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At least 1,171 records · Page 65

Electrochemical compressor refrigeration appartus with integral leak detection system

An electrochemical compressor system, such as an electrochemical refrigeration system includes a sealed vessel that reduces leak issues related to the electrochemical cell. The sealed vessel may be molded or formed from a polymer or a composite polymer having reinforcing materials, such as fibers therein. The sealed vessel may be plated with metal to reduce gas permeation through the wall of the vessel and to accommodate and improve the attachment of conduits, including metal conduits thereto. A metal conduit may be brazed onto a vessel and the brazing material may be selected for polymer to metal joining and for reduced contamination potential of the system. The electrochemical compressor system incorporates a leak sensor configured at least partially within the sealed rigid vessel that measures the pressure within the vessel.

Bahar, Bamdad↗

Source identification by non-negative matrix factorization combined with semi-supervised clustering

Machine-learning methods and apparatus are provided to solve blind source separation problems with an unknown number of sources and having a signal propagation model with features such as wave-like propagation, medium-dependent velocity, attenuation, diffusion, and/or advection, between sources and sensors. In exemplary embodiments, multiple trials of non-negative matrix factorization are performed for a fixed number of sources, with selection criteria applied to determine successful trials. A semi-supervised clustering procedure is applied to trial results, and the clustering results are evaluated for robustness using measures for reconstruction quality and cluster separation. The number of sources is determined by comparing these measures for different trial numbers of sources. Source locations and parameters of the signal propagation model can also be determined. Disclosed methods are applicable to a wide range of spatial problems including chemical dispersal, pressure transients, and electromagnetic signals, and also to non-spatial problems such as cancer mutation.

97 MATHEMATICS AND COMPUTING↗

Ionic liquid carbon nanotube composites for wireless chemical sensing

A wireless sensor platform design and a single walled carbon nanotube/ionic liquid-based chemidosimeter system can incorporated into a highly sensitive and selective chemical hazard badge that can dosimetrically detect an analyte down to a sub parts-per-million concentration.

Swager, Timothy M.↗

Advances in PFAS Monitoring and Remediation Using a Functionalized Material Approach

The growing global concerns about the effects to public health from human exposure to per- and polyfluoroalkyl substances (PFAS) motivates the development of strategies for reliable monitoring of PFAS in environmental streams, as well as for their rapid, effective removal if detected. For the continuous PFAS monitoring, an inexpensive, field-deployable, in situ sensor is urgently needed; yet the prevalent in situ techniques often struggle to strike a balance between the practical sensitivity and selectivity demands of the real world. Similarly, for effective PFAS removal, strategies for their fast, selective, and quantitative capture are desired, yet the present commercially available sorbents are unable to meet the requirements of rapid, quantitative capture of all PFAS components, and are notably inefficient in removing the more toxic smaller chains. To address these twin challenges, Pacific Northwest National Laboratory is developing strategies for improved detection and remediation of PFAS. For the rapid, selective, quantitative removal of PFAS from environmental streams, the strategy relies on designing capture probes with exclusively tailored electronic and spatial affinities for the PFAS that are able to selectively capture them from environmental streams. For the in situ detection and quantification of PFAS in complex, multicomponent matrices such as groundwater, the approach relies on the targeted capture of specific PFAS by these PFAS-specific capture probes immobilized on a platform. The platform acts as an electrode to directly measure PFAS concentration through a proportional change in electrical response upon their capture. A combination of optimization of platform design and incorporation of additional, sensitive detection modalities have allowed us to achieve detection limits as low as 0.5 ng/L for detection of PFAS compounds (compared to the 70 ng/L Health Advisory Limit of the U.S. Environmental Protection Agency).

Per- and poly-fluorinated alkyl substances (PFAS),↗

Source identification by non-negative matrix factorization combined with semi-supervised clustering

Machine-learning methods and apparatus are provided to solve blind source separation problems with an unknown number of sources and having a signal propagation model with features such as wave-like propagation, medium-dependent velocity, attenuation, diffusion, and/or advection, between sources and sensors. In exemplary embodiments, multiple trials of non-negative matrix factorization are performed for a fixed number of sources, with selection criteria applied to determine successful trials. A semi-supervised clustering procedure is applied to trial results, and the clustering results are evaluated for robustness using measures for reconstruction quality and cluster separation. The number of sources is determined by comparing these measures for different trial numbers of sources. Source locations and parameters of the signal propagation model can also be determined. Disclosed methods are applicable to a wide range of spatial problems including chemical dispersal, pressure transients, and electromagnetic signals, and also to non-spatial problems such as cancer mutation.

Alexandrov, Boian S.↗

Tailoring the d-band center on Ru 1 Cu single-atom alloy nanotubes for boosting electrochemical non-enzymatic glucose sensing

The development of cost-effective and highly efficient electrocatalysts is critical to help electrochemical non-enzymatic sensors achieve high performance. Here, in this work, a new class of catalyst, Ru single atoms confined on Cu nanotubes as a single-atom alloy (Ru 1 Cu NTs), with a unique electronic structure and property, was developed to construct a novel electrochemical non-enzymatic glucose sensor for the first time. The Ru 1 Cu NTs with a diameter of about 24.0 nm showed a much lower oxidation potential (0.38 V) and 9.0-fold higher response (66.5 μA) current than Cu nanowires (Cu NWs, oxidation potential 0.47 V and current 7.4 μA) for glucose electrocatalysis. Moreover, as an electrochemical non-enzymatic glucose sensor, Ru1Cu NTs not only exhibited twofold higher sensitivity (54.9 μA mM −1 cm −2 ) and wider linear range (0.5–8 mM) than Cu NWs, but also showed a low detection limit (5.0 μM), excellent selectivity, and great stability. According to theoretical calculation results, the outstanding catalytic and sensing performance of Ru 1 Cu NTs could be ascribed to the upshift of the d-band center that helped promote glucose adsorption. This work presents a new avenue for developing highly active catalysts for electrochemical non-enzymatic sensors.

electrochemistry↗

Characterizing the Relationships Among Lightning and Storm Parameters: Lightning as a Proxy Variable

We have gained important insights from prior studies that have suggested relationships between lightning and storm growth, decay, convective rain flux, vertical distribution of storm mass and echo volume in the region, and storm energetics. A study was initiated in the Summer of 1996 to determine how total (in-cloud plus ground) lightning observations might provide added knowledge to the forecaster in the determination and identification of severe thunderstorms and weather hazards in real-time. The Melbourne Weather Office was selected as a primary site to conduct this study because Melbourne is the only site in the world with continuous and open access to total lightning (LDAR) data and a Doppler (WSR-88D) radar. A Lightning Imaging Sensor Data Applications Demonstration (LISDAD) system was integrated into the forecaster's workstation during the Summer 1996 to allow the forecaster to interact in real-time with the multi-sensor data being displayed. LISDAD currently ingests LDAR data, the cloud-to-ground National Lightning Detection Network (NLDN) data, and the Melbourne radar data in f real-time. The interactive features provide the duty forecaster the ability to perform quick diagnostics on storm cells of interest. Upon selection of a storm cell, a pop-up box appears displaying the time-history of various storm parameters (e.g., maximum radar reflectivity, height of maximum reflectivity, echo-top height, NLDN and LDAR lightning flash rates, storm-based vertically integrated liquid water content). This product is archived to aid on detailed post-analysis.

Goodman, S. J.↗

Freestanding VO 2 membranes on epidermal nanomesh for ultra-sensitive correlated breathable sensors

The interest in highly sensitive sensors is rapidly increasing for detecting very tiny signals for Internet of Things devices. Here, we achieve ultra-sensitive correlated breathable sensors based on freestanding VO 2 membranes. We fabricate the membranes by growing VO 2 films onto sacrificial Sr 3 Al 2 O 6 layer grown on SrTiO 3 , selectively dissolving the Sr 3 Al 2 O 6 in water, and then rendering freestanding VO 2 membrane on nanomesh. The nanomeshes are extremely flexible, sweat permeable, and readily skin-adhesive. The resistance of the VO 2 membranes is reversibly tuned by human’s tiny mechanical stimuli and breath stimuli. The stimuli modulate the Peierls dimerization of one-dimensional V-V chains in the VO 2 lattice which concomitantly controls the electron correlation and hence resistivity. Since our breathable sensors operate based on quantum-mechanical correlation effects, their sensitivity is 1-2 orders of magnitude higher than conventional tactile and respiratory sensors based on other materials. Thus, the freestanding membranes of correlated oxides on epidermal nanomeshes are multifunctional platforms for developing ultra-sensitive correlated breathable sensors.

36 MATERIALS SCIENCE↗

New screening methodology to select low outgassing materials for cold, spaceborne optical instruments

Standardized techniques for outgassing tests are developed and set forth for use in the screening of materials for aerospace instruments with cooled sensors, optics, and/or detectors. Materials for optical instruments are discussed in terms of molecular outgassing, and material-outgassing test results are presented which relate to several test conditions. The existing outgassing standard is found to be inadequate, and revised outgassing standards related to four application levels are given. The test protocols are designed for the development of materials for optical instruments that operate in environments with temperatures below 20 C. Consideration is also given to potential molecular contamination in the space environment and to outgas screening of instruments with a variety of sensor/optics/detector temperatures. The standards are designed for use with existing outgassing-test data as well as contamination analyses relating to the instrument being tested.

O'Donnell, T.↗

Thermal Performance Comparison and Lessons Learned for the Thermal Infrared Sensor Instruments 1 & 2

The Thermal Infrared Sensor (TIRS-1) is one of two instruments on the Landsat-8 Mission, which launched in February of 2013 and remains operational. The TIRS-2 instrument was developed for the Landsat-9 Mission, which is scheduled to launch in September of 2021. The TIRS-2 instrument design was adjusted to account for requirements changes and to include key lessons learned from its predecessor. The overall thermal subsystem design of the TIRS Sensor Unit remained comparable from mission to mission, but there were some areas that needed modifications. The general design is comprised of five thermal zones which range in temperature from less than 43 Kelvin to 320 Kelvin. Most zones are proportional heater controlled. A two-stage cryocooler provided by Ball Aerospace is used to cool the cryogenic subsystem, and excess power dissipation is rejected via ammonia transport heat pipes to a dedicated cryocooler radiator with embedded ammonia heat pipes. The cryogenic subsystem includes a series of shells used to radiatively and conductively isolate the cold stage from the warmer surroundings. The Optical System (telescope) is passively cooled to 180-195 Kelvin using a dedicated radiator with embedded dual-bore ethane heat pipes. The warmer end of the instrument includes a Scene Select Mechanism, an on-board Black Body Calibrator with a dedicated radiator, and a Focal Plane Electronics Box, all of which are attached to the Sensor Unit primary structure. The TIRS-1 thermal subsystem design was successfully verified during an extended testing campaign and during more than 8years of on-orbit operations. The TIRS-2 thermal subsystem design was successfully verified during months of ground testing prior to delivery in August of 2019and at the Observatory level in the Spring of 2021. A detailed comparison of the thermal performance of the two instruments has been made with a focus on key lessons learned during each instrument development, and with the benefit of on-orbit data acquired for the TIRS-1 instrument.

Veronica Otero↗

Short-term solar irradiance forecasting via satellite/model coupling

Here, the short-term (0-3 h) prediction of solar insolation for renewable energy production is a problem well-suited to satellite-based techniques. The spatial, spectral, temporal and radiometric resolution of instrumentation hosted on the geostationary platform allows these satellites to describe the current cloud spatial distribution and optical properties. These properties relate directly to the transient properties of the downwelling solar irradiance at the surface, which come in the form of 'ramps' that pose a central challenge to energy load balancing in a spatially distributed network of solar farms. The short-term evolution of the cloud field may be approximated to first order simply as translational, but care must be taken in how the advection is handled and where the impacts are assigned. In this research, we describe how geostationary satellite observations are used with operational cloud masking and retrieval algorithms, wind field data from Numerical Weather Prediction (NWP), and radiative transfer calculations to produce short-term forecasts of solar insolation for applications in solar power generation. The scheme utilizes retrieved cloud properties to group pixels into contiguous cloud objects whose future positions are predicted using four-dimensional (space + time) model wind fields, selecting steering levels corresponding to the cloud height properties of each cloud group. The shadows associated with these clouds are adjusted for sensor viewing parallax displacement and combined with solar geometry and terrain height to determine the actual location of cloud shadows. For mid/high-level clouds at mid-latitudes and high solar zenith angles, the combined displacements from these geometric considerations are non-negligible. The cloud information is used to initialize a radiative transfer model that computes the direct and diffuse-sky solar insolation at both shadow locations and intervening clear-sky regions. Here, we describe the formulation of the algorithm and validate its performance against Surface Radiation (SURFRAD; Augustine et al., 2000, 2005) network observations. Typical errors range from 8.5% to 17.2% depending on the complexity of cloud regimes, and an operational demonstration outperformed persistence-based forecasting of Global Horizontal Irradiance (GHI) under all conditions by ~10 W/m 2 .

14 SOLAR ENERGY↗

The Consortium for Advanced Sorghum Phenomics (CASP). Final report

The goal of CASP was to accelerate breeding of biomass sorghum [Sorghum bicolor (L.) Moench] by identifying genotypes exhibiting high yield under well-watered, pre- or post-drought and/or salinity-stress conditions. We did this by combining high-throughput, non-invasive drone phenotyping with genomics and molecular profiling. Field-based phenotyping utilized a multi-modal sensor suite of LiDAR, multispectral cameras, and thermal cameras mounted on a commercial drone to detect traits required for yield prediction and selection of drought and saline tolerant lines of sorghum. Traits of interest included plant height (PH), leaf area index (LAI), wet biomass (BMW), and biomass at 65% moisture (BM65) and were measured from emergence to harvest on a weekly basis over three growing seasons. The final output were measurements of traits on a plot-by-plot basis, identified by the plot ID used by the Proprietary data processing software enabled raw field data to be turned into plant traits and delivered to the PNNL and JGI within the same workday.

09 BIOMASS FUELS↗

COVID-19 Biomarkers and Advanced Sensing Technologies for Point-of-Care (POC) Diagnosis

COVID-19, also known as SARS-CoV-2 is a novel, respiratory virus currently plaguing humanity. Genetically, at its core, it is a single-strand positive-sense RNA virus. It is a beta-type Coronavirus and is distinct in its structure and binding mechanism compared to other types of coronaviruses. Testing for the virus remains a challenge due to the small market available for at-home detection. Currently, there are three main types of tests for biomarker detection: viral, antigen and antibody. Reverse Transcription-Polymerase Chain Reaction (RT-PCR) remains the gold standard for viral testing. However, the lack of quantitative detection and turnaround time for results are drawbacks. This manuscript focuses on recent advances in COVID-19 detection that have lower limits of detection and faster response times than RT-PCR testing. The advancements in sensing platforms have amplified the detection levels and provided real-time results for SARS-CoV-2 spike protein detection with limits as low as 1 fg/mL in the Graphene Field Effect Transistor (FET) sensor. Additionally, using multiple biomarkers, detection levels can achieve a specificity and sensitivity level comparable to that of PCR testing. Proper biomarker selection coupled with nano sensing detection platforms are key in the widespread use of Point of Care (POC) diagnosis in COVID-19 detection.

60 APPLIED LIFE SCIENCES↗

Machine processing of remotely sensed data; Proceedings of the Conference, Purdue University, West Lafayette, Ind., October 16-18, 1973

Topics discussed include the management and processing of earth resources information, special-purpose processors for the machine processing of remotely sensed data, digital image registration by a mathematical programming technique, the use of remote-sensor data in land classification (in particular, the use of ERTS-1 multispectral scanning data), the use of remote-sensor data in geometrical transformations and mapping, earth resource measurement with the aid of ERTS-1 multispectral scanning data, the use of remote-sensor data in the classification of turbidity levels in coastal zones and in the identification of ecological anomalies, the problem of feature selection and the classification of objects in multispectral images, the estimation of proportions of certain categories of objects, and a number of special systems and techniques. Individual items are announced in this issue.

Source record↗

The Seasat commercial demonstration program

The background and development of the Seasat commercial demonstration program are reviewed and the Seasat spacecraft and its sensors (altimeter, wind field scatterometer, synthetic aperture radar, and scanning multichannel microwave radiometer) are described. The satellite data distribution system allows for selected sets of data, reformatted or tailored to specific needs and geographical regions, to be available to commercial users. Products include sea level and upper atmospheric pressure, sea surface temperature, marine winds, significant wave heights, primary wave direction and period, and spectral wave data. The results of a set of retrospective case studies performed for the commercial demonstration program are described. These are in areas of application such as marine weather and ocean condition forecasting, offshore resource exploration and development, commercial fishing, and marine transportation.

Mccandless, S. W.↗

Automatic thermal control switches

Two automatic, flexible connection thermal control switches have been designed and tested in a thermal vacuum facility and in the Get Away Special (GAS) container flown on the third Shuttle flight. The switches are complementary in that one switch passes heat when the plate on which it is mounted exceeds some selected temperature and the other switch will pass heat only when the mounting plate temperature is below the selected value. Both switches are driven and controlled by phase-change capsule motors and require no other power source or thermal sensors.

Wing, L. D.↗

Spacecraft on-board SAR processing technology

This paper provides an assessment of the on-board SAR processing technology for Eos-type missions. The proposed Eos SAR sensor and flight data system are introduced, and the SAR processing requirements are described. The SAR on-board SAR processor architecture selection is discussed, and a baseline processor architecture using a frequency-domain processor for range correlation and a modular fault-tolerant VLSI time-domain parallel array for azimuth correlation are described. The mass storage and VLSI technologies needed for implementing the proposed SAR processing are assessed. It is shown that acceptable processor power and mass characteristics should be feasible for Eos-type applications. A proposed development strategy for the on-board SAR processor is presented.

Liu, K. Y.↗

Autonomous aircraft initiative study

The results of a consulting effort to aid NASA Ames-Dryden in defining a new initiative in aircraft automation are described. The initiative described is a multi-year, multi-center technology development and flight demonstration program. The initiative features the further development of technologies in aircraft automation already being pursued at multiple NASA centers and Department of Defense (DoD) research and Development (R and D) facilities. The proposed initiative involves the development of technologies in intelligent systems, guidance, control, software development, airborne computing, navigation, communications, sensors, unmanned vehicles, and air traffic control. It involves the integration and implementation of these technologies to the extent necessary to conduct selected and incremental flight demonstrations.

Hewett, Marle D.↗