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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,189 records · Page 66

All sources NASA NTRS DOE OSTI

NASA NTRS1978

Sprayable low density ablator and application process

A sprayable, low density ablative composition is described consisting esentially of: (1) 100 parts by weight of a mixture of 25-65% by weight of phenolic microballoons, 0-20% by weight of glass microballoons, 4-10% by weight of glass fibers, 25-45% by weight of an epoxy-modified polyurethane resin, 2-4% by weight of a bentonite dispersing aid, and 1-2% by weight of an alcohol activator for the bentonite; (2) 1-10 parts by weight of an aromatic amine curing agent; and (3) 200-400 parts by weight of a solvent.

Sharpe, M. H.↗

NASA NTRS1978

Surfactant-assisted liquefaction of particulate carbonaceous substances

A slurry of carbonaceous particles such as coal containing an oil soluble polar substituted oleophilic surfactant, suitably an amine substituted long chain hydrocarbon, is liquefied at high temperature and high hydrogen presence. The pressure of surfactant results in an increase in yield and the conversion product contains a higher proportion of light and heavy oils and less asphaltene than products from other liquefaction processes.

Hsu, G. C.↗

NASA NTRS1978

Phosphorylated epoxy adhesives

Fire retardant adhesives for aircraft interiors are developed. Monomers, epoxy synthesis, diamine synthesis, acrylic modified epoxy, and phosphorylated amine epoxy blends are examined.

Bilow, N.↗

NASA NTRS1978

Polyglutaraldehyde - A new reagent for coupling proteins to microspheres and for labeling cell-surface receptors

Glutaraldehyde polymerized in basic aqueous solutions was found to react with low molecular weight amines, immunoglobulins and hemoglobin. The polyglutaraldehyde was covalently bound to hydrophilic microspheres. The rate of addition of proteins to the polyglutaraldehyde-derivatized microspheres was investigated spectrophotometrically as a function of pH and temperature. The reaction of polyglutaraldehyde was found to be faster than that of the monomer. The findings led to successful labeling of human lymphocyte subpopulations.

Rembaum, A.↗

NASA NTRS1979

Space transportation system options for extended duration and power

A modification kit for the Space Transportation System (STS) Orbiter is proposed to provide more power and mission duration for payloads. The power extension package (PEP) - a flexible-substrate solar array deployed on the Space Shuttle Orbiter remote manipulator system - can provide as much as 29 kW total power for durations of 10 to 48 days. The kit is installed only for those flights which require enhanced power or duration. Modifications to the Orbiter thermal control and life support systems to improve heat balance and to reduce consumables are proposed. The changes consist of repositioning the Orbiter forward radiators and replacing the lithium hydroxide scrubber with a regenerable solid amine.

Loftus, J. P., Jr.↗

NASA NTRS1981

High char yield epoxy curing agents

Class of imide-amine curing agents preserves structural integrity, prevents fiber release, and is fully compatible with conventional epoxy resins; agents do not detract from composite properties while greatly reducing char yield. Materials utilizing curing are used in aerospace, automotive, and other structural components where deterioration must be minimized and fiber release avoided in event of fire.

Delvigs, P.↗

NASA NTRS1979

Extended duration orbiter study: CO2 removal and water recovery

Two electrochemical depolarized carbon dioxide concentrator subsystems were evaluated against baseline lithium hydroxide for (1) the baseline orbiter when expanded to accommodate a crew of seven (mission option one), (2) an extended duration orbiter with a power extension package to reduce fuel cell expendables (mission option two), and (3) an extended duration orbiter with a full capability power module to eliminate fuel cell expendables (mission option three). The electrochemical depolarized carbon dioxide concentrator was also compared to the solid amine regenerable carbon dioxide removal concept. Water recovery is not required for Mission Option One since sufficient water is generated by the fuel cells. The vapor compression distillation subsystem was evaluated for mission option two and three only. Weight savings attainable using the vapor compression distillation subsystem for water recovery versus on-board water storage were determined. Combined carbon dioxide removal and water recovery was evaluated to determine the effect on regenerable carbon dioxide removal subsystem selection.

Marshall, R. D.↗

NASA NTRS1979

Toughening of thermosetting polyimides

Work directed toward increasing the resistance to crack propagation of thermoset polyimides is described. Rubber modification and Teflon microfiber impregnation techniques for increasing fracture toughness are investigated. Unmodified Kerimid 601 has a fracture surface work value of 0.20 in-lbs/sq in. Dispersed particles of amine terminated butadiene acrylonitrile liquid rubber or of silicone rubber do not raise this value much. By contrast, 5 percent of well fibrillated Teflon produces an eight-fold increase in fracture toughness. Further process improvements should increase this factor to 20-30.

Gollob, D. S.↗

NASA NTRS1980

Liquid chromatographic characterization of PMR-15 resin and prepreg

A liquid chromatographic method has been developed capable of providing a chemical fingerprint of PMR-15 resin solutions and prepreg. The amounts of two of the monomers can be quantified so their experimentally determined molar ratio can be compared to the formulated one. Only the monomers were detected in fresh resin solution, whereas several additional components, resulting from an association or reaction between the norbornenyl endcap and the amine, were detected in a resin solution aged for three days. Two commercial prepregs exhibited fingerprints similar to that of laboratory material, but three others contained additional components corresponding to higher esters and nadimides.

Reed, K. E.↗

NASA NTRS1980

Space Shuttle power extension package

A modification kit for the Space Transportation System (STS) Orbiter is proposed to provide more power and mission duration for payloads. The power extension package (PEP), a flexible-substrate solar array deployed on the Space Shuttle Orbiter remote manipulator system, can provide as much as 29 kW total power for durations of 10 to 48 days. The kit is installed only for those flights which require enhanced power or duration. The PEP is made possible by development of the flexible-substrate array technology and, in itself, contributes to the technology base for the use of large area solar cells. Modifications to the Orbiter thermal control and life support systems to improve heat balance and to reduce consumables are proposed. The changes consist of repositioning the Orbiter forward radiators and replacing the lithium hydroxide scrubber with a regenerable solid amine.

Loftus, J. P., Jr.↗

NASA NTRS1977

Insoluble polyelectrolyte and ion-exchange hollow fiber impregnated therewith

The number of quaternary sites and ion exchange capacity of a polyquaternary, cross linked, insoluble copolymer of a vinyl pyridine and a dihalo organic compound is increased by about 15-35% by reaction of the polymer with an amine followed by quaternization, if required. The polymer forms spontaneously in the presence of a substrate such as within the pores of a hollow fiber. The improved resin impregnated fiber may be utilized to remove ions from waste or process steams.

Rembaum, A.↗

NASA NTRS1981

Composition and method for making polyimide resin-reinforced fabric

A composition for making polyimide resin reinforced fibers or fabric is discussed. The composition includes a polyfunctional ester, a polyfunctional amine, and an end capping agent. The composition is impregnated into fibers or fabric and heated to form prepreg material. The tack retention characteristics of this prepreg material are improved by incorporating into the composition a liquid olefinic material compatible with the other ingredients of the composition. The prepreg material is heated at a higher temperature to effect formation of the polyimide resin and the monomeric additive is incorporated in the polyimide polymer structure.

Serafini, T. T.↗

NASA NTRS1980

Lightside Atmospheric Revitalization System

The system was studied as a replacement to the present baseline LiOH system for extended duration shuttle missions. The system consists of three subsystems: a solid amine water desorbed regenerable carbon dioxide removal system, a water vapor electrolysis oxygen generating system, and a Sabatier reactor carbon dioxide reduction system. The system is designed for use on a solar powered shuttle vehicle. The majority of the system's power requirements are utilized on the Sun side of each orbit, when solar power is available.

Colling, A. K.↗

NASA NTRS1980

Advanced resin systems for graphite epoxy composites

The value of resin/carbon fiber composites as lightweight structures for aircraft and other vehicle applications is dependent on many properties: environmental stability, strength, toughness, resistance to burning, smoke produced when burning, raw material costs, and complexity of processing. A number of woven carbon fiber and epoxy resin composites were made. The epoxy resin was commercially available tetraglycidylmethylene dianiline. In addition, composites were made using epoxy resin modified with amine and carboxyl terminated butadiene acrylonitrile copolymer. Strength and toughness in flexure as well as oxygen index flammability and NBS smoke chamber tests of the composites are reported.

Gilwee, W. J.↗

NASA NTRS1981

The effect of elastomer chain length on properties of silicone-modified polyimide adhesives

A series of polyimides containing silicone elastomers was synthesized in order to study the effects of the elastomer chain length on polymer properties. The elastomer with repeat units varying from n=10 to 105 was chemically reacted into the backbone of an addition polyimide oligomer via reactive aromatic amine groups. Glass transition temperatures of the elastomer and polyimide phases were observed by torsional braid analysis. The elastomer-modified polyimides were tested as adhesives for bonding titanium in order to determine their potential for aerospace applications. Adhesive lap shear tests were performed before and after aging bonded specimens at elevated temperatures.

St.clair, A. K.↗

NASA NTRS1981

Structural studies on HCN oligomers

NMR spectral studies on the HCN oligomers suggest the presence of carboxamide and urea groupings. The release of CO2, H2O, HCN, CH3CN, HCONH2 and pyridine on pyrolysis is consistent with the presence of these groupings as well as carboxylic acid groups. No basic primary amine groupings could be detected with fluorescamine. Hydrazinolysis of the HCN oligomers releases 10% of the amino acids normally released by acid hydrolysis. The oligomers give a positive biuret test but this is not due to the presence of peptide bonds. There is no conclusive evidence for the presence of peptide bonds in the HCN oligomers. No diglycine was detected on partial hydrolysis of the HCN oligomers at pH 8.5 suggesting that HCN oligomers were not a source of prebiotic peptides.

Ferris, J. P.↗

NASA NTRS1980

Chemical analysis of LARC-160 polyimide

As part of a detailed NASA-sponsored study of chemical composition/property sensitivity of the LARC-160 polymerization of monomeric reactants (PMR) polyimide system, a number of liquid chromatographic techniques have been employed. The ester monomers in this system are characterized by a reverse-phase ion-suppression method. Mono, di, and triesters of the 3,3',4,4'-benzophenonetetracarboxylic acid ingredient are identified and their isomeric forms resolved. The 5-norbornene-2,3-dicarboxylic acid ester (nadic ester) endcapper is detected by low wavelength ultraviolet sensing. A second method, reverse-phase ion-pair chromatography, is employed for determining unreacted amines. The extent of resin B-staging is monitored through analysis of the ester/amine oligomers.

Dynes, P. J.↗

NASA NTRS1980

Analysis of aromatic polyamine mixtures for formulation of LARC-160 resin

An investigation was conducted to identify a potential substitute for the aromatic polyamine mixture, Jeffamine AP-22, currently used to formulate LARC-160 polyimide precursor resin. Jeffamine AP-22 was characterized by high pressure liquid chromatography and mass spectrometry. Eleven different aromatic amines in the mixture were isolated and identified. Subsequent liquid chromatographic analysis of nine additional commercially available aromatic polyamine mixtures identified three candidates that are similar in composition to AP-22.

Young, P. R.↗