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DOE OSTI2020

High-power Mg batteries enabled by heterogeneous enolization redox chemistry and weakly coordinating electrolytes

Magnesium batteries have long been pursued as potentially low-cost, high-energy and safe alternatives to Li-ion batteries. However, Mg 2+ interacts strongly with electrolyte solutions and cathode materials, leading to sluggish ion dissociation and diffusion, and consequently low power output. Here we report a heterogeneous enolization chemistry involving carbonyl reduction (C=O ↔ C–O-), which bypasses the dissociation and diffusion difficulties, enabling fast and reversible redox processes. This kinetically favoured cathode is coupled with a tailored, weakly coordinating boron cluster-based electrolyte that allows for dendrite-free Mg plating/stripping at a current density of 20 mA cm -2 . The combination affords a Mg battery that delivers a specific power of up to 30.4 kW kg -1 , nearly two orders of magnitude higher than that of state-of-the-art Mg batteries. Here, the cathode and electrolyte chemistries elucidated here propel the development of magnesium batteries and would accelerate the adoption of this low-cost and safe battery technology.

25 ENERGY STORAGE↗

DOE OSTI2022

Bimetallic Ir x Pb nanowire networks with enhanced electrocatalytic activity for the oxygen evolution reaction

Metallic nanowire networks (MNNs) have attracted increasing attention due to their high surface area and tunable compositions. Although enormous efforts have been devoted to preparing noble metal MNNs with different compositions, the composition optimization and the formation mechanism of Ir-based MNNs have not been thoroughly investigated. Here, this work presents a facile method for synthesizing robust Ir-based bimetallic MNNs by chemical reduction. As unveiled by our characterization, the network structure is constructed by ultrafine nanowires evolved from aggregated nanoparticles. The element analysis confirms the even distribution of Pb and Ir elements. The introduction of Pb is found to be beneficial to the stable formation of Ir x Pb MNNs in the sol–gel process. By tuning the precursor ratio of Ir and Pb, the optimized Ir x Pb catalyst delivers an enhanced oxygen evolution reaction (OER) performance in acid media (307 mV at 10 mA cm −2 ), which is superior to that of the commercial IrO 2 catalyst. Besides, due to the robust structure of the Ir x Pb MNNs, excellent OER durability is observed in the accelerated durability test (ADT) (2000 cycles).

Bimetallic↗

DOE OSTI2024

In situ formed catalysts for active, durable, and thermally stable ammonia protonic ceramic fuel cells at 550 °C

Ammonia protonic ceramic fuel cells (NH 3 -PCFCs) are promising and attractive energy-conversion devices owing to their high energy density, zero-carbon emission, and safety. The development of NH 3 -PCFCs, however, depends largely on the insufficient activity and poor durability of typical Ni-based anodes for ammonia decomposition, especially at low temperatures such as 550 °C. Herein, we report a self-assembled heterostructured Ru 0.95 Cu 0.05 Ni x (RCN) catalyst obtained through an in situ reaction between the surface-decorated Ru 0.95 Cu 0.05 nanoparticles and the Ni grain in the anode under typical processing conditions. At 550 °C, Ni–BaZr 0.1 Ce 0.7 Y 0.1 Yb 0.1 O 3 anode-supported PCFCs with RCN catalysts exhibit a high peak power density of 0.732 W cm -2 and a significantly enhanced durability of 100 h in NH 3 . Moreover, the cells demonstrate improved thermal stability compared with the bare cell during a 31-cycle thermal cycling test in NH 3 between 550 and 700 °C. In conclusion, the enhanced performance is likely attributed to the synergistic effects of Ru and Cu in RCN for NH 3 decomposition, resulting in a more vital interaction of NH 3 than that of the bare anode surfaces, as confirmed by NH 3 thermal conversion, electrochemical performance, and theoretical simulations.

30 DIRECT ENERGY CONVERSION↗

DOE OSTI2024

Epitaxial heterointerfacial electron bridge synchronizes oxygen evolution activity and stability on a layered double hydroxide surface

Scalable green hydrogen production via electrocatalytic water splitting is largely restricted by the insufficient activity and stability of oxygen evolution reaction (OER) catalysts at the anode. As a class of the most active OER catalysts in alkaline electrolyzers, the application of layered double hydroxides (LDHs) remains a main challenge owing to the unstable lattice oxygen dissolution due to the dominant lattice oxygen-involving OER mechanism during long-term operation. Herein, we found that using an epitaxial hetero-interfacing nickel hydroxide (namely Ni(OH) 2 ) as an electron bridge between an active FeCo LDH and Ni foam support to form an LDH*/NFO catalyst, the electronic storage capacity around the Fermi level (-0.5 to +0.5 eV, e-D FE ) sharply increases from 0.93 per cell to 1.51 per cell. Subsequently, we demonstrate that this high e-D FE enables ceaseless and fast power injection into the kinetic process of intermediate species conversion and inhibits lattice oxygen dissolution in the active FeCo LDH. Consequently, it demonstrated a low OER overpotential of 246 mV at a current density of 100 mA cm -2 and ultrahigh stability for up to 3500 hours with an ultraslow overpotential increase rate of 9.4 × 10 -3 mV h -1 . Therefore, we developed an epitaxial hetero-interfacial electron bridging strategy to synchronize the activity and stability of available catalysts for scalable green hydrogen production via electrocatalytic water splitting.

25 ENERGY STORAGE↗

DOE OSTI2024

A Highly Efficient and Affordable Hybrid System for Hydrogen and Electricity Production (Final Project)

The pursuit of clean, secure, and sustainable energy has sparked significant interest in fuel cells for power generation and electrolyzer cells for hydrogen production. Among all types of fuel and electrolyzer cells, solid oxide cells (SOCs) have emerged as promising candidates due to their high efficiency and versatility. However, conventional oxygen-ion conductive SOCs face several challenges related to their performance and durability associated with their high-temperature operation (≥ 800 ºC). This has led to a growing interest in intermediate-temperature (≤ 650 ºC) proton-conducting solid oxide cells (p-SOCs) as potential alternatives. In collaboration between Phillips 66 and Georgia Tech, this project aims to achieve a 1 kW p-SOCs system to demonstrate the commercial viability of efficient SOC systems. This report addresses four primary areas and key challenges we overcame: (1) development of efficient and durable proton-conducting electrolyte (e.g., BaHf 0.1 Ce 0.7 Yb 0.2 O 3-δ ) and electrode/catalyst materials, (2) large area cell fabrication (10 x 10 cm 2 ), (3) scalable stack design and building (250 W and 1 kW), and (4) demonstration of a 1 kW prototype system. Notably, significant challenges faced during the large area cell fabrication process were addressed by achieving cell flatness, improving fabrication yield, and ensuring electrode/electrolyte interfacial adhesion. Stack designs were also developed, focusing on reducing contact resistance and optimizing stack components (e.g., sealants). These efforts resulted in the achievement of high performance and durability with promising outputs of 250 W and 1 kW. Furthermore, the integration of these stacks into a fuel-powered system was explored, with refinements made to heat management, as well as to pressure and heating conditions. The results demonstrated the potential applicability of our p-SOC technology in commercial energy storage and power generation systems. Additionally, the report discusses techno-economic analysis and a market transformation plan, aiming to evaluate and advance the commercial feasibility of this technology.

25 ENERGY STORAGE↗

NASA NTRS1980

Copernicus observations of C I and CO in diffuse interstellar clouds

Copernicus was used to observe absorption lines of C I in its ground state and excited fine structure levels and CO toward 29 stars. We use the C I data to infer densities and pressures within the observed clouds, and because our results are of higher precision than previous work, much more precise estimates of the physical conditions in clouds are obtained. In agreement with previous work, the interstellar thermal pressure appears to be variable, with most clouds having values of p/k between 1000/cu cm K and 10,000/cu cm K, but there are some clouds with p/k as high as 100,000/cu cm K. Our results are consistent with the view that the interstellar thermal pressure is so variable that the gas undergoes continuous dynamic evolution. Our observations provide useful constraints on the physical processes on the surfaces of grains. In particular, we find that grains are efficient catalysts of interstellar H2 in the sense that at least half of the hydrogen atoms that strike grains come off as part of H2. Results place strong constraints on models for the formation and destruction of interstellar CO. In many clouds, an order of magnitude less CO than predicted in some models was found.

Jenkins, E. B.↗

NASA NTRS1983

A search for the Sunyaev-Zel'dovich effect at millimeter wavelengths

It is believed that X-ray emission from clusters of galaxies represents thermal bremsstrahlung from a hot plasma. According to Sunyaev and Zel'dovich (1972), the plasma column density and temperature derived from this model imply a measurable distortion of the cosmic background radiation (CBR) in the cluster direction. This distortion results from the Compton scattering of the CBR photons by the electrons in the plasma, resulting in an average increase of each photon. This process, known as the Sunyaev-Zel'dovich effect, is photon conserving and 'shifts' the CBR spectrum to higher frequencies. The result is a decrease of flux at frequencies below 7.5 per cm (the Rayleigh-Jeans region), and an increase above. The investigation is concerned with measurements of the Sunyaev-Zel'dovich effect at frequencies in the range from 3 to 10 per cm. Attention is given to the employed observing and analysis technique, and an initial null result for the cluster Abell 1795.

Meyer, S. S.↗

NASA NTRS1984

Development of GaAs/Si and GaAs/Si monolithic structures for future space solar cells

The results of heteroepitaxial growth of GaAs and GaAlAs directly on Si are presented, and applications to new cell structures are suggested. The novel feature is the elimination of a Ge lattice transition region. This feature not only reduces the cost of substrate preparation, but also makes possible the fabrication of high efficiency monolithic cascade structures. All films to be discussed were grown by organometallic chemical vapor deposition at atmospheric pressure. This process yielded reproducible, large-area films of GaAs, grown directly on Si, that are tightly adherent and smooth, and are characterized by a defect density of 5 x 10(6) power/sq cm. Preliminary studies indicate that GaAlAs can also be grown in this way. A number of promising applications are suggested. Certainly these substrates are ideal for low-weight GaAs space solar ells. For very high efficiency, the absence of Ge makes the technology attractive for GaAlAs/Si monolithic cascades, in which the Si substrates would first be provided with a suitable p/n junction. An evaluation of a three bandgap cascade consisting of appropriately designed GaAlAs/GaAs/Si layers is also presented.

Spitzer, M. B.↗

NASA NTRS1986

Requirements for high-efficiency solar cells

Minimum recombination and low injection level are essential for high efficiency. Twenty percent AM1 efficiency requires a dark recombination current density of 2 x 10 to the minus 13th power A/sq cm and a recombination center density of less than 10 to the 10th power /cu cm. Recombination mechanisms at thirteen locations in a conventional single crystalline silicon cell design are reviewed. Three additional recombination locations are described at grain boundaries in polycrystalline cells. Material perfection and fabrication process optimization requirements for high efficiency are outlined. Innovative device designs to reduce recombination in the bulk and interfaces of single crystalline cells and in the grain boundary of polycrystalline cells are reviewed.

Sah, C. T.↗

NASA NTRS1988

Arcing and discharges in high-voltage subsystems of Space Station

Arcing and other types of electrical discharges are likely to occur in high-voltage subsystems of the Space Station. Results from ground and space experiments on the arcing of solar cell arrays are briefly reviewed, showing that the arcing occurs when the conducting interconnects in the arrays are at negative potential above a threshold, which decreases with the increasing plasma density. Furthermore, above the threshold voltages the arcing rate increases with the plasma density. At the expected operating voltages (approximately 200 V) in the solar array for the space station, arcing is expected to occur even in the ambient ionospheric plasma. If the ionization of the contaminants increases the plasma density near the high-voltage systems, the adverse effects of arcing on the solar arrays and the space station are likely to be enhanced, In addition to arcing other discharge processes are likely to occur in high-voltage subsystems. For example, Paschen discharge is likely to occur when the neutral density N sub n greater that 10 to the 12th cu cm, the corresponding neutral pressure P greater than 3 x 10 to the -5 Torr.

Singh, N.↗

NASA NTRS1993

Composition and Maturity of Apollo 16 Regolith Core 60013/14

Samples from every half-centimeter dissection interval of double drive tube 60013/14 (sections 60013 and 60014) were analyzed by magnetic techniques for Fe concentration and surface maturity parameter I(sub s)/ Fe(O), and by neutron activation for concentrations of 25 lithophile and siderophile elements. Core 60013/14 is one of three regolith cores taken in a triangular array 40-50 m apart on the Cayley plains during Apollo 16 mission to the Moon. The core can be divided into three zones based both on I(sub s)/FeO and composition. Unit A (0-44 cm depth) is compositionally similar to other soils from the surface of the central region of the site and is mature throughout, although maturity decreases with depth. Unit B (44-59 cm) is submature and compositionally more feldspathic than Unit A. Regions of lowest maturity in Unit B are characterized by lower Sm/Sc ratios than any soil obtained from the Cayley plains as a result of some unidentified lithologic component with low surface maturity. The component is probably some type of mafic anorthosite that does not occur in such high abundance in any of the other returned soils. Unit C (59-62 cm) is more mature than Unit B and compositionally equivalent to an 87: 13 mixture of soil such as that from Unit A and plagioclase such as found in ferroan anorthosite. Similar soils, but containing greater abundances of anorthosite (plagioclase), are found at depth in the other two cores of the array. These units of immature to submature soil enriched to varying degrees (compared to the mature surface soil) in ferroan anorthosite consisting of approx. 99% plagioclase are the only compositionally distinct subsurface similarities among the three cores. Each of the cores contains other units that are compositionally dissimilar to any soil unit in the other two cores. These compositionally distinct units probably derive from local subsurface blocks deposited by the event(s) that formed the Cayley plains. The ferroan anorthosite with approx. 99% plagioclase, however, must represent some subsurface lithology that is significant on the scale of tens of meters. The compositional uniformity of the surface soil (0-10 cm depth) over distances of kilometers reflects the large-scale uniformity of the plains deposits; the fine- structure reflects small-scale nonuniformity and the inefficiency of the impact-mixing process at depths as shallow as even one meter.

Korotev, Randy T.↗

NASA NTRS1997

The Effects of Laterite and Associated Terrain Components on PBMR Response in HAPEX-Sahel

Terrain characteristics such as roughness and vegetation have been shown to significantly affect the interpretation of microwave brightness temperatures (T(B)s) for mapping soil moisture. This study, a part of the 1992 HAPEX-Sahel experiment (Hydrologic Atmospheric Pilot Experiment in the Sahel), aimed to determine the effects of laterite and associated terrain components (i.e. vegetation, soil, and exposed water bodies) on the T(B) response of the Pushbroom Microwave Radiometer (PBMR, L-band, 21 cm wavelength), using the NS001 Thematic Mapper Simulator data as a surrogate for ground data. Coincident PBMR and NS001 data acquired from the high altitude (about 1500 m) long transect flights were processed to obtain TBs and radiances, respectively. The transects covered a range of moisture conditions. For this preliminary evaluation, no atmospheric corrections were applied, and the data sets were aligned by matching the acquisition times of the data records. NS001 pixels (about 4 m) were averaged to approximate the resolution of the PBMR (about 450 m), before their flight line data were compared. The laterite plateaux were found to have a surprisingly strong effect on the PBMR T(B) response. T(B) variations along the flight line could largely be explained by a combination of density and dielectric properties of laterite. The effect of surface moisture was distinguishable from the laterite effect, with the distinction apparently related to the occurrence of ephemeral pools of water after rainfall. Model simulated T(B)s agreed reasonably well with the observed T(B)s.

Teng, William L.↗

NASA NTRS2003

Obliquity, Ice Sheets, and Layered Sediments on Mars: What Spacecraft Observations and Climate Models are Telling Us

The Mars Odyssey Gamma-Ray Spectrometer (GRS) data present a quandary: On the one hand, large deposits of (inferred) water ice are located where thermal models suggest they would form and best be protected, e.g., if deposited during periods of higher obliquity. On the other hand, the volume mixing ratios (approx. 70%) are so high that diffusive deposition of water in regolith pore space (which is the process assumed by these models) cannot be the primary formation mechanism. Furthermore, given that the water is inferred to be so close to the surface (less than a few 10's of cm's), it must be in communication with the atmosphere on time scales that are geologically relatively short (10(exp 3)-10(exp 6) years); therefore the water cannot be archaic. Considering the GRS data, images of mantled, fretted, and disaggregated terrain, and new climate modeling of Mars orbital cycles, we are led to an alternate conclusion about the ice deposits: that they form as subaerial ice sheets. This scenario not only provides a simple explanation for these observations, but may also help explain the formation of globally distributed, sedimentary layered deposits.

Richardson, M. I.↗

NASA NTRS2005

Time Resolved Spectroscopy of Eclipsing Polars

No changes have been made since the last annual progress report was submitted in conjunction with a unilateral NCX. Dr. Barrett was affected by an STScI Reduction in Force (RIF). He is now employed by the Johns Hopkins University and plans to continue his research there. No expenses have been charged to this grant, however the FUSE data for the eclipsing polar V1432 Aql has been received and processed using CALFWSE v3.0.6. The resulting summed spectrum has been used for a preliminary analysis of the interstellar absorption towards V1432 Aql. We find a hydrogen column density of less than 1.5e21 cm^-2. We have used this result in the paper "X-Ray Emission and Optical Polarization of V1432 Aquilae: An Asynchronous Polar" to fix the hydrogen column density in the soft (<0.5 keV) X-ray band when analyzing the XMM-Newton spectra of this polar. This has enabled us to find an accurate temperature for the blackbody component of 88+/-2 eV, which is significantly higher than that of other polars (20 - 40 eV). We hope to complete our analysis of the phase-resolved emission line spectra of V1432 Aql and to prepare the results for publication in a refereed journal. We hope to begin work on this star within the next few months.

Barrett, Paul↗

NASA NTRS2008

Fabricating Large-Area Sheets of Single-Layer Graphene by CVD

This innovation consists of a set of methodologies for preparing large area (greater than 1 cm(exp 2)) domains of single-atomic-layer graphite, also called graphene, in single (two-dimensional) crystal form. To fabricate a single graphene layer using chemical vapor deposition (CVD), the process begins with an atomically flat surface of an appropriate substrate and an appropriate precursor molecule containing carbon atoms attached to substituent atoms or groups. These molecules will be brought into contact with the substrate surface by being flowed over, or sprayed onto, the substrate, under CVD conditions of low pressure and elevated temperature. Upon contact with the surface, the precursor molecules will decompose. The substituent groups detach from the carbon atoms and form gas-phase species, leaving the unfunctionalized carbon atoms attached to the substrate surface. These carbon atoms will diffuse upon this surface and encounter and bond to other carbon atoms. If conditions are chosen carefully, the surface carbon atoms will arrange to form the lowest energy single-layer structure available, which is the graphene lattice that is sought. Another method for creating the graphene lattice includes metal-catalyzed CVD, in which the decomposition of the precursor molecules is initiated by the catalytic action of a catalytic metal upon the substrate surface. Another type of metal-catalyzed CVD has the entire substrate composed of catalytic metal, or other material, either as a bulk crystal or as a think layer of catalyst deposited upon another surface. In this case, the precursor molecules decompose directly upon contact with the substrate, releasing their atoms and forming the graphene sheet. Atomic layer deposition (ALD) can also be used. In this method, a substrate surface at low temperature is covered with exactly one monolayer of precursor molecules (which may be of more than one type). This is heated up so that the precursor molecules decompose and form one monolayer of the target material.

Bronikowski, Michael↗

NASA NTRS2009

Device for Measuring Low Flow Speed in a Duct

A multiple-throat venturi system has been invented for measuring laminar flow of air or other gas at low speed (1 to 30 cm/s) in a duct while preserving the laminar nature of the flow and keeping the velocity profile across the duct as nearly flat as possible. While means for measuring flows at higher speeds are well established, heretofore, there have been no reliable means for making consistent, accurate measurements in this speed range. In the original application for which this system was invented, the duct leads into the test section of a low-speed wind tunnel wherein uniform, low-speed, laminar flow is required for scientific experiments. The system could also be used to monitor a slow flow of gas in an industrial process like chemical vapor deposition. In the original application, the multiple- throat venturi system is mounted at the inlet end of the duct having a rectangular cross section of 19 by 14 cm, just upstream of an assembly of inlet screens and flow straighteners that help to suppress undesired flow fluctuations (see Figure 1). The basic venturi measurement principle is well established: One measures the difference in pressure between (1) a point just outside the inlet, where the pressure is highest and the kinetic energy lowest; and (2) the narrowest part (the throat) of the venturi passage, where the kinetic energy is highest and the pressure is lowest. Then by use of Bernoulli s equation for the relationship between pressure and kinetic energy, the volumetric flow speed in the duct can be calculated from the pressure difference and the inlet and throat widths. The design of this system represents a compromise among length, pressure recovery, uniformity of flow, and complexity of assembly. Traditionally, venturis are used to measure faster flows in narrower cross sections, with longer upstream and downstream passages to maintain accuracy. The dimensions of the passages of the present venturi system are sized to provide a readily measurable pressure drop. Multiple throats are used to minimize the length needed to recover internal energy and enable the velocity profile to recover to near flatness.

Quinn, Frank↗

NASA NTRS2009

Measuring Thermal Conductivity of a Small Insulation Sample

Miller, Robert A.↗

NASA NTRS2010

Spacecraft Internal Acoustic Environment Modeling

Acoustic modeling can be used to identify key noise sources, determine/analyze sub-allocated requirements, keep track of the accumulation of minor noise sources, and to predict vehicle noise levels at various stages in vehicle development, first with estimates of noise sources, later with experimental data. This paper describes the implementation of acoustic modeling for design purposes by incrementally increasing model fidelity and validating the accuracy of the model while predicting the noise of sources under various conditions. During FY 07, a simple-geometry Statistical Energy Analysis (SEA) model was developed and validated using a physical mockup and acoustic measurements. A process for modeling the effects of absorptive wall treatments and the resulting reverberation environment were developed. During FY 08, a model with more complex and representative geometry of the Orion Crew Module (CM) interior was built, and noise predictions based on input noise sources were made. A corresponding physical mockup was also built. Measurements were made inside this mockup, and comparisons were made with the model and showed excellent agreement. During FY 09, the fidelity of the mockup and corresponding model were increased incrementally by including a simple ventilation system. The airborne noise contribution of the fans was measured using a sound intensity technique, since the sound power levels were not known beforehand. This is opposed to earlier studies where Reference Sound Sources (RSS) with known sound power level were used. Comparisons of the modeling result with the measurements in the mockup showed excellent results. During FY 10, the fidelity of the mockup and the model were further increased by including an ECLSS (Environmental Control and Life Support System) wall, associated closeout panels, and the gap between ECLSS wall and mockup wall. The effect of sealing the gap and adding sound absorptive treatment to ECLSS wall were also modeled and validated.

Chu, Shao-Sheng R.↗