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At least 1,171 records · Page 65

Designing order–disorder transformation in high-entropy ferritic steels

Order–disorder transformations hold an essential place in chemically complex high-entropy ferritic steels (HEFSs) due to their critical technological application. The chemical inhomogeneity arising from mixing of multi-principal elements of varying chemistry can drive property altering changes at the atomic scale, in particular short-range order. Using density-functional theory-based linear-response theory, we predict the effect of compositional tuning on the order–disorder transformation in ferritic steels—focusing on Cr–Ni–Al–Ti–Fe HEFSs. We show that Ti content in Cr–Ni–Al–Ti–Fe solid solutions can be tuned to modify short-range order that changes the order–disorder path from BCC-B2 (Ti atomic-fraction = 0) to BCC-B2-L2 1 (Ti atomic-fraction > 0) consistent with existing experiments. Our study suggests that tuning degree of SRO through compositional variation can be used as an effective means to optimize phase selection in technologically useful alloys.

36 MATERIALS SCIENCE↗

Commissioning of a Cask Enabling Characterization of Irradiated Nuclear Fuels with Pulsed Neutrons

Irradiation tests are a key component of nuclear fuel development and identifying typical and atypical regions in the irradiated fuel volume relies on very few characterization techniques. The goal of the effort reported here is to provide complementary measurements adding to the available parameter space for post irradiation examination as well as to inform subsequent hot cell PIE examinations by identifying typical and atypical regions with respect to microstructure, tomographic data, or isotope densities. Pulsed neutrons, enabling diffraction as well as energy-resolved neutron imaging and neutron absorption resonance spectroscopy, offer unique capabilities for this purpose. Time-of-flight neutron diffraction has the potential to offer efficient, non-destructive and non-contact microstructural characterization of irradiated fuel pins with spatial resolution of 1 mm 3 to 1 cm 3 while for energy-resolved neutron imaging (and by extension tomography) a resolution of 100 μm was demonstrated. The potential results include crystallinity vs. amorphous volumes and microstructural information such as phase compositions, lattice strains (indicative of residual stresses or chemistry variations) and textures from the diffraction data as well as distances (e.g. pellet to cladding), cracks, and isotopic distributions of minor actinides, fission products as well as fission gas partial pressures e.g. in the plenum from energy resolved neutron imaging.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Progress Report on Mockup Irradiation Capsule Fuel Measurements at LANSCE

Irradiation tests are a key component of nuclear fuel development and identifying typical and atypical regions in the irradiated fuel volume relies on very few characterization techniques. The goal of the effort reported here is to provide complementary measurements adding to the available parameter space for post irradiation examination as well as to inform subsequent hot cell PIE examinations by identifying typical and atypical regions with respect to microstructure, tomographic data, or isotope densities. Pulsed neutrons, enabling diffraction as well as energy-resolved neutron imaging and neutron absorption resonance spectroscopy, offer unique capabilities for this purpose. Time-of-flight neutron diffraction has the potential to offer efficient, non-destructive and non-contact microstructural characterization of irradiated fuel specimen with spatial resolution of 1 mm 3 to 1 cm 3 while for energy-resolved neutron imaging (and by extension tomography) a resolution of 100 μm 3 was demonstrated. The potential results include crystallinity vs. amorphous volumes and microstructural information such as phase compositions, lattice strains (indicative of residual stresses or chemistry variations) and textures from the diffraction data as well as distances (e.g. pellet to cladding), cracks, and isotope densities of minor actinides, fission products as well as fission gas partial pressures e.g. in the plenum from energy resolved neutron imaging.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Cathodoluminescence of Al/x/Ga/1-x/As grown by liquid-phase epitaxy

Small-area contrast fluctuations observed in cathodoluminescence-mode SEM images of thin Al(x)Ga(1-x)As layers grown by liquid-phase epitaxy on GaAs:Cr substrates are attributed to local variations in alloy composition. Quantitative estimates of the composition excursions are obtained from the variations in CL intensity by calibration against compositions known from electron-probe microanalysis. In a typical sample, the CL variations are shown to correspond to peak-to-peak fluctuations of about 1 at. % of Al and occur over irregular regions generally in the range 6-20 microns in diameter.

Levin, E. R.↗

Ultraviolet and optical spectroscopic studies of Lambda Andromedae - The chromosphere and interstellar medium

Chromospheric lines of, and interstellar lines toward, the spectroscopic binary Lambda And (primary component G7-G8 III-IV) have been observed in the ultraviolet with the spectrometer and telescope on board the Copernicus satellite. An extensive, high-resolution spectroscopic study of the Ca II H and K profiles has also been undertaken. Some of these optical spectra were obtained simultaneously with the ultraviolet data. The ultraviolet emission lines of Lamba And are compared to the sun and to stars of similar spectral type. The star Lamba And resembles the active sun in surface brightness of chromospheric emissions and in appearance of the Mg II and Ca II profiles. The largest variations in the integrated calcium emission cores amount to an 80% increase in the K core and a corresponding 40% increase in the H core between observations two years apart. Variations in the cores may show a dependence on spectroscopic phase, and may be contributed to by circumstellar matter in the binary system. Previously unreported, transient emission features have also been observed, at a velocity of -70 km/s with respect to the Ca II emission cores.

Baliunas, S. L.↗

International planetary patrol observations of Saturn's rings. II - Four color phase curves and their analysis

New phase curves for Saturn's rings at an intermediate tilt angle B of about 17 deg are presented. Quantitative results for each of the A and B rings are reported in terms of the opposition effect, phase coefficient, and best logarithmic fit to the phase curve. There was no significant difference between the shape of the phase curves for the two rings in each of the four colors, and a four-parameter multiple scattering model of the rings was consistent with the observations. In this model, the difference in the phase curves for different colors can be explained by a variation in the single scattering albedo with wavelength. The observations allow the particles to have the same composition in the A and B rings, so that their different photometric behavior is explained by differences in optical depth and volume density in the two rings.

Esposito, L. W.↗

The effect of the sea breeze circulation on surface ozone levels at Wallops Island, Virginia

Surface measurements of windspeed, direction, and ozone concentration collected at Wallops Island, Virginia, during the summers of 1977 and 1978 are analyzed to study the effects of the dominant mesoscale sea breeze circulation on the local photochemical oxidant levels. A bimodality in the atmospheric dynamics is linked to systematic variations in ozone concentration. It is concluded that during certain phases of the two circulation modes, increased wind speed reduces the resistance of the earth's surface to the deposition of ozone, and decreased ozone concentration levels result. For other phases, light winds occur, signifying high resistance to deposition and high ozone levels. This modulation by the local dynamics is a major impediment for pollutant studies in coastal environments, especially those centering on transport, because it tends to mask other processes that may be occurring.

Parsons, C. L.↗

Design and breadboard evaluation of the SPS reference phase control system concept

The total breadboard system includes one pilot transmitter, one pilot receiver, nine phase distribution units, and two power transponders. With this complement of equipment, segments of a typical phase distribution system can be assembled to facilitate the evaluation of significant system parameters. The achievable accuracy of a large phase distribution system, the sensitivity of the system to parameter variations, and the limitations of commercially available components in such applications were determined.

Hopkins, P. M.↗

X-ray bright points and the sunspot cycle - Further results and predictions

X-ray images obtained during two rocket flights near the maximum of sunspot cycle 21 now allow the study of the variation of X-ray bright point number over an eleven-year period covering the maxima of the last two cycles. The new data are consistent with the earlier conclusion that the temporal variation of bright point and sunspot number are out of phase. The quantities are related through a power law with a negative exponent of 2/3.

Davis, J. M.↗

Autoregressive harmonic analysis of the earth's polar motion using homogeneous International Latitude Service data

The homogeneous set of 80-year-long (1900-1979) International Latitude Service (ILS) polar motion data is analyzed using the autoregressive method (Chao and Gilbert, 1980), which resolves and produces estimates for the complex frequency (or frequency and Q) and complex amplitude (or amplitude and phase) of each harmonic component in the data. The ILS data support the multiple-component hypothesis of the Chandler wobble. It is found that the Chandler wobble can be adequately modeled as a linear combination of four (coherent) harmonic components, each of which represents a steady, nearly circular, prograde motion. The four-component Chandler wobble model 'explains' the apparent phase reversal during 1920-1940 and the pre-1950 empirical period-amplitude relation. The annual wobble is shown to be rather stationary over the years both in amplitude and in phase, and no evidence is found to support the large variations reported by earlier investigations. The Markowitz wobble is found to be marginally retrograde and appears to have a complicated behavior which cannot be resolved because of the shortness of the data set.

Chao, B. F.↗

The Dynamics of Ionospheric D Region over East Siberia

Some main results of experimental investigations of the dynamical regime of the ionospheric D-region over East Siberia are presented. Regular measurements of horizontal ionospheric drifts by the radio method of closely spaced receivers, using a long wavelength transmitter operating at a frequency of 200 kHz, were carried out near Irkutsk, USSR, since 1975. The seasonal and inter-annual variations of prevailing wind (zonal and meridional), and amplitudes and phases of semi-diurnal tides are investigated. Evidence is presented to show the response of D-region dynamics to stratospheric warmings. Planetary and gravity waves are found in the wind field. Comparison with results of analogous measurements in Central Europe (Collm, GDR) reveals a longitudinal effect on the dynamical regime of the mid-latitude lower thermosphere.

Kazimirovsky, E. S.↗

Corrected sidereal anisotropy for underground moons

Data from underground muon telescopes in New Mexico and Bolivia are analyzed in sidereal time and anti-sidereal time in the rigidity range 20 GV to a few 100's of GV. Using both vertical and north- and south- pointing telescopes in both hemispheres, a latitude range of 70 N to 50 S is covered. It is shown that there is an anti-sidereal variation of the P 1 over 2 type, having opposite phase in the Northern and Southern Hemispheres, and maximum amplitude at mid latitudes. The anti-sidereal data are used to correct the sidereal data, using the Nagashima method (Nagashima, 1984); the resulting corrected sidereal vectors for northern hemisphere telescopes have their sidereal maxima close to 3h sidereal time, in reasonable agreement with sidereal data at higher energies from small air showers. The Nagashima correction also eliminates effects due to the reversal of the Sun's polar magnetic field which show up in the uncorrected sidereal data.

Swinson, D. B.↗

Variable polarization in X-ray binaries - HD 153919 (= 4U1700 - 37) and HD 152667 (= OAO1653 - 40?)

Variable linear polarization has been observed in the optical radiation from two presumed X-ray binary systems, HD 153919 (= 4U1700 - 37) and HD 152667 (probably not OAO1653 - 40). This intrinsic polarization appears correlated with the orbital phase of the binary, but the polarimetric light curve shows variations from year to year. The Stokes parameter q, u light curves are consistent with the polarization being caused by the Rayleigh scattering of light from the primary by gas streams in the vicinity of the secondary. Several orbital and physical parameters of the binary systems are derived from the polarimetric observations.

Dolan, J. F.↗

H-alpha manifestation of an energetic limb flare, June 21, 1980

H-alpha observations of a limb flare, which were associated with exceptional gamma-ray and hard X-ray emission, are presented and discussed. The good spatial and temporal resolution of the H-alpha data allow investigation of the detailed structure of the elevated flare loops and the intensity variations of the loops, footpoints and surrounding chromosphere during each phase of the flare event. A delay time of about 12 s was found between at least one of the hard X-ray (28-485 keV) peaks and corresponding H-alpha intensity maximum at a loop footpoint. A comparison is made between this event and another well-observed limb flare with many similar characteristics, to seek evidence for the large difference in their levels of energy release.

Mccabe, M. K.↗

Physics and chemistry of sulfur lakes on Io

Based on data from Loki and other hot spot regions, a model for a convecting sulfur lake that is heated from below is constructed. Temperature profiles and fluxes in the silicate and sulfur regions are consistent with the observed Loki highest-temperature component and excess flux. Evaporatin of sulfur sets a strong upper limit on the lake surface temperature, and the intermediate temperature in the Loki region is identified with sulfur vapor condensing primarily along lake shores. Simple models of sulfur vapor transport can be used to match the Voyager IRIS data, assuming sulfur vapor condensed on the shore radiates like a blackbody. The 1 - 100 year lifetime of such a lake in steady state implies that long-term earth-based observations interpreted with this model could detect variations in the Loki thermal output. The sodium-sulfur phase diagram is also presented and used to show that evaporated lakes may leave behind sodium-rich residue which could supply the torus with sodium. Finally, uncertainties in the model are assessed, including the lack of sulfur emission features in the Loki spectrum.

Lunine, J. I.↗

Voyager observations of the azimuthal brightness variations in Saturn's rings

The present Voyagers I and II measurements of Saturn A ring azimuthal brightness variations in reflected light are noted to be in general agreement with earth-based measurements. Voyager images of the rings in light transmitted through them also indicate the presence of these brightness variations, but with greater amplitude and an about 65-deg phase discrepancy with those seen in reflection. These differences in photometric behavior are qualitatively accounted for in terms of the widespread presence of particle wakes in the A ring.

Franklin, F. A.↗