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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,189 records · Page 66
All sourcesNASA NTRSDOE OSTI
NASA NTRS2004

Lithium Polymer Electrolytes and Solid State NMR

Research is being done at the Glenn Research Center (GRC) developing new kinds of batteries that do not depend on a solution. Currently, batteries use liquid electrolytes containing lithium. Problems with the liquid electrolyte are (1) solvents used can leak out of the battery, so larger, more restrictive, packages have to be made, inhibiting the diversity of application and decreasing the power density; (2) the liquid is incompatible with the lithium metal anode, so alternative, less efficient, anodes are required. The Materials Department at GRC has been working to synthesize polymer electrolytes that can replace the liquid electrolytes. The advantages are that polymer electrolytes do not have the potential to leak so they can be used for a variety of tasks, small or large, including in the space rover or in space suits. The polymers generated by Dr. Mary Ann Meador's group are in the form of rod -coil structures. The rod aspect gives the polymer structural integrity, while the coil makes it flexible. Lithium ions are used in these polymers because of their high mobility. The coils have repeating units of oxygen which stabilize the positive lithium by donating electron density. This aids in the movement of the lithium within the polymer, which contributes to higher conductivity. In addition to conductivity testing, these polymers are characterized using DSC, TGA, FTIR, and solid state NMR. Solid state NMR is used in classifying materials that are not soluble in solvents, such as polymers. The NMR spins the sample at a magic angle (54.7') allowing the significant peaks to emerge. Although solid state NMR is a helpful technique in determining bonding, the process of preparing the sample and tuning it properly are intricate jobs that require patience; especially since each run takes about six hours. The NMR allows for the advancement of polymer synthesis by showing if the expected results were achieved. Using the NMR, in addition to looking at polymers, allows for participation on a variety of other projects, including aero-gels and carbon graphite mat en als. The goals of the polymer electrolyte research are to improve the physical properties of the polymers. This includes improving conductivity, durability, and expanding the temperature range over which it is effective. Currently, good conductivity is only present at high temperatures. My goals are to experiment with different arrangements of rods and coils to achieve these desirable properties. Some of my experiments include changing the number of repeat units in the polymer, the size of the diamines, and the types of coil. Analysis of these new polymers indicates improvement in some properties, such as lower glass transition temperature; however, they are not as flexible as desired. With further research we hope to produce polymers that encompass all of these properties to a high degree.

Berkeley, Emily R.↗
NASA NTRS2023

Missed Approach Procedures in Advanced Air Mobility: Conceptual Exploration

The High Density Vertiplex Sub-Project, as part of NASA’s Advanced Air Mobility (AAM) Project, has been in collaboration with a team from Wisk Aero focusing on vertiport operations, procedures, and concept development. A particular area of focus has been on the development of missed approach scenarios and procedures that highlight the potential changes in the nearer- and further-term operational time frames. Such changes relate to topic areas such as airspace design, automation and autonomy, roles and responsibilities of actors and stakeholders, airspace management services and systems, as well as technologies specific to vertiport operations management. This paper presents the current state of joint concept development through the established collaboration and the application of elements in ongoing testing as part of NASA’s High Density Vertiplex Sub-Project’s research strategy.

vertiport↗
NASA NTRS1985

Fatigue response of notched graphite/epoxy laminates

Tests were performed to determine the damage states in quasi-isotropic graphite/epoxy laminates with center holes caused by cyclic tensile loading. The influence of the stacking sequence on the initiation and interaction of damage modes and the relationship between damage, strength, stiffness, and life of the laminates were also studied. X-ray radiography, moire interferometry, and stiffness change were used to monitor damage. Fatigue damage in both laminates began with matrix cracks around the holes leading to delaminations. In laminates cycled at the same percent of notched tensile strength the stacking sequence influenced the density of the matrix cracks and the modes and distribution of the damage. Ply cracking was also caused by the stacking sequence. The damage states in the two laminates produced stiffness changes of 15 to 20 percent, different rates of change in residual strength, and a factor of two to four difference in fatigue life. It was determined that continued cyclic loading produced matrix cracks which led to fatigue of the laminates.

Kress, G. R.↗
NASA NTRS1994

High charge state carbon and oxygen ions in Earth's equatorial quasi-trapping region

Observations of energetic (1.5 - 300 keV/e) medium-to-high charge state (+3 less than or equal to Q less than or equal to +7) solar wind origin C and O ions made in the quasi-trapping region (QTR) of Earth's magnetosphere are compared to ion trajectories calculated in model equatorial magnetospheric magnetic and electric fields. These comparisons indicate that solar wind ions entering the QTR on the nightside as an energetic component of the plasma sheet exit the region on the dayside, experiencing little or no charge exchange on the way. Measurements made by the CHarge Energy Mass (CHEM) ion spectrometer on board the Active Magnetospheric Particle Tracer Explorer/Charge Composition Explorer (AMPTE/CCE) spacecraft at 7 less than L less than 9 from September 1984 to January 1989 are the source of the new results contained herein: quantitative long-term determination of number densities, average energies, energy spectra, local time distributions, and their variation with geomagnetic disturbance level as indexed by Kp. Solar wind primaries (ions with charge states unchanged) and their secondaries (ions with generally lower charge states produced from primaries in the magnetosphere via charge exchange)are observed throughout the QTR and have distinctly different local time variations that persist over the entire 4-year analysis interval. During Kp larger than or equal to 3 deg intervals, primary ion (e.g., O(+6)) densities exhibit a pronounced predawn maximum with average energy minimum and a broad near-local-noon density minimum with average energy maximum. Secondary ion (e.g., O(+5)) densities do not have an identifiable predawn peak, rather they have a broad dayside maximum peaked in local morning and a nightside minimum. During Kp less than or equal to 2(-) intervals, primary ion density peaks are less intense, broader in local time extent, and centered near midnight, while secondary ion density local time variations diminish. The long-time-interval baseline helps to refine and extend previous observations; for example, we show that ionospheric contribution to O(+3)) is negligible. Through comparison with model ion trajectories, we interpret the lack of pronounced secondary ion density peaks colocated with the primary density peaks to indicate that: (1) negligible charge exchange occurs at L greater than 7, that is, solar wind secondaries are produced at L less than 7, and (2) solar wind secondaries do not form a significant portion of the plasma sheet population injected into the QTR. We conclude that little of the energetic solar wind secondary ion population is recirculated through the magnetosphere.

Christon, S. P.↗
NASA NTRSDate not supplied

A materials-informatics based study of solid electrolytes and protective coatings for Li batteries

All-solid-state batteries with Li metal anode can address the safety issues surrounding traditional Li-ion batteries as well as the demand for higher energy densities. However, the development of solid electrolytes and protective coatings simultaneously possessing high ionic conductivity and wide electrochemical stability has proven to be a challenge. Here, we present a data-driven approach to explore the Li compound space for promising solid electrolytes and coatings. This is accomplished through the generation of a large database of battery-related materials properties of Li compounds by computing Li+ migration barriers using bond-valence-based pair potentials, and stability windows using density functional theory energies. Using this database, we implement machine learning models that can accurately predict migration barriers and electrochemical stability windows for any new Li compound. Through feature engineering, we ensure that our models are both accurate and interpretable. We perform feature importance analysis on our models to highlight materials properties that can be tuned for future design of coatings/electrolytes. Our database and informatics approach provide a valuable tool for the rapid discovery of new solid-state battery chemistries.

Solid state batteries↗
NASA NTRS1974

Spectroscopic results in helium from the NASA Lewis Bumpy Torus plasma

Spectroscopic measurements were carried out on the NASA Lewis Bumpy Torus experiment in which a steady state ion heating method based on the modified Penning discharge is applied in a bumpy torus confinement geometry. Electron temperatures in pure helium are measured from the ratio of spectral line intensities. Measured electron temperatures range from 10 to 100 eV. Relative electron densities are also measured over the range of operating conditions. Radial profiles of temperature and relative density are measured in the two basic modes of operation of the device called the low and high pressure modes. The electron temperatures are used to estimate particle confinement times based on a steady state particle balance.

Richardson, R. W.↗
NASA NTRS1974

Spectroscopic results in helium from the NASA Lewis Bumpy Torus plasma

Spectroscopic measurements have been carried out on the NASA Lewis Bumpy Torus experiment in which a steady state ion heating method based on the modified Penning discharge is applied in a bumpy torus confinement geometry. Electron temperatures in pure helium are measured from the ratio of spectral line intensities. Measured electron temperatures range from 10 to 100 eV. Relative electron densities are also measured over the range of operating conditions. Radial profiles of temperature and relative density are measured in the two basic modes of operation of the device called the low and high pressure modes. The electron temperatures are used to estimate particle confinement times based on a steady state particle balance.

Richardson, R. W.↗
NASA NTRS1973

Effect of bottom topography, eddy diffusivity, and wind variation on circulation in a two-layer stratified lake

The steady-state, wind-driven circulation is calculated in a stratified lake composed of two layers having uniform but unequal densities and eddy diffusivities. The position of the thermocline and the velocities in both layers are calculated from an asymptotic solution of the shallow lake equations when the Ekman number in the epilimnion (upper layer) is of order one but the ratio of hypolimnion (lower layer) to epilimnion eddy diffusivities is much less than one. Large differences in the thermocline shape and the velocities occur between the solution for uniform wind stress and the one for unit order wind stress gradients. For the latter solution the hypolimnion eddy diffusivity magnitude and the bottom topography have a large and important effect.

Gedney, R. T.↗
NASA NTRS1977

On the photographic processing and digital texture for remote sensing of Kujukuri Coast of Chiba in Japan

Remote sensing of various coastal phenomena on the Kujukuri Coast and Kashimanada Coast was done by the use of aircraft for the purpose of investigating the characteristics of shore reefs and floating sand, and the depth of the sea. A multispectral camera and a video ITV camera were used as sensors. The first flight was over the Kashimanada and Kujukuri Coasts and the next flight was over the Katsuura Bay. The shape of shore reefs, the state of floating sand, the depth of the sea, etc., are represented by equidensitographs using texture. The interval of density slices is 0.05. Correlations between the textures represented by equidensitographs, digital graphs and analog display are estimated.

Genda, H.↗
NASA NTRS1978

A case of elasto-plastic flow using a new special element

Using a new special element for elasto-plastic flow, a nearly square, center-cracked plate of simulated A533 steel is analyzed. Selected results are examined locally to the crack's tip. It is found that a sharp transition in the distribution of deformation and stress occurs after the initial elastic response, and that this state is followed by fairly stable behavior over a considerable portion of the load range. Distribution of strain energy density is noted, and implications for use of the parameter J and for additional work are discussed briefly.

Swedlow, J. L.↗
NASA NTRS1978

Temperature and ionization balance dependence of O VII line ratios

The forbidden-plus-intersystem to resonance line ratio (G) for the heliumlike ion O VII is calculated, taking into account cascades, blended satellite lines, and radiative plus dielectric recombination. It is noted that G is of particular use for investigating radiative-transfer effects and nonequilibrium ionization in the solar corona and that the calculations are applicable to a low-density optically thin Maxwellian plasma. The temperature dependence of G is considered for the case of a steady-state equilibrium plasma, and the effect of departures from ionization equilibrium on G is examined. It is found that G is quite insensitive to temperature over the range from 600,000 to 6 million K for a steady-state plasma, but that recombinations may be suppressed or dominant, depending on the relative abundance of O VIII, for a plasma in which the state of ionization is not in equilibrium with the electron temperature. This latter effect is shown to be capable of causing large variations in G that are dependent on electron temperature.

Acton, L. W.↗
NASA NTRS1980

Copernicus observations of C I and CO in diffuse interstellar clouds

Copernicus was used to observe absorption lines of C I in its ground state and excited fine structure levels and CO toward 29 stars. We use the C I data to infer densities and pressures within the observed clouds, and because our results are of higher precision than previous work, much more precise estimates of the physical conditions in clouds are obtained. In agreement with previous work, the interstellar thermal pressure appears to be variable, with most clouds having values of p/k between 1000/cu cm K and 10,000/cu cm K, but there are some clouds with p/k as high as 100,000/cu cm K. Our results are consistent with the view that the interstellar thermal pressure is so variable that the gas undergoes continuous dynamic evolution. Our observations provide useful constraints on the physical processes on the surfaces of grains. In particular, we find that grains are efficient catalysts of interstellar H2 in the sense that at least half of the hydrogen atoms that strike grains come off as part of H2. Results place strong constraints on models for the formation and destruction of interstellar CO. In many clouds, an order of magnitude less CO than predicted in some models was found.

Jenkins, E. B.↗
NASA NTRS1981

Stratospheric aerosols

The current state of information on stratospheric aerosols is reviewed. Aerosol properties such as size, size distribution, composition, refractive index, number density, extinction, optical depth, and single scattering albedo are considered and generalized as much as possible to be representative of the global aerosol in times of volcanic and nonvolcanic (background) periods. Data are presented that show the global distribution of stratospheric aerosols as measured by the stratospheric aerosol and gas experiment (SAGE) satellite system for background and volcanic (post-Mount St. Helens) conditions. In addition, lidar and dustsonde data are presented that show the changes in stratospheric aerosol over an 8-year period.

Mccormick, M. P.↗
NASA NTRS1982

Design of a 35-kilowatt bipolar nickel-hydrogen battery for low Earth orbit application

The needs of multikilowatt storage for low Earth orbit applications are featured. The modular concept, with projected energy densities of 20-24 W-hr/lb and 700-900 W-hr/ft3, has significant improvements over state of the art capabilities. Other design features are; active cooling, a new scheme for H2-O2 recombination, and pore size engineering of all cell components.

Cataldo, R. L.↗
NASA NTRS1981

Global simulation of auroral arcs

Numerical simulation of global formation of auroral arcs is carried out for a three-dimensional coupled ionosphere-magnetosphere system. With the presence of the stationary convection electric field, the field-aligned current driven by the polarization and drift of the ionospheric conductivity enhancement is shown to be responsible for the feedback instability of the shear Alfven wave. The simulation result demonstrates the dynamic process of auroral arc formation, where an ionospheric perturbation nearly resonant with the magnetospheric Alfven wave (toroidal mode) can eventually grow into auroral arcs. Many of the important characteristics of quiet auroral arcs are demonstrated, and it is shown that the overall distribution of auroras depends critically on the stationary state of the auroral oval characterized by the large-scale Birkeland current, the electric field, and the electron density distribution.

Miura, A.↗
NASA NTRS1982

Axisymmetric collapse of rotating, isothermal clouds

The results of over 50 new models of the axisymmetric collapse of rotating, isothermal clouds are presented, with the following objectives: (1) to fully explore the initial conditions necessary for collapse from uniform density and uniform rotation, subject to constant volume and constant pressure boundary conditions; (2) to catalog the possible end states for cloud collapse from these initial conditions; and (3) to determine if there is a critical value of rotational energy/gravitational energy associated with ring formation, as appears to be the case for adiabatic clouds. Three end states are obtained: Bonnor-Ebert spheroids, rings and collapsing disks. The rings are formed with values of the ratio of rotational energy to the absolute value of the gravitational energy typically less than the Maclaurin spheroid value for dynamic instability to ring formation.

Boss, A. P.↗
NASA NTRS1984

Development of a lightweight nickel electrode

Nickel electrodes made using lightweight plastic plaque are about half the weight of electrodes made from state of the art sintered nickel plaque. This weight reduction would result in a significant improvement in the energy density of batteries using nickel electrodes (nickel hydrogen, nickel cadmium and nickel zinc). These lightweight electrodes are suitably conductive and yield comparable capacities (as high as 0.25 AH/gm (0.048 AH/sq cm)) after formation. These lightweight electrodes also show excellent discharge performance at high rates.

Britton, D. L.↗
NASA NTRS1985

MPS solidification model. Analysis and calculation of macrosegregation in a casting ingot

Work performed on several existing solidification models for which computer codes and documentation were developed is presented. The models describe the solidification of alloys in which there is a time varying zone of coexisting solid and liquid phases; i.e., the S/L zone. The primary purpose of the models is to calculate macrosegregation in a casting or ingot which results from flow of interdendritic liquid in this S/L zone during solidification. The flow, driven by solidification contractions and by gravity acting on density gradients in the interdendritic liquid, is modeled as flow through a porous medium. In Model 1, the steady state model, the heat flow characteristics are those of steady state solidification; i.e., the S/L zone is of constant width and it moves at a constant velocity relative to the mold. In Model 2, the unsteady state model, the width and rate of movement of the S/L zone are allowed to vary with time as it moves through the ingot. Each of these models exists in two versions. Models 1 and 2 are applicable to binary alloys; models 1M and 2M are applicable to multicomponent alloys.

Poirier, D. R.↗