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At least 1,189 records · Page 66

Atlas of high resolution infrared spectra of carbon dioxide

An atlas of long-path room-temperature absorption spectra of carbon dioxide is presented for the spectral intervals 1830-2100 cm, 2395-2680 cm, and 3140-3235 cm. The spectral data were recorded at high signal to noise with the 0.01 cm resolution Fourier transform interferometer. The spectra were obtained with pressures between 1 and 10 Torr of CO2 and with total paths between 24 and 384 meters. A compilation of the measured line positions and the assignments derived from the analysis are presented. Of the 3336 lines in the atlas, 94 percent were identified as CO2 lines or as residual lines H2O and CO. Calculated positions are presented for the carbon dioxide lines; a total of 52 bands of C-12O2-16, C-13O2-16, C-12O-16O-18, C-12O-16O-17, and C-13O-16O18 were identified. The weakest carbon dioxide lines marked in the atlas have intensities of approximately 0.5 x 10 to the negative 26th power cm/molecule at room temperature.

Rinsland, C. P.↗

Astronomy on a manned Mars mission

Three extra-solar-system astronomical experiments onboard a manned Mars mission are proposed. First, a modest, 50 cm aperture optical-ultraviolet-infrared telescope (or pair used as an interferometer) coupled with the Mars-Sun baseline would increase the number (by a factor of 3.4) and a volume of stars with accurately measured distances via stellar parallax and, therefore, greatly improve upon the cosmic distance scale; the darker sky at Mars would also provide nearly a full astronomical magnitude deeper images of distant and low brightness objects (limited by zodiacal light). Second, a gamma-ray burst detector coupled with similar detectors in other parts of the solar system will be used to reduce the position error boxes and to study the nature of these energetic sources. Third, the long baselines on a Mars mission radio interferometer will provide a view of the radio universe at unprescedented resolution, 4 x 10 to the minus 9th arcsec at 1 mm wavelength, which can potentially resolve the engine in nearby active galaxies. Each of these experiments is relatively inexpensive, taking advantage of the human presence for operation and maintenance, and the long Earth to Mars baseline.

Burns, Jack O.↗

Method of resolving radio phase ambiguity in satellite orbit determination

For satellite orbit determination, the most accurate observable available today is microwave radio phase, which can be differenced between observing stations and between satellites to cancel both transmitter- and receiver-related errors. For maximum accuracy, the integer cycle ambiguities of the doubly differenced observations must be resolved. To perform this ambiguity resolution, a bootstrapping strategy is proposed. This strategy requires the tracking stations to have a wide ranging progression of spacings. By conventional 'integrated Doppler' processing of the observations from the most widely spaced stations, the orbits are determined well enough to permit resolution of the ambiguities for the most closely spaced stations. The resolution of these ambiguities reduces the uncertainty of the orbit determination enough to enable ambiguity resolution for more widely spaced stations, which further reduces the orbital uncertainty. In a test of this strategy with six tracking stations, both the formal and the true errors of determining Global Positioning System satellite orbits were reduced by a factor of 2.

Councelman, Charles C., III↗

Resolution of seven-axis manipulator redundancy: A heuristic issue

An approach is presented for the resolution of the redundancy of a seven-axis manipulator arm from the AI and expert systems point of view. This approach is heuristic, analytical, and globally resolves the redundancy at the position level. When compared with other approaches, this approach has several improved performance capabilities, including singularity avoidance, repeatability, stability, and simplicity.

Chen, I.↗

Wavelength-multiplexed fiber-optic position encoder for aircraft control systems

NASA-Lewis has developed wavelength-multiplexed digital position fiber-optics transducers for use in aircraft control systems. A prototype LED-powered rotary encoder for a commercial aircraft turbofan engine is under construction which will have 8-bit resolution and an operational temperature in the 90 C range. A compact electrooptics module is also under development which will be able to withstand gas turbine environments. A second-generation device will incorporate integrated photonics technologies to increase optical power margin.

Beheim, Glenn↗

Precision Magnetic Bearing Six Degree of Freedom Stage

Magnetic bearings are capable of applying force and torque to a suspended object without rigidly constraining any degrees of freedom. Additionally, the resolution of magnetic bearings is limited only by sensors and control, and not by the finish of a bearing surface. For these reasons, magnetic bearings appear to be ideal for precision wafer positioning in lithography systems. To demonstrate this capability a linear magnetic bearing has been constructed which uses variable reluctance actuators to control the motion of a 14.5 kg suspended platen in five degrees of freedom. A Lorentz type linear motor of our own design and construction is used to provide motion and position control in the sixth degree of freedom. The stage performance results verify that the positioning requirements of photolithography can be met with a system of this type. This paper describes the design, control, and performance of the linear magnetic bearing.

Williams, M. E.↗

Strategies and Technologies for In Situ Mineralogical Investigations on Mars

Surface landers on Mars (Viking and Pathfinder) have not revealed satisfying answers to the mineralogy and lithology of the planet's surface. In part, this results from their prime directives: Viking focused on exobiology, Pathfinder focused on technology demonstration. The analytical instruments on board the landers made admirable attempts to extract the mineralogy and geology of Mars, as did countless modeling efforts after the missions. Here we suggest a framework for elucidating martian, or any other planetary geology, through an approach that defines (a) type of information required, (b) explorational strategy harmonious with acquisition of these data, (c) interpretation approach to the data, (d) compatible mission architecture, (e) instrumentation for interrogating rocks and soil. (a) Data required: The composition of a planet is ordered at scales ranging from molecules to minerals to rocks, and from geological units to provinces to planetary-scale systems. The largest ordering that in situ compositional instruments can attempt to interrogate is rock type "aggregate" information. This is what the geologist attempts to identify first. From this, mineralogy can be either directly seen or inferred. From mineralogy can be determined elemental abundances and perhaps the state of the compounds as being crystalline or amorphous. Knowledge of rock type and mineralogy is critical for elucidating geologic process. Mars landers acquired extremely valuable elemental data, but attempted to move from elements to aggregates, but this can only be done by making many assumptions and sometimes giant leaps of faith. Data we believe essential are elements, minerals, degree of ordering of compounds, and the aggregate or rock type that these materials compose. (b) Explorational strategy: A lander should function as a surrogate geologist. Of the total landscape, a geologist sees much, but gives detailed attention to an infinitesimally small amount of what is seen. To acquire samples worth detailed scrutiny, as many samples as possible need examining at a cursory or reconnaissance level. A representative, statistically-meaningful sample number cannot be overemphasized. This maxim still applies to geological exploration of our own planet of which we have abundant knowledge. Analysis of many samples mandates low-power consumption per sample. (c) Data interpretation: No single instrument can analyze the full spectrum of the x-axis. An instrument is optimized for detecting certain material characteristics and must therefore affix itself to some point on the x-axis. Any conclusions drawn about data to the left or right of the instrument's position on this axis must necessarily be derived by inference. Hence, it seems logical to include on a mission, instruments that are not closely spaced in their x-axis-position, and if only two analytical methods are used, as shown, they should start at opposite ends of the axis and work towards the center. As examples, we depict a high-resolution camera to evaluate rock type ("aggregate" state) and mineralogy, and an x-ray diffractometer-fluorescence spectrometer (XRD-XRF) to determine elements, minerals, and the degree of order of materials. (d) Mission architecture: No instrument or suite of instruments can be relied upon to always give truly unequivocal analyses. The suite of instruments should therefore permit conclusions of one instrument to be checked against those of another through closed analytical loops. These "loops" can be structured by a combination of orbital imagery, descent imagery, broad-band site viewing/analysis, and data that cover both x and y axes. For example, the detection of a basaltic-looking rock with a microscope should be checked against the elements detected, the appearance of the rock as a lava flow from descent imagery, and so forth. (e) Instrumentation: To satisfy the above criteria, it is necessary to: (i) See the rock or soil with high resolution + magnification, (ii) Examine many samples, (iii) Consume little power per analysis, (iv) Determine elemental species, (v) Determine mineralogy directly (not inferentially) and the degree of ordering of compounds, (vi) Start analyzing from both ends of the x-axis. Every geologist wants to see the hand sample first, and apply a hand lens to its surface. This has not been the starting point for missions to Mars. Thus, our technology satisfies all these criteria . This XRD-XRF-Optical instrument currently being developed, analyses rock or soil surfaces without the need for sample acquisition or preparation; this satisfies the power criterion, and enables many analyses. The device acquires direct mineralogy and determines elemental species. The embedded endoscopic camera satisfies the critical criterion of close inspection of samples; the fiber optic cable can also be used for IR, LTV, or laser sample analysis. Additional information is contained in the original (Figures).

Marshall, J. R.↗

New Applications for the Testing and Visualization of Wireless Networks

Traditional techniques for examining wireless networks use physical link characteristics such as Signal-to-Noise (SNR) ratios to assess the performance of wireless networks. Such measurements may not be reliable indicators of available bandwidth. This work describes two new software applications developed at NASA Glenn Research Center for the investigation of wireless networks. GPSIPerf combines measurements of Transmission Control Protocol (TCP) throughput with Global Positioning System (GPS) coordinates to give users a map of wireless bandwidth for outdoor environments where a wireless infrastructure has been deployed. GPSIPerfView combines the data provided by GPSIPerf with high-resolution digital elevation maps (DEM) to help users visualize and assess the impact of elevation features on wireless networks in a given sample area. These applications were used to examine TCP throughput in several wireless network configurations at desert field sites near Hanksville, Utah during May of 2004. Use of GPSIPerf and GPSIPerfView provides a geographically referenced picture of the extent and deterioration of TCP throughput in tested wireless network configurations. GPSIPerf results from field-testing in Utah suggest that it can be useful in assessing other wireless network architectures, and may be useful to future human-robotic exploration missions.

Griffin, Robert I.↗

Reconnection Onset in the Breakout Model for CME Initiation

Fast coronal mass ejections (CMEs) are the most massive explosions in the heliosphere, and the primary drivers of geoeffective space weather. Although it is generally agreed that magnetic reconnection is the key to fast CME initiation, different models incorporate reconnection in different ways. One promising model --- the breakout scenario --- involves reconnection in two distinct yet interconnected locations: breakout reconnection ahead of the CME, and flare reconnection behind it. We will discuss what we have learned about the early evolution of breakout and flare reconnection from recent high-resolution 2.5D adaptively refined MHD simulations of CME initiation, including the evolving properties of the breakout and flare current sheets, the conditions that trigger reconnection onset in each sheet, the ensuing positive feedback between breakout and flare reconnections, and implications for electron acceleration in flares.

Karpen, Judy T.↗

SCExAO/CHARIS Near-infrared Integral Field Spectroscopy of the HD 15115 Debris Disk

We present new, near-infrared (1.1–2.4 μm) high-contrast imaging of the debris disk around HD 15115 with the Subaru Coronagraphic Extreme Adaptive Optics (SCExAO) system coupled with the Coronagraphic High Angular Resolution Imaging Spectrograph (CHARIS). The SCExAO/CHARIS resolves the disk down to ρ ∼ 0."2 (r(proj) ∼ 10 au), a factor of ∼3–5 smaller than previous recent studies. We derive a disk position angle of PA ∼ 279.°4–280.°5 and an inclination of i ∼ 85.°3–86.2.°. While recent SPHERE/IRDIS imagery of the system could suggest a significantly misaligned two-ring disk geometry, CHARIS imagery does not reveal conclusive evidence for this hypothesis. Moreover, optimizing models of both one- and two-ring geometries using differential evolution, we find that a single ring having a Hong-like scattering phase function matches the data equally well within the CHARIS field of view (ρ ≲ 1''). The disk's asymmetry, well evidenced at larger separations, is also recovered; the west side of the disk appears, on average, around 0.4 mag brighter across the CHARIS bandpass between 0farcs25 and 1''. Comparing Space Telescope Imaging Spectrograph (STIS) 50CCD optical photometry (2000–10500 Å) with CHARIS near-infrared photometry, we find a red (STIS/50CCD−CHARIS broadband) color for both sides of the disk throughout the 0farcs4–1'' region of overlap, in contrast to the blue color reported at similar wavelengths for regions exterior to ∼2''. Further, this color may suggest a smaller minimum grain size than previously estimated at larger separations. Finally, we provide constraints on planetary companions and discuss possible mechanisms for the observed inner disk flux asymmetry and color.

Kellen Lawson↗

Technical Characteristics and Accuracy Capabilities of Delta Differential One-Way Ranging (DeltaDOR) as a Spacecraft Navigation Tool

The technique of determining spacecraft angular position by Delta Differential One-Way Ranging (DeltaDOR) is described. The dependence of measurement accuracy on parameters which define the spacecraft signal spectrum is shown. An illustration of DeltaDOR measurement accuracy, using the Mars Observer spacecraft, is presented. Guidelines for specifying spacecraft tone spectra are presented based on typical accuracy and ambiguity resolution needs, on frequency allocation for deep space tracking, on the efficient use of spacecraft signal power, and on the efficient use of ground tracking resources.

VLBI Very Long Baseline Interferometry DOR tones D↗

Design of a precision etalon position control system for a cryogenic spectrometer

The Upper Atmosphere Research Satellite (UARS) will be launched in 1988 to study the distribution of a series of trace elements in the upper atmosphere and to study atmospheric dynamics. The UARS carries on board a cryogenically cooled infrared spectrometer to measure the concentration of a series of chemical species that are important for understanding the ozone layer in the stratosphere. This device, known as the Cryogenic Limb Array Etalon Spectrometer (CLAES), uses a multiposition filter wheel combined with tilt-scanned Fabry Perot etalons to obtain the high resolution required for these experiments. The CLAES optical system is sealed in a dewar where it is maintained at cryogenic temperatures by a supply of solid hydrogen. Operating temperatures for CLAES range from 130 K at the entrance aperture to 13 K at the focal plane. The design and test of a special control system using a unique actuator concept to provide position and can control for the CLAES etalon are described. Results of performance tests at cryogenic temperatures simulating the CLAES on-orbit environment are discussed.

Aubrun, J. N.↗

High Resolution Spectroscopy to Support Atmospheric Measurements

The major research activities performed during the cooperative agreement enhanced our spectroscopic knowledge of molecules of atmospheric interest such as carbon dioxide, water vapor, ozone, methane, and carbon monoxide, to name a few. Measurements were made using the NASA Langley Tunable Diode Laser Spectrometer System (TDL) and several Fourier Transform Spectrometer Systems (FTS) around the globe. The results from these studies made remarkable improvements in the line positions and intensities for several molecules, particularly ozone and carbon dioxide in the 2 to 17-micrometer spectral region. Measurements of pressure broadening and pressure induced line shift coefficients and the temperature dependence of pressure broadening and pressure induced line shift coefficients for infrared transitions of ozone, methane, and water vapor were also performed. Results from these studies have been used for retrievals of stratospheric gas concentration profiles from data collected by several Upper Atmospheric Research satellite (UARS) infrared instruments as well as in the analysis of high resolution atmospheric spectra such as those acquired by space-based, ground-based, and various balloon-and aircraft-borne experiments. Our results made significant contributions in several updates of the HITRAN (HIgh resolution TRANsmission) spectral line parameters database. This database enjoys worldwide recognition in research involving diversified scientific fields.

Benner, D. Chris↗

High Resolution Spectroscopy to Support Atmospheric Measurements

The major research activities performed during the cooperative agreement enhanced our spectroscopic knowledge of molecules of atmospheric interest such as carbon dioxide, water vapor, ozone, methane, and carbon monoxide, to name a few. Measurements were made using the NASA Langley Tunable Diode Laser Spectrometer System (TDL) and several Fourier Transform Spectrometer Systems (FTS) around the globe. The results from these studies made remarkable improvements in the line positions and intensities for several molecules, particularly ozone and carbon dioxide in the 2 to 17-micrometer spectral region. Measurements of pressure broadening and pressure induced line shift coefficients and the temperature dependence of pressure broadening and pressure induced line shift coefficients for infrared transitions of ozone, methane, and water vapor were also performed. Results from these studies have been used for retrievals of stratospheric gas concentration profiles from data collected by several Upper Atmospheric Research satellite (UARS) infrared instruments as well as in the analysis of high resolution atmospheric spectra such as those acquired by space-based, ground-based, and various balloon- and aircraft-borne experiments. Our results made significant contributions in several updates of the HITRAN (HIgh resolution TRANsmission) spectral line parameters database. This database enjoys worldwide recognition in research involving diversified scientific fields.

Benner, D. Chris↗

Manifestation of quasi-biennial oscillation in ozone vertical distribution

The quasi-biennial oscillations (QBO) in ozone and temperature vertical distributions are studied on the basis of ozonesonde data of 21 stations. Maximum QBO amplitudes in ozone are noted in the 16-20 kn layer over Resolute (75N), Aspendale (38S) and in the northern mid-latitude band, but in the 20-24 km layer in the northern subtropical band. In the upper layers the QBO effect is less evident. In the tropospheric layer it is difficult to note the QBO-related effect in all the groups of the data. In all the layers where the QBO effect is noted the positive deviations precede, but the negative deviations follow the time of maximum of the easterly equatorial wind at 50 mb level. No essential differences in phase or amplitude characteristics of the ozone QBO were noted for the Aspendale data compared with that for the Northern Hemisphere data. The QBO-effect is not noted in the temperature data in the mid-latitudes. Above Resolute and in subtropics the ozone and temperature effects are roughly in phase each with other, except in the 28-32 km layer over subtropics, where they are opposite each to other.

Sitnov, Sergey A.↗

Solvent organization in the ultrahigh-resolution crystal structure of crambin at room temperature

Ultrahigh-resolution structures provide unprecedented details about protein dynamics, hydrogen bonding and solvent networks. The reported 0.70 Å, room-temperature crystal structure of crambin is the highest-resolution ambient-temperature structure of a protein achieved to date. Sufficient data were collected to enable unrestrained refinement of the protein and associated solvent networks using SHELXL . Dynamic solvent networks resulting from alternative side-chain conformations and shifts in water positions are revealed, demonstrating that polypeptide flexibility and formation of clathrate-type structures at hydrophobic surfaces are the key features endowing crambin crystals with extraordinary diffraction power.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

X-ray chemical imaging for assessing redox microsites within soils and sediments

Redox reactions underlie several biogeochemical processes and are typically spatiotemporally heterogeneous in soils and sediments. However, redox heterogeneity has yet to be incorporated into mainstream conceptualizations and modeling of soil biogeochemistry. Anoxic microsites, a defining feature of soil redox heterogeneity, are non-majority oxygen depleted zones in otherwise oxic environments. Neglecting to account for anoxic microsites can generate major uncertainties in quantitative assessments of greenhouse gas emissions, C sequestration, as well as nutrient and contaminant cycling at the ecosystem to global scales. However, only a few studies have observed/characterized anoxic microsites in undisturbed soils, primarily, because soil is opaque and microsites require µm-cm scale resolution over cm-m scales. Consequently, our current understanding of microsite characteristics does not support model parameterization. To resolve this knowledge gap, we demonstrate through this proof-of-concept study that X-ray fluorescence (XRF) 2D mapping can reliably detect, quantify, and provide basic redox characterization of anoxic microsites using solid phase “forensic” evidence. First, we tested and developed a systematic data processing approach to eliminate false positive redox microsites, i.e., artefacts, detected from synchrotron-based multiple-energy XRF 2D mapping of Fe (as a proxy of redox-sensitive elements) in Fe-“rich” sediment cores with artificially injected microsites. Then, spatial distribution of Fe II and Fe III species from full, natural soil core slices (over cm-m lengths/widths) were mapped at 1–100 µm resolution. These investigations revealed direct evidence of anoxic microsites in predominantly oxic soils such as from an oak savanna and toeslope soil of a mountainous watershed, where anaerobicity would typically not be expected. We also revealed preferential spatial distribution of redox microsites inside aggregates from oak savanna soils. We anticipate that this approach will advance our understanding of soil biogeochemistry and help resolve “anomalous” occurrences of reduced products in nominally oxic soils.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗