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At least 1,171 records · Page 65

A 4-D Climatology (1979-2009) of the Monthly Tropospheric Aerosol Optical Depth Distribution over the Mediterranean Region from a Comparative Evaluation and Blending of Remote Sensing and Model Products

Since the 1980s several spaceborne sensors have been used to retrieve the aerosol optical depth (AOD) over the Mediterranean region. In parallel, AOD climatologies coming from different numerical model simulations are now also available, permitting to distinguish the contribution of several aerosol types to the total AOD. In this work, we perform a comparative analysis of this unique multiyear database in terms of total AOD and of its apportionment by the five main aerosol types (soil dust, seasalt, sulfate, black and organic carbon). We use 9 different satellite-derived monthly AOD products: NOAA/AVHRR, SeaWiFS (2 products), TERRA/MISR, TERRA/MODIS, AQUA/MODIS, ENVISAT/MERIS, PARASOL/POLDER and MSG/SEVIRI, as well as 3 more historical datasets: NIMBUS7/CZCS, TOMS (onboard NIMBUS7 and Earth- Probe) and METEOSAT/MVIRI. Monthly model datasets include the aerosol climatology from Tegen et al. (1997), the climate-chemistry models LMDz-OR-INCA and RegCM-4, the multi-model mean coming from the ACCMIP exercise, and the reanalyses GEMS and MACC. Ground-based Level- 2 AERONET AOD observations from 47 stations around the basin are used here to evaluate the model and satellite data. The sensor MODIS (on AQUA and TERRA) has the best average AOD scores over this region, showing a relevant spatio-temporal variability and highlighting high dust loads over Northern Africa and the sea (spring and summer), and sulfate aerosols over continental Europe (summer). The comparison also shows limitations of certain datasets (especially MERIS and SeaWiFS standard products). Models reproduce the main patterns of the AOD variability over the basin. The MACC reanalysis is the closest to AERONET data, but appears to underestimate dust over Northern Africa, where RegCM-4 is found closer to MODIS thanks to its interactive scheme for dust emissions. The vertical dimension is also investigated using the CALIOP instrument. This study confirms differences of vertical distribution between dust aerosols showing a large vertical spread, and other continental and marine aerosols which are confined in the boundary layer. From this compilation, we propose a 4-D blended product from model and satellite data, consisting in monthly time series of 3-D aerosol distribution at a 50 km horizontal resolution over the Euro-Mediterranean marine and continental region for the 2003-2009 period. The product is based on the total AOD from AQUA/MODIS, apportioned into sulfates, black and organic carbon from the MACC reanalysis, and into dust and sea-salt aerosols from RegCM-4 simulations, which are distributed vertically based on CALIOP climatology.We extend the 2003-2009 reconstruction to the past up to 1979 using the 2003-2009 average and applying the decreasing trend in sulfate aerosols from LMDz-OR-INCA, whose AOD trends over Europe and the Mediterranean are median among the ACCMIP models. Finally optical properties of the different aerosol types in this region are proposed from Mie calculations so that this reconstruction can be included in regional climate models for aerosol radiative forcing and aerosol-climate studies.

troposphere↗

Noble gas studies on grain size separates of Apollo 15 and 16 deep drill cores

A description is presented of noble gas analyses of grain-size separates of eight Apollo 15 drill-core samples over the depth range 2-80 cm. Noble gas data on grain-size separates of seven Apollo 16 drill-core samples are also reported. On the basis of the obtained results it is suggested that cosmogenic Ne and He in the Apollo 15 core material has been preferentially lost relative to cosmogenic Ar in the Apollo 15 core material in proportion to soil maturity and degree of solar irradiation. A plot of He-4/Ne-20 against Ar-40/Ar-36 demonstrates that material in the lowest 35 cm of the Apollo 16 drill core is distinct from all other analyzed samples in the core, and distinct from nearly all surface soils.

Bogard, D. D.↗

New Views of the Moon: Improved Understanding Through Data Integration

Understanding the Moon is crucial to future exploration of the solar system.The Moon preserves a record of the first billion years of the Earth-Moon system's history, including evidence of the Moon's origin as accumulated debris from a giant impact into early Earth. Lunar rocks provide evidence of early differentiation and extraction of a crust. Lacking an atmospheric shield, the Moon's regolith retains a record of the activity of solar wind over the past 4 billion years. It also holds a complete record of impact cratering, and analysis of samples has allowed calibration of ages, and thus dating of other planetary surfaces. And because of its proximity to Earth, it's low gravity well, and stable surface, the Moon's resources will be useful both in establishing lunar habitations and as fuel for exploration beyond the Moon. Lunar science has advanced tremendously in the 30 years since the Apollo and Luna missions. We know that the Moon is strongly differentiated, and recent tungsten isotope studies indicate that this differentiation occurred soon after solar system formation. The Moon probably accreted rapidly from debris that formed as a large planetesimal struck the early Earth. Ancient highland rocks provide evidence of early lunar differentiation, and basalts formed by later melting within the mantle reveal it cumulus nature. However, the timing, extent, and depth of differentiation, variations within the mantle, and lateral and vertical variations within the crust can only be surmised from the limited sample suites,gravity studies,and surface geophysics of the Apollo era. Data from the recent Lunar Prospector and Clementine missions permit reassessment of the global characteristics of the Moon and a reexamination of the distribution of elemental components, rock and soil types, and resources, as well as remanent magnetism, gravity field, and global topography New research provides some answers, but also leads to new questions.

Jolliff, B. L.↗

Lunar and Planetary Science XXXV: Mars: Radar, Gamma Ray Spectrometer, and Cratering Mineralogy

The session "Mars: Radar, Gamma Ray Spectrometer, and Cratering Mineralogy" contained the following reports:The Dielectric Properties of Martian Soil Simulant JSC Mars-1 in the Range from 20Hz to 10kHz; Eastern Sahara Geology from Orbital Radar: Potential Analog to Mars On the Dielectric Properties of the Martian-like Surface Sediments; Radar Observations of Recent Mars Landing Sites; Sounding of Subsurface Water Through Conductive Media in Mars Analog Environments Using Transient Electromagnetics and Low Frequency Ground-penetrating Radar; Burial Depth of the Reservoirs of Hydrogen at the Equatorial Latitudes on Mars; Elemental Composition Variations for Large Dusty and Rocky Regions on Mars Using Gamma-Ray Data from the Mars Odyssey Gamma-Ray Spectrometer; The Distribution of Non-Volatile Elements on Mars: Mars Odyssey GRS Results; Using Mars Odyssey GRS Data to Assess Models for the Bulk Composition of Mars; Mars: The Terra Arabia Low Epithermal Neutron Flux Anomaly; The Isidis Basin of Mars: New Results from MOLA, MOC, and THEMIS; Remote Sensing of the Haughton Impact Structure (HIS): A Terrestrial Proof of Concept for Using the Remote Sensing of Martian Craters as a Probe of Subsurface Composition;and Thermal Emission Spectra of Impact Glass and Shocked Deccan Basalt from Lonar Crater, India and Implications for Remote Sensing of Mars.

Source record↗

Particle track record in Apollo 15 deep core from 54 to 80 cm depths.

Particle track measurements have been made in nearly 500 individual grains from 13 levels in the 54-80 cm depth range of the Apollo 15 deep core. They reveal a wide range of track densities at all depths and some systematic variations within layers, indicating that both predepositional mixing and subsequent layering are present and that separate sublayers exist within larger regions where no sublayers are visible. Minimum track densities are inferred to be useful measures of maximum residence times for undisturbed layers. Using the observed minimum track densities, we conclude that the average deposition rate in this section of soil column was greater than 0.4 cm/million years.

Fleischer, R. L.↗

Performance of a Borehole X-ray Fluorescence Spectrometer for Planetary Exploration

We have designed and constructed a borehole X-ray Fluorescence Spectrometer (XRFS) as part of the Mars Subsurface Access program [1]. It can be used to determine the composition of the Mars regolith at various depths by insertion into a pre-drilled borehole. The primary requirements and performance metrics for the instrument are to obtain parts-per-million (ppm) lower limits of detection over a wide range of elements in the periodic table (Magnesium to Lead). Power consumption during data collection was also measured. The prototype instrument is complete and preliminary testing has been performed. Terrestrial soil Standard Reference Materials were used as the test samples. Detection limits were about 10 weight ppm for most elements, with light elements being higher, up to 1.4 weight percent for magnesium. Power consumption (excluding ground support components) was 12 watts.

Kelliher, Warren C.↗

Soil organic carbon accumulation rates on Mediterranean abandoned agricultural lands

Secondary succession on abandoned agricultural lands can produce climate change mitigation co-benefits, such as soil carbon sequestration. However, the accumulation of soil organic carbon (SOC) in Mediterranean regions has been difficult to predict and is subject to multiple environmental and land management factors. Gains, losses, and no significant changes have all been reported. Here we compile chronosequence data (n = 113) from published studies and new field sites to assess the response of SOC to agricultural land abandonment in peninsular Spain. In this work we found an overall SOC accumulation rate of +2.3% yr -1 post-abandonment. SOC dynamics are highly variable and context-dependent. Minimal change occurs on abandoned cereal croplands compared to abandoned woody croplands (+4% yr -1 ). Accumulation is most prevalent within a Goldilocks climatic window of ~13–17 °C and ~450–900 mm precipitation, promoting >100% gains after three decades. Our secondary forest field sites accrued 40.8 Mg C ha -1 (+172%) following abandonment and displayed greater SOC and N depth heterogeneity than natural forests demonstrating the long-lasting impact of agriculture. Although changes in regional climate and crop types abandoned will impact future carbon sequestration, abandonment remains a low-cost, long-term natural climate solution best incorporated in tandem with other multipurpose sustainable land management strategies.

54 ENVIRONMENTAL SCIENCES↗

Simulated plant-mediated oxygen input has strong impacts on fine-scale porewater biogeochemistry and weak impacts on integrated methane fluxes in coastal wetlands

Methane (CH 4 ) emissions from wetland ecosystems are controlled by redox conditions in the soil, which are currently underrepresented in Earth system models. Plant-mediated radial oxygen loss (ROL) can increase soil O 2 availability, affect local redox conditions, and cause heterogeneous distribution of redox-sensitive chemical species at the root scale, which would affect CH 4 emissions integrated over larger scales. In this study, we used a subsurface geochemical simulator (PFLOTRAN) to quantify the effects of incorporating either spatially homogeneous ROL or more complex heterogeneous ROL on model predictions of porewater solute concentration depth profiles (dissolved organic carbon, methane, sulfate, sulfide) and column integrated CH 4 fluxes for a tidal coastal wetland. From the heterogeneous ROL simulation, we obtained 18% higher column averaged CH 4 concentration at the rooting zone but 5% lower total CH 4 flux compared to simulations of the homogeneous ROL or without ROL. This difference is because lower CH 4 concentrations occurred in the same rhizosphere volume that was directly connected with plant-mediated transport of CH 4 from the rooting zone to the atmosphere. Sensitivity analysis indicated that the impacts of heterogeneous ROL on model predictions of porewater oxygen and sulfide concentrations will be more important under conditions of higher ROL fluxes or more heterogeneous root distribution (lower root densities). Despite the small impact on predicted CH 4 emissions, the simulated ROL drastically reduced porewater concentrations of sulfide, an effective phytotoxin, indicating that incorporating ROL combined with sulfur cycling into ecosystem models could potentially improve predictions of plant productivity in coastal wetland ecosystems.

54 ENVIRONMENTAL SCIENCES↗

Mid-Latitude Composition of Mars from Thermal and Epithermal Neutrons

Epithermal neutron data acquired by Mars Odyssey have been analyzed to determine global maps of water-equivalent hydrogen abundance. By assuming that hydrogen was distributed uniformly with depth within the surface, a map of minimum water abundance was obtained. The addition of thermal neutrons to this analysis could provide information needed to determine water stratigraphy. For example, thermal and epithermal neutrons have been used together to determine the depth and abundance of water-equivalent hydrogen of a buried layer in the south polar region. Because the emission of thermal neutrons from the Martian surface is sensitive to absorption by elements other than hydrogen, analysis of stratigraphy requires that the abundance of these elements be known. For example, recently published studies of the south polar region assumed that the Mars Pathfinder mean soil composition is representative of the regional soil composition. This assumption is partially motivated by the fact that Mars appears to have a well-mixed global dust cover and that the Pathfinder soil composition is representative of the mean composition of the Martian surface. In this study, we have analyzed thermal and epithermal neutron data measured by the neutron spectrometer subsystem of the gamma ray spectrometer to determine the spatial distribution of the composition of elements other than hydrogen. We have restricted our analysis to mid-latitude regions for which we have corrected the neutron counting data for variations in atmospheric thickness.

T H Prettyman↗

Artificial Linear Brush Abrasion of Coatings for Photovoltaic Module First Surfaces

Natural soiling and the subsequent requisite cleaning of photovoltaic (PV) modules result in abrasion damage to the cover glass. The durability of the front glass has important economic consequences, including determining the use of anti-reflective and/or anti-soiling coatings as well as the method and frequency of operational maintenance (cleaning). Artificial linear brush abrasion using Nylon 6/12 bristles was therefore examined to explore the durability of representative PV first-surfaces, i.e., the surface of a module incident to direct solar radiation. Specimens examined include silane surface functionalized-, roughened (etched)-, porous silica-coated-, fluoropolymer-coated-, and ceramic (TiO2 or ZrO2/SiO2/ZrO2/SiO2)-coated-glass, which are compared to monolithic-poly(methyl methacrylate) and -glass coupons. Characterization methods used in this study include: optical microscopy, ultraviolet-visible-near-infrared (UV-VIS-NIR) spectroscopy, sessile drop goniometry, white-light interferometry, atomic force microscopy (AFM), and depth-profiling X-ray photoelectron spectroscopy (XPS). The corresponding characteristics examined include: surface morphology, transmittance (i.e., optical performance), surface energy (water contact angle), surface roughness, scratch width and depth, and chemical composition, respectively. The study here was performed to determine coating failure modes; identify characterization methods that can detect nascent failures; compare the durability of popular contemporary coating materials; identify their corresponding damage characteristics; and compare slurry and dry-dust abrasion. This study will also aid in developing an abrasion standard for the PV industry.

41 EE - Solar Energy Technologies Office (EE-4S)↗

Microbial partner (MiPner) analysis

Introduction Although a few bacteria have been studied in great depth, relatively little is known about the characteristics of microbe-microbe interactions that occur within ecosystems on a daily basis. A simple, robust technique was developed to set up the foundation for investigating pairwise bacterial-bacterial interactions, using cell-cell binding as a self-selective mechanism to identify interesting bacterial species pairs. Methods Using a Serratia marcescens strain (SMC43) isolated from Georgia soil as a “bait”, specific bacteria were purified by their specificity in binding SMC43 bacteria that were themselves attached to a wooden applicator stick. Results The isolated Microbial Partners (MiPners) were greatly enriched for members of the genera Sphingobium and Caulobacter . Two streaked MiPners were unable to grow on the plates employed after separation from SMC43to be separated from, and grow on the plate type tested without, SMC43. Discussion This suggests that the MiPner technology will be one strategy for purifying bacteria that were previously recalcitrant to culturing.

Bennetzen, Jeffrey L.↗

Integrated Studies of Impact-Basin Ejecta as Probes of the Lunar Crust: Imbrium and Serenitatis

The large, late, basin impacts on the Earth side of the Moon fundamentally reshaped the structure of the crust, its surface morphology, and the composition of the megaregolith and surface soils. The latest (except for Orientale on the western limb) and largest was the Imbrium impact, which produced massive ejecta deposits over much of the Procellarum region and beyond, and ejected material that mixed with surface regolith nearly Moonwide. The basins serve as natural probes into the lunar crust; therefore, understanding the nature and composition of ejecta produced by them provides information about the crust at depth. Gravity data allow modeling of the structure of the crust beneath the basins, and from such models one can infer depths of excavation and the nature of crustal response following impact.

Jolliff, Brad L.↗

Artificial linear brush abrasion of coatings for photovoltaic module first-surfaces

Natural soiling and the subsequent necessary cleaning of photovoltaic (PV) modules result in abrasion damage to the cover glass. The durability of the front glass has important economic consequences, including determining the use of anti-reflective and/or anti-soiling coatings as well as the method and frequency of operational maintenance (cleaning). Artificial linear brush abrasion using Nylon 6/12 bristles was therefore examined to explore the durability of representative PV first-surfaces, i.e., the surface of a module incident to direct solar radiation. Specimens examined include silane surface functionalized-, roughened (etched)-, porous silica-coated-, fluoropolymer-coated-, and ceramic (TiO 2 or ZrO 2 /SiO 2 /ZrO 2 /SiO 2 )-coated-glass, which are compared to monolithic-poly(methyl methacrylate) and -glass coupons. Characterization methods used in this study include: optical microscopy, ultraviolet–visible–near-infrared (UV-VIS-NIR) spectroscopy, sessile drop goniometry, white-light interferometry, atomic force microscopy (AFM), and depth-profiling X-ray photoelectron spectroscopy (XPS). The corresponding characteristics examined include: surface morphology, transmittance (i.e., optical performance), surface energy (water contact angle), surface roughness, scratch width and depth, and chemical composition, respectively. The study here was performed to determine coating failure modes; identify characterization methods that can detect nascent failures; compare the durability of popular contemporary coating materials; identify their corresponding damage characteristics; and compare slurry and dry-dust abrasion. This study will also aid in developing an abrasion standard for the PV industry.

14 SOLAR ENERGY↗

Remote Sensing of Groundwater Storage Changes in Illinois using the Gravity Recovery and Climate Experiment (GRACE)

Regional groundwater storage changes in Illinois are estimated from monthly GRACE total water storage change (TWSC) data and in situ measurements of soil moisture for the period 2002-2005. Groundwater storage change estimates are compared to those derived from the soil moisture and available well level data. The seasonal pattern and amplitude of GRACE-estimated groundwater storage changes track those of the in situ measurements reasonably well, although substantial differences exist in month-to-month variations. The seasonal cycle of GRACE TWSC agrees well with observations (correlation coefficient = 0.83), while the seasonal cycle of GRACE-based estimates of groundwater storage changes beneath 2 m depth agrees with observations with a correlation coefficient of 0.63. We conclude that the GRACE-based method of estimating monthly to seasonal groundwater storage changes performs reasonably well at the 200,000 sq km scale of Illinois.

Yeh, Pat J.-F.↗

Systems Analysis of the Physiological and Molecular Mechanisms of Sorghum Nitrogen Use Efficiency, Water Use Efficiency and Interactions with the Soil Microbiome (Final Report for DE-SC0014395)

The specific project objectives were to: 1) Conduct deep census surveys of root microbiomes concurrent with phenotypic characterizations of a diverse panel of sorghum genotypes across multiple years to define the microbes associated with the most productive lines under drought and low nitrogen conditions. 2) Associate systems-level genotypic, microbial, and environmental factors with improved sorghum performance using robust statistical approaches. 3) Develop culture collections of sorghum root/leaf associated microbes that recapitulate root-enriched sequences defined in the census. 4) Perform controlled environment experiments for in-depth characterization and hypothesis testing of G sorghum x G microbe x E interactions . Validate physiological mechanisms, map genetic loci for stress tolerance, and determine the persistence of optimal microbial strains under greenhouse and field conditions.

59 BASIC BIOLOGICAL SCIENCES↗

Application of ecological, geological and oceanographic ERTS-1 imagery to Delaware's coastal resources management

The author has identified the following significant results. Data from twelve successful ERTS-1 passes over Delaware Bay have been analyzed with special emphasis on coastal vegetation, land use, current circulation, water turbidity and pollution dispersion. Secchi depth, suspended sediment concentration and transmissivity as measured from helicopters and boats were correlated with ERTS-1 image radiance. Multispectral signatures of acid disposal plumes, sediment plumes and slick were investigated. Ten vegetative cover and water discrimination classes were selected for mapping: (1) forest-land; (2) Phragmites communis; (3) Spartina patens and Distichlis spicata; (4) Spartina alterniflora; (5) cropland; (6) plowed cropland; (7) sand and bare sandy soil; (8) bare mud; (9) deep water; and (10) sediment-laden and shallow water. Canonical analysis predicted good classification accuracies for most categories. The actual classification accuracies were very close to the predicted values with 8 of 10 categories classified with greater than 90% accuracy indicating that representative training sets had been selected.

Klemas, V.↗

High-frequency and Vertical Variations of Soil Moisture and their Impact on Ecosystem Dynamics

The vertical distribution of subsurface moisture is a major control on ecosystem dynamics and climate. The Mediterranean climate of California, with wet winters and dry summers, provides a testbed for understanding how transpiration is sustained through extended dry periods. The project developed and tested a new subsurface hydrology model that includes a parameterization of stochastic hydraulic conductivity to capture fracture flow, a diagnostic model of rooting profile that depends on the subsurface hydrology, and a representation of hydraulic redistribution by plant roots. A sensitivity study shows that it is plants with rooting depths >8 m that could access the subsurface moisture. The insight is applied to understand differential tree mortality during the 2012-2016 drought in California. The analysis shows that greater mortality trees on plutonic rocks than on sedimentary rocks. The study demonstrates, for the first time, the importance of lithology for the distribution and health of ecosystems.

54 ENVIRONMENTAL SCIENCES↗

In-situ measurement of the rate of U-235 fission induced by lunar neutrons

The depth profile of the neutron-induced fission rate of U-235 was directly measured to a depth of 350 g/sq cm by the Apollo 17 Lunar Neutron Probe Experiment. The fission rate rises sharply from the surface to a broad maximum from 110 to 160 g/sq cm and drops off at greater depths. The shape of the theoretical depth profile of Lingenfelter et al (1972) fits the measured capture rates well at all depths. The absolute magnitude of the experimental fission rates are (11 plus or minus 17)% lower than those calculated theoretically. The excellent agreement between theory and experiment implies that conclusions drawn previously by interpreting lunar sample data with the theoretical capture rates will not require revision. In particular, lunar surface processes, rather than uncertainties in the capture rates, are required to explain the relatively low neutron fluences observed for surface soil samples compared to the fluences expected for a uniformly mixed regolith.

Woolum, D. S.↗