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At least 1,171 records · Page 65
All sourcesNASA NTRSDOE OSTI
NASA NTRS1993

The quantum dynamics of electronically nonadiabatic chemical reactions

Considerable progress was achieved on the quantum mechanical treatment of electronically nonadiabatic collisions involving energy transfer and chemical reaction in the collision of an electronically excited atom with a molecule. In the first step, a new diabatic representation for the coupled potential energy surfaces was created. A two-state diabatic representation was developed which was designed to realistically reproduce the two lowest adiabatic states of the valence bond model and also to have the following three desirable features: (1) it is more economical to evaluate; (2) it is more portable; and (3) all spline fits are replaced by analytic functions. The new representation consists of a set of two coupled diabatic potential energy surfaces plus a coupling surface. It is suitable for dynamics calculations on both the electronic quenching and reaction processes in collisions of Na(3p2p) with H2. The new two-state representation was obtained by a three-step process from a modified eight-state diatomics-in-molecules (DIM) representation of Blais. The second step required the development of new dynamical methods. A formalism was developed for treating reactions with very general basis functions including electronically excited states. Our formalism is based on the generalized Newton, scattered wave, and outgoing wave variational principles that were used previously for reactive collisions on a single potential energy surface, and it incorporates three new features: (1) the basis functions include electronic degrees of freedom, as required to treat reactions involving electronic excitation and two or more coupled potential energy surfaces; (2) the primitive electronic basis is assumed to be diabatic, and it is not assumed that it diagonalizes the electronic Hamiltonian even asymptotically; and (3) contracted basis functions for vibrational-rotational-orbital degrees of freedom are included in a very general way, similar to previous prescriptions for locally adiabatic functions in various quantum scattering algorithms.

Truhlar, Donald G.↗
NASA NTRS1995

Non-WKB Alfven waves in the solar wind: Propagation and reflection of pulses

The non-WKB propagation of Alfven waves has been studied either for harmonic waves, or in terms of the evolution of power spectra. Here we present analytical and numerical solutions for the propagation of pulses, the goal being to understand how waves reflect in a smoothly varying medium. We here limit our discussion to a radial magnetic field. If we launch an outward-propagating delta function, it leaves behind an inward-propagaing signal which is roughly a square wave whose amplitude is proportional to the area under the initial pulse. The inward-propagating signal also reflects, producing an outward propagating pulse which is roughly triangular in shape and which grows with time. These signals also oscillate if v is less than v(A), but they grow if v is greater than v(A). The result reported by us earlier, that the 'ingoing Elsasser variable' can have outgoing phase, is now understood to be a consequence of interference. The inward-propagating signal depends to lowest order on the integral of the outgoing waves which have preceded it. Thus the ingoing signal can be expected to develop as a random walk. This will affect the radial evolution of cross-helicity in the solar wind.

Hollweg, J. V.↗
NASA NTRS1983

Large-amplitude hydromagnetic waves in collisionless relativistic plasma - Exact solution for the fast-mode magnetoacoustic wave

An exact nonlinear solution is found to the relativistic kinetic and electrodynamic equations (in their hydromagnetic limit) that describes the large-amplitude fast-mode magnetoacoustic wave propagating normal to the magnetic field in a collisionless, previously uniform plasma. It is pointed out that a wave of this kind will be generated by transverse compression of any collisionless plasma. The solution is in essence independent of the detailed form of the particle momentum distribution functions. The solution is obtained, in part, through the method of characteristics; the wave exhibits the familiar properties of steepening and shock formation. A detailed analysis is given of the ultrarelativistic limit of this wave.

Barnes, A.↗
NASA NTRS1972

Handbook of operation and maintenance instructions for Model 5208A bit synchronizer unit

Electrical/mechanical characteristics, operation, theory of operation, parts list, and electrical diagrams for the model 5208A bit synchronizer unit are provided. The unit is capable of performing the functions of bit synchronization and signal conditioning on demodulated wave trains containing amplitude, frequency, and phase distortions, as well as additive noise. Operating frequencies in the 1 to 27 MHz bit rate range are accommodated through the use of discrete frequency plug-in subunits. The unit provides 0 and 180 degree clocks and either a single signal hard decision, or a three bit quantized soft decision data output.

Source record↗
NASA NTRS1972

Electromagnetic scattering by arbitrarily oriented ice cylinders.

The scattering of electromagnetic waves by arbitrarily oriented, infinitely long circular cylinders is solved by following the procedures outlined by van de Hulst. The far-field intensities for two cases of a linearly polarized incident wave are derived. The scattering coefficients involve the Bessel functions of the first kind, the Hankel functions of the second kind, and their first derivatives. Calculations are made for ice cylinders at three wavelengths: 0.7, 3, and 10 microns. The numerical results of intensity coefficients are presented as functions of the observation angle. A significant cross-polarized component for the scattered field, which vanishes only at normal incidence, is obtained. It is also shown that the numerous interference maxima and minima of the intensity coefficients due to single-particle effects depend on the size parameter as well as on the oblique incident angle.

Liou, K.-N.↗
NASA NTRS1973

Automation of measurement of spatial damping parameters

A traveling wave unit was built to process measurement data on spatial damping parameters and to simplify statistical treatment of the results. Mean values of the loss coefficient, lengths of flexual waves, and wave propagation velocities for a given set of discrete functions were determined. Results are given in a table.

Akolzin, A. N.↗
NASA NTRS1974

Attenuation characteristics of nonlinear pressure waves propagating in pipes

A series of experiments was conducted to investigate temporal and spatial velocity distributions of fluid flow in 3-in. open-end pipes of various lengths up to 210 ft, produced by the propagation of nonlinear pressure waves of various intensities. Velocity profiles across each of five sections along the pipes were measured as a function of time with the use of hot-film and hot-wire anemometers for two pressure waves produced by a piston. Peculiar configurations of the velocity profiles across the pipe section were noted, which are uncommon for steady pipe flow. Theoretical consideration was given to this phenomenon of higher velocity near the pipe wall for qualitative confirmation. Experimentally time-dependent velocity distributions along the pipe axis were compared with one-dimensional theoretical results obtained by the method of characteristics with or without diffusion term for the purpose of determining the attenuation characteristics of the nonlinear wave propagation in the pipes.

Shih, C. C.↗
NASA NTRS1974

Binary stellar winds

Stellar winds from a binary star will interact with each other along a contact discontinuity. We discuss qualitatively the geometry of the flow and field resulting from this interaction in the simplest case where the stars and winds are identical. We consider the shape of the critical surface (defined as the surface where the flow speed is equal to the sound speed) as a function of stellar separation and the role of shock waves in the flow field. The effect of stellar spin and magnetic sectors on the field configuration is given. The relative roles of mass loss and magnetic torque in the evolution of orbital parameters are discussed.

Siscoe, G. L.↗
NASA NTRS1974

Binary stellar winds

Stellar winds from a binary star pair will interact with each other along a contact discontinuity. We discuss qualitatively the geometry of the flow and field resulting from this interaction in the simplest case where the stars and winds are identical. We consider the shape of the critical surface (defined as the surface where the flow speed is equal to the sound speed) as a function of stellar separation and the role of shock waves in the flow field. The effect of stellar spin and magnetic sectors on the field configuration is given. The relative roles of mass loss and magnetic torque in the evolution of orbital parameters is discussed.

Siscoe, G. L.↗
NASA NTRS1977

Periodic variations of total ozone and of its vertical distribution

The phase and amplitude of the annual, semiannual, and quasi-biennial oscillations to total ozone data for the Northern Hemisphere in the period 1957-1972 and for Northern Hemisphere ozonesonde data for variable periods from 1962-1974 have been plotted as functions of latitude, longitude, and altitude. The largest annual wave amplitude in total ozone occurs over eastern Siberia. In total ozone, the region of maximum quasi-biennial oscillation (QBO) coincides with that of the annual wave. The major feature of the QBO in the vertical distribution is the maximum amplitude in the arctic just above the tropopause. As for the semiannual wave, the maximum in total ozone lies in the arctic, displaced slightly to the Siberian side. In the vertical, its maximum amplitude is near 18 km. The phase appears to progress poleward, with maxima at high latitudes occurring in March-April.

Wilcox, R. W.↗
NASA NTRS1978

Bubbly flow model for the dynamic characteristics of cavitating pumps

The recent experimental transfer matrices obtained by Ng and Brennen (1978) for some axial flow pumps revealed some dynamic characteristics which were unaccounted for by any existing theoretical analysis; their visual observations suggested that the bubbly cavitating flow in the blade passages could be responsible for these effects. A theoretical model of the dynamic response of this bubbly blade-passage flow is described in the present paper. Void-fraction fluctuations in this flow result not only from pressure fluctuations but also because the fluctuating angle of attack causes fluctuations in the rate of production of bubbles near the leading edge. The latter causes kinematic waves which interact through the boundary conditions with the dynamic waves caused by pressure fluctuation. The resulting theoretical transfer functions which results are in good qualitative agreement with the experiments; with appropriate choices of two parameters good quantitative agreement is also obtained. The theoretical model also provides one possible explanation of the observation that the pump changes from an essentially passive dynamic element in the absence of cavitation to a progressively more active element as the extent of cavitation increases.

Brennen, C.↗
NASA NTRS1978

Remote sensing of the ozone profile in the lower stratosphere using UV and IR measurements from Nimbus-4

A method of combining the information from the infrared interferometer spectrometer (IRIS) and the backscatter ultraviolet spectrometer (BUV) on board the Nimbus-4 satellite to derive the ozone profile from 10 mb to surface is described. The radiance in the IRIS 9-micron band can be related to the ozone profile by the radiative transfer equation. The IR intensity due to ozone is dependent on the pressure broadening of spectral lines, and an estimate of a weighted mean pressure of the ozone layer can be obtained from total ozone supplied by BUV long wave intensity measurements. With the aid of the Chapman function, a model of the ozone concentration profile described by three parameters is obtained. Given the ozone concentration at 10 mb one calculates several possible combinations of the three parameters that can produce the required total ozone, and the final choice of parameter is determined from IR measurements. An ozone profile calculated in this way reproduces well the gross features of balloon ozone sounding results. Meridional cross sections of ozone concentration have also been derived which are in reasonably good agreement with balloon-derived cross-section for the northern latitudes and tropics.

Prabhakara, C.↗
NASA NTRS1979

Status of equation of state of solids

The results of equation of state (pressure-volume-temperature) measurements for the rare gas solids, alkali metals and alkali halides are reviewed. The precision and errors associated with the techniques most commonly used to obtain measurements of volume as a function of pressure, including piston volume displacement, ultrasonic, shock wave, and Brillouin scattering techniques, length change measurement, and combined length change and ultrasonic transit techniques, are presented. The various equations of state which are normally used to represent these measurements are discussed.

Ruoff, A. L.↗
NASA NTRS1979

Fluctuations of inverted V electron fluxes

Fluctuations of low-energy electron fluxes during an inverted V event on Nov. 5, 1975 were detected by fixed-energy electrostatic analyzers used in the LEE (low-energy electron) experiment onboard the AE-D satellite. The flux fluctuations were observed at energies of 0.78, 1.38, and 2.62 keV, when these energies were below that of the monoenergetic beam. This suggests that the fluctuations might occur over a wide range of energies. The fluctuations were confined within a pitch angle of 15 degrees, the amplitude increasing with decreasing pitch angle. The oscillation frequencies centered around 1.75 Hz. Fluctuations at two energies were generally correlated. The heating of secondary electrons, deduced from an analysis of the distribution function, is attributed to anomalous heating by electron plasma wave turbulence, whose intensity was modulated by a low-frequency wave. The results are consistent with a model, according to which auroral precipitating electron beams enhance the anomalous resistivity at the topside ionosphere through parametric instabilities.

Lin, C. S.↗
NASA NTRS1980

The confrontation between general relativity and experiment

Experiments that test the foundations of gravitation theory in terms of the Einstein equivalence principle are discussed along with solar system tests of general relativity at the post-Newtonian level. These include classical (light-deflection, time delay and perihelion shift) tests as well as tests of the strong equivalence principle. The binary pulsar is discussed as an extra-solar-system gravitational testing ground, and attention is given to the multipolarity of the waves and the amount of radiation damping. The mass function, periastron shift, redshift-Doppler parameter and rate of change of the orbit period (Pb) of the binary pulsar are also considered, and it is suggested that the measurement of Pb represents the first observation of the effects of gravitational radiation.

Will, C. M.↗