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At least 1,189 records · Page 66
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

Planetary spectroscopy

Spectroscopic and spectrophotometric data on the atmospheres of comets, the outer planets, and Titan at ultraviolet to near-infrared wavelengths were acquired. These data support an effort aimed at characterizing the physical properties and distribution of aerosol particles in the atmospheres of these bodies. New spectrophotometry was acquired of Uranus at 0.2 lambda 0.3 micrometer with IUE; archival IUE spectrophotometry of Uranus and Neptune in this wavelength range was acquired and recalibrated. New estimates of radiometric Bond albedos and global energy budges of Uranus, Neptune and Titan were published.

Bergstralh, J. T.↗
NASA NTRS1989

Light scattering instrumentation for micro gravity research

The analysis of light scattered from an ensemble of particles has long been a preferred method for characterizing their physical properties. Instrumentation to perform the measurements which forms the basis for such analysis is available in many forms based upon a variety of different experimental techniques. A system is presented which is singularly applicable for making many types of measurements in a microgravity environment. The commercial version of this device, the DAWN-F, has been used in many labs throughout the world to perform analyses of particular importance for both research and production. Light scattering theory is reviewed and the structure and function of the system is described.

Wyatt, Philip J.↗
NASA NTRS1990

Radiative properties of visible and subvisible Cirrus: Scattering on hexagonal ice crystals

One of the main objectives of the First International Satellite Cloud Climatology Project (ISCCP) Regional Experiment (FIRE) is to provide a better understanding of the physics of upper level clouds. The focus is on just one specific aspect of cirrus physics, namely on characterizing the radiative properties of single, nonspherical ice particles. The basis for further more extensive studies of the radiative transfer through upper level clouds is provided. Radiation provides a potential mechanism for strong feedback between the divergence of in-cloud radiative flux and the cloud microphysics and ultimately on the dynamics of the cloud. Some aspects of ice cloud microphysics that are relevant to the radiation calculations are described. Next, the Discrete Dipole Approximation (DDA) is introduced and some new results of scattering by irregular crystals are presented. The Anomalous Diffraction Theory (ADT) was adopted to investigate the scattering properties of even larger crystals. In this way the scattering properties of nonspherical particles were determined over a range of particle sizes.

Flatau, Piotr J.↗
NASA NTRS1991

Annular denuder systems: Precision and applicability to stratospheric sampling

Annular denuder systems (ADS) are designed to sample both gases and particles from ambient air without cross interference. The ADS's were used to detect chemical gradients over rural forest canopies. Accurate and precise methods for the sampling and analysis of low concentrations of gaseous and particulate species over short sampling periods were developed. Typical analytical precision data for nitrate and sulfate are shown. Both sampling and analytical precision data for a 2 hour test using four collocated ADS's are presented. On this particular day, the overall precision for HNO3 was unusually poor. The overall precision for the major constituents of interest is generally about 3 to 5 percent for typical ambient concentrations. The ADS's could potentially be used to determine the concentrations of HNO3 and fine-particle nitrate in the stratosphere, and to simultaneously characterize the chemical composition of stratospheric aerosols. Assuming 50 mb pressure, a 2 hour sampling time, a 50 Lpm sampling rate, and a low blank value, an overal precision of about 15 percent should be possible for 1 ppbv of HNO3 or nitrate, which would include nitric-acid trihydrate (NAT); and pump-driven systems could accommodate more complex systems involving denuders and filter packs in sequence. Alternate coatings could possibly be developed to selectively sample species such as Cl2 and ClNO3. The ADS's might also be useful in laboratory studies of heterogeneous chemical reactions involving NAT aerosols.

Randtke, Stephen J.↗
NASA NTRS1992

Boundary layer structure over the ocean observed by LEANDRE 1 during a tramontane event

A new airborne backscatter lidar, has been developed by CNRS (Service d'Aeronomie, (SA) Laboratoire de Meteorologie Dynamique (LMD) and the Institut des Sciences de 1'Univers) in the frame of the LEANDRE research program. It has been qualified on board the ARAT in autumn 1989 and spring 1990 and was involved in its first cooperative campaign during PYREX in October and November 1990. During this campaign, lidar observations of the perturbations induced on tropospheric flow and boundary layer structure were performed, and results are presented. A large number of experiments were performed, for synoptic situation description (meteorological radiosoundings, constant level balloons) and local flow analysis (aircrafts, radars, sodars). For the first time in such an experiment, a lidar has been flown on a research aircraft to perform altitude resolved observations of these perturbations, and we will present here results obtained for deflected flow structure. In the presence of a synoptic northerly flow, part of it is deflected to the east by the Pyrenees, and accelerated over the Mediterranean by the mountain surroundings. In this case, a low level wind is generated (the Tramontane) bringing cold and dry air over the Mediterranean Sea. As the sea is still at a warm temperature in November (around 17 degrees), an Internal Marine Boundary Layer rapidly grows over the first tens of kilometers and stabilizes at about 1 km depth, corresponding to an altitude just below the Lifting Condensation Level. The whole Marine Atmospheric Boundary Layer (MABL) is characterized by highly turbulent motions bringing large humid particles from the surface up to its top. The lidar signal due to scattering by these particles is then representative of the turbulent kinetic energy in this layer.

Flamant, C.↗
NASA NTRS1993

The nanosphere iron mineral(s) in Mars soil

A series of surface-modified clays containing nanophase (np) iron/oxyhydroxides of extremely small particle sizes, with total iron contents as high as found in Mars soil, were prepared by iron deposition on the clay surface from ferrous chloride solution. Comprehensive studies of the iron mineralogy in these 'Mars-soil analogs' were conducted using chemical extractions, solubility analyses, pH and redox, x ray and electron diffractometry, electron microscopic imaging specific surface area and particle size determinations, differential thermal analyses, magnetic properties characterization, spectral reflectance, and Viking biology simulation experiments. The clay matrix and the procedure used for synthesis produced nanophase iron oxides containing a certain proportion of divalent iron, which slowly converts to more stable, fully oxidized iron minerals. The noncrystalline nature of the iron compounds precipitated on the surface of the clay was verified by their complete extractability in oxalate. Lepidocrocite (gamma-FeOOH) was detected by selected area electron diffraction. It is formed from a double iron Fe(II)/Fe(III) hydroxyl mineral such as 'green rust', or ferrosic hydroxide. Magnetic measurements suggested that lepidocrocite converted to the more stable meaghemite (gamma-Fe203) by mild heat treatment and then to nanophase hematite (aplha-Fe203) by extensive heat treatment. Their chemical reactivity offers a plausible mechanism for the somewhat puzzling observations of the Viking biology experiments. Their unique chemical reactivities are attributed to the combined catalytic effects of the iron oxide/oxyhydroxide and silicate phase surfaces. The mode of formation of these (nanophase) iron oxides on Mars is still unknown.

Banin, A.↗
NASA NTRS1998

Ultrasonic Velocity Variations with Soil Composition for Moisture Measurement

Soil moisture content may be measured by many methods, but the presently available techniques all have drawbacks when used in ground truth measurements for remote sensing. Ultrasonic velocity varies with soil moisture content, and may be used as the basis of a new measurement technique. In order to characterize a sensor capable of field use, soil particle size distribution data are compared to ultrasonic velocity in a variety of soils over a wide moisture range.

Metzl, R.↗
NASA NTRS1992

Reflective Insulation

NRC-2 Superinsulation, manufactured by Metallized Products, Inc. (MPI), is designed for superconducting magnets used in MRI systems and particle accelerators. It is a thin, polyester film characterized by a unique crinkled surface that provides surface stand-off between layers and minimizes heat transfer in multilayer applications. NRC-2/Two is a two-sided metallized film. The material, originally developed as a skin for balloon-like satellites, was later used by NASA as a thermal barrier. MPI worked with NASA on the development of the original material and now supplies it for both space and consumer applications.

Source record↗
NASA NTRS1996

Two-stage model of radon-induced malignant lung tumors in rats: effects of cell killing

A two-stage stochastic model of carcinogenesis is used to analyze lung tumor incidence in 3750 rats exposed to varying regimens of radon carried on a constant-concentration uranium ore dust aerosol. New to this analysis is the parameterization of the model such that cell killing by the alpha particles could be included. The model contains parameters characterizing the rate of the first mutation, the net proliferation rate of initiated cells, the ratio of the rates of cell loss (cell killing plus differentiation) and cell division, and the lag time between the appearance of the first malignant cell and the tumor. Data analysis was by standard maximum likelihood estimation techniques. Results indicate that the rate of the first mutation is dependent on radon and consistent with in vitro rates measured experimentally, and that the rate of the second mutation is not dependent on radon. An initial sharp rise in the net proliferation rate of initiated cell was found with increasing exposure rate (denoted model I), which leads to an unrealistically high cell-killing coefficient. A second model (model II) was studied, in which the initial rise was attributed to promotion via a step function, implying that it is due not to radon but to the uranium ore dust. This model resulted in values for the cell-killing coefficient consistent with those found for in vitro cells. An "inverse dose-rate" effect is seen, i.e. an increase in the lifetime probability of tumor with a decrease in exposure rate. This is attributed in large part to promotion of intermediate lesions. Since model II is preferable on biological grounds (it yields a plausible cell-killing coefficient), such as uranium ore dust. This analysis presents evidence that a two-stage model describes the data adequately and generates hypotheses regarding the mechanism of radon-induced carcinogenesis.

NASA Program Radiation Health↗
NASA NTRS2006

An Assessment of NASA Glenn's Aeroacoustic Experimental and Predictive Capabilities for Installed Cooling Fans: Aerodynamic Performance - Part 1

Driven by the need for low production costs, electronics cooling fans have evolved differently than the bladed components of gas turbine engines which incorporate multiple technologies to enhance performance and durability while reducing noise emissions. Drawing upon NASA Glenn's experience in the measurement and prediction of gas turbine engine aeroacoustic performance, tests have been conducted to determine if these tools and techniques can be extended for application to the aerodynamics and acoustics of electronics cooling fans. An automated fan plenum installed in NASA Glenn's Acoustical Testing Laboratory was used to map the overall aerodynamic and acoustic performance of a spaceflight qualified 80 mm diameter axial cooling fan. In order to more accurately identify noise sources, diagnose performance limiting aerodynamic deficiencies, and validate noise prediction codes, additional aerodynamic measurements were recorded for two operating points: free delivery and a mild stall condition. Non-uniformities in the fan s inlet and exhaust regions captured by Particle Image Velocimetry measurements, and rotor blade wakes characterized by hot wire anemometry measurements provide some assessment of the fan aerodynamic performance. The data can be used to identify fan installation/design changes which could enlarge the stable operating region for the fan and improve its aerodynamic performance and reduce noise emissions.

VanZante, Dale E.↗
NASA NTRSDate not supplied

Airborne High Spectral Resolution Lidar Measurements of Aerosol Distributions and Properties During the NASA CAMP2Ex Mission

The NASA Clouds, Aerosols and Monsoon Processes-Philippines Experiment (CAMP2Ex) occurred during August-October, 2019,primarily over the ocean near the Philippines, including the ocean west of Luzon. CAMP2Ex attempts to characterize the role of anthropogenic and natural aerosol particles in modulating warm and mixed-phase precipitation in the maritime continent during the Southwest Monsoon. This mission is also examining relationships between spatial heterogeneity in the aerosol and cloud fields and radiative heating rates and studying the effects of aerosol concentration and composition on the microphysical properties of shallow cumulus and cumulus congestus clouds. Critical to the successful investigation of these objectives is profiling of aerosol, cloud and meteorological properties throughout the atmospheric column. For the CAMP2Ex experiment, we deployed the second generation NASA Langley airborne High Spectral Resolution Lidar (HSRL-2) on the NASA P-3 aircraft to obtain profile measurements of aerosol and thin cloud extinction and optical thickness via the HSRL technique at 355 and 532 nm, and of backscatter and depolarization at 355, 532, and 1064 nm. The HSRL technique allows for the independent measurement of extinction and backscatter without the need to assume modeled lidar ratios. Additional HSRL-2 data products include aerosol type, mixed layer depth, and range-resolved aerosol microphysical parameters. The HSRL measurements reveal the temporal, spatial, and vertical variability of aerosol optical properties over these locations. The HSRL-2 measured these backscatter, extinction, and depolarization profiles during all nineteen science flights and the transit flights to and from the aircraft operations base at Clark International Airport.In this presentation, we use these HSRL-2 measurements to show the horizontal and vertical distributions of aerosols in the CAMP2Ex operational area as well as provide insight into the optical and physical characteristics of these aerosols. We also discuss how these aerosols are distributed within and above the mixed layer.

aerosol↗
DOE OSTI2017

HI-SCALE Nanoparticle Composition and Precursors Field Campaign Report

From 21 August to 27 September, 2016, during the second Intensive Operational Period (IOP) of the Holistic Interactions of Shallow Clouds, Aerosols, and Land-Ecoystems (HI-SCALE) field campaign, a suite of instruments were placed in the Guest Instrument Facility (GIF) at the Central Facility of the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Climate Research Facility’s Southern Great Plains (SGP) site in Lamont, Oklahoma. The goal of these measurements was to fully characterize the formation and evolution of atmospheric aerosol particles through measurements of gas-phase precursor and ambient nanoparticle composition. Specifically, we sought to: 1. investigate the role of acid-base chemistry in new-particle growth through measurements of ammonia and amines as well as organic and inorganic acids in both atmospheric nanoparticles and the gas phase; 2. investigate the contribution of other surface-area or volume-controlled processes to nanoparticle formation and growth, such as the uptake of extremely low volatility organic compounds (ELVOCs); 3. evaluate the performance of a new instrument being developed with funding from the DOE Small Business Innovation Research (SBIR) program for measuring gas-phase amines and related compounds; and 4. together with colleagues measuring on the ground and onboard the ARM Gulfstream-1 (G-1) aircraft during HI-SCALE, create a comprehensive data set related to new particle formation and growth that can be used in modeling efforts by the research team as well as DOE collaborators.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Effect of particle size and moisture on flow performance of loblolly pine anatomical fractions: Experimental findings and model predictions

The rising energy demand has highlighted biomass as a promising next-generation energy source. However, commercializing biomass-derived energy faces challenges, particularly in handling biomass feedstock. Factors like particle size, shape, moisture content, and surface roughness significantly impact biomass flowability. This study addresses a crucial knowledge gap by examining the effects of particle size and moisture content on the flow behavior and shear properties of different anatomical fractions of loblolly pine (Pinus taeda). The bulk shear behavior was examined using a Schulze ring shear tester, while flow performance was tested through gravity-driven flow experiments in a variable wedge-shape hopper. Results were incorporated into empirical and machine learning-based flow prediction models to evaluate their accuracy and limitations. The study found that samples with higher moisture content show higher unconfined yield strength. The critical arching distance increased with particle size, e.g., from approximately 13 and 33 mm for 2- and 6-mm whole chips, respectively at a 32-degree inclination angle. Conversely, the flow rate decreased for a given hopper opening as particle size increased. For instance, at a 60-mm hopper opening and a 32-degree inclination angle, the mass flow rates for 2- and 6-mm whole chips were 7.83 and 6.42 tonne/h, respectively. The empirical model consistently overpredicted the mass flow rate for all anatomical fractions, while the machine learning model more accurately predicted the central tendency of flow rate but was insensitive to varying tissue proportions. These novel findings provide comprehensive characterization of anatomical fractions, reveal significant combined effects of particle size and moisture content on biomass flow behavior, and demonstrate a better predictive accuracy of a machine learning model, all of which are useful for optimizing material handling strategies and biomass utilization technologies in the industry.

09 - BIOMASS FUELS↗
NASA NTRSDate not supplied

Seasonal, Spectral, and Regional Characterization of Deep Convective Clouds Top-of-Atmosphere Bidirectional Reflectance for Improved Satellite Intercalibration

The NASA CERES project provides the scientific community with regional broadband fluxes designed for long-term climate monitoring. The CERES climate quality dataset requires that the CERES instrument, as well as the MODIS and VIIRS imager records to be radiometrically stable over time. Deep Convective Clouds (DCCs) are spectrally uniform, near-Lambertian natural diffusers offering high signal-to-noise ratio and stable radiometric response in the VIS-NIR spectrum. For shortwave infrared (SWIR) wavelengths greater than 1.2µm, the DCC response is significantly influenced by cloud particle size and atmospheric absorption. Previous studies improved the characterization of the SWIR band DCC radiance, by using channel specific monthly empirical BRDFs as well as using the probability density function mean statistic to track the SWIR band stability. Also, that the DCC radiance is greater over land than over ocean and that the TWP DCC radiance has the lowest tropical DCC radiance. This study confirms and improves upon the previous studies. The study stratified the tropics regionally into land and ocean domains and applied their respective ocean-only and land-only empirical monthly BRDFs and normalized the land DCC BRDF corrected radiances with their ocean counterpart. This approach provided the most stable DCC response. The DCC BRDF corrected radiance monthly standard error was 0.24%, 0.62%, 0.59%, and 0.43% for the 1.24µm, 1.37µm, 1.61µm, and 2.25µm SWIR bands, which reduced the standard error 20%, 13%, 24%, and 26%, respectively when compared with the all-surface approach. The same approach was attempted over the Tropical Western Pacific and found not to be an improvement over the tropical domain. Further stratification of the tropical domain will need to balance sufficient sampling while accounting for regional DCC radiance differences.

Prathana Khakurel↗
DOE OSTI2022

Fine Ash-Bearing Particles as a Major Aerosol Component in Biomass Burning Smoke

Biomass burning (BB) events are occurring globally with increasing frequency, and their emissions are having more impacts on human health and climate. Large ash particles are recognized as a BB product with major influences on soil and water environments. However, fine-ash particles, which have diameters smaller than several microns and characteristic morphologies and compositions (mainly Ca and Mg carbonates), have not yet been explicitly considered as a major BB aerosol component either in field observations or climate models. This study measured BB aerosol samples using transmission electron microscopy (TEM) and ion chromatography during the Fire Influence on Regional to Global Environments and Air Quality (FIREX-AQ) campaign. We show that significant amounts of fine ash-bearing particles are transported >100 km from their fire sources. Our environmental chamber experiments suggest that they can act as cloud condensation and ice nuclei. We also found considerable amounts of fine ash-bearing particles in the TEM samples collected during previous campaigns (Biomass Burning Observation Project and Megacity Initiative: Local and Global Research Observations). These ash particles are commonly mixed with organic matter and make up ~8% and 5% of BB smoke by number and mass, respectively, in samples collected during the FIREX-AQ campaign. The measured ash-mass concentrations are approximately five times and six times greater than those of BB black carbon and potassium, respectively, scaling to an estimated global emission of 11.6 Tg yr -1 with a range of 8.8–16.3 Tg yr -1 . Better characterization and constraints on these fine ash-bearing particles will improve BB aerosol measurements and strengthen assessments of BB impacts on human health and climate.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

A Closure Study of Total Scattering Using Airborne In Situ Measurements from the Winter Phase of TCAP

We examine the performance of our approach for calculating the total scattering coefficient of both non-absorbing and absorbing aerosol at ambient conditions from aircraft data. Our extended examination involves airborne in situ data collected by the U.S. Department of Energy’s (DOE) Gulf Stream 1 aircraft during winter over Cape Cod and the western North Atlantic Ocean as part of the Two-Column Aerosol Project (TCAP). The particle population represented by the winter dataset, in contrast with its summer counterpart, contains more hygroscopic particles and particles with an enhanced ability to absorb sunlight due to the larger fraction of black carbon. Moreover, the winter observations are characterized by more frequent clouds and a larger fraction of super-micron particles. We calculate model total scattering coefficient at ambient conditions using size spectra measured by optical particle counters (OPCs) and ambient complex refractive index (RI) estimated from measured chemical composition and relative humidity (RH). We demonstrate that reasonable agreement (~20% on average) between the observed and calculated scattering can be obtained under subsaturated ambient conditions (RH < 80%) by applying both screening for clouds and chemical composition data for the RI-based correction of the OPC-derived size spectra.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

The Importance of Surface Oxygen for Lithiation and Morphology Evolution during Calcination of High-Nickel NMC Cathodes

Nanoscale morphology has a direct impact on the performance of materials for electrochemical energy storage. Despite this importance, little is known about the evolution of primary particle morphology nor its effect on chemical pathways during synthesis. In this work, operando characterization is combined with atomic-scale and continuum simulations to clarify the relationship between morphology of cathode primary particles and their lithiation during calcination of LiNi 0.8 Mn 0.1 Co 0.1 O 2 (NMC-811). This combined approach reveals a key role for surface oxygen adsorption in facilitating the lithiation reaction by promoting metal diffusion and oxidation, and simultaneously providing surface sites for lithium insertion. Furthermore, oxygen surface termination is shown to increase the activation energy for sintering, leading to smaller primary particle sizes at intermediate temperatures. Smaller particles provide both shorter diffusion lengths for lithium incorporation and increased surface site density for lithium insertion. These insights provide a foundation for more tailored syntheses of cathode materials with optimized performance characteristics.

25 ENERGY STORAGE↗
NASA NTRS2006

Genesis Solar Wind Sample Curation: A Progress Report

In the year since the Genesis solar wind collector fragments were returned, early science samples, specimens for cleaning experiments, and science allocations have been distributed. Solar wind samples are stored under nitrogen and handled in an ISO Class 4 (Class 10) laboratory. For array collector fragments, a basic characterization process has been established. This characterization consists of identification of solar wind regime, whole fragment image for identification and surface quality, higher magnification images for contaminant particle density, and assessment of molecular film contaminant thickness via ellipsometry modeling. Compilations of this characterization data for AuOS (gold film on sapphire), and sapphire from the bulk solar wind for fragments greater than 2 cm are available. Removal of contaminant particles using flowing ultrapure water (UPW) energized megasonically is provided as requested.

Allton, Judith H.↗