesized through a leaching-precipitation-hydrothermal process, leading to the formation of a nanosheet-like hematite precursor consisting of Fe 3+ as primary element and minor cations including Al 3+ , Mg 2+ and other cations (e.g. Ca 2+ and Ti 4+ ). During the WGSR, the nanosheets broke into smaller particles with a core of magnetite with a diameter of ~20 nm, whereas the inherent impurity elements were activated and migrated to the outer surface forming a shell with a thickness of ~4 nm. Due to the protection of shell, the as-synthesized catalyst exhibited improved activity, thermal stability and long-term durability for HT-WGSR at 400 °C and 450 °C. Compared to the pure hematite, this catalyst exhibited much higher activity and stability, i.e., increased CO conversion and decreased deactivation rate constant, by a factor of four and three, respectively. Additionally, through a bottom-up reverse synthesis, we have confirmed that Al 3+ functioned as a textual promoter enhancing the interfacial area of the catalyst. On the other hand, the presence of minor impurity elements, in particular 2.58 wt% Mg 2+ and 0.18 wt% Ti 4+ , were found to increase the basicity, and promote the adsorption rate of CO, the redox of catalysts, and the alteration of the reaction mechanism from regenerative to associative with the formation of a strong intermediate formate. Finally, this study not only opens a new direction on the valorization of solid waste into high-value catalysts, promoting the sustainability of solid waste management, but also provides an alternative, cost-effective and scalable approach for the design and fine-tuning of encapsulated catalysts.

01 COAL, LIGNITE, AND PEAT↗
NASA NTRS2016

Measuring Solar Doppler Velocities in the He II 30.38 nm Emission Using the EUV Variability Experiment (EVE)

The EUV Variability Experiment (EVE) onboard the Solar Dynamics Observatory has provided unprecedented measurements of the solar EUV irradiance at high temporal cadence with good spectral resolution and range since May 2010. The main purpose of EVE was to connect the Sun to the Earth by providing measurements of the EUV irradianceas a driver for space weather and Living With a Star studies, but after launch the instrument has demonstrated the significance of its measurements in contributing to studies looking at the sources of solar variability for pure solar physics purposes. This paper expands upon previous findings that EVE can in fact measure wavelength shifts during solar eruptive events and therefore provide Doppler velocities for plasma at all temperatures throughout the solar atmosphere from the chromosphere to hot flaring temperatures. This process is not straightforward as EVE was not designed or optimized for these types of measurements. In this paper we describe the many detailed instrumental characterizations needed to eliminate the optical effects in order to provide an absolute baseline for the Doppler shift studies. An example is given of a solar eruption on 7 September 2011 (SOL2011-09-07), associated with an X1.2 flare, where EVE Doppler analysis shows plasma ejected from the Sun in the He II 30.38 nm emission at a velocity of almost 120 km s(exp -1) along the line-of-sight.

Chamberlin, Phillip Clyde↗
DOE OSTI2018

Copper-dependent amino oxidase 3 governs selection of metabolic fuels in adipocytes

Copper (Cu) has emerged as an important modifier of body lipid metabolism. However, how Cu contributes to the physiology of fat cells remains largely unknown. We found that adipocytes require Cu to establish a balance between main metabolic fuels. Differentiating adipocytes increase their Cu uptake along with the ATP7A-dependent transport of Cu into the secretory pathway to activate a highly up-regulated amino-oxidase copper-containing 3 (AOC3)/semicarbazide-sensitive amine oxidase (SSAO); in vivo, the activity of SSAO depends on the organism's Cu status. Activated SSAO oppositely regulates uptake of glucose and long-chain fatty acids and remodels the cellular proteome to coordinate changes in fuel availability and related downstream processes, such as glycolysis, de novo lipogenesis, and sphingomyelin/ceramide synthesis. The loss of SSAO-dependent regulation due to Cu deficiency, limited Cu transport to the secretory pathway, or SSAO inactivation shifts metabolism towards lipid-dependent pathways and results in adipocyte hypertrophy and fat accumulation. The results establish a role for Cu homeostasis in adipocyte metabolism and identify SSAO as a regulator of energy utilization processes in adipocytes.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2024

Strain shift measured from stress-controlled oscillatory shear: Evidence for a continuous yielding transition and new techniques to determine recovery rheology measures

Understanding the yielding of complex fluids is an important rheological challenge that affects our ability to engineer and process materials for a wide variety of applications. Common theoretical understandings of yield stress fluids follow the Oldroyd–Prager formalism in which the material behavior below the yield stress is treated as solidlike, and above the yield stress as liquidlike, with an instantaneous transition between the two states. This formalism was built on a quasi-static approach to the yield stress, while most applications, ranging from material processing to end user applications, involve a transient approach to yielding over a finite timescale. Using stress-controlled oscillatory shear experiments, we show that yield stress fluids flow below their yield stresses. This is quantified through measuring the strain shift, which is the value about which the strain oscillates during a stress-controlled test and is a function of only the unrecoverable strain. Measurements of the strain shift are, therefore, measurements of flow having taken place. These experimental results are compared to the Herschel–Bulkley form of the Saramito model, which utilizes the Oldroyd–Prager formalism, and the recently published Kamani–Donley–Rogers (KDR) model, in which one constitutive equation represents the entire range of material responses. Scaling relationships are derived, which allow us to show why yield stress fluids will flow across all stresses, above and below their yield stress. Finally, derivations are presented that show strain shift can be used to determine average metrics previously attainable only through recovery rheology, and these are experimentally verified.

Mechanics↗
DOE OSTI2025

Adoption of AI in the Utility T&D Sector: Use Cases, Consequence, Assessment and Benefits

Digital transformation and utilization of artificial intelligence (AI) in the electric grid are fundamentally changing the industry’s approach to common problems and enabling a broader paradigm shift in grid planning and operations. The change in approach is circularly both enabling and driving modernization, with load growth and reliable management of data center and AI infrastructure shifting away from planning approaches with relatively predictable behaviors and toward a mix of consumer and industrial choices that surpass human cognitive abilities to process. This movement has potential to condition humans to not understand the system on which the AI depends, while requiring it for development of the necessary infrastructure. Approaches which would address most likely grid conditions and events, such as faults, aging of equipment, and weather, now must also account for large loads which shift not based upon weather or time of day, but the computational load. Quantifying computational load is independent of the traditional grid forecasting variables, where a data center’s aggregate load is determined by user and AI system behavior and decoupled from normal grid planning and operations. AI is both the cause and solution for these challenges, with new grid planning tools integrating massive amounts of decisions into frameworks.

24 POWER TRANSMISSION AND DISTRIBUTION↗
NASA NTRS1987

Atmosphere dynamic processes structure at 80-105 km altitude

Determination of wind velocity by means of Doppler meteor radars is based on the assumption that an ionized meteor trail drifts together with the neutral atmosphere. From the Doppler frequency shift it is possible to estimate the radial velocity of the trail drift. Conversion of the recorded radial velocity to the true wind velocity vector in the given space region depends both on the radar technical parameters and the chosen atmospheric motion model. The atmospheric dynamic processes structure is considered.

Kalchenko, B. V.↗
DOE OSTI2013

Project Plan, Status, and Lessons Learned for the LANL 3,706 m{sup 3} TRU Waste Campaign - 13085

The Los Alamos National Laboratory (LANL) is currently engaged in a campaign to disposition 3,706 m{sup 3} of transuranic (TRU) waste stored above grade at its Technical Area 54 (TA-54) Area G waste management facility before June 30, 2014. This campaign includes complete removal of all non-cemented above-grade TRU waste that was in storage on October 1, 2011, and is defined as 3,706 m{sup 3} of material. TRU waste containers were placed into storage up to 40 years ago, and most of the older containers must be remediated to address compliance issues before the waste can be characterized, certified as meeting the Waste Isolation Pilot Plant (WIPP) Waste Acceptance Criteria (WAC), and shipped for disposition. More than half of the remaining TRU waste volume stored above grade is contained within oversize boxes that contain waste items that must be repackaged or size reduced. Facilities and major types of equipment needed to remediate and characterize the TRU waste inventory include two additional oversize box processing lines that are being brought into service as Nuclear Hazard Category III facilities in fiscal year (FY) 2013. Multiple work shifts are scheduled for most remediation lines in FY 2013. An integrated risk-based project management schedule for all disposition activities has been developed that is based on a 'Solution Package' approach. Inventories of containers that have issues in common were compiled into about 15 waste categories and about 75 'Solution Packages' that identify all of the activities needed to disposition the inventory of TRU waste in storage. Scheduled activities include all precursor activities to begin remediation, remediation processing, characterization and certification to the WIPP WAC, and shipping of containers to WIPP. Other industrial processing practices that have been adopted to improve efficiency include staging of containers for remediation, characterization, and shipping; establishment of a transportation center; and load management practices for transportation payloads. Progress and accomplishments during FY 2012 are reviewed, and plans for FY 2013 are presented in some detail. Lessons learned on adoption of industrial processing practices are also discussed. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2022

Geological activity shapes the microbiome in deep-subsurface aquifers by advection

Subsurface environments host diverse microorganisms in fluid-filled fractures; however, little is known about how geological and hydrological processes shape the subterranean biosphere. Here, we sampled three flowing boreholes weekly for 10 mo in a 1478-m-deep fractured rock aquifer to study the role of fracture activity (defined as seismically or aseismically induced fracture aperture change) and advection on fluid-associated microbial community composition. We found that despite a largely stable deep-subsurface fluid microbiome, drastic community-level shifts occurred after events signifying physical changes in the permeable fracture network. The community-level shifts include the emergence of microbial families from undetected to over 50% relative abundance, as well as the replacement of the community in one borehole by the earlier community from a different borehole. Null-model analysis indicates that the observed spatial and temporal community turnover was primarily driven by stochastic processes (as opposed to deterministic processes). We, therefore, conclude that the observed community-level shifts resulted from the physical transport of distinct microbial communities from other fracture(s) that outpaced environmental selection. Given that geological activity is a major cause of fracture activity and that geological activity is ubiquitous across space and time on Earth, our findings suggest that advection induced by geological activity is a general mechanism shaping the microbial biogeography and diversity in deep-subsurface habitats across the globe.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2011

Verification of the linac isocenter for stereotactic radiosurgery using cine-EPID imaging and arc delivery

Purpose:Verification of the mechanical isocenter position is required as part of comprehensive quality assurance programs for stereotactic radiosurgery/radiotherapy (SRS/SRT) treatments. Several techniques have been proposed for this purpose but each of them has certain drawbacks. In this paper, a new efficient and more comprehensive method using cine-EPID images has been introduced for automatic verification of the isocenter with sufficient accuracy for stereotactic applications. Methods: Using a circular collimator fixed to the gantry head to define the field, EPID images of a Winston-Lutz phantom were acquired in cine-imaging mode during 360 deg. gantry rotations. A robust matlab code was developed to analyze the data by finding the center of the field and the center of the ball bearing shadow in each image with sub-pixel accuracy. The distance between these two centers was determined for every image. The method was evaluated by comparison to results of a mechanical pointer and also by detection of a manual shift applied to the phantom position. The repeatability and reproducibility of the method were tested and it was also applied to detect couch and collimator wobble during rotation. Results:The accuracy of the algorithm was 0.03 {+-} 0.02 mm. The repeatability was less than 3 {mu}m and the reproducibility was less than 86 {mu}m. The time elapsed for the analysis of more than 100 cine images of Varian aS1000 and aS500 EPIDs were {approx}65 and 20 s, respectively. Processing of images taken in integrated mode took 0.1 s. The output of the analysis software is printable and shows the isocenter shifts as a function of angle in both in-plane and cross-plane directions. It gives warning messages where the shifts exceed the criteria for SRS/SRT and provides useful data for the necessary adjustments in the system including bearing system and/or room lasers. Conclusions: The comprehensive method introduced in this study uses cine-images, is highly accurate, fast, and independent of the observer. It tests all gantry angles and is suitable for pretreatment QA of the isocenter for stereotactic treatments.

62 RADIOLOGY AND NUCLEAR MEDICINE↗