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At least 1,189 records · Page 66

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NASA NTRS1974

The formation of lunar glasses

The work investigates experimentally the conditions required to form glasses out of a number of lunar compositions. Viscous flow and crystallization behavior of several compositions were studied over a wide range of temperature. These data exhibit the form generally found for glass-forming liquids. Combining growth rate with viscosity data, the fraction of preferred growth sites on the crystal-liquid interfaces is found to increase with increasing undercooling for all lunar compositions. The detailed forms of the kinetic data are predicted by recent computer simulations of crystal growth. Calorimetry studies indicate that lunar orange soil was formed under conditions of much slower cooling rate than 1000 deg K per sec.

Uhlmann, D. R.↗

NASA NTRS1975

Glass-Si heterojunction solar cells

An increase in efficiency from 2% to over 7% was achieved by a solar cell that used polycrystal silicon heterojunction with SnO2 glass. For Single crystal substrates, efficiencies close to 10% were measured. These cells had the same structures as polycrystalline cells. Work on p+/n heterojunction using In2O3 glass resulted in cells of 3% efficiency on polycrystalline material and 4% efficiency on single crystal material.

Ahrons, R. W.↗

NASA NTRS1976

Three synthetic lunar glasses

Glasses have been synthesized that have the approximate compositions of lunar rocks 61156, 68415, and 77135, respectively. The glasses have been analyzed by conventional analytical and electron microprobe techniques and have been found to be highly homogeneous. They have been used successfully as electron microprobe standards and for experimental studies of crystallization and solar-wind implantation. Small amounts of these materials can be provided to investigators who would find them useful.

Minkin, J. A.↗

NASA NTRS1976

Manufacturing unique glasses in space

An air suspension melting technique is described for making glasses from substances which to date have been observed only in the crystalline condition. A laminar flow vertical wind tunnel was constructed for suspending oxide melts that were melted using the energy from a carbon dioxide laser beam. By this method it is possible to melt many high-melting-point materials without interaction between the melt and crucible material. In addition, space melting permits cooling to suppress crystal growth. If a sufficient amount of under cooling is accompanied by a sufficient increase in viscosity, crystallization will be avoided entirely and glass will result.

Happe, R. P.↗

NASA NTRS1977

Study of diffusion coefficients of glasses under Zero-G

A diffusion experiment for glasses was formulated, such theoretical and earth bound results as were available were outlined, and the preliminary earth based experimental work in preparation for a weightless experiment was done. The fundamental premise of the work was that diffusion studies of the glass forming ion can be conducted in zero-g environments, and diffusion data obtained from these experiments are unique and valuable because of earth based experimental difficulties.

Kinser, D. L.↗

NASA NTRS1977

Thermal expansion of an epoxy-glass microsphere composite

The thermal expansion of a composite of epoxy (diglycidyl ether of bisphenol A) and solid glass microspheres was investigated. The microspheres had surfaces which were either untreated or treated with a silicone release agent, an epoxy coupling agent, or a general purpose silane coupling agent. Both room temperature (about 300 K) and elevated temperature (about 475 K) cures were used for the epoxy. Two microsphere size ranges were used, about 50 microns, which is applicable in filled moldings, and about 125 microns, which is applicable as bond line spacers. The thermal expansion of the composites was measured from 300 to 350 K or from 300 to 500 K, depending on the epoxy cure temperature. Measurements were made on composites containing up to .6 volume fraction microspheres. Two predictive models, which required only the values of thermal expansion of the polymer and glass and their specific gravities, were tested against the experimental data. A finite element analysis was made of the thermal strain of a composite cell containing a single microsphere surrounded by a finite-thickness interface.

Price, H. L.↗

NASA NTRS1978

Glass tubes for protecting solar cells

Protecting solar cells against environmental effects is accomplished by putting them inside glass tubes instead of hermetically sealing them between pairs of flat glass sheets. If cells are coupled with storage battery integrated into tube, freestanding power source could be built.

Shelpuk, B.↗

NASA NTRS1978

Preliminary evaluation of Glass Resin materials for solar cell cover use

The glass resins were deposited by several techniques on 200 micron thick cells and on 50 microns thick wafers. The covered cells were exposed to ultraviolet light in vacuum to an intensity of 10 UV energy-equivalent solar constants at air mass zero for 728 hr. The exposure was followed by a single long thermal cycle from ambient temperature to -150 C. Visual inspection of the samples indicated that all samples had darkened to varying degrees. The loss in short-circuit current was found to range from 8 to 24%, depending on the resin formulation. In another test over 40 glass resin-coated silicon wafers withstood 15 thermal cycles from 100 to-196 C in one or more of the thicknesses tested. Several of the resin-coated wafers were tested at 65 C and 90% relative humidity for 170 hr. No change in physical appearance was detected.

Marsik, S. J.↗

NASA NTRS1976

Integral glass sheet encapsulation for terrestrial panel applications

Concepts for integral glass sheet encapsulation of terrestrial solar cell modules using techniques based upon electrostatic bonding are being developed. It is possible for the glass to provide hermetic encapsulation, the structural support, and a vehicle for integral interconnection of the solar cells. Anticipated capabilities, present status, and cost projections for large scale terrestrial utilization are discussed.

Minnucci, J. A.↗

NASA NTRS1977

Glass transitions in lubricants - Its relation to elastohydrodynamic lubrication /EHD/

A preliminary investigation into the possible role of glass transition and glassy state behavior of lubricants in EHD contacts is reported. Measurements of the glass transition of lubricants as a function of pressure by two methods are presented along with a discussion indicating possible implications of the results to EHD lubrication.

Alsaad, M.↗

NASA NTRS1978

Polarization by a tilted absorbing glass plate

Formulas for the response of an optical detector to the transmitted component of a tilted absorbing glass plate are derived in terms of the angle of incidence, the thickness of the plate, and the absorption coefficient and index of refraction of the glass. Numerical results are discussed for detectors of various sizes compared to the width of the incident beam and thickness of the plate.

Walraven, R. L.↗

NASA NTRS1978

Traction and lubricant film temperature as related to the glass transition temperature and solidification

Does a traction fluid have to be a glass or solid under operating conditions. Infrared spectra on dynamic EHD contacts of several types of fluid were used to determine the surface and oil-film temperatures. Polarized spectral runs were made to study molecular alignment. Static glass transition pressures at appropriate temperatures were between 0.1 and 2.0 GPa, with the traction fluid showing the highest. In the EHD contact region, the traction fluid showed both the highest film temperatures as well as the greatest degree of molecular alignment. A plot of the difference between the film and surface temperatures vs shear rate resulted in a master plot valid for all the fluids. From this work, the authors propose a model of 'fluid' traction, where friction between parallel rough molecules provides the traction.

Lauer, J. L.↗

NASA NTRS1979

Characterizing glass frits for slurries

Glass frit can be mixed with consistently reproducible properties even from different batches of glass frit using technique to measure one quantity that determines integrated properties of frit for combination with given liquid.

Nakano, H. N.↗

NASA NTRS1979

Crystal nucleation in glass-forming alloy and pure metal melts under containerless and vibrationless conditions

Crystal nucleation behavior in metallic alloys known to form glasses in melt quenching was characterized and from this characterization the possibility that massive amounts of certain alloys could be slow cooled to the glass state was assessed. Crystal nucleation behavior of pure liquid metals was examined experimentally, under containerless conditions, and theoretically.

Turnbull, D.↗

NASA NTRS1979

The upgrading of glass microballoons

The processes and mechanisms involved in producing glass microballoons of acceptable quality for laser fusion by gas jet levitation and manipulation were studied. Glass microballoons (GMBs) levitated at temperatures below, as well as above the liquidus, appear to diffuse sulfur dioxide, a polar molecule with a moderately large diameter, and hydrogen, a much smaller molecule at comparable rates. Rates on the order of tens of atmospheres per hour (constant volume) per atmosphere of partial pressure differential have been observed at temperatures around the liquidus. Relatively rapid and convenient filling of molten GMBs by levitation in deuterium and tritium appears to be a possibility.

Dunn, S. A.↗

NASA NTRS1978

Soils from Mare Crisium - Agglutinitic glass chemistry and soil development

Agglutinates were studied in 29 polished thin sections of grain mounts from various size fractions of six Luna 24 soil horizons. Three populations of agglutinitic glass compositions were found: a high-MgO, high-FeO group identified as a coarse-grained basaltic component; a low-MgO, low-FeO group from a highland source; and a low-MgO, high-FeO group probably from the subophitic basalt component. The presence of a significant amount of admixed highland component probably accounts for an enrichment in plagioclase and a depletion in ferromagnesian elements displayed by the agglutinitic glass compositions relative to the bulk soil.

Hu, H.-N.↗

NASA NTRS1978

Green glass vitrophyre 78526 - An impact of very low-Ti mare basalt composition

Rake sample 78526 is an 8.77 g rock consisting primarily of vitrophyric pale green glass with subordinate mineral and lithic relics. Petrographic and compositional evidence leads to the following conclusions: (1) the bulk composition represents that of a mixture formed by impact melting of at least two different textural and compositional varieties of VLT mare basalt that are now present in the rock as lithic relics and a poorly defined low-Ti mare basalt component observed in thin section only in the form of isolated mineral relics; (2) the admixed VLT mare basalts had REE abundances lower than those found in other mare basalts (but probably higher than emerald green glass) and REE patterns showing significant enrichment of the heavy relative to light REE's, suggesting that they were derived by comparatively high degrees of partial melting of a clinopyroxene-rich source region; and (3) the impact melt supercooled to produce the vitrophyre, with rather sharply contrasting textural domains present in the vitrophyre resulting from differences in nucleation kinetics and degrees of supercooling in various portions of the sample.

Warner, R. D.↗

NASA NTRS1978

Lonar crater glasses and high-magnesium australites - Trace element volatilization and meteoritic contamination

Radiochemical neutron activation analysis was used to detect six siderophile elements (Ni, Re, Os, Pd, Ir and Au) and three volatile elements (Zn, Se and Cd) in two basalts, a pumice and three impact glasses from Lonar crater, India, and in six high-magnesium australites. Significant depletions in Re and Se with respect to the parent basalts were found in the Lonar glasses. These depletions, apparently correlated with the degree of shock, are probably due to volatilization under the oxidizing conditions characteristic of earth. One of the australites is substantially enriched in siderophiles relative to the level of these elements in the other five tektites. The element patterns in the australites resemble those of the carbonaceous or cometary component of an Apollo 16 soil.

Morgan, J. W.↗