SEARCH · Engineering Papers

Results for “MOLECULES”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,189 records · Page 66

All sources NASA NTRS DOE OSTI

NASA NTRS1971

Microwave evidence for interstellar molecules.

The present state of microwave observations of interstellar molecules is reviewed, with emphasis on the need for accurate theoretical understanding of their rates and modes of production. Typical abundances of molecular species in dark interstellar clouds are tabulated, and it is shown that in addition to abundance information observations of molecular lines can yield data on the isotope contents, velocities, and temperatures of the clouds in which they exist. Collisions, spontaneous emission, the isotropic radiation, radiation trapping, and higher-frequency radiation are evaluated as factors contributing to molecular excitation processes.

Townes, C. H.↗

NASA NTRS1971

Vibration-rotation double resonance effects in symmetrical top molecules.

Rotational transitions in symmetrical top molecules in the wavelength regions of 1-3 mm are sufficiently strong to be observed directly on an oscilloscope. Changes in the vibrational level populations induced by laser radiations affect the intensity of the rotational transitions. Observation of the microwave lines under the influence of chopped laser radiation shows a variety of interesting and potentially informative effects. At pressures above a few tenths of a torr the effect of laser radiation is to reduce the microwave response. This is true for all microwave lines at all those laser frequencies which are absorbed by the gas, and this effect is roughly proportional to the absorption coefficient. The rise and decay times of this effect increase with pressure and the the linear dimensions of the absorption cell. At low pressures the microwave response may increase, decrease, or remain unaffected depending on the observed microwave transitions and the specific laser line applied to the gas.

Marantz, H.↗

NASA NTRS1971

Heat transfer and forces on concave surfaces in free molecule flow.

A Monte Carlo modeling technique is described for mathematically simulating free molecular flows over a concave spherical surface and a concave cylindrical surface of finite length. The half-angle of the surfaces may vary from 0 to 90 degrees, and the incident flow may have an arbitrary speed ratio and an arbitrary angle of attack. Partial diffuse reflection and imperfect energy accommodation for molecules colliding with the surfaces are also considered. Results of heat transfer, drag and lift coefficients are presented for a variety of flow conditions. The present Monte Carlo results are shown to be in very good agreement with certain available theoretical solutions.

Fan, C.↗

NASA NTRS1972

Organic molecules in space.

Examination of the question of chemical evolution. Observational evidence for the occurrence of some organic compounds in space is presented, and the likely existence of more complex molecules which are as yet undetected or unidentified is pointed out. This implies that massive solid objects, i.e., planets and asteroids, were accumulated from material which already contained a variety of organic compounds. The objects or regions of the galaxy studied are comets, interstellar space, prestellar nebulae, and cool stellar atmospheres.

Donn, B.↗

NASA NTRS1972

Ion-quadrupole effects in ion-molecule collisions.

Ion-quadrupole effects are investigated via numerical calculations of capture cross sections and computer-plotter studies of ion trajectories in the quadrupole field. Capture cross sections are roughly equal to Langevin values for low rotational temperatures; a large fraction of multiple reflection captures are calculated corresponding to formation of ion-molecule complexes.

Dugan, J. V., Jr.↗

NASA NTRS1972

Collision integrals for isotopic hydrogen molecules.

The study was undertaken to determine the effects of reduced mass and differences in asymmetry on the collision integrals and thermal diffusion factors of isotopic hydrogen systems. Each system selected for study consisted of two diatoms, one in the j = 0 rotation state and the other in the j = 1 state. The molecules interacted with a Lennard-Jones type potential modified to include angular terms. A set of cross sections and collision integrals were obtained for each system.

Brown, N. J.↗

NASA NTRS1972

Molecular parameters of the O2 molecule.

By analyzing all existing frequency data of the oxygen molecule in microwave, submillimeter, and infrared spectroscopy, a new set of molecular parameters is obtained. The parameters are tabulated and compared with values obtained by other authors. Observed and calculated frequencies of oxygen lines are also given.

Welch, W. M.↗

NASA NTRS1972

On circumstellar molecules in the Pleiades.

Consideration of both old and new observations of the interstellar 4232-A line of CH(+) for the brightest members of the Pleiades. These observations suggest that the molecules are circumstellar in some sense, perhaps resembling in this respect the micron-sized grains inferred to be present in this region.

Hobbs, L. M.↗

NASA NTRS1972

Classical scattering calculations for diatomic molecules: A general procedure and application to the microwave spectrum O2

Many properties of gaseous systems such as electromagnetic absorption and emission, sound dispersion and absorption, may be elucidated if the nature of collisions between the particles in the system is understood. A procedure for the calculation of the classical trajectories of two interacting diatomic molecules is described. The dynamics of the collision will be assumed to be that of two rigid rotors moving in a specified potential. The actual outcome of a representative sample of many trajectories at 298K was computed, and the use of these values at any temperature for calculations of various molecular properties will be described. Calculations performed for the O2 microwave spectrum are given to demonstrate the use of the procedure described.

Mingelgrin, U.↗

NASA NTRS1972

Electric dipole moment of diatomic molecules by configuration interaction. V - Two states of /2/Sigma/+/ symmetry in CN.

Previous accurate dipole moment calculation techniques are modified to be applicable to higher excited states of symmetry. The self-consistent fields and configuration interactions are calculated for the X(2)Sigma(+) and B(2)Sigma(+) states of CN. Spin hyperfine constants and spin density at the nucleus are considered in the context of one-electron operator properties. The values of the self-consistent field and configuration interaction for the spin density are compared with experimental values for several diatomic molecules.

Green, S.↗

NASA NTRS1972

The formation of diatomic molecules in interstellar clouds.

The formation of the classical interstellar molecules CH, CH(+), and CN is investigated, giving attention to the chemistry of moderate-density interstellar clouds. An H I region is considered in the model employed in the study. The major constituents in the region are atoms or ions because of the intensity of the UV radiation field. Aspects of radiative association are discussed together with chemical reactions, the electronic states and optical properties of CH and CH(+), and photodissociation rates.

Solomon, P. M.↗

NASA NTRS1974

Measurements of ion-molecule reactions of He plus, H plus, HeH plus with H sub 2 and D sub 2

A drift tube mass spectrometer apparatus has been used to determine the rate coefficient, energy dependence and product ions of the reaction He(+) +H2. The total rate coefficient at 300 K is 1.1 plus or minus 0.1) 10 to minus 13th power cu cm/sec. The reaction proceeds principally by dissociative charge transfer to produce H(+), with the small remainder going by charge transfer to produce H2(+) and by atom rearrangement to produce HeH(+). The rate coefficient increases slowly with increasing ion mean energy, reaching a value of 2.8 x ten to the minus 13th power cu cm sec at 0.18 eV. The corresponding reaction with deuterium, He(+) + D2, exhibits a value (5 plus or minus 1) x 10 to the minus 14th cu cm/sec at 300K. The reaction rates for conversion of H(+) and HeH(+) to H3(+) on collisions with H2 molecules are found to agree well with results of previous investigations.

Johnsen, R.↗

NASA NTRS1973

Spectroscopic and photochemical study of molecules important in chemical evolution

The primary broad goals of this research are to investigate (1) the possible reactions responsible for generation of compounds important in chemical evolution, and (2) reactions of compounds important in chemical evolution. In both cases the interest includes molecules that exist in interstellar space as well as those present on or near other planets and those which were thought to be present on or near the primitive earth.

Becker, R. S.↗

NASA NTRS1973

Product distributions and rate constants for ion-molecule reactions in water, hydrogen sulfide, ammonia, and methane

The thermal energy, bimolecular ion-molecule reactions occurring in gaseous water, hydrogen sulfide, ammonia, and methane have been identified and their rate constants determined using ion cyclotron resonance methods. Absolute rate constants were determined for the disappearance of the primary ions by using the trapped ion method, and product distributions were determined for these reactions by using the cyclotron ejection method. Previous measurements are reviewed and compared with the results using the present methods. The relative rate constants for hydrogen-atom abstraction, proton transfer, and charge transfer are also determined for reactions of the parent ions.

Huntress, W. T., Jr.↗

NASA NTRS1973

Vibrational deactivation of O3/101/ molecules in gas mixtures

The laser excited fluorescence method has been employed to determine rate constants for vibrational relaxation of O3(101) molecules by O3, O2, CO2, H2, D2, CH4, N2, He, and Ar collision partners at 298 K. Excitation of the O3(001) level by absorption of laser transitions on the CO2 9.5-micron band have permitted the first measurements of vibrational relaxation on O3.

Rosen, D. I.↗

NASA NTRS1973

Formation mechanism for interstellar molecules

The major ions in the region of the interstellar clouds include H(+) and H2(+). The ions may be formed by photo ionization, cosmic rays, or other processes. The chemistry of H2(+) is considered and reactions involving carbon atoms are described. The formation of nitrogen-containing molecules may occur mainly on interstellar grains. Reactions involving negative ions may also contribute to the production of certain species.

Harteck, P.↗

NASA NTRS1974

Ion-molecule reactions and vibrational deactivation of H2/+/ ions in mixtures of hydrogen and helium

Use of ion cyclotron resonance methods to measure the thermal energy rate constants for a number of ion-molecule reactions involving hydrogen and hydrogen-helium mixtures. Assuming that the distribution of initial vibrational states in the H2(+) ion is a near-Franck-Condon distribution, the occurrence of collisional deactivation of vibrationally excited H2(+) ions by He atoms is identified, and an approximate rate constant for the deactivation process and its dependence on vibrational energy are given.

Theard, L. P.↗

NASA NTRS1973

Molecule formation in normal clouds

Some aspects of molecule formation in normal interstellar clouds, i.e., clouds having particle densities of less than 100 per cu cm, are discussed in light of recent studies. It is pointed out that, with their relatively large depletion parameter values (DPVs), CH clouds are 'young', whereas OH clouds have small DPVs and are 'old'. The theoretical reason for this is that OH, as a product of grain catalysis, persists over a much longer period of cloud evolution, whereas CH(+), CH, and CN, as products of gas-phase reaction, can be found only in 'young' clouds where depletion has not yet occurred. This may explain why OH has not been seen in radio observations of regions where CH(+), CH, and CN have been seen optically.

Aannestad, P. A.↗