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Comparison Between Lidar and Nephelometer Measurements of Aerosol Hygroscopicity at the Southern Great Plains Atmospheric Radiation Measurement Site

Aerosol hygroscopicity has a significant effect on radiative properties of aerosols. Here a lidar method, applicable to cloud-capped, well-mixed atmospheric boundary layers, is employed to determine the hygroscopic growth factor f(RH) under unperturbed, ambient atmospheric conditions. The data used for the analysis were collected under a wide range of atmospheric aerosol levels during both routine measurement periods and during the intensive operations period (IOP) in May 2003 at the Southern Great Plains (SGP) Climate Research Facility in Oklahoma, USA, as part of the Atmospheric Radiation Measurement (ARM) program. There is a good correlation (approx. 0.7) between a lidar-derived growth factor (measured over the range 85% RH to 96% RH) with a nephelometer-derived growth factor measured over the RH range 40% to 85%. For these RH ranges, the slope of the lidar-derived growth factor is much steeper than that of the nephelometer-derived growth factor, reflecting the rapid increase in particle size with increasing RH. The results are corroborated by aerosol model calculations of lidar and nephelometer equivalent f(RH) based on in situ aerosol size and composition measurements during the IOP. It is suggested that the lidar method can provide useful measurements of the dependence of aerosol optical properties on relative humidity, and under conditions closer to saturation than can currently be achieved with humidified nephelometers.

Pahlow, M.↗

Enhancing Radiative Transfer Models for Optimized Assimilation of Microwave and Radar Observations

Radiative transfer models are extensively used for the assimilation of satellite observations into NWP models as well as retrieving geophysical products from satellite measurements. The Community Radiative Transfer Model (CRTM) is a community model developed by NOAA JCSDA and widely used for different purposes requiring RT calculations. CRTM requires bulk optical properties of hydrometeors in the form of lookup tables in order to perform all-sky RT calculations. However, the current cloud scattering lookup tables in CRTM assume spherical shapes for all frozen hydrometeors, whereas actual clouds contain frozen particles with diverse shapes. The first part of this talk presents the implementation and validation of a comprehensive Discrete Dipole Approximation (DDA) cloud scattering database into CRTM, specifically targeting microwave frequencies. The DDA technique proves effective in simulating the optical properties of non-spherical hydrometeors in the microwave region. The original DDA database assumes total random orientation in calculating single scattering properties. To generate the required mass scattering parameters for CRTM, the single scattering properties and water content dependent particle size distributions are used. The evaluation of results involved a collocated dataset comprising short-term forecasts from the Integrated Forecast System of the European Center for Medium-Range Weather Forecasts and satellite microwave data. The findings demonstrate that the DDA lookup tables significantly reduce discrepancies between simulated and observed values when compared to the Mie tables. Passive instruments lack the ability to provide vertically resolved measurements of clouds and precipitation, which can be obtained by active radar instruments. However, incorporating these active measurements into data assimilation systems presents challenges due to the absence of fast forward radiative transfer models and difficulties in error modeling. The second part of the talk focuses on the development, evaluation, and sensitivity analysis of a forward radar model integrated into CRTM. The forward radar model utilizes scattering properties obtained from hydrometeor lookup tables generated using the discrete dipole approximation. By utilizing CRTM instrument-specific coefficients, the model can calculate both reflectivity and attenuated reflectivity for any given radar instrument and zenith angles. Evaluation using CloudSat measurements demonstrates a strong agreement between simulations and observations when the input profiles of hydrometeors align with the measured reflectivity profiles.

Isaac Moradi↗

Optimizing Assimilation of Microwave and Radar Observations in the NWP Models

Radiative transfer models are extensively used for the assimilation of satellite observations into NWP models as well as retrieving geophysical products from satellite measurements. The Community Radiative Transfer Model (CRTM) is a community model developed by NOAA JCSDA and widely used for different purposes requiring RT calculations. CRTM requires bulk optical properties of hydrometeors in the form of lookup tables in order to perform all-sky RT calculations. However, the current cloud scattering lookup tables in CRTM assume spherical shapes for all frozen hydrometeors, whereas actual clouds contain frozen particles with diverse shapes. The first part of this talk presents the implementation and validation of a comprehensive Discrete Dipole Approximation (DDA) cloud scattering database into CRTM, specifically targeting microwave frequencies. The DDA technique proves effective in simulating the optical properties of non-spherical hydrometeors in the microwave region. The original DDA database assumes total random orientation in calculating single scattering properties. To generate the required mass scattering parameters for CRTM, the single scattering properties and water content dependent particle size distributions are used. The evaluation of results involved a collocated dataset comprising short-term forecasts from the Integrated Forecast System of the European Center for Medium-Range Weather Forecasts and satellite microwave data. The findings demonstrate that the DDA lookup tables significantly reduce discrepancies between simulated and observed values when compared to the Mie tables. Passive instruments lack the ability to provide vertically resolved measurements of clouds and precipitation, which can be obtained by active radar instruments. However, incorporating these active measurements into data assimilation systems presents challenges due to the absence of fast forward radiative transfer models and difficulties in error modeling. The second part of the talk focuses on the development, evaluation, and sensitivity analysis of a forward radar model integrated into CRTM. The forward radar model utilizes scattering properties obtained from hydrometeor lookup tables generated using the discrete dipole approximation. By utilizing CRTM instrument-specific coefficients, the model can calculate both reflectivity and attenuated reflectivity for any given radar instrument and zenith angles. Evaluation using CloudSat measurements demonstrates a strong agreement between simulations and observations when the input profiles of hydrometeors align with the measured reflectivity profiles.

Isaac Moradi↗

Assimilation of Spaceborne Microwave and Radar Observations

Radiative transfer models are extensively used for the assimilation of satellite observations into NWP models as well as retrieving geophysical products from satellite measurements. The Community Radiative Transfer Model (CRTM) is a community model developed by NOAA JCSDA and widely used for different purposes requiring RT calculations. CRTM requires bulk optical properties of hydrometeors in the form of lookup tables in order to perform all-sky RT calculations. However, the current cloud scattering lookup tables in CRTM assume spherical shapes for all frozen hydrometeors, whereas actual clouds contain frozen particles with diverse shapes. The first part of this talk presents the implementation and validation of a comprehensive Discrete Dipole Approximation (DDA) cloud scattering database into CRTM, specifically targeting microwave frequencies. The DDA technique proves effective in simulating the optical properties of non-spherical hydrometeors in the microwave region. The original DDA database assumes total random orientation in calculating single scattering properties. To generate the required mass scattering parameters for CRTM, the single scattering properties and water content dependent particle size distributions are used. The evaluation of results involved a collocated dataset comprising short-term forecasts from the Integrated Forecast System of the European Center for Medium-Range Weather Forecasts and satellite microwave data. The findings demonstrate that the DDA lookup tables significantly reduce discrepancies between simulated and observed values when compared to the Mie tables. Passive instruments lack the ability to provide vertically resolved measurements of clouds and precipitation, which can be obtained by active radar instruments. However, incorporating these active measurements into data assimilation systems presents challenges due to the absence of fast forward radiative transfer models and difficulties in error modeling. The second part of the talk focuses on the development, evaluation, and sensitivity analysis of a forward radar model integrated into CRTM. The forward radar model utilizes scattering properties obtained from hydrometeor lookup tables generated using the discrete dipole approximation. By utilizing CRTM instrument-specific coefficients, the model can calculate both reflectivity and attenuated reflectivity for any given radar instrument and zenith angles. Evaluation using CloudSat measurements demonstrates a strong agreement between simulations and observations when the input profiles of hydrometeors align with the measured reflectivity profiles.

Isaac Moradi↗

Development of a climatological data base to help forecast cloud cover conditions for shuttle landings at the Kennedy Space Center

The Space Shuttle is an extremely weather sensitive vehicle with very restrictive constraints for both launches and landings. The most important difference between Shuttle and normal aircraft landings is that the Shuttle has no go-around capability once it begins its decent into the earth's atmosphere. The de-orbit burn decision is generally made approximately 90 minutes before landing requiring a forecast with little room for error. Because of the Shuttle's rapid re-entry to earth, the pilot must be able to see all runway and visual navigation aids from high altitude to land the Shuttle. In addition, the heat resistant tiles which are used to protect the Shuttle during its re-entry into the earth's atmosphere are extremely sensitive to any type of precipitation. Extensive damage to these tiles could occur if the Shuttle passes through any cloud that contains precipitation size particles. To help guard against changing weather conditions or any type of weather problems that might occur prior to landing, flight rules have been developed as guidelines for all landings. Although the rules vary depending on the location of the landing (Kennedy Space Center or Edwards AFB), length of mission, and weight of vehicle, most of the rules can be condensed into 4 major groupings. These are: (1) Cloud ceilings should not be less than 3048 m (10,000 feet), (2) Visibility should not be less than 13 km (7 nm), (3) Cross-wind no greater than 5-8 m/s (10-15 knots); and (4) No showers or thunderstorms at or within 56 km (30 nm) of the Shuttle Landing Facility. This study consisted of developing a climatological database of the Shuttle Landing Facility (SLF) surface observations and performing an analysis of observed conditions one and two hours subsequent to given conditions at the SLF to help analyze the 0.2 cloud cover rule. Particular emphasis was placed on Shuttle landing weather violations and the amounts of cloud cover below 3048 m (10,000 ft.). This analysis has helped to determine the best and worst times to land the Shuttle at KSC. In addition, nomograms have been developed to help forecasters make cloud cover forecasts for End of Mission (EOM) and Return to Launch Site (RTLS) at KSC. Results of categorizing this data by month, season, time of day, and surface and upper-air wind direction are presented.

Atchison, M. Kevin↗

Distribution of silicon between kamacite and taenite

Meteorites formed under highly reducing conditions can incorporate substantial amounts of Si in solid solution in their metallic phases. In enstatite meteorites, reduced Si appears in shreibersite, perryite and, in variable amounts, in the kamacite, taenite, and tetrataenite. Microprobe bulk analysis of Si in Fe,Ni particles of aubrites show a large variation from grain to grain; this large compositional range has been attributed to local equilibrium conditions in the specific T and/or fO2 environments in which they are formed. Si concentrations are homogeneous in the kamacite; in contrast, the Ni-rich phases (taenite and tetrataenite) show a characteristic Si profile. Concentrations of this element in tetrataenite are substantially higher than in the adjacent kamacite, and decrease smoothly towards the center of the taenite grain, matching very closely the M-shaped profile of Ni. Other elements with similar distribution patterns are Ge and Cu. A satisfactory explanation for this behavior cannot be given in the absence of experimental data for the diffusion of Si between alpha and gamma-Fe alloys. However, two end-member possibilities can be envisioned: the distribution of Si between kamacite and taenite may be controlled by (1) the crystallographic structure or (2) the chemical composition of the host phases. These possibilities are explored.

Casanova, Ignacio↗

Comparative study of energetic heliospheric electrons at wind and geotail

The current fleet of both heliospheric and magnetospheric spacecraft provides a unique opportunity of studying spatio-temporal plasma phenomena. Among the numerous topics that can be addressed by such a fleet, figures the 3D study of energetic (greater than 20 keV) solar electron) solar electron events. WIND and GEOTAIL are particulary interesting for such analysis: more than two years of data; up to 3/4 continuous days spent by GEOTAIL in the solar wind; and comparable experiments. During solar electron events, rapid electron flux changes can be associated with these structures. Sometimes they are seen at both spacecraft with a time difference corresponding to the convection time, but sometimes they are observed at one spacecraft but not at the other. Several preliminary conclusions can be drawn from such events: (1) there is direct evidence that, within distances lower than 1.5 x 10(exp 6) km at 1 A (approximately 7000 km at the sun), there are significant spatial variations of (a) the magnetic field line connections to the source region and probably of (b) the particle propagation features; (2) magnetic field lines inside and outside particle propagation structures can keep distinct access to the source region for more than one hour; (3) flux waves, of probable local origin, were observed; and (4) within one hour, spatial flux discrepancies, separated by magnetic structures, may remain or disappear.

Chaizy, P. A.↗

Particle Engulfment and Pushing by Solidifying Interfaces: Micro-Gravity Experiments and Theoretical Analysis - Pt. 2

Results of the directional solidification experiments on Particle Engulfment and Pushing by Solidifying Interfaces (PEP) conducted on the space shuttle Columbia during the Life and Microgravity Science Mission are reported. Two pure aluminum (99.999%) 9 mm cylindrical rods, loaded with about 2 vol.% 500 micrometers diameter zirconia particles were melted and resolidified in the microgravity (microg) environment of the shuttle. One sample was processed at step-wise increased solidification velocity, while the other at step-wise decreased velocity. It was found that a pushing-to-engulfment transition (PET) occurred in the velocity range of 0.5 to 1 micrometers. This is smaller than the ground PET velocity of 1.9 to 2.4 micrometers. This demonstrates that natural convection increases the critical velocity. A previously proposed analytical model for PEP was further developed. A major effort to identify and produce data for the surface energy of various interfaces required for calculation was undertaken. The predicted critical velocity for PET was of 0.775 micrometers/s.

Stefanescu, Doru M.↗

Kinetic plasma processes occurring in the outer plasmasphere

One area of data analysis work that was begun under this contract is the fitting of the perpendicular velocity distributions of equatorially trapped ions with a Kappa function. This type of characterization of the trapped ions will be very useful for comparison with velocity distributions produced by the model. A second area of data analysis is to study data from consecutive passes when DE 1's apogee was near the magnetic equator and the spacecraft was often skimming along nearly the same L shell. In 1982 three such periods occurred in May, June, and July. For these consecutive events we have Kp histories, density measurements from a number of sources (Whistler data, DE SFR, ISEE SFR) and consecutive samples of ion pitch angle distributions along field lines. It is clear from this data how the pitch angle distributions evolve during a flux tube refilling event. Our modeling of the flow of plasma along closed field lines is following two basic tracks. The first is a study of the basic refilling process without the effect of wave-particle heating near the equator or the effect of large or abrupt field-aligned electric potential drops. This model includes the effects of Coulomb self-collisions and collisions with the O+ ions in the topside ionosphere. The second track is a study of the effects of wave produced pitch-angle scattering and perpendicular heating occurring near the magnetic equator, in connection with the development of large potential drops that result from electron heating and the development of density gradients.

Wilson, Gordon R.↗

Assessment of Clear Sky Radiative Forcing in the Caribbean Region Using an Aerosol Dispersion Model and Ground Radiometry During Puerto Rico Dust Experiment

This study investigates the surface and top of the atmosphere solar radiative forcing by long-range transport of Saharan dust. The calculations of radiative forcing are based on measurements collected in the Puerto Rico Dust Experiment (PRIDE) carried out during July, 2000. The purpose of the experiment was the characterization of the Saharan dust plume, which frequently reaches the Caribbean region during the summer. The experiment involved the use of three approaches to study the plume: space and ground based remote sensing, airborne and ground based in-situ measurements and aerosol dispersion modeling. The diversity of measuring platforms provides an excellent opportunity for determination of the direct effect of dust on the clear sky radiative forcing. Specifically, comparisons of heating rates, surface and TOA fluxes derived from the Navy global aerosol dispersion model NAAPS (NRL Aerosol Analysis and Prediction System) and actual measurements of fluxes from ground and space based platforms are shown. In addition, the direct effect of dust on the clear sky radiative forcing is modeled. The extent and time of evolution of the radiative properties of the plume are computed with the aerosol concentrations modeled by NAAPS. Standard aerosol parameterizations, as well as in-situ composition and size distributions measured during PRIDE, are utilized to compute the aerosol optical depth, single scattering albedo and asymmetry factor. Radiative transfer computations are done with an in-house modified spectral radiative transfer code (Fu-Liou). The code includes gas absorption and cloud particles (ice and liquid phase) and it allows the input of meteorological data. The code was modified to include modules for the aerosols contribution to the calculated fluxes. This comparison study helps to narrow the current uncertainty in the dust direct radiative forcing, as recently reported in the 2001 IPCC assessment.

Gasso, Santiago↗

Analysis of Lunar Highland Regolith Samples from Apollo 16 Drive Core 64001/2 and Lunar Regolith Simulants - An Expanding Comparative Database

We present modal data from QEMSCAN(registered TradeMark) beam analysis of Apollo 16 samples from drive core 64001/2. The analyzed lunar samples are thin sections 64002,6019 (5.0-8.0 cm depth) and 64001,6031 (50.0-53.1 cm depth) and sieved grain mounts 64002,262 and 64001,374 from depths corresponding to the thin sections, respectively. We also analyzed lunar highland regolith simulants NU-LHT-1M, -2M, and OB-1, low-Ti mare simulants JSC-1, -lA, -1AF, and FJS-1, and high-Ti mare simulant MLS-1. The preliminary results comprise the beginning of an internally consistent database of lunar regolith and regolith simulant mineral and glass information. This database, combined with previous and concurrent studies on phase chemistry, bulk chemistry, and with data on particle shape and size distribution, will serve to guide lunar scientists and engineers in choosing simulants for their applications. These results are modal% by phase rather than by particle type, so they are not directly comparable to most previously published lunar data that report lithic fragments, monomineralic particles, agglutinates, etc. Of the highland simulants, 08-1 has an integrated modal composition closer than NU-LHT-1M to that of the 64001/2 samples, However, this and other studies show that NU-LHT-1M and -2M have minor and trace mineral (e.g., Fe-Ti oxides and phosphates) populations and mineral and glass chemistry closer to these lunar samples. The finest fractions (0-20 microns) in the sieved lunar samples are enriched in glass relative to the integrated compositions by approx.30% for 64002,262 and approx.15% for 64001,374. Plagioclase, pyroxene, and olivine are depleted in these finest fractions. This could be important to lunar dust mitigation efforts and astronaut health - none of the analyzed simulants show this trend. Contrary to previously reported modal analyses of monomineralic grains in lunar regolith, these area% modal analyses do not show a systematic increase in plagiociase/pyroxene as size fraction decreases.

Schrader, Christian M.↗

Theoretical and measured electron-density distributions for the ram vehicle at high altitudes.

Application of a viscous shock-layer analysis to the calculation of nonequilibrium-flow species distributions in the plasma layer of a blunt-nosed vehicle at high altitudes. The theoretical electron-density results obtained are in good agreement with those measured in flight for a hemisphere-9 deg cone entry vehicle. The flight measurements were obtained using electrostatic probes that protruded well into the shock layer. In addition, the theoretically obtained heavy-particle translational temperatures appear to agree fairly well with the electron temperatures that were measured in the flight experiments using voltage-swept thin-wire electrostatic probes. The influence of the reaction rate coefficients on the calculated electron densities has been assessed and shown to be within the uncertainty in the flight data. The theoretical results demonstrate the importance of including in the chemical model the positive ions N2(+), O2(+), N(+), and O(+), in addition to NO(+), for the high altitudes and velocities considered.

Kang, S.-W.↗

Status of the Viking missions

A chronology of Viking 1 lander activities is presented for the first 43 sols (Martian days) of surface sampling and analysis. The orbital insertion of the second Viking spacecraft is reviewed along with the search for the second landing site. A general assessment of the planet is made on the basis of the data thus far obtained. Some of the findings reported are that: (1) there is extensive evidence of volcanism, fluvial and aeolian erosion, and deposition over the entire surface; (2) the floor of Vallis Marineris is significantly younger than the planet's surface; (3) the morphology of Martian crater ejecta is indicative of surface flow rather than ballistic deposition; (4) the rocks in the immediate vicinity of the lander are all covered by a layer of fine red dust; (5) the atmosphere is optically thick and well mixed, with suspended particles giving the sky a pink color; (6) the N and Ar isotopic ratios are different from those on earth; (7) atmospheric water vapor varies with both time of day and location; (8) the summer northern polar regions have a high water concentration in the atmosphere; (9) a large fraction of magnetic material resides in the surface; and (10) no complex organic compounds have been detected in the two samples analyzed.

Soffen, G. A.↗

Theory and simulations of broadband electrostatic noise in the geomagnetic tail

The excitation mechanism for broadband electrostatic noise (BEN) and the effects of BEN particles in the geomagnetic tail are examined using the linear analysis theory and particle simulations. The linear theory for electrostatic instabilities is discussed. The plasma sheet particle population is simulated using counter-streaming cold ion beams, and warm ions and electrons. The ion-ion instability, ion-acoustic mode, and the electrostatic ion cyclotron harmonic waves are studied. The velocity distributions, electric field intensity, and electron plasma waves for the plasma sheet boundary layer are evaluated. The frequency wave spectrum and particle distributions are computed and analyzed. The conditions for the two simulations, which differ only in beam ion drift speed, are described; it is observed that in the first simulation the dominate modes propagate parallel to the magnetic field and in the second simulation the propagation modes are oblique. The simulation data reveal that when beam temperature is smaller than plasma sheet temperature ion-acoustic and ion-ion instabilities grow to large amplitudes heating both electrons and ions. The data are compared to ISEE-1 observations and good correlation is obtained.

Ashour-Abdalla, M.↗

NASA Tech Briefs, Februrary 2013

Topics covered include: Measurements of Ultra-Stable Oscillator (USO) Allan Deviations in Space; Gaseous Nitrogen Orifice Mass Flow Calculator; Validation of Proposed Metrics for Two-Body Abrasion Scratch Test Analysis Standards; Rover Low Gain Antenna Qualification for Deep Space Thermal Environments; Automated, Ultra-Sterile Solid Sample Handling and Analysis on a Chip; Measuring and Estimating Normalized Contrast in Infrared Flash Thermography; Spectrally and Radiometrically Stable, Wideband, Onboard Calibration Source; High-Reliability Waveguide Vacuum/Pressure Window; Methods of Fabricating Scintillators With Radioisotopes for Beta Battery Applications; Magnetic Shield for Adiabatic Demagnetization Refrigerators (ADR); CMOS-Compatible SOI MESFETS for Radiation-Hardened DC-to-DC Converters; Silicon Heat Pipe Array; Adaptive Phase Delay Generator; High-Temperature, Lightweight, Self-Healing Ceramic Composites for Aircraft Engine Applications; Treatment to Control Adhesion of Silicone-Based Elastomers; High-Temperature Adhesives for Thermally Stable Aero-Assist Technologies; Rockballer Sample Acquisition Tool; Rock Gripper for Sampling, Mobility, Anchoring, and Manipulation; Advanced Magnetic Materials Methods and Numerical Models for Fluidization in Microgravity and Hypogravity; Data Transfer for Multiple Sensor Networks Over a Broad Temperature Range; Using Combustion Synthesis to Reinforce Berms and Other Regolith Structures; Visible-Infrared Hyperspectral Image Projector; Three-Axis Attitude Estimation With a High-Bandwidth Angular Rate Sensor Change_Detection.m; AGATE: Adversarial Game Analysis for Tactical Evaluation; Ionospheric Simulation System for Satellite Observations and Global Assimilative; Modeling Experiments (ISOGAME); An Extensible, User- Modifiable Framework for Planning Activities; Mission Operations Center (MOC) - Precipitation Processing System (PPS) Interface Software System (MPISS); Automated 3D Damaged Cavity Model Builder for Lower Surface Acreage Tile on Orbiter; Mixed Linear/Square-Root Encoded Single-Slope Ramp Provides Low-Noise ADC with High Linearity for Focal Plane Arrays; RUSHMAPS: Real-Time Uploadable Spherical Harmonic Moment Analysis for Particle Spectrometers; Powered Descent Guidance with General Thrust-Pointing Constraints; X-Ray Detection and Processing Models for Spacecraft Navigation and Timing; and Extreme Ionizing-Radiation-Resistant Bacterium

Source record↗

Friction-Stir Welding - Heavy Inclusions in Bi-metallic welds of Al 2219/2195

Heavy Inclusions (HI) were detected for the first time by radiographic examination in aluminum alloy 2219forging/2195plate (advancing/retreating side) Friction Sir Welds (FSW) for the Space Shuttle External Tank (ET) Program. Radiographic HI indications appear as either small (approx.0.005"-0.025") individual particles or clusters of small particles. Initial work was performed to verify that the HI was not foreign material or caused by FSW pin tool debris. That and subsequent elemental analysis determined that the HI were large agglomerations of Al2Cu (theta phase), which is the strengthening precipitate in Al2219. A literature search on that subject determined that the agglomeration of phase has also been found in Al2219 bead on plate FSW [Ref. 1]. Since this was detected in ET space flight hardware, an investigative study of the effect of agglomerated theta phase particles in FSW Al2219f/2195p was performed. Numerous panels of various lengths were welded per ET weld procedures and radiographically inspected to determine if any HI was detected. Areas that had HI were sampled for room temperature and cyclic cryogenic (-423F) tensile testing and determined no significant adverse affect on mechanical properties when compared to test specimens without HI and historical data. Fracture surface examination using the Scanning Electron Microscope (SEM) revealed smaller phase agglomerations undetectable by radiographic inspection dispersed throughout the Al2219f/2195p FSW. This indicates that phase agglomeration is inherent to the Al2219f/2195p FSW process and only rarely creates agglomerations large enough to be detected by radiography. HI has not been observed in FSW of plate to plate material for either Al2219 or AL2195.

Rietz, Ward W., Jr.↗

Reduction and analysis of seasons 15 and 16 (1991 - 1992) Pioneer Venus radio occulation data and correlative studies with observations of the near infrared emission of Venus

In this study, we sought to characterize variations in the abundance and distribution of subcloud H2SO4(g) in the Venus atmosphere by using a number of 13cm radio occultation measurements conducted with the Pioneer Venus Orbiter near the inferior conjunction of 1991. A total of ten data sets were examined and analyzed, producing vertical profiles of temperature and pressure in the neutral atmosphere, and sulfuric acid vapor abundance below the main cloud layer. Two of the vertical profiles of the abundance of H2SO4(g) were correlated with NIR images of the night side of Venus made during the same period of time by Boris Ragent (under a separate PVO Guest Investigator Grant). Initially, we had hoped that the combination of these two different types of data would make it possible to constrain or identify the composition of the large particles causing the features observed in the NIR images. However, the sparseness of the radio occultation data set, combined with the sparseness of the NIR data set (one image per day over an 8 day period) made it impossible to draw strong conclusions. Considered on their own, however, the parameters retrieved from the radio occultation experiments are valuable science products.

Jenkins, Jon M.↗

Optical and Probe Diagnostics Applied to Reacting Flows

The general theme of the research my NASA colleague and I have planned is "Optical and probe diagnostics applied to reacting flows". We plan to explore three major threads during the fellowship period. The first interrogates the flame synthesis of carbon nanotubes using aerosol catalysts. Having demonstrated the viability of the technique for nanotube synthesis, we seek to understand the details of this reacting system which are important to its practical application. Laser light scattering will reveal changes in particle size at various heights above the burner. Analysis of the flame gas by mass spectroscopy will reveal the chemical composition of the mixture. Finally, absorption measurements will map the nanotube concentration within the flow. The second thread explores soot oxidation kinetics. Despite the impact of soot on engine performance, fire safety and pollution, models for its oxidation are inhibited by uncertainty in the values of the oxidation rate. We plan to employ both optical and microscopic measurements to refine this rate. Cavity ring-down absorption measurements of the carbonaceous aerosol can provide a measure of the mass concentration with time and, hence, an oxidation rate. Spectroscopic and direct probe measurements will provide the temperature of the system needed for subsequent modeling. These data will be benchmarked against changes in soot nanostructures as revealed by transmission electron microscopic images from directly sampled material.

Ticich, Thomas M.↗