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NASA NTRS1981

Constraints on the origin and interior structure of the major planets

Fitting models to the external gravity field of the major planets (Uranus, Neptune, Jupiter, and Saturn), it is found that certain interior characteristics may be common to all four. For Uranus and Neptune, a model with a central iron-silicate core of approximately four earth masses, an 'ice' layer of H2O, CH4, and NH3 in solar proportions of about 10 earth masses, and an H2-He atmosphere of about 1-2 earth masses gives a good fit to available constraints, including heat flow measurements. Models of Jupiter and Saturn have cores very similar to those of Uranus and Neptune; the H2-He layer, however, is markedly more extensive. Modes of origin that are consistent with these features are discussed. Models of this type predict a considerable enrichment of deuterium relative to primordial solar abundances in Uranus and Neptune. Such enrichment is not observed in Uranus; implications are discussed for interior structure and origin.

Hubbard, W. B.↗

NASA NTRS1982

The origin of Uranus - Compositional considerations

Implications of two broad classes of theories for the origin of the solar system for the composition of Uranus are examined as an approach to the testing of alternative hypotheses. Consideration is given to accretional theories of planetary formation, which predict interior structures consisting of a rock core surrounded by an envelope of H2, He, H2O, NH3 and CH4 with different ratios of H2 to ice, and to theories postulating the formation of giant gaseous protoplanets as a result of an encounter with an extended protostar, the condensation of eddies (flocules) in a cloud, with supersonic turbulence and the breakup of a ring formed in a collapsing massive solar nebula. It is shown that whereas accretional theories can easily account for the high density of Uranus relative to Jupiter and Saturn, the apparent absence of NH3, and the observed D/H ratio being about three times the solar ratio, the giant protoplanet theories do not clearly demonstrate how the compositions were achieved.

Podolak, M.↗

NASA NTRS1981

Longitudinal variability of methane and ammonia bands on Saturn

A total of 129 spectra of the center of the disk of Saturn were obtained in March 1980 in order to search for possible longitudinal variations in the CH4 6190 and NH3 6450 bands. The spectra were reduced to reflectivities, and the band equivalent widths were measured using a blind, automated continuum fitting technique. The methane and ammonia equivalent widths are well correlated with each other. There are some latitude regions in which both bands show enhanced absorption and some latitudes in which both bands are weaker than the average. The continuum reflectivity is quite constant with latitude and shows no apparent correlation with molecular band equivalent width. The observed variations may be explained by a longitudinal variation in the altitude of the top of the thick cloud of about + or - 2 km from the mean.

Cochran, A. L.↗

NASA NTRS1981

The atmosphere and ionosphere of Jupiter

The thermal structure of the upper atmosphere of Jupiter, the composition of the atmosphere and the strength of mechanical mixing, and sources and sinks of ionization in the Jupiter ionosphere are described from Voyager UV spectrometer, radio, IR, and imaging data. A topside ionospheric temperature of 1300 K was observed, along with an energy equilibrium between the plasma and neutral gas in the upper atmosphere. A composite thermal structure is provided, noting a close similarity to earth conditions at upper levels, and enhanced thermal behavior has been detected between the times of solar minimum and maximum activity. Ammonia photochemistry is examined, and measured concentrations of H2, CH4, C2H6, and C2H2 as a function of height are outlined. Eddy diffusion coefficient calculations are carried out, yielding a highest Ly-alpha intensity of 100 million sq cm/sec. The increased exospheric temperature between 1973 and 1980 is stressed to have no known satisfactory explanation.

Atreya, S. K.↗

NASA NTRS1982

Spatially resolved reflectivities of Saturn - 3000-6000 A

Absolute reflectivity reductions are presented for spectrophotometric observations of seven spatially-resolved regions on the disk of Saturn in the 3000-6000 A region. An asymmetry is found between northern and southern hemisphere data, in the equivalent width of the CH4, 5430-A band and in the continuum reflectivity. In addition, the spectra are found not to include the 4700 A reflectivity peak found by Bergstralh et al (1981), and to exhibit general agreement with the Podolack and Danielson (1977) model. The blue and visual spectral region continuum reflectivity of a planetary atmosphere provides constraints for determining aerosol particle single-scattering albedo and vertical distribution, which are in turn important to an understanding of planetary energy balance, atmospheric dynamics, and planetary molecular absorption spectrum interpretation.

Cochran, W. D.↗

NASA NTRS1981

Atmospheric structure of the outer planets from thermal emission data

Methods for determining atmospheric structure exploit the opacities provided by the collision induced H2 dipole and the nu4 fundamental of CH4. In addition to earth-based observations, useful measurements of thermal emission from Jupiter and Saturn have been or soon will be made by several spacecraft, with results cross-checked with independent radio occultaion results. For Uranus and Neptune, only a limited set of whole-disk earth-based data exists. All the outer planets show evidence for stratospheric temperature inversions; temperature minima range from about 105 K for Jupiter and 87 K for Saturn, to roughly 55 K for Uranus and Neptune. Remaining problems may be resolved by better quantitative understanding of gas and aerosol absorption and scattering properties, chemical composition, and non-LTE source functions. Ultimately, temperature structure results must be supplemented by quantitative energy equilibrium models which will allow some meaning to be given to the relationships between such characteristics as temperature, clouds, incident solar and planetary radiation, and chemical composition.

Orton, G. S.↗

NASA NTRS1982

The spectrum of the Jovian Aurora 1150-1700 A

A series of observations of the northern hemisphere of Jupiter was made in January 1981 using the International Ultraviolet Explorer short-wavelength spectrograph. Exposures of 15 minutes each were made at regular intervals of about 45 minutes around the time when Jupiter's north magnetic pole was tilted toward the earth. The auroral emissions of H Lyman-alpha, and the H2 Lyman- and Werner-bands are seen to emanate from a localized region near the north pole. Their intensity increases and decreases in a periodic way as the planet rotates with the maximum occurring at lambda sub III approximately equal to 185 deg. Using the three observations nearest the observed maximum, a composite spectrum of the aurora is obtained with about 8 A resolution and high signal-to-noise ratio, and many of the H2 Lyman- and Werner-bands in this spectral region (1150-1700 A) are identified. This spectrum is compared with a laboratory H2 spectrum and with photoabsorption cross sections for CH4 and C2H6. An upper limit to the slant column density of these hydrocarbons above the auroral emissions is found to be approximately 2 x 10 to the 17th/sq cm.

Durrance, S. T.↗

NASA NTRS1982

Methane and nonmethane hydrocarbon concentrations in the Atlantic marine boundary layer

The reactions of reduced tropospheric trace gases with hydroxyl radicals are thought to play a significant role in global tropospheric photochemistry. Since tropospheric methane and nonmethane hydrocarbon (NMHC) concentrations will affect the tropospheric hydroxyl radical concentrations, accurate measurements of tropospheric CH4 and NMHC concentrations are necessary. Such measurements were, therefore, included in the first leg (from Hamburg, West Germany to Montevideo, Uruguay) of the 1980-1981 Antarctic Expedition. On the basis of the obtained data, a pronounced gradient between northern and southern hemispheric methane concentrations was observed in the marine boundary layer in the region of the intertropical convergence zone. Methane concentrations gradually decreased from about 1.70 ppmv at 40 deg N latitude to about 1.68 ppmv at 14 deg N latitude, then dropped sharply between 14 deg N and 10 deg N latitude to about 1.61 ppmv. NMHC data are also discussed.

Cofer, W. R., III↗

NASA NTRS1982

CO, O3, and aerosol measurements from NASA Global Tropospheric Experiment - Test flights 1981

A series of four instrument test flights was conducted during July 1981 in preparation for the NASA Global Tropospheric Experiment. The purpose of the flights was to demonstrate the feasibility and value of simultaneously measuring several specific atmospheric pollutants over a 25 deg latitudinal range. Carbon monoxide and methane grab samples were obtained simultaneously with nearly continuous in situ ozone and remote ozone and aerosol optical radar measurements. The sampling platform was a NASA Electra, a four engine turboprop aircraft. Attention is given to CO and CH4 sample collection and analysis, ozone measurement methods, the aerosol measurement method, an interpretation of the optical radar display, and a synergistic consideration of results.

Hinton, R. R.↗

NASA NTRS1981

Differences in the concentrations of atmospheric trace gases in and above the tropical boundary layer

Weekly air samples were collected at Cape Kumakahi (0 km) and at nearby Mauna Loa Observatory (3.4 km) which is above the boundary layer. EC/GC and GC/FID techniques were used to measure CH3I, CHCl3, CO and CH4 which are largely natural in origin, and C2Cl4, CCl4, CH3CCl3, (F-11), CCl2F2, (F-12), CHClF, (F-22) and C2F3Cl3 (F-113), which are due to anthropogenic (CCl3F) etc. activities. It was found that all these gases are significantly (alpha is equal to or less than 0.05) more abundant in the boundary layer than above it.

Rasmussen, R. A.↗

NASA NTRS1982

Molecular-beam sampling study of extinguishment of methane-air flames by dry chemicals

The use of Al2O3, NaHCO3, KHCO3, NH4H2PO4 and KCl powders for the inhibition of a methane/oxygen diffusion flame is studied through measurement of composition and temperature profiles, using a molecular beam mass spectrometer sampling system. In order to obtain significant inhibition without extinguishing the flame, a powder feeding rate of 2 mg/liter of gas was used for KCl and Al2O3, and of 3 mg/liter of gas for the remaining powders. CH4, O2, N2, H2O and CO2 concentrations were measured by the mass spectrometer, while temperature was measured by the time-of-flight technique. For the powder feeding rates used, Al2O3 was the least and KCl and NH2H4PO2 the most effective in reducing temperature; in reaction-inhibition effectiveness, Al2O3 was again lowest while KCl was superior to all others. Because the KCl concentration was only 2/3 that of NH4H2PO4, it is recommended as the most effective temperature reducer and reaction inhibitor.

Knuth, E. L.↗

NASA NTRS1982

Chemistry and evolution of Titan's atmosphere

The chemistry and evolution of Titan's atmosphere are reviewed, in light of the scientific findings from the Voyager mission. It is argued that the present N2 atmosphere may be Titan's initial atmosphere, rather than one photochemically derived from an original NH3 atmosphere. The escape rate of hydrogen from Titan is controlled by photochemical production from hydrocarbons. CH4 is irreversibly converted to less hydrogen-rich hydrocarbons, which over geologic time accumulate on the surface to a layer thickness of about 0.5 km. Magnetospheric electrons interacting with Titan's exosphere may dissociate enough N2 into hot, escaping N atoms to remove about 0.2 of Titan's present atmosphere over geologic time. The energy dissipation of magnetospheric electrons exceeds solar EUV energy deposition in Titan's atmosphere by an order of magnitude, and is the principal driver of nitrogen photochemistry. The environmental conditions in Titan's upper atmosphere are favorable to building up complex molecules, particularly in the north polar cap region.

Strobel, D. F.↗

NASA NTRS1982

Precursor gases of aerosols in the Mount St. Helens eruption plumes at stratospheric altitudes

Nineteen stratospheric samples from the eruption plumes of Mount St. Helens were collected in five flight experiments. The plume samples were collected at various altitudes from 13.1 to 20.7 km by using the Ames cryogenic sampling system on board the NASA U-2 aircraft. The enriched, cryogenically collected samples were analyzed by chromatography. The concentrations of aerosols precursor gases (OCS, SO2, and CS2), CH3Cl, N2O, CF2Cl2, and CFCl3 were measured by gas chromatography. Large enhancement of the mixing ratio of SO2 and moderate enhancement of CS2 and OCS were found in the plume samples compared with similar measurement under pre-volcanic conditions. A fast decay rate of the SO2 mixing ratio in the plume was observed. Measurement of Cl(-), SO2(2-), and NO3(-) by ion chromatography was also carried out on water solutions prepared from the plume samples. The results obtained with this technique imply large mixing ratios of HCl, (NO + NO2 + HNO3), and SO2, in which these constituents are the respective sources of the anions. Measurement of the Rn222 concentration in the plume was made. Other stratospheric constituents in the plume samples, such as H2O, CO2, CH4, and CO, were also observed.

Inn, E. C. Y.↗

NASA NTRS1982

A comparison of constituents of Mount St. Helens eruption clouds with those of some other volcanoes

Gases from Mount St. Helens were collected from the eruption clouds using an airplane during the period April 2 to April 8, 1980, and were analyzed for CO2, H2, CH4, and COS. The results were of similar magnitude to those obtained from magmatic eruptions in Central America. Thus, although the eruptions were evidently largely phreatic, magmatic gases may have played a larger role in these early small eruptions than has generally been believed. Electron micrographs of ash particles collected from the Mount St. Helens eruption clouds showed that the particles were for the most part much larger than those from the Central American eruptions.

Cadle, R. D.↗

NASA NTRS1983

High pressure cosmochemistry applied to major planetary interiors: Experimental studies

The infrared spectra of H2O ice VII and D2O ice VII were studied and techniques were developed for measuring adiabats of phases of NH3-H2O to 5 GPa. A mixing system for pressurized fluids was constructed in which liquid solutions of definite compositions can be prepared and loaded reliably into diamond cells in a project which seeks to determine the properties and boundaries of several high pressure phases of the H2-He-H2O-NH3-CH4 system. These data are needed to constrain theoretical models of the interiors of the major planets.

Nicol, M. F.↗

NASA NTRS1983

Tribological and microstructural characteristics of ion-nitrided steels

Three steels AISI 4140, AISI 4340 and AISI 304 stainless steel were ion nitrided in a plasma consisting of a 75:25 mixture of H2:N2, sometimes with a trace of CH4. Their surface topography was characterized by SEM and two distinct compound phases were identified: the gamma and the epsilon. The core-case hardness profiles were also established. The low Cr alloy steels have an extended diffusion zone in contrast to the 304 stainless steels which have a sharp interface. The depth of ion-nitriding is increased as the Cr content is decreased. Friction tests reveal that the gamma surface phase has a lower coefficient of friction than the epsilon phase. The lowest coefficient of friction is achieved when both the rider and the specimen surface are ion nitrided.

Spalvins, T.↗

NASA NTRS1983

Halogen Occultation Experiment (HALOE) gas cell life test program

The Halogen Occultation Experiment (HALOE) will use gas filter correlation radiometry to measure the atmospheric concentration profiles of HCl, HF, NO, and CH4 from the Upper Atmosphere Research Satellite. The need to contain the gases for the gas filter measurements has resulted in the development of gas cells and the need for a life test program to demonstrate that the gas cells will perform their functions for extended periods (several years) of time. This report describes the tests in the life test program, the test apparatus used, and the analysis techniques developed. The report also presents data obtained during the first 14 months of the test program.

Sullivan, E. M.↗

NASA NTRS1982

Long term storage of cryogens in space

Experimental design procedures leading to the configuration of a space-based cryogenic fluids test system are reported. Large quantities of cryogenic fluids are expected to be required in space for cooling systems, chemical and electrical OTVs, and resupply tankers. The design was guided by the necessity for representative storage and supply systems to be compatible with the Shuttle. Consideration was given to liquid hydrogen, oxygen, methane, and argon containers and concommitant fluid dynamics, thermal, and structural analyses. A 5% initial ullage was included for the liquids, except for methane, which was calculated at 8.9%. The Ar, CH4, and O2 tanks were set at 12.5 cu m, while the H2 tank was 37.4 cu m. The orbital experiment is required to provide actual thermal stabilization lags in a zero-g environment. Details of the Cryogenic Fluid Management Facility test module for flight on board the Shuttle are presented.

Fester, D. A.↗