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At least 1,171 records · Page 65

National Energy Water Treatment & Speciation (NEWTS): A Water & Critical Mineral Database and Dashboard

The scarcity of water resources, the need for beneficial water reuse, and the challenges of wastewater treatment are becoming increasingly pressing in economic, social, and environmental domains. Addressing these concerns requires effective treatment strategies to manage wastewater streams and tackle environmental and economic issues. Furthermore, the recovery of critical minerals from the waste streams associated with energy production holds the promise of offsetting treatment costs and securing local sources of valuable minerals. However, relevant data on these waste streams are dispersed and challenging to locate. The process of ingesting such data into modeling software often involves multiple steps, requiring data restructuring to meet software-input requirements. The non-standardized reporting of water data makes data aggregation and reformatting a time-consuming process. Additionally, essential attributes necessary for modeling water treatment and mineral scale formation are frequently missing. Moreover, data gaps vary depending on the region of interest. Consequently, there is a pressing need for high-quality energy-water composition data that can be easily imported into water chemistry modeling software. To address this need, the National Energy Technology Laboratory has created the National Energy Water Treatment and Speciation (NEWTS) Database and Dashboard—a free online tool catering to community leaders and water researchers. NEWTS facilitates a comprehensive understanding of the composition of energy-related wastewater streams in the United States. The datasets provide detailed concentrations and speciation of major and minor aqueous compounds in energy-related wastewater streams, including power plant leachate, acid mine drainage, brackish water, and oil and gas produced water across the United States. Many of the aqueous species are critical minerals (Li, REEs) in high demand to modernize the world’s energy infrastructure. Many of the datasets also contain volumetric flow-rates needed to model the treatment and reuse scenarios in advanced aqueous chemistry software programs. The NEWTS Database and Dashboard offer public access to hitherto challenging-to-access datasets, presented in a standardized format that is tailored for easy input into aqueous chemistry modeling software. By performing the work needed to transform dispersed, disparate data sources into unified, model-ready datasets, NEWTS serves as an essential resource in advancing water treatment research and sustainable water resource management.

produced water management↗

Identification of Human-Induced Changes in Atmospheric Moisture Content

Data from the satellite-based Special Sensor Microwave Imager (SSM/I) show that the total atmospheric moisture content over oceans has increased by 0.41 kg/sq m per decade since 1988. Results from current climate models indicate that water vapor increases of this magnitude cannot be explained by climate noise alone. In a formal detection and attribution analysis using the pooled results from 22 different climate models, the simulated "fingerprint" pattern of anthropogenically caused changes in water vapor is identifiable with high statistical confidence in the SSM/I data. Experiments in which forcing factors are varied individually suggest that this fingerprint "match" is primarily due to human-caused increases in greenhouse gases and not to solar forcing or recovery from the eruption of Mount Pinatubo. Our findings provide preliminary evidence of an emerging anthropogenic signal in the moisture content of earth's atmosphere.

Santer, B.D.↗

Developing Land Use Land Cover Maps for the Lower Mekong Basin to Aid Hydrologic Modeling and Basin Planning

This paper discusses research methodology to develop Land Use Land Cover (LULC) mapsfor the Lower Mekong Basin (LMB) for basin planning, using both MODIS and Landsat satellitedata. The 2010 MODIS MOD09 and MYD09 8-day reflectance data was processed into monthlyNDVI maps with the Time Series Product Tool software package and then used to classify regionallycommon forest and agricultural LULC types. Dry season circa 2010 Landsat top of atmosphere reflectance mosaics were classified to map locally common LULC types. Unsupervised ISODATAclustering was used to derive most LULC classifications. MODIS and Landsat classifications werecombined with GIS methods to derive final 250-m LULC maps for Sub-basins (SBs) 1–8 of the LMB.The SB 7 LULC map with 14 classes was assessed for accuracy. This assessment compared randomlocations for sampled types on the SB 7 LULC map to geospatial reference data such as Landsat RGBs,MODIS NDVI phenologic profiles, high resolution satellite data, and Mekong River Commissiondata (e.g., crop calendars). The SB 7 LULC map showed an overall agreement to reference data of~81%. By grouping three deciduous forest classes into one, the overall agreement improved to ~87%.The project enabled updated regional LULC maps that included more detailed agriculture LULCtypes. LULC maps were supplied to project partners to improve use of Soil andWater AssessmentTool for modeling hydrology and water use, plus enhance LMB water and disaster managementin a region vulnerable to flooding, droughts, and anthropogenic change as part of basin planningand assessment.

land use land cover mapping; SWAT hydrologic model↗

The Surface Water and Ocean Topography Satellite Mission - An Assessment of Swath Altimetry Measurements of River Hydrodynamics

The Surface Water and Ocean Topography (SWOT) satellite mission, scheduled for launch in 2020 with development commencing in 2015, will provide a step-change improvement in the measurement of terrestrial surface water storage and dynamics. In particular, it will provide the first, routine two-dimensional measurements of water surface elevations, which will allow for the estimation of river and floodplain flows via the water surface slope. In this paper, we characterize the measurements which may be obtained from SWOT and illustrate how they may be used to derive estimates of river discharge. In particular, we show (i) the spatia-temporal sampling scheme of SWOT, (ii) the errors which maybe expected in swath altimetry measurements of the terrestrial surface water, and (iii) the impacts such errors may have on estimates of water surface slope and river discharge, We illustrate this through a "virtual mission" study for a approximately 300 km reach of the central Amazon river, using a hydraulic model to provide water surface elevations according to the SWOT spatia-temporal sampling scheme (orbit with 78 degree inclination, 22 day repeat and 140 km swath width) to which errors were added based on a two-dimension height error spectrum derived from the SWOT design requirements. Water surface elevation measurements for the Amazon mainstem as may be observed by SWOT were thereby obtained. Using these measurements, estimates of river slope and discharge were derived and compared to those which may be obtained without error, and those obtained directly from the hydraulic model. It was found that discharge can be reproduced highly accurately from the water height, without knowledge of the detailed channel bathymetry using a modified Manning's equation, if friction, depth, width and slope are known. Increasing reach length was found to be an effective method to reduce systematic height error in SWOT measurements.

Wilson, Matthew D.↗

Sea Ice Collision Risk Assessment for Tidal Turbine Siting in Cook Inlet, Alaska

Cook Inlet has great potential for tidal stream energy development. However, the presence of drifting sea ice could create hazardous collision risks for tidal turbine farms. Before turbines can be installed in Cook Inlet, sites must be surveyed to determine how often sea ice is present, how fast it will be moved by the current, and where the trajectories of drifting sea ice will be concentrated. In this study, we use remotely sensed data to characterize the seasonal sea ice conditions in Cook Inlet, a hydrodynamic model to map the water velocities, and a particle trajectory tracking model to calculate collision risks. The resulting sea ice coverage and collision risk maps will enable tidal energy developers to choose the best locations for the deployment of tidal turbines and other offshore platforms in Cook Inlet.

16 TIDAL AND WAVE POWER↗

Exchange of water vapor between the atmosphere and surface of Mars.

A model for exchange of water from the atmosphere to condensing CO2 caps is developed. The rate of water condensation in the caps is assumed to be proportional to the meridional heat flux. It follows that the amount of water condensed in the caps varies inversely with the amount of CO2 condensed. The seasonal phase of the release of water from the caps is not consistent with observed variations in the abundance of atmospheric water. Seasonal variations of atmospheric water abundance are most consistent with vapor exchange between the atmosphere and permafrost in the subtropics.

Leovy, C. B.↗

Developing lake sampling strategies with existing Landsat data

On the basis of the assumptions that Landsat image densities relate to water quality, that lake densities can be modeled, and that homogeneous water quality areas can therefore be predicted, a method is developed for the selection of optimum water quality sampling locations on Oneida Lake in central New York. Patterns of Oneida Lake density on 24 Landsat band 5 images were traced from the screen of a density slicer, and the lake was gridded into 161 1.25 X 1.25-km cells, with image density levels encoded for each cell. Cell density levels were then employed as the dependent variable in correlations and multiple regression equations with degree days, resultant wind speed, and resultant direction. Cell density levels were averaged over two-week periods, and the averages were correlated with water quality measurements.

Philipson, W. R.↗

A study on diagnosability of space station ECLSS

The use is demonstrated of the Multigraph Architecture (MGA) for studies on the Environment Control and Life Support System (ECLSS). The objective was the following: (1) to create an updated set of models of the Potable Water Subsystem (PWS) by using the graphical model building tools of the Multigraph Programming Environment (MPE); (2) to derive a real time alarm simulator from the models; and (3) to demonstrate the effects of sensor allocation on the diagnosability of the PWS. This work may serve as a preliminary study for the detailed analysis of the sensor allocation and diagnosability problems in the ECLSS.

Padalkar, S.↗

A Technique for Assimilating GOES-Derived Land Surface Products into Regional Models to Improve the Representation of Land Surface Forcing

As the parameterizations of surface energy budgets in regional models have become more complete physically, models have the potential to be much more realistic in simulations of coupling between surface radiation, hydrology, and surface energy transfer. Realizing the importance of properly specifying the surface energy budget, many institutions are using land-surface models to represent the lower boundary forcing associated with biophysical processes and soil hydrology. However, the added degrees of freedom due to inclusion of such land-surface schemes require the specification of additional parameters within the model system such as vegetative resistances, green vegetation fraction, leaf area index, soil physical and hydraulic characteristics, stream flow, runoff, and the vertical distribution of soil moisture. A technique has been developed for assimilating GOES-IR skin temperature tendencies into the surface energy budget equation of a mesoscale model so that the simulated rate of temperature change closely agrees with the satellite observations. A critical assumption of the technique is that the availability of moisture (either from the soil or vegetation) is the least known term in the model's surface energy budget. Therefore, the simulated latent heat flux, which is a function of surface moisture availability, is adjusted based upon differences between the modeled and satellite-observed skin temperature tendencies. An advantage of this technique is that satellite temperature tendencies are assimilated in an energetically consistent manner that avoids energy imbalances and surface stability problems that arise from direct assimilation of surface shelter temperatures. The fact that the rate of change of the satellite skin temperature is used rather than the absolute temperature means that sensor calibration is not as critical. An advantage of this technique for short-range forecasts is that it does not require a complex land-surface formulation within the atmospheric model. As a result, the need to specify poorly known soil and vegetative characteristics is eliminated. The GOES assimilation technique has been incorporated into the PSU/NCAR MM5. Results will be presented to demonstrate the ability of the assimilation scheme to improve short-term simulations of near-surface air temperature and mixing ratio during the warm season for several selected cases during June of 1995 and June 1997 which exhibit a variety of atmospheric and land-surface conditions. In addition, the simulations produced by the assimilation technique will be compared with those produced by the MM5/BATS coupled model initialized with soil water content derived from a soil hydrology model.

Lapenta, William M.↗

Water Phase Change Heat Exchanger System Level Analysis for Low Lunar Orbit

In low Lunar orbit (LLO) the thermal environment is cyclic - extremely cold in the eclipse and as warm as room temperature near the subsolar point. Phase change material heat exchangers (PCHXs) are the best option for long term missions in these environments. The Orion spacecraft will use a n-pentadecane wax PCHX for its envisioned mission to LLO. Using water as a PCM material is attractive because its higher heat of fusion and greater density result in a lighter, more compact PCHX. To assess the use of a water PCHX for a human spacecraft in a circular LLO, a system level analysis was performed for the Orion spacecraft. Three cases were evaluated: 1) A one-to-one replacement of the wax PCHX on the internal thermal control loop with a water PCHX (including the appropriate control modifications), 2) reducing the radiator return setpoint temperature below Orion's value to enhance PCHX freezing, and 3) placing the water PCM on the external loop. The model showed that the water PCHX could not be used as a drop-in replacement for the wax PCHX. It did not freeze fully during the eclipse owing to its low freezing point. To obtain equivalent performance, 40% more radiator area than the Orion baseline was required. The study shows that, although water PCHXs are attractive at a component level, system level effects mean that they are not the best choice for LLO.

Navarro, Moses↗

Water-Film Cooling of an 80 deg Total-Angle Cone at a Mach Number of 2 for Airstream Total Temperatures up to 3,000 deg R

Film-cooling tests, with water as the coolant, were made on an 80 deg total-angle cone in a Mach number 2 free jet at sea-level pressure. The tests were made at free-stream total temperatures from 1,500 deg R to 3,000 deg R and at free-stream Reynolds numbers per foot from 8 x 10(exp 6) to 3 x 10(exp 6). The tests showed that the downstream end of the model became very hot if the coolant rate was too small to cover the complete model with a water film. This water film was fairly symmetrical when the model was at zero angle of attack but was very asymmetrical when the model was at an angle of attack of 5 deg. A comparison with results of a previous transpiration-cooling test showed that, with water as the coolant, transpiration cooling was at least 2.5 times as efficient as the film cooling of the present tests.

Carter, Howard S.↗

Modeling Clustered DNA Damage by Ionizing Radiation Using Multinomial Damage Probabilities and Energy Imparted Spectra

Simple and complex clustered DNA damage represent the critical initial damage caused by radiation. In this paper, a multinomial probability model of clustered damage is developed with probabilities dependent on the energy imparted to DNA and surrounding water molecules. The model consists of four probabilities: (A) direct damage of sugar-phosphate moieties leading to SSB, (B) OH− radical formation with subsequent SSB and BD formation, (C) direct damage to DNA bases, and (D) energy imparted to histone proteins and other molecules in a volume not leading to SSB or BD. These probabilities are augmented by introducing probabilities for the relative location of SSB using a ≤10 bp criteria for a double-strand break (DSB) and for the possible success of a radical attack that leads to SSB or BD. Model predictions for electrons, 4He, and 12C ions are compared to the experimental data and show good agreement. Thus, the developed model allows an accurate and rapid computational method to predict simple and complex clustered DNA damage as a function of radiation quality and to explore the resulting challenges to DNA repair.

Biochemistry & Molecular Biology↗

Pretest Plan for a Quarter Scale AFT Segment of the SRB Filament Wound Case in the NSWC Hydroballistics Facility

In support of preflight design loads definition, preliminary water impact scale model are being conducted of space shuttle rocket boosters. The model to be used as well as the instrumentation, test facilities, and test procedures are described for water impact tests being conducted at test conditions to simulate full-scale initial impact at vertical velocities from 65 to 85 ft/sec. zero horizontal velocity, and angles of 0,5, and 10 degrees.

Adoue, J. A.↗

Shock layer vacuum UV spectroscopy in an arc-jet wind tunnel

An experimental program is being developed to obtain measurements of the incident surface radiation in the 1000 A to 2000 A range from the shock stagnation region of a blunt model in the Ames 20 MW Arc-Jet Wind Tunnel. The setup consists of a water-cooled blunt model, with a magnesium fluoride forward-viewing window. Radiation incident on the window is optically imaged via an evacuated system and reflective optical elements onto the entrance slit of a spectrograph. The model will be exposed to the supersonic plasma stream from the exit nozzle of the arc-jet tunnel. The resulting bow shock radiation will be measured. It is expected that this experiment will help evaluate the importance of atomic N and O lines to the radiative heating of future Aeroassist Space Transfer Vehicles (ASTVs).

Palumbo, G.↗

Clouds and Radiation Processes in Regional Climate Models Evaluated Using Observations Over the Ice‐free Arctic Ocean

Abstract The presence of clouds in the Arctic regulates the surface energy budget (SEB) over the sea‐ice surface and the ice‐free ocean. Following several previous field campaigns, the cloud‐radiation relationship, including cloud vertical structure and phase, has been elucidated; however, modeling of this relationship has matured slowly. In recognition of the recent decline in the Arctic sea‐ice extent, representation of the cloud system in numerical models should consider the effects of areas covered by sea ice and ice‐free areas. Using an in situ stationary meteorological observation data set obtained over the ice‐free Arctic Ocean by the Japanese Research Vessel Mirai (September 2014), coordinated evaluation of six regional climate models (RCMs) with nine model runs was performed by focusing on clouds and the SEB. The most remarkable findings were as follows: (1) reduced occurrence of unstable stratification with low‐level cloud water in all models in comparison to the observations, (2) significant differences in cloud water representations between single‐ and double‐moment cloud schemes, (3) extensive differences in partitioning of hydrometeors including solid/liquid precipitation, and (4) pronounced lower‐tropospheric air temperature biases. These issues are considered as the main sources of SEB uncertainty over ice‐free areas of the Arctic Ocean. The results from a coupled RCM imply that the SEB is constrained by both the atmosphere and the ocean (and sea ice) with considerable feedback. Coordinated improvement of both stand‐alone atmospheric and coupled RCMs would promote a more comprehensive and improved understanding of the Arctic air‐ice‐sea coupled system.

Inoue, Jun↗

Thermal conductivity of comets

The thermal conductivity of two comet models is calculated. Both models assume the comets to be heterogeneous in composition. One model considers the comet to have a nucleus of water-ice mixed with basaltic and meteoritic material in the form of dust and agglomerated particles surrounded by a layer of water-frost. The second model assumes the frost and water-ice layers have sublimated, leaving a porous structure to some depth composed of solid basaltic and meteoritic material with residual gases. K values are calculated as a function of depth, density, temperature and porosity.

Kumar, G. N.↗

The role of molecular hydrogen and methane oxidation in the water vapour budget of the stratosphere

The detailed photochemistry of methane oxidation has been studied in a coupled chemical/dynamical model of the middle atmosphere. The photochemistry of formaldehyde plays an important role in determining the production of water vapor from methane oxidation. At high latitudes, the production and transport of molecular hydrogen is particularly important in determining the water vapor distribution. It is shown that the ratio of the methane vertical gradient to the water vapor vertical gradient at any particular latitude should not be expected to be precisely 2, due both to photochemical and dynamical effects. Modeled H2O profiles are compared with measurements from the Limb Infrared Monitor of the Stratosphere (LIMS) experiment at various latitudes. Molecular hydrogen is shown to be responsible for the formation of a secondary maximum displayed by the model water vapor profiles in high latitude summer, a feature also found in the LIMS data.

Le Texier, H.↗

Changes in water vapor adsorption and water film thickness in clayey materials as a function of relative humidity

Abstract Soil water, with adsorbed water being an important component, plays an important role in fluid flow and chemical movement in the unsaturated zone. The adsorbed water consists of water film and interlayer water, and its content is related to the relative humidity (RH). This study theoretically and experimentally focuses on the variation in adsorbed water content in clayey materials as the RH changes. Based on a slit‐pore model, three types of water (water film, interlayer water, and capillary water) could be present in the water vapor adsorption process. The variation of water film is obtained from the analysis of interfacial forces, and then the total water content can be quantitatively subdivided into these three types of water for different RH values. The slit‐pore adsorption model was used with experimental measurements (water vapor adsorption and N 2 physisorption) to quantify the amounts and interrelationships of these three different types of water to six clayey materials, namely three clay minerals (kaolinite, montmorillonite, and illite–smectite mixed layer) and three clay‐rich sediments from the Jianghan Plain in China. The main results are that (a) the volumes of water vapor adsorption are much greater than those of N 2 adsorption except for kaolinite; (b) interlayer water largely dominates the growth of total water content in montmorillonite and results in a concentration of 0.090 ml g −1 at 95% RH; and (c) the minimum thickness of water film is calculated to be 0.23 nm, and the maximum value is one‐third of the pore width by considering the interfacial forces.

54 ENVIRONMENTAL SCIENCES↗