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At least 1,171 records · Page 65

Application of a Chemical Index to Aerosol Mass Spectrometry: Delta Plots and Functional Group Distributions

A better understanding of the chemical properties of organic aerosol (OA) particles will improve our ability to characterize their sources and predict their lifetime. The high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) is widely used to measure OA in real time using thermal vaporization followed by electron ionization (EI). EI creates fragment ions that can be assigned to functional groups using delta analysis, a method of classifying mass spectra according to the presence of different chemically related ion series. In this study, we demonstrate the application of delta analysis to characterize molecular structures using a new visualization method. We also use delta analysis to quantify the functional group distribution with an average absolute error of ∼5–6% for individual standard molecules, comparable to the error observed for OA mixtures from biomass and coal combustion fit with Fourier transform infrared spectroscopy. Finally, we apply delta functional group analysis to AMS positive matrix factorization (PMF) factors across seven different field campaigns and find a similar composition across the more oxidized factors with about 55% acid and 26% alcohol groups. The analysis method described here can be applied to any HR-ToF-AMS data set to provide quantitative relative functional group distributions for OA mixtures.

aerosol↗

The U.S. Agrivoltaic Shading Tool: A National-Scale Interface for Modeling Light and Shade Patterns in Ten Common Agrivoltaic Configurations

Agrivoltaic systems are dual-use configurations that co-locate agriculture and photovoltaic (PV) infrastructure and require careful design to balance crop performance and energy generation. A critical element of agrivoltaic design is the spatial and temporal distribution of irradiance and shade within and around PV arrays. To support research, planning, and stakeholder decision-making, we introduce the U.S. Agrivoltaic Shading Tool, a novel web-based application that delivers high-resolution irradiance and photosynthetically active radiation (PAR) modeling for ten standardized PV configurations across the conterminous United States. The tool leverages the National Laboratory of the Rockies (NLR) System Advisor Model (SAM) to perform detailed irradiance simulations, using meteorological data from the National Solar Radiation Database (NSRDB). Outputs include seasonal, monthly, weekly, and diurnal patterns of available sunlight, amount of shade, irradiance, and PAR at ground level within agrivoltaic system footprints. For a user's selected location, these results are visualized through interactive visualizations, heatmaps, and time-series plots, designed to be accessible to both technical and non-technical users. In addition to facilitating rapid spatial exploration of agrivoltaic light environments, the tool will offer seamless integration with the InSPIRE Agrivoltaics Design and Analysis Model (ADAM). This optional workflow will allow users to port selected site and configuration parameters into a more advanced modeling environment for further customization of structural layouts, crop-system compatibility, power generation, and technoeconomic performance. Finally, to promote open science, the entire dataset will be hosted and available for open access through the OpenEI platform. By standardizing and disseminating high-quality irradiance data and design tools, the U.S. Agrivoltaic Shading Tool supports a wide range of users, including researchers, landowners, energy developers, and policymakers, in evaluating the agronomic and energetic feasibility of agrivoltaic systems across the United States.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Error analysis of multi-conic techniques

A general error analysis of three recently developed multi-conic methods of three-body trajectory integration has been carried out. Single-step error functions for position and velocity have been derived as Taylor series in powers of the time step and also in integral form. These error functions are used to investigate the relative accuracy of the three methods in various regions of the earth-moon space and to provide a method of variable step size control for the trajectory integration procedure. Numerical results are used to compare the multi-step performance of the methods for both large and small step sizes.

D'Amario, L. A.↗

Satellite Observations of Spatial and Interannual Variability of Lightning and Radar Reflectivity

The authors use satellite data to examine the relationship between lightning and upper-level radar reflectivity. They find correlations between average flash rates and upper-level reflectivities over both land and ocean, although both flash rates and reflectivities are much lower over ocean than land. Analysis of the data using Empirical Orthogonal Functions (EOFs) shows similar EOFs for averaged lightning and reflectivity. In contrast, the EOFs of the anomalies of lightning and reflectivity have different spatial patterns; however, both have principal component time series that are correlated with the Southern Oscillation Index and, hence, El Nino. Differences in behavior of the lightning and reflectivity anomaly EOFs and principal components suggest that El Nino plays a smaller role in lightning anomaly than precipitation anomaly.

lightning↗

Accuracy Assessment of Global Internal-Tide Models Using Satellite Altimetry Models Using Satellite Altimetry

Altimeter measurements are corrected for several geophysical parameters in order to access ocean signals of interest, like mesoscale or sub-mesoscale variability. The ocean tide is one of the most critical corrections due to the amplitude of the tidal elevations and to the aliasing phenomena of high-frequency signals into the lower-frequency band, but the internal-tide signatures at the ocean surface are not yet corrected globally. Internal tides can have a signature of several centimeters at the surface with wavelengths of about 50–250 km for the first mode and even smaller scales for higher-order modes. The goals of the upcoming Surface Water Ocean Topography (SWOT) mission and other high-resolution ocean measurements make the correction of these small-scale signals a challenge, as the correction of all tidal variability becomes mandatory to access accurate measurements of other oceanic signals. In this context, several scientific teams are working on the development of new internal-tide models, taking advantage of the very long altimeter time series now available, which represent an unprecedented and valuable global ocean database. The internal-tide models presented here focus on the coherent internal-tide signal and they are of three types: empirical models based upon analysis of existing altimeter missions, an assimilative model and a three-dimensional hydrodynamic model. A detailed comparison and validation of these internal-tide models is proposed using existing satellite altimeter databases. The analysis focuses on the four main tidal constituents: M2, K1, O1 and S2. The validation process is based on a statistical analysis of multi-mission altimetry including Jason-2 and Cryosphere Satellite-2 data. The results show a significant altimeter variance reduction when using internal-tide corrections in all ocean regions where internal tides are generating or propagating. A complementary spectral analysis also gives some estimation of the performance of each model as a function of wavelength and some insight into the residual non-stationary part of internal tides in the different regions of interest. This work led to the implementation of a new internal-tide correction (ZARON'one) in the next geophysical data records version-F (GDR-F) standards.

Loren Carrere↗

Accelerating Large Data Analysis By Exploiting Regularities

We present techniques for discovering and exploiting regularity in large curvilinear data sets. The data can be based on a single mesh or a mesh composed of multiple submeshes (also known as zones). Multi-zone data are typical to Computational Fluid Dynamics (CFD) simulations. Regularities include axis-aligned rectilinear and cylindrical meshes as well as cases where one zone is equivalent to a rigid-body transformation of another. Our algorithms can also discover rigid-body motion of meshes in time-series data. Next, we describe a data model where we can utilize the results from the discovery process in order to accelerate large data visualizations. Where possible, we replace general curvilinear zones with rectilinear or cylindrical zones. In rigid-body motion cases we replace a time-series of meshes with a transformed mesh object where a reference mesh is dynamically transformed based on a given time value in order to satisfy geometry requests, on demand. The data model enables us to make these substitutions and dynamic transformations transparently with respect to the visualization algorithms. We present results with large data sets where we combine our mesh replacement and transformation techniques with out-of-core paging in order to achieve significant speed-ups in analysis.

Moran, Patrick J.↗

ILRS Analysis Activities After the Adoption of ITRF2020

"The contribution of the International Laser Ranging Service (ILRS) to the most recent realization of the International Terrestrial Reference System (ITRS) was the result of an analysis strategy with two major modifications compared to the operational products: a modeling for stations long-term systematic errors (biases reported in the ILRS Data Handling File) and an updated model of the target signature error (satellite Centre of Mass model). Both refined models were used as input information for the ILRS contribution to the ITRF2020 (International Terrestrial Reference Frame 2020). Thereafter, the ILRS Analysis Standing Committee (ASC) focused its effort on implementing the new reference frame in its operational products, define a strategy to improve the ongoing monitoring of the systematic errors, compute the ILRS contribution to the planned ITRF2020 update, and to include LARES-2 among the considered satellites for the operational products. The ILRS ASC implemented the ITRF2020/SLRF2020 into all its official operational products (TRF, Earth Orientation Parameters, predicted and combined satellite orbits) and its impact was evaluated. The operational products benefit from the continuous monitoring of the station systematic errors and the frequent updates of the Data Handling File whenever a significant change in the station systematic error is observed. In the future, a change-point detection algorithm, jointly estimating the times and the number of discontinuities, will be implemented to detect potential new discontinuities in the range bias series. The inclusion of LARES-2 among the satellites whose data are operationally analyzed will furtherly increase the robustness of the estimated parameters. Finally, the ILRS ASC activities include the benchmarking of a new analysis center (CNES) which will formally begin its own contribution in 2024."

Satellite Laser Ranging↗

Integrated Experimental and Computational K-Edge X-ray Absorption Near-Edge Structure Analysis of Vanadium Catalysts

X-ray Absorption Near-Edge Structure (XANES) spectroscopy is a powerful tool to reveal key structural and electronic features of isolated catalytic sites, yet insights into molecular structure and more detailed orbital analysis through a combination of experimental and computed XANES analysis are necessary for accurate interpretation of the spectra, especially when significant heterogeneity exits among the catalytic sites. Herein, we present an integrated computational and experimental strategy to determine both primary and secondary bonding interactions within the XANES pre-edge region for organovanadium complexes, which was developed using a series of well-defined molecular vanadium complexes and then applied to the characterization of a supported organovanadium olefin hydrogenation catalyst. Time-dependent density functional theory is used to predict the energy of pre-edge XANES features for a series of vanadium complexes with a variety of oxidation states and local coordination environments. Further, a calibration scheme incorporating different density functionals and basis sets is established, resulting in an optimized scheme that accurately predicts pre-edge energies with a mean absolute error of 0.40 eV. Second-shell coordination (e.g., V---V) effects within XANES are identified through the analysis of the computed dominant orbital contributions for multi-vanadium complexes. Orbital analysis also provided confirmation that the vanadium-hydride formation combined with the heterogeneity of the catalytic active species in ole-fin hydrogenation caused the energy shift and broadening of the pre-edge peak after hydrogen treatment of the silica-supported organovanadium pre-catalyst. This work further elucidates computational XANES simulations and techniques potentially guiding characterization in surface organometallic chemistry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Performance analysis of a laser propelled interorbital tansfer vehicle

Performance capabilities of a laser-propelled interorbital transfer vehicle receiving propulsive power from one ground-based transmitter was investigated. The laser transmits propulsive energy to the vehicle during successive station fly-overs. By applying a series of these propulsive maneuvers, large payloads can be economically transferred between low earth orbits and synchronous orbits. Operations involving the injection of large payloads onto escape trajectories are also studied. The duration of each successive engine burn must be carefully timed so that the vehicle reappears over the laser station to receive additional propulsive power within the shortest possible time. The analytical solution for determining these time intervals is presented, as is a solution to the problem of determining maximum injection payloads. Parameteric computer analysis based on these optimization studies is presented. The results show that relatively low beam powers, on the order of 50 MW to 60 MW, produce significant performance capabilities.

Minovitch, M. A.↗

Results of Propellant Mixing Variable Study Using Precise Pressure-Based Burn Rate Calculations

A designed experiment was conducted in which three mix processing variables (pre-curative addition mix temperature, pre-curative addition mixing time, and mixer speed) were varied to estimate their effects on within-mix propellant burn rate variability. The chosen discriminator for the experiment was the 2-inch diameter by 4-inch long (2x4) Center-Perforated (CP) ballistic evaluation motor. Motor nozzle throat diameters were sized to produce a common targeted chamber pressure. Initial data analysis did not show a statistically significant effect. Because propellant burn rate must be directly related to chamber pressure, a method was developed that showed statistically significant effects on chamber pressure (either maximum or average) by adjustments to the process settings. Burn rates were calculated from chamber pressures and these were then normalized to a common pressure for comparative purposes. The pressure-based method of burn rate determination showed significant reduction in error when compared to results obtained from the Brooks' modification of the propellant web-bisector burn rate determination method. Analysis of effects using burn rates calculated by the pressure-based method showed a significant correlation of within-mix burn rate dispersion to mixing duration and the quadratic of mixing duration. The findings were confirmed in a series of mixes that examined the effects of mixing time on burn rate variation, which yielded the same results.

Stefanski, Philip L.↗

Approximation methods for combined thermal/structural design

Two approximation concepts for combined thermal/structural design are evaluated. The first concept is an approximate thermal analysis based on the first derivatives of structural temperatures with respect to design variables. Two commonly used first-order Taylor series expansions are examined. The direct and reciprocal expansions are special members of a general family of approximations, and for some conditions other members of that family of approximations are more accurate. Several examples are used to compare the accuracy of the different expansions. The second approximation concept is the use of critical time points for combined thermal and stress analyses of structures with transient loading conditions. Significant time savings are realized by identifying critical time points and performing the stress analysis for those points only. The design of an insulated panel which is exposed to transient heating conditions is discussed.

Haftka, R. T.↗

Exploring the Genetic Basis of Wild Boar ( Sus scrofa ) and Its Connection to Classical Swine Fever Spread

Classical swine fever (CSF) is the one of the most devastating contagious diseases in domestic swine and wild boar/pigs (Sus scrofa). Population genetics is often used to estimate animal dispersal and can also help evaluate host population connectivity, which is crucial for understanding pathogen dispersal. We surveyed genetic population structure of boars using MIG-seq analysis to clarify the geographic barriers that influence boar dispersal in north-central Japan and to demonstrate the relationship between the spread of CSF infection among boars and their population structure. We obtained 382 single-nucleotide polymorphisms from 348 wild boar samples, and the results of STRUCTURE analysis indicated that the highest ΔK value was at K = 2, followed by K = 4. Based on these results, it is evident that the Abukuma river, a major river within north-central Japan, does not act as a barrier to the gene flow of boars, but rather that human infrastructure hinders their dispersal. Further, according to the time series change in the capture site of CSF-infected wild boar and the sum of the probability of belonging to each of the four clades in individual CSF-infected wild boar, our results indicated that the genetic structure of boar populations was correlated with the outbreak pathway of CSF across our study region. Our study suggests that predictions of disease spread, especially for widely distributed host species, is challenging because of the risk of cryptic breaks and changes in wide range connectivity; however, understanding the genetic population structure of wild boar can be a useful tool for predicting the spread of CSF. We concluded that genetic analysis of host population structure may have the possibility to improve predictions of the future dynamics of disease spread.

60 APPLIED LIFE SCIENCES↗

Lunar Reconnaissance Orbiter Orbit Determination Accuracy Analysis

Results from operational OD produced by the NASA Goddard Flight Dynamics Facility for the LRO nominal and extended mission are presented. During the LRO nominal mission, when LRO flew in a low circular orbit, orbit determination requirements were met nearly 100% of the time. When the extended mission began, LRO returned to a more elliptical frozen orbit where gravity and other modeling errors caused numerous violations of mission accuracy requirements. Prediction accuracy is particularly challenged during periods when LRO is in full-Sun. A series of improvements to LRO orbit determination are presented, including implementation of new lunar gravity models, improved spacecraft solar radiation pressure modeling using a dynamic multi-plate area model, a shorter orbit determination arc length, and a constrained plane method for estimation. The analysis presented in this paper shows that updated lunar gravity models improved accuracy in the frozen orbit, and a multiplate dynamic area model improves prediction accuracy during full-Sun orbit periods. Implementation of a 36-hour tracking data arc and plane constraints during edge-on orbit geometry also provide benefits. A comparison of the operational solutions to precision orbit determination solutions shows agreement on a 100- to 250-meter level in definitive accuracy.

Gravitation↗

Time-dependent probability density function analysis of H-mode transitions

Abstract The first application of time-dependent probability density function (PDF) analysis to the L-H transition in fusion plasmas is presented. PDFs are constructed using Doppler Backscattering data of perpendicular fluctuation velocity, , and turbulence from the edge region of the DIII-D tokamak. These raw time-series data are sliced into millisecond-long sliding time-windows to create PDFs. During the transition, the PDFs develop strong right tails, indicative of turbulence-suppressing localised flows in the plasma edge; such features and other subtle behaviours are explored using novel information geometry techniques. This letter examines the applicability of these techniques to predict L-H transitions and investigate predator-prey self-regulation theories between turbulence and perpendicular velocity.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Correlation of asperity contact-time fraction with elastohydrodynamic film thickness in a 20-millimeter-bore ball bearing

Elastohydrodynamic film thicknesses and asperity contact-time fractions were measured for a 20 mm bore ball bearing by using the capacitance and conductance techniques. The bearing was thrust loaded to 90, 445, and 778 N. The corresponding maximum stresses on the inner race were 1.28, 2.09, and 2.45 GPa. The test speed ranged from 400 to 15,000 rpm. The test bearing was mist lubricated with a MIL-L-23699A turbine oil. The temperature was 27 C. The experimental results were correlated to give the percent film (no-contact-time fraction) as a function of measured film thickness. Measurements were made for three test series that represented the test bearing in various conditions of run-in. The measurements show that the percent film changes with bearing run-in time. The experimental results agreed well with theoretical predictions based on surface trace analysis for a new bearing. For the run-in state, they agreed with previously reported experimental results. The results show that asperity contact existed at a film thickness-roughness ratio lambda of 6.0 or less for a new bearing. After run-in, no asperity contact occurred at a lambda of 3.5 or greater.

Coy, J. J.↗

Ground-based microwave observations of ozone in the upper stratosphere and mesosphere

A 9-month-long series of mesurements of ozone in the upper stratosphere and mesosphere is reported. The measurements are presented as monthly averages of profiles in blocks of roughly 20 min local time and as night-to-day ratios. An error analysis predicts accuracies of 5-26% for the monthly profiles and 2.5-9% for the ratios. The data are compared to historical data from Solar Mesosphere Explorer (SME) and limb infrared monitor of the stratosphere (LIMS), and it is shown how to remove the effect of different vertical resolution from the comparisons. The microwave data typically agree to better than 10% with SMF and nighttime LIMS ozone at all altitudes below the 0.1-mbar surface. Comparison of the microwave night-to-day ratio with the corresponding ratio from LIMS suggests that nonlocal thermodynamic equilibrium effects in the LIMS daytime data exceed 10% at all pressures less than or equal to 1 mbar.

Connor, Brian J.↗

Principal Investigator in a Box Technical Description Document

This document provides a brief overview of the PI-in-a-Box system, which can be used for automatic real-time reaction to incoming data. We will therefore outline the current system's capabilities and limitations, and hint at how best to think about PI-in-a-Box as a tool for real-time analysis and reaction in section two, below. We also believe that the solution to many commercial real-time process problems requires data acquisition and analysis combined with rule-based reasoning and/or an intuitive user interface. We will develop the technology reuse potential in section three. Currently, the system runs only on Apple Computer's Macintosh series.

Groleau, Nick↗

Relating Aerial Infrared Thermography Defects to Photovoltaic Performance: Preprint

In this research, we examine the relationship between aerial IR defect analysis and photovoltaic (PV) performance data for twelve utility- and commercial-scale solar sites in the United States. To do this, we fuse the site diagram geoJSON's, aerial infrared thermography (aIRT) defect analyses, and associated inverter time series, allowing for a direct comparison between site defects and time series data. Defect analyses were provided by Zeitview, under its Solar Insights platform. Following the data fusion process, we look at the relationship between system performance and aIRT defects. We investigate the relationship between degradation and hotspot defects, as well as the relationship between AC power data and offline strings and misaligned modules. In general, system degradation was not affected by long-term or balance-of-system (BoS) defects as they occurred infrequently in the data set. However, for one system, a near statistically significant relationship (p-value=0.057) was found when comparing the degradation of inverter blocks with several multi-hotspot defects to all other inverter blocks without this particular defect. There was strong alignment when comparing short-term recoverable module defects such as stuck trackers and offline strings to time series data. In general, we found that when an inverter block has more than 80% of modules flagged for one of these defects, its AC power time data is flat-lined and the inverter block is not producing.

aerial inspection↗