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At least 1,171 records · Page 65

Alloying multiple halide perovskites on the same sublattice in search of stability and target band gaps

Single-component halide perovskites (HPs) rarely satisfy all the necessary criteria for optoelectronic applications, such as achieving an optimal band gap while maintaining high chemical and structural stability. Alloying halide perovskites has emerged as a promising strategy, not only to enhance stability but also to fine-tune their electronic and optical properties. In this work, we explore multiple degrees of freedom in alloy design, considering different substitution sublattices sites (A, B, or X in ABX3 perovskites), various chemical species (isovalent and hetero-valent elements), and multi-component compositions on a given sublattice. Using first-principles calculations based on density functional theory (DFT), we investigate how compositional variations influence the electronic (band gap) and structural properties (mixing enthalpy) of HP alloys. Our approach employs the polymorphous cell model, allowing full local relaxation which breaks local symmetry while preserving global cubic symmetry—an essential framework for accurately modeling HPs. Our results reveal that X-site mixing (halogen substitution) primarily affects the valence band maximum, allowing target band gap engineering. Additionally, variations in halogen radii introduce internal strain through octahedral distortions, influencing the mixing enthalpy. A-site substitution, while not directly contributing to the band edge states, modifies structural stability via volume effects, indirectly impacting the band gap. B-site alloying plays a dominant role in band gap modulation, leading to either positive or negative band gap bowing. Specifically, isovalent B-site mixing (Sn–Pb) induces strong positive bowing, where the alloy band gap is smaller than the average gap of parent compounds, whereas hetero-valent mixing (Cd–Pb) results in pronounced negative bowing. As an aside, we investigate the competition between the excess energy of disordered alloys vs. that of long-range ordered double perovskites of the same compositions, seeking examples of ordered phases emerging from disordered alloys. Furthermore, our findings provide fundamental insights into the electronic and structural behavior of HP alloys, offering valuable design principles for the development of stable and efficient materials for next-generation photovoltaic and optoelectronic devices.

14 SOLAR ENERGY↗

Solar Photovoltaic (PV) Damage Assessment After Typhoon Mawar: Findings and Recommendations for Resilient PV on Guam

A team from the National Renewable Energy Laboratory (NREL) visited Guam in August 2023 to assess failure modes of solar photovoltaic (PV) systems after Typhoon Mawar and to provide recommendations to increase the resilience of PV systems on Guam. The team visited 30 systems: commercial and utility scale, and rooftop and ground-mounted. The team observed systems with no apparent damage, as well as systems that were completely lost. Systems fared very well overall. The average failure rate of rooftop systems was 18%, with a median failure rate of 2%, meaning the few systems that suffered total loss pulled up the average. Only eight 8 of the 25 rooftop systems suffered more than 5% damage. All ground-mounted systems suffered less than 0.5% damage, aside from a carport that lost 16% of its modules. PV systems at Andersen Air Force Base suffered 5% damage on average, with a median system failure of 0.6%. In almost all cases, failures were the result of: (1) Inadequate clamping of the module frame to the mount, (2) Module mounting clamps rotating out of underlying support rail (i.e., T-bolt that rotates free at less than 60 degrees of rotation), (3) An object hitting the panel resulting in a fracture, and in some cases leading to a cascading failure of several more panels, and (4) Excessive tilt angle (in Guam, greater than 5 degrees can be a risk due to wind speed, and power production trade-offs are insignificant).

14 SOLAR ENERGY↗

Stirling Convertor Technologies Being Developed for a Stirling Radioisotope Generator

The Department of Energy, Lockheed Martin, Stirling Technology Company (STC), and the NASA Glenn Research Center are developing a high-efficiency Stirling Radioisotope Generator (SRG) for NASA space science missions. The SRG is being developed for multimission use, including providing electric power for unmanned Mars rovers and deep space missions. On Mars, rovers with SRGs would be used for missions that might not be able to use photovoltaic power systems, such as exploration at high Martian latitudes and missions of long duration. The projected SRG system efficiency of 23 percent will reduce the required amount of radioisotope by a factor of 4 or more in comparison to currently used Radioisotope Thermoelectric Generators. The Department of Energy recently named Lockheed Martin as the system integration contractor. Lockheed Martin has begun to develop the SRG engineering unit under contract to the Department of Energy, and has contract options to develop the qualification unit and the first flight units. The developers expect the SRG to produce about 114 Wdc at the beginning of mission, using two opposed Stirling convertors and two General Purpose Heat Source modules. STC previously developed the Stirling convertor under contract to the Department of Energy and is now providing further development as a subcontractor to Lockheed Martin. Glenn is conducting an in-house technology project to assist in developing the convertor for space qualification and mission implementation. A key milestone was recently reached with the accumulation of 12 000 hr of long-term aging on two types of neodymium-iron boron permanent magnets. These tests are characterizing any possible aging in the strength or demagnetization resistance of the magnets used in the linear alternator. Preparations are underway for a thermal/vacuum system demonstration and unattended operation during endurance testing of the 55-We Technology Demonstration Convertors. In addition, Glenn is developing a charging system for the convertors to ensure clean fills of the helium working fluid and to monitor levels of any possible contaminants at different test intervals. Possible oxidation effects depend on the level of any oxygen contamination-regenerator materials and displacer radiation shields are now being evaluated for possible oxidation effects.

Thieme, Lanny G.↗

Achieving American Leadership in the Solar Photovoltaics Supply Chain Factsheet

Developing U.S. photovoltaic (PV) manufacturing could mitigate global supply chain challenges and lead to tremendous benefits for the climate as well as for U.S. workers, employers, and the economy. The solar supply chain is global and reliant on products from China or companies with close ties to China. Significant growth in U.S. manufacturing across the supply chain is possible with incentives that offset the higher cost of manufacturing in the United States. Existing polysilicon production facilities are currently idle or supplying polysilicon to other industries. Expansion in the ingot and wafer sectors outside of China would create demand for existing U.S. polysilicon producers to run at high capacity. The United States can expand production of thin-film modules, which do not rely on obtaining materials from Chinese companies. The thin film supply chain is concentrated in Ohio. There is a cluster of solar module manufacturers in Alabama, Florida, and Georgia, which presents an opportunity to grow a competitive supply chain of module components in the region.

Source record↗

An Updated Life Cycle Assessment of Utility-Scale Solar Photovoltaic Systems Installed in the United States

Given the high deployment targets for solar photovoltaics (PV) needed to meet U.S. decarbonization goals, and the limited carbon budget remaining to limit global temperature rise, accurate accounting of the energy-use and greenhouse-gas emissions over the life-cycle of PV systems is needed. In the United States, most PV systems are large utility-scale systems which use single-axis trackers and central inverters, which are not commonly examined in existing life-cycle assessment (LCA) literature. In this study, we present a cradle-to-grave LCA of a typical silicon U.S. utility PV (UPV) installation which is consistent with the utility system features documented in the annual NREL PV system cost benchmark reports. We analyze and present results for four main metrics: cumulative energy demand (CED), greenhouse gas (GHG) emissions, energy payback time (EPBT), and carbon payback time (CPBT). We consider six primary manufacturing options: three based on an imported PV module supply chain (comparing low-carbon imports, high-carbon imports, and average imports), and three based on a potential domestic PV module supply chain (comparing low-carbon U.S. regions, high-carbon U.S. regions, and average U.S. regions). These manufacturing options were then paired with installation locations to create six main cases: low-carbon options were installed in Phoenix (Arizona), high-carbon options were installed in Seattle (Washington), and average options were installed in Fredonia (Kansas). These locations were selected to represent a range of irradiance and grid mixes in the United States, in order to illustrate the likely range of EPBTs and CPBTs possible across the United States. For all six cases, a sensitivity analysis for end-of-life (EOL) handling was explored to capture current and future management options: landfilling, partial recycling, and high-quality recycling. For the purposes of this report, the benchmark system was defined to use an average imported supply chain with partial recycling, installed in Fredonia (Kansas). CED results show ratios at or below 0.1 MJ oil-eq /MJgenerated which demonstrates efficient use of primary energy resources (below a 1:1 ratio), and represents a slight improvement over previous results in literature. GHG emissions per kWh range from 10-36 g CO 2 e, which are consistent with or lower than previous results published by NREL and IEA-PVPS. We use a graphical approach for calculating EPBT and CPBT in this report, which improves upon methods typically used in literature by accounting for non-linearity and avoiding data quality issues associated with long-term projections. EPBT was determined to vary from 0.5 to 1.2 years, with a benchmark EPBT of 0.6 years; CPBT was shown to vary from 0.8 to 20 years, with benchmark CPBT of 2.1 years, which is lower than other estimates from recent literature (typically >2 years).

14 SOLAR ENERGY↗

Solar Cell Efficiency Tables (Version 67)

Consolidated tables showing an extensive listing of the highest independently confirmed efficiencies for solar cells and modules are presented. Guidelines for inclusion of results into these tables are outlined and new entries since July 2025 are reviewed.

14 SOLAR ENERGY↗

Co-design optimization of combined heat and power-based microgrids

With the emergent need for clean and reliable energy resources, hybrid energy systems, such as the microgrid, are widely adopted in the United States. A microgrid can consist of various distributed energy resources, for instance, combined heat and power (CHP) systems. Here, the CHP module is a distributed cogeneration technology that produces electricity and recaptures heat generated as a by-product. It is an energy-efficient technology converting heat that would otherwise be wasted to valuable thermal energy. For an optimal system configuration, this study develops a novel co-design optimization framework for CHP-based cogeneration microgrids. The framework provides the stakeholder with a method to optimize investments and attain resilient operations. The proposed co-design framework has a mixed integer programming (MIP) model that outputs decisions for both plant designs and operating controls. The microgrid considered in this study contains six components: the CHP, boiler, heat recovery unit, thermal storage system, power storage system, and photovoltaic plant. After solving the MIP model, the optimal design parameters of each component can be found to minimize the total installation cost of all components in the microgrid. Furthermore, the online costs from energy production, operation, maintenance, machine startup, and disruption-induced unsatisfied loads are minimized by solving the optimal control decisions for operations. Case studies based on designing a CHP-based microgrid with empirical data are conducted. Moreover, we consider both nominal and disruptive operational scenarios to validate the performance of the proposed co-design framework in terms of a cost-effective, resilient system.

42 ENGINEERING↗

Improvement in PV Plant LCOE from Convection Heat Transfer Changes from Altered Plant Layout

Heat transfer modeling that accounts for how convective cooling changes with PV array layout has been found to improve system LCOE in certain climates conditions. Analysis of fixed tilt systems performed using the System Advisor Model reveals that reducing system ground coverage ratio from 0.46 to 0.35 can lead to as much as a 1.7% increase in module annual energy output in Phoenix. Depending on climate conditions, these energy increases due to changing convective cooling flow can lead to LCOE improvements for systems with increased row spacing despite the increased wiring and land costs associated with increased module row spacing. While the energy gain from decreasing system ground coverage ratio can be largely attributed to increased plane of array irradiance, the convection cooling considerations presented here can have a non-negligible impact on PV power plant energy output and economic viability depending on climate conditions and array spacing parameters.

heat transfer↗

Comparative Study and Validation of Photovoltaic Model Formulations for the IBPSA Modelica Library based on Rooftop Measurement Data

Domain-overarching system models are crucial to investigate sector coupling concepts. Specifically, the coupling of building and electrical energy systems becomes crucial to integrate renewable energy sources such as photovoltaic power systems (PV). For such interdisciplinary simulation models, Modelica is a suitable language. However, most open-source Modelica libraries are either domain-specific or lack simple-to-parameterize PV models. We close this gap by developing a PV model for the IBPSA Modelica library. The model comprises two I-V-characteristic models and three mounting-dependent approaches to calculate the cell temperature. The I-V-characteristic models follow a single- and two-diodes approach. This study uses measurement data from a rooftop PV system in Berlin, Germany, for validation. The focus lies on comparing the implemented single- and two-diodes approach. Results prove that both models accurately calculate the modules’ DC power output and cell temperature. The two-diodes approach slightly outperforms the single-diode one at the expense of a higher parameterization effort.

Maier, Laura↗

Progress toward goals in silicon sheet development

One of the goals of the national photovoltaic program in the U.S. is the establishment of an industry producing photovoltaic material which can be sold at a price not exceeding $0.70/W by 1986. A key element concerning the achievement of this goal is the development and utilization of improved methods for producing silicon sheet. Specific technologies being investigated in this connection can be divided into two categories. Methods of one category are based on a utilization of sheet growth techniques including film-fed growth, dendritic web, and silicon-on-ceramic processes. The approaches used by methods of the second category involve ingot and wafering processes, including Czochralski growth, the heat exchanger method, multiblade procedures, and the use of a fixed abrasive multiwire. It is found that using $84/kg silicon, most sheet technologies would yield module prices in the $2.00/Wp to $3.00/Wp range.

Koliwad, K. M.↗

Luminescence and Thermal Imaging Applied to Half-Cut-Cell and Emitter-Wrap-Through-Cell Modules

Imaging techniques provide spatial details and visualization of module defects and degradation mechanisms that affect energy conversion efficiency and performance. We apply photoluminescence, electroluminescence, and dark lock-in thermography imaging techniques to evaluate new modules in their initial state and after applying stresses of damp heat, light-induced-degradation regeneration parameters, thermal cycling, and humidity-freeze cycles. One module uses emitter-wrap-through cells with back contacts connected to a metal-foil backplane, and the other is composed of half-cut cells. Imaging shows examples on non-uniform degradation and damage such as cells that degrade and recover under the applied conditions, cells with cracks and handling damage, and cells with increasing series resistance.

degradation↗

De-Risking Large-Scale PV Systems Through Data Analytics

Large-scale photovoltaic system performance analysis is being conducted within the US Department of Energy's-sponsored PV Fleet Performance Data Initiative. This collaboration with commercial PV system owners collects and evaluates PV field performance data, and provides reports on aggregated results. Drawing on over 2200 sites across the US and over 24,000 separate PV inverters we have collected in excess of 8.3 gigawatts (GW) of performance data, representing 6-7% of the entire US installed PV capacity. A mixture of utility-scale and large commercial systems are represented, averaging 4.1 megawatts (MW) in size and 5 years in age. Initial results show average system degradation rates at -0.75% / year, which is slightly higher than historically reported module-level values of -0.5%/year. We also found that the availability of systems averaged 97.7%, which is lower than the typical 99% uptime assumed by many project economic forecasts. Given these results, we compared monthly performance with expected production values, based on satellite weather data and a simple PVWatts performance model. We found that systems were performing within 10% of monthly expectation over 90% of the time, with a fleet average vs expected monthly value of 0.994. We also evaluated the impact of extreme weather events on system performance, and found a range of short-term and longer-term performance effects ranging from grid outage, system downtime, module damage and accelerated long-term degradation rate.

analysis↗

A unified large language model–based framework for heterogeneous PV image diagnosis

With advances in imaging technologies, modern photovoltaic (PV) systems generate large volumes of heterogeneous image data, including visible, electroluminescence (EL), and infrared (IR) images. Existing PV image analysis models, particularly deep learning approaches, are typically task-specific and lack cross-modality generalization. To address this limitation, this paper proposes an open-source large language model (LLM)–based unified framework for heterogeneous PV image diagnostics. Through task-aware diagnostic prompting, the framework enables analysis of visible, EL, and IR images within a single pipeline, supporting both zero-shot and few-shot inference and binary and multiclass classification. It is compatible with state-of-the-art multimodal LLMs, including ChatGPT, Gemini, Claude, Qwen, and CLIP. The framework is evaluated on PV module condition classification (clean, soiling, snow, hail, and bird droppings) using visible images, cell crack detection using EL images, and hotspot detection using IR images. GPT-5.1 in few-shot mode achieves the best performance, with classification accuracy exceeding 97.3%. Open-source models such as Qwen and CLIP also deliver competitive results on visible images (around 90% accuracy), though their performance is more limited on EL and IR modalities. On the full ELPV dataset, the framework achieves 83.5% zero-shot accuracy, within 2.8% of the supervised CNN baseline, confirming scalability to larger benchmarks. Practical aspects such as reproducibility, response latency, and confidence estimation are systematically analyzed. The framework operates across PV image modalities without modality- or task-specific training, making it well suited as a rapid pre-screening tool to support downstream detailed diagnostics. A benchmark dataset of diverse labeled PV images is also released.

Li, Baojie↗

A universal co-solvent dilution strategy enables facile and cost-effective fabrication of perovskite photovoltaics

Cost management and toxic waste generation are two key issues that must be addressed before the commercialization of perovskite optoelectronic devices. We report a groundbreaking strategy for eco-friendly and cost-effective fabrication of highly efficient perovskite solar cells. This strategy involves the usage of a high volatility co-solvent, which dilutes perovskite precursors to a lower concentration (<0.5 M) while retaining similar film quality and device performance as a high concentration (>1.4 M) solution. More than 70% of toxic waste and material cost can be reduced. Mechanistic insights reveal ultra-rapid evaporation of the co-solvent together with beneficial alteration of the precursor colloidal chemistry upon dilution with co-solvent, which in-situ studies and theoretical simulations confirm. The co-solvent tuned precursor colloidal properties also contribute to the enhancement of the stability of precursor solution, which extends its processing window thus minimizing the waste. This strategy is universally successful across different perovskite compositions, and scales from small devices to large-scale modules using industrial spin-coating, potentially easing the lab-to-fab translation of perovskite technologies.

36 MATERIALS SCIENCE↗

Development and Reliability of Screen-Printable Fire-Through Cu Paste for Passivated Contact Solar Cells

We present the development of copper (Cu) paste which has been screen printed on Selective Emitter-Passivated Emitter Rear Contact (SE-PERC) solar cells. This paste can also be applied to Tunnel Oxide Passivated Contact (TOPCON) solar cells due to its fire-through nature. Champion PERC cells have achieved ....efficiency with ...parameters . Accelerated testing to investigate reliability performance of the SE- PERC mini-modules were carried out in damp heat chamber with 85oC and 85% humidity. The devices were found to be operational even after 1,500 hours. Devices with screen printed Ag contacts on the front side have been studied in parallel to the Cu contacts for comparison.

copper paste↗

High-Resolution Floating Solar PV Data

This dataset contains over two years of 1-minute resolution data collected from four floating solar sites, as well as data from a land-based PV system co-located with one of the floating sites. The dataset includes highly granular module temperature measurements - five modules per floating site, with three sensors per module, totaling 15 module temperature sensors per floating site. In addition to the module temperature data, meteorological data collected at the floating sites is also included, along with traditional PV system-level parameters. The data is intended for analysis of solar energy production, efficiency, and performance degradation over time. For information about the data file usage see the "README" resource below. See "Metadata File" for information about individual files and other metadata information.

Array↗

Improving Computational Efficiency of Mechanical Finite Element Method Simulations for PV Modules: Preprint

In this work we have elucidated the trade off between structural mechanics FEM model accuracy and computation time by employing lower fidelity viscoelastic models. Results indicate that computation time can easily be cut in half while only expecting a potential maximum error of 10 % by considering lower fidelity models. A novel approach to produce the Prony Series fit for viscoelastic characterization has also been presented. Employing this approach, we were able to achieve a further 10 % reduction in computation time without further sacrificing simulation accuracy.

41 EE - Solar Energy Technologies Office (EE-4S)↗