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A material for separating and pumping oxygen is disclosed. The material is a zeolite doped with a chemical element having an electron density of between 30 kJ/mol and 150 kJ/mol. The material is configured for controllable oxygen desorption between 150° C. and 300° C. and pumping the released oxygen into an area having an ambient pressure of less than 100 pascals.
Thermal Energy Storage (TES) systems have demonstrated significant potential to manage the fluctuating nature of energy demand and shifting peak loads. This technology has made significant recent advances, including new research on the integration of TES with residential and commercial Heating, Ventilation, and Air-Conditioning (HVAC) systems. In this paper, we present the use of a novel laboratory assessment framework for a prototype heat pump system integrated with latent heat phase change material-based TES. The assessment framework consists of 22 total test points (11 heating, 11 cooling) using psychrometric conditions from AHRI Standard 210/240 and includes transient conditions to evaluate TES charging and discharging modes. In addition, both continuous mode and cyclic mode were evaluated for charging and discharging to explore the benefits to TES heat transfer from repeated transient operation. The ambient conditions evaluated include heating mode charging at cold-climate heat pump conditions when winter-peaking utilities may most require demand reduction (H4Full conditions, 5°F/-15°C) and cooling mode charging at high ambient temperature that may occur during times of day when excess solar power generation results in low-cost electricity (105°F/40.6°C). The work demonstrates the demand reduction capabilities of integrating TES with HVAC, including up to 44% in cooling mode and 60% in heating mode compared to conventional HVAC equipment without TES.
As part of the ongoing effort to transition from preventive maintenance strategies to condition-based maintenance strategies in nuclear power plants, there is significant reliance on using machine learning techniques. To develop a robust machine learning model that can diagnose all the fault modes of a vertical motor-driven pump, data capturing the unique signature of each fault mode is required. In practice, it is difficult to collect or capture data that captures all the fault modes from a single plant site. So to address this situation, a computational model of a vertical motor-driven pump is developed using the multipurpose finite element software COMSOL Multiphysics. The developed model is used to generate simulated data under normal operation and is compared with the vibration data collected using vibration sensors. Once the simulation model is verified under normal operating condition, simulated data for the fault mode for which minimal or no evidence is available in historical plant process data is developed. This simulated data is used to develop fault signatures to achieve robust predictive models. This paper presents modeling details and verification of the model that can used to generate data for fault modes that are not available at a plant site for condition monitoring purpose.
As part of the ongoing effort to transition from preventive maintenance strategies to condition-based maintenance strategies in nuclear power plants, there is significant reliance on using machine learning techniques. To develop a robust machine learning model that can diagnose all the fault modes of a vertical motor-driven pump, data capturing the unique signature of each fault mode is required. In practice, it is difficult to collect or capture data that captures all the fault modes from a single plant site. So to address this situation, a computational model of a vertical motor-driven pump is developed using the multipurpose finite element software COMSOL Multiphysics. The developed model is used to generate simulated data under normal operation and is compared with the vibration data collected using vibration sensors. Once the simulation model is verified under normal operating condition, simulated data for the fault mode for which minimal or no evidence is available in historical plant process data is developed. This simulated data is used to develop fault signatures to achieve robust predictive models. This paper presents modeling details and verification of the model that can used to generate data for fault modes that are not available at a plant site for condition monitoring purpose.
Heat pump water heaters (HPWHs) offer an efficient alternative to electric resistance water heaters, but they suffer from limited market penetration. This paper reviews the current state of HPWHs in the USA, focusing on technology developments and programs to increase adoption. What technological improvements are needed to make HPWHs a good fit in more homes? Additionally, what are the best ways of promoting HPWHs to consumers? Improved communication and controls will allow HPWHs to provide demand response and follow dynamic utility rates. To enable fuel-switching, HPWHs are being developed that only need a standard 120V outlet. Split HPWHs can alleviate the cooling and noise that limit the use of HPWHs in small homes, multifamily buildings, and cold climates. Additionally, new utility programs aim to train installers and provide incentives to distributors to increase the number of HPWHs installed. Some utilities offer novel incentive programs that have led to increased customer uptake. Those advances, coupled with improved controls for load shifting and new products such as split HPWHs and HPWHs that can run on 120V power, may finally move the market forward.
Air-source heat pumps (ASHPs) operating in cold climates experience problems with frosting and high refrigerant temperatures. These problems increase energy consumption, and their severity depends on the climatic conditions. In the present paper, a methodology for identifying the prevailing problem between frosting and high discharge temperatures is presented. Three performance indices, the frosting index (FI), the discharge index (DI), and the total loss index (TLI), are proposed to quantify the impacts of frosting and high discharge temperatures on the annual performance of ASHPs in different climatic conditions. The FI and DI show which problem (frosting or high discharge temperature) dominates, and the TLI indicates the combined effect of frosting and high discharge temperatures on the performance of an ASHP. A thermodynamic model of an ASHP coupled with the TRNSYS building simulation tool is used to estimate the performance of an ASHP and the proposed loss indices to estimate the impact of both frosting and high discharge temperatures for 45 cities in Canada. The results can be extended to other parts of the world that experience similar climatic conditions The results reveal that in cities in ASHRAE climatic zones 5 and 6 (classified as cold regions) where the ambient air temperatures are predominantly between -15 °C to 6 °C, ASHPs are heavily impacted by frosting. The problem of high discharge temperatures in ASHPs is predominant in cities in climate zones 7 and 8 (classified as very cold and subarctic regions) where the temperatures are frequently below -20 °C in winter. Among the cities considered, St. John, NL has the highest fraction of heating hours experiencing frosting (90 %), where the annual increase in energy consumption due to frosting is 13.5 % of the annual heating energy consumption. The highest annual increase in energy consumption due to high discharge temperatures is in Isachsen, NU (zone 8), where the increase is 30 % of the annual heating energy consumption. Based on the proposed indices, another index called the performance gain index (PGI) is created, which can be used as a first step to assess the energy-saving potential of design modifications applied to ASHPs to solve the problems of frosting and high discharge temperatures. The PGI will aid in developing climate specific ASHPs. One possible design modification is the use of a two-stage ASHP with an economizer. It is observed that the two-stage ASHP with economizer can mitigate high discharge temperatures and improve performance in very cold and subarctic regions (zones 7 and 8). However, it is not as beneficial in zones 5 and 6, where the impact of high discharge temperatures on performance is minimal and frosting dominates. Finally, a case study, using the PGI to evaluate the economic and environmental effectiveness of a two-stage ASHP with economizer is presented for the city of Saskatoon.
This archive contains both a link to Oak Ridge National Laboratory's Ground Source Heat Pump (GSHP) Screening Tool and related resources documenting its development, technical features, and applications. The web-based screening tool is a techno-economic analysis resource designed to evaluate the feasibility, costs, and benefits of implementing GSHP systems in buildings across various U.S. climate zones. It is intended for use by building owners, HVAC system designers, and installers to support decision-making in residential and commercial applications, incorporating advanced modeling capabilities such as ground heat exchanger design. The included resources detail the tool's creation and use, covering topics such as innovative ground heat exchanger design methodologies, the development of an open library of g-functions for borehole configurations, and studies on GSHP performance and economic viability in retrofitting single-family homes.
Pumped storage hydropower (PSH) capabilities are generally characterized as either open-loop or closed-loop. The U.S. Department of Energy (DOE) defines open-loop PSH as “continuously connected to a naturally flowing water feature,” and closed-loop PSH as “not continuously connected to a naturally flowing water feature.” All the PSH projects constructed in the United States to date are open-loop, so the potential environmental effects of closed-loop systems are not as well documented as the effects of open-loop systems. To address this knowledge gap, the DOE Water Power Technologies Office, under its HydroWIRES Initiative, has prepared this report to: (1) compare the potential environmental effects of open-loop PSH projects with those of closed-loop PSH projects; (2) describe how these effects are being avoided, minimized, or mitigated at existing projects in other countries and proposed projects in the United States; and (3) discuss the relative significance of the environmental issues. The report begins with a brief introduction on the current status of PSH development in the United States. Next, the report describes the current Federal Energy Regulatory Commission (FERC) hydropower licensing process, emphasizing some recent regulatory changes that affect closed-loop PSH development. The report then provides a summary comparison of the environmental effects of constructing and operating open-loop and closed-loop PSH systems and discusses the relative significance of those issues. This comparison and discussion are based on the results of a literature review and a review of FERC licensing records. The literature review includes journal articles, technical reports, and presentations on the environmental effects of PSH systems. It includes literature from the United States as well as countries where closed-loop PSH projects have been constructed. The FERC records review examines the FERC licensing record (e.g., National Environmental Policy Act documents and license orders) to identify the environmental effects anticipated and mitigation measures proposed for six of the closed-loop PSH projects currently licensed or permitted in the United States. For comparison, the FERC records review also discusses the environmental effects and mitigation measures for four open-loop PSH projects proposed or currently operating in the United States. The comparison of effects between open-loop and closed-loop projects is relative; that is, it characterizes the impacts of each project type as generally lower or higher than another project type. The comparison reflects general trends among project types because there are sometimes exceptions to the examples cited. The comparison is based on both spatial (location) and temporal (duration) factors and reflects both the severity and likelihood of effects. The report concludes that the environmental effects of closed-loop PSH projects are generally lower (i.e., more localized and of shorter duration) than those of open-loop PSH projects because they are located “off-stream,” minimizing aquatic and terrestrial impacts, and often have greater siting flexibility than open-loop PSH projects. For certain closed-loop project designs, however, impacts to groundwater may be higher relative to open-loop projects and should be considered in any environmental review.
This conference presentation presents the results from a DOE FE funded study on the integration of a Malta Pumped Heat Energy Storage system with a retiring coal-fired power plant, and the economic benefits to the asset owner and the local community.
This booklet is geared toward homeowners who want to learn about air source heat pumps and covers how the technology works, how it performs in various cold-climate environments, and NREL project highlights.
This chapter considers the combination of solar thermal systems with an energy storage device known as a Carnot Battery which charges thermal storage with a heat pump or electric heater. Integrating these systems can provide a variety of advantages, such as dispatchable renewable power generation and electricity storage services. In this chapter a variety of methods for hybridizing these systems are described, and ideal cycle analysis is used to assess their relative merits.
In this report, accurate performance evaluation of a wrapped-around condenser for heat pump water heaters (WHPWH) is critical since the COP of the system depends heavily on thermal stratification and condenser design. An analytical, quasi-steady state heat balance method has been developed to determine the optimal spacing between adjacent channels, tube diameter, tube shape, and total refrigerant charge amount for the condenser. The heat transfer rate is compared among three approaches: the refrigerant thermodynamic model, the condenser-wrap fin model, and the analytical natural convection model on the inside of the tank for the three regions based on the refrigerant phase (e.g., super-heated, saturated, or subcooled). The heat transfer rate was predicted by a combination of slug-plug and annular flow for a D-shaped helical tube. Experimental data were used as boundary conditions for validating the model. The rate of heat transfer based on tube shape and tank wall temperatures was compared by CFD analysis. Parametric analysis indicates a tradeoff between refrigerant mass, pressure drop, tube diameter, and tube length to maximize the heat transfer rate. The model suggests the saturated region length can be extended by 400%, and the condenser pressure drop can be reduced by 23% with an optimal spacing pattern.
This study investigates the heating performance of an integrated air-source heat pump (ASHP) with a thermoelectric subcooler (TES) module, revealing significant performance enhancements, particularly in colder temperatures. Results show that adding the portable TES boosts the ASHP's heating capacity, making it feasible for residential applications. The coefficient of performance (COP) for the TE system, which is influenced by condensing temperatures and ambient conditions, ranges from 1.51 to 2.07. If condensing temperatures are consistently maintained above 35 °C, a TE COP of approximately 2.07 is achievable, supporting system downsizing and reducing supplemental heating. When coupled with an oversized indoor coil, the TES-ASHP system delivers comparable heating to a baseline unit while achieving a 10 % higher COP. Capacity increases by 8.7 %–24 % with TES in colder conditions, though COP declines by 9 %–18 %, diminishing as temperatures drop. Compared to systems with supplemental heating, this setup achieves a COP 10 %–17 % higher. Future work will involve extended field testing in various climates, exploration of advanced materials for thermal efficiency, and assessment of alternative refrigerants to improve performance and sustainability. This integrated ASHP-TES system holds promise for increased efficiency and reduced environmental impact in cold climates.
Faults in air-cooled vapor compression air-conditioning systems are known to reduce performance, including efficiency, capacity, and lifespan. Their effects have been studied, and fault detection and diagnostic (FDD) methods have been developed as tools for field technicians to install or repair systems, or for monitoring to alert operators to the fault’s presence. Most of this work has focused on faults that occur singly. It is likely that in some systems, multiple faults occur simultaneously, but it is uncertain what effects this may have on diagnostics. Here, this paper describes a laboratory study of a split system air source heat pump in which combinations of two, three, and four simultaneous faults occur. The study includes all combinations of: improper evaporator airflow; overcharge or undercharge of refrigerant; liquid line restrictions; and non-condensable gas in the refrigerant, each at multiple fault intensities. Fault features – those characteristics that can be determined from measurements, for use in diagnostics – are analyzed, and the key fault features are presented. A robust existing method for determining refrigerant charge, the virtual refrigerant charge sensor (VRC) is tested using the multiple fault data, in order to understand how its performance is impacted by the combined faults. The VRC performs well, typically able to correctly determine whether a system is undercharged or overcharged, but the magnitude estimates are impacted. The results suggest that simple subcooling-based methods of charging a system are likely to provide unsatisfactory results when other faults are present.
In this work, a gas-fired air-to-water ejector heat pump (EHP) for domestic hot water production is proposed and analyzed thermodynamically. The COP of the EHP is improved by using binary fluids (HFE7500 and water), and the high backpressure in the primary ejector (first-stage) is actively controlled by either a second-stage ejector and/or a LiBr-H 2 O absorption subsystem. A thermodynamic model is established for analysis and performance evaluation. A case study shows the backpressure of the first-stage ejector is reduced by 53.5%, and the backpressure control using the second-stage ejector increases the system COP by 21.0% compared with that using LiBr-H 2 O absorption. Parametric studies are conducted to investigate the roles of the first-stage ejector, the second-stage ejector, and the LiBr-H 2 O absorption subsystem. The first-stage ejector plays a dominant role in the EHP system performance. The EHP’s heating COP can reach 2.0 with an entrainment ratio of 0.12 in the first-stage ejector. EHP performance can be improved with a high entrainment ratio and a low-temperature primary working fluid in the first-stage and second-stage ejectors, a low condensation temperature in the first-stage ejector, and a high generating temperature and a low concentration of the LiBr-H 2 O solution.
This article describes a techno-economic model for pumped thermal energy storage systems based on recuperated Joule-Brayton cycles and two-tank liquid storage. Models have been developed for each component, with particular emphasis on the heat exchangers. Economic metrics such as the power and energy capital costs (i.e., per-kW and per-kWh capacity) and levelized cost of storage are evaluated by gathering numerous cost correlations from the literature, thereby enabling estimates of uncertainty. It is found that the use of heat exchangers with effectivenesses up to 0.95 is economically worthwhile, but higher values lead to rapidly escalating component size and system cost. Several hot storage fluids are considered; those operating at the highest temperatures (chloride salts) improve the round-trip efficiency but the benefit is marginal and may not warrant the additional material costs and risk when compared to lower-temperature nitrate salts. Cost-efficiency trade-offs are explored using a multi-objective optimization algorithm, yielding optimal designs with round-trip efficiencies in the range 59-72% and corresponding levelized storage costs of 0.12 0.03 and 0.38 0.10 $/kWhe. Lifetime costs are competitive with lithium-ion batteries for discharging durations greater than 6 h under current scenarios.
Relative intensity noise (RIN) inherent in fiber lasers poses a serious obstacle to their use in pump–probe spectroscopy and imaging. RIN can be removed through an analog balanced detector, or, as we have previously shown, software adaptive noise cancellation (ANC) on digitized signals. One major drawback to software ANC is the added time required for digitizing and post-processing. In this article, we describe a design for ANC on a field-programmable gate array (FPGA), making use of high-level synthesis tools and fixed-point arithmetic to achieve real-time laser RIN suppression at 25 MHz sample rates. Unlike the software-ANC approach, the FPGA-ANC device can serve as a dedicated drop-in denoiser, placed between the detectors and a commercial lock-in amplifier. We demonstrate its application to transient absorption spectroscopy and microscopy, lowering the noise floor to ~17 dB above the shot noise limit. Furthermore, we demonstrate a dramatic improvement in data acquisition time from ~6 h to ~5 min in a real-time imaging scenario.
Ejector-driven systems have the ability to operate at high efficiencies, utilizing recycled thermal energy as a power source. For a typical ejector heat pump (EHP) system, the increase of the condenser temperature reduces the coefficient of performance (COP). In addition, if the condenser temperature is higher than the critical temperature, the ejector may not function. In this situation, the condenser temperature must be reduced, and an additional heater will be utilized to heat the production water from the condenser temperature to the desired temperature. In this study, a single-stage gas-fired EHP is investigated and thermodynamically modeled to optimize the system COP for the purpose of heating water by utilizing the thermal energy from the ambient air. The effects of the high-temperature evaporator (HTE) and low-temperature evaporator (LTE) on the ejector critical back pressure and the EHP system performance are examined for a HTE temperature range of 120–180 °C and LTE temperatures of 15.5, 17.5, and 19.5 °C. Our results show that an optimized COP for the EHP system exists and is dependent on HTE and LTE temperatures and the primary nozzle throat diameter. In addition, it is found that the peak EHP COP does not necessarily coincide with a large ejector COP. From this study, a maximum EHP COP of 1.31 is achieved at a HTE temperature of 170 °C and LTE temperature of 19.5 °C with a total heating capacity of 15.98 kW.