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NASA NTRS2000

Laboratory Astrochemistry: Interstellar PAH Analogs

Polycyclic aromatic hydrocarbons (PAHs) are now considered to be an important and ubiquitous component of the organic material in space. PAHs are found in a large variety of extraterrestrial materials such as interplanetary dust particles (IDPs) and meteoritic materials. PAHs are also good candidates to account for the infrared emission bands (UIRs) and the diffuse interstellar optical absorption bands (DIBs) detected in various regions of the interstellar medium. The recent observations made with the Infrared Space Observatory (ISO) have confirmed the ubiquitous nature of the UIR bands and their carriers. PAHs are though to form through chemical reactions in the outflow from carbon-rich stars in a process similar to soot formation. Once injected in the interstellar medium, PAHs are further processed by the interstellar radiation field, interstellar shocks and energetic particles. A major, dedicated, laboratory effort has been undertaken over the past years to measure the physical and chemical characteristics of these complex molecules and their ions under experimental conditions that mimic the interstellar conditions. These measurements require collision-free conditions where the molecules and ions are cold and chemically isolated. The spectroscopy of PAHs under controlled conditions represents an essential diagnostic tool to study the evolution of extraterrestrial PAHs. The Astrochemistry Laboratory program will be discussed through its multiple aspects: objectives, approach and techniques adopted, adaptability to the nature of the problem(s), results and implications for astronomy as well as for molecular spectroscopy. A review of the data generated through laboratory simulations of space environments and the role these data have played in our current understanding of the properties of interstellar PAHs will be presented. The discussion will also introduce the newest generation of laboratory experiments that are currently being developed in order to provide a closer simulation of space environments and a better support to space missions.

Salama, Farid↗

NASA NTRS2000

Molecular Spectroscopy in Astrophysics: Interstellar PAHs

Polycyclic aromatic hydrocarbons (PAHs) are now considered to be an important and ubiquitous component of the organic material in space. PAHs are found in a large variety of extraterrestrial materials such as interplanetary dust particles (IDPs) and meteoritic materials. PAHs are also good candidates to account for the infrared emission bands (UIRs) and the diffuse interstellar optical absorption bands (DIBs) detected in various regions of the interstellar medium. The recent observations made with the Infrared Space Observatory (ISO) have confirmed the ubiquitous nature of the UIR bands and their carriers. PAHs are thought to form through chemical reactions in the outflow from carbon-rich stars in a process similar to soot formation. Once injected in the interstellar medium, PAHs are further processed by the interstellar radiation field, interstellar shocks and energetic particles. A long-term laboratory effort has been undertaken to measure the physical and chemical characteristics of these carbon molecules and their ions under experimental conditions that mimic the interstellar conditions. These measurements require collision-free conditions where the molecules and ions are cold and chemically isolated. The spectroscopy of PAHs under controlled conditions represents an essential diagnostic tool to study the evolution of extraterrestrial PAHs. The laboratory results will be discussed as well as the implications for astronomy and for molecular spectroscopy. A review of the data generated through laboratory simulations of space environments and the role these data have played in our current understanding of the properties of interstellar PAHs will be presented. We will also present the new generation of laboratory experiments that are currently being developed in order to provide a closer simulation of space environments and a better support to space missions.

Salama, Farid↗

NASA NTRS2000

Laboratory Studies of Interstellar PAH Analogs

Salama, Farid↗

NASA NTRS1990

Practical Estimates of the Errors Associated with the Governing Shearography Equation

In a series of papers Hung pioneered the development of shearography, an optical NDE technique that detects gradients of surface displacements. Its utility for qualitative flaw characterization has been demonstrated, and while there is a need for using shearography in NDE for quantitative analysis, a large amount of the research has concentrated on the qualitative evaluation of structures and materials. The purpose of this paper is to begin building upon a foundation for the newly emerging quantitative shearography. We begin the analysis by considering the approximations leading to the governing shearography equation.

Fulton, J. P.↗

NASA NTRS2003

The ISO View of Palomar-Green Quasars

Mining the ISO data archive we provide the complete ISO view of PG quasars containing 64 infrared spectral energy distributions between 5 and 200 mu m. About half of the sample was supplemented by MAMBO and SCUBA (sub-)millimeter data. Since the PG quasars were selected optically, the high infrared detection rate of more than 80% suggests that every quasar possesses luminous to hyper-luminous dust emission with dust masses comparable to Seyferts and ultra-luminous IR galaxies (ULIRGs). The gas to-dust mass ratio (of those sources where CO measurements are available in the literature) is consistent with the galactic value providing further evidence for the thermal nature of the IR emission of radio quiet quasars. The SEDs represent templates of unprecedented detail and sensitivity. We suggest that the diversity of the SEDs reflects largely the evolution of the dust distribution, and we propose a classification of the SED shapes as well as an evolutionary scheme in which this variety can be understood. During the evolution the surrounding dust redistributes, settling more and more into a torus/disk like configuration, while the SEDs show an initial FIR bump, then an increasing MIR emission and a steeper near- to mid-infrared slope, both of which finally also decrease. Regarding cosmic evolution, our hyper-luminous quasars in the "local" universe at z=l do not show the hyper-luminous (LFIR >? 10(exp 13) L(sub sun)) starburst activity inferred for z=4 quasars detected in several (sub-)millimeter surveys. In view of several caveats this difference should be established further, but it already suggests that in the early dense universe stronger merger events led to more powerful starbursts accompanying the quasar phenomenon, while at later cosmic epochs any coeval starbursts obviously do not reach that high power and are outshone by the AGN. Additional information is included in the original extended abstract.

Haas, M.↗

NASA NTRS2007

Tracing the Jet Contribution to the Mid-IR over the 2005 Outburst of GRO J1655-40 via Broadband Spectral Modeling

We present new results from a multi-wavelength (radio/infrared/optical/X-ray) study of the black hole Xray binary GRO 51655-40 during its 2005 outburst. We detected, for the first time, mid-infrared emission at 24 micron from the compact jet of a black hole X-ray binary during its hard state, when the source shows emission from a radio compact jet, as well as a strong non-thermal hard X-ray component. These detections strongly constrain the optically thick part of the synchrotron spectrum of the compact jet, which is consistent with it being flat over 4 orders of magnitude in frequency. Moreover, using this unprecedented coverage, and especially thanks to the new Spitzer observations, we can test broadband disk and jet models during the hard state. Two of the hard-state broadband spectra are reasonably well fitted using a jet model with parameters that overall are similar to those previously found for Cyg X-1 and GX 339-4. Differences are also present; most notably, the jet power in GRO J1655-40 appears to be a factor of at least approximately 3-5 higher (depending on the distance) than those of Cyg X-1 and GX-339-4 at comparable disk luminosities. Furthermore, a few discrepancies between the model and the data, previously not found for the other two black hole systems for which there was no mid-IR/IR and optical coverage, are evident, and will help to constrain and refine theoretical models.

Migliari, S.↗

NASA NTRS2009

Optoelectronic tweezers for microparticle and cell manipulation

An optical image-driven light induced dielectrophoresis (DEP) apparatus and method are described which provide for the manipulation of particles or cells with a diameter on the order of 100 .mu.m or less. The apparatus is referred to as optoelectric tweezers (OET) and provides a number of advantages over conventional optical tweezers, in particular the ability to perform operations in parallel and over a large area without damage to living cells. The OET device generally comprises a planar liquid-filled structure having one or more portions which are photoconductive to convert incoming light to a change in the electric field pattern. The light patterns are dynamically generated to provide a number of manipulation structures that can manipulate single particles and cells or groups of particles/cells. The OET preferably includes a microscopic imaging means to provide feedback for the optical manipulation, such as detecting position and characteristics wherein the light patterns are modulated accordingly.

Wu, Ming Chiang↗

NASA NTRS2010

How Well Can Infrared Sounders Observe the Atmosphere and Surface Through Clouds?

Infrared sounders, such as the Atmospheric Infrared Sounder (AIRS), the Infrared Atmospheric Sounding Interferometer (IASI), and the Cross-track Infrared sounder (CrIS), have a cloud-impenetrable disadvantage in observing the atmosphere and surface under opaque cloudy conditions. However, recent studies indicate that hyperspectral, infrared sounders have the ability to detect cloud effective-optical and microphysical properties and to penetrate optically thin clouds in observing the atmosphere and surface to a certain degree. We have developed a retrieval scheme dealing with atmospheric conditions with cloud presence. This scheme can be used to analyze the retrieval accuracy of atmospheric and surface parameters under clear and cloudy conditions. In this paper, we present the surface emissivity results derived from IASI global measurements under both clear and cloudy conditions. The accuracy of surface emissivity derived under cloudy conditions is statistically estimated in comparison with those derived under clear sky conditions. The retrieval error caused by the clouds is shown as a function of cloud optical depth, which helps us to understand how well infrared sounders can observe the atmosphere and surface through clouds.

Zhou, Daniel K.↗

NASA NTRS2014

Optoelectronic Tweezers for Microparticle and Cell Manipulation

An optical image-driven light induced dielectrophoresis (DEP) apparatus and method are described which provide for the manipulation of particles or cells with a diameter on the order of 100 micromillimeters or less. The apparatus is referred to as optoelectric tweezers (OET) and provides a number of advantages over conventional optical tweezers, in particular the ability to perform operations in parallel and over a large area without damage to living cells. The OET device generally comprises a planar liquid-filled structure having one or more portions which are photoconductive to convert incoming light to a change in the electric field pattern. The light patterns are dynamically generated to provide a number of manipulation structures that can manipulate single particles and cells or group of particles/cells. The OET preferably includes a microscopic imaging means to provide feedback for the optical manipulation, such as detecting position and characteristics wherein the light patterns are modulated accordingly.

Wu, Ming Chiang↗

NASA NTRS2011

Characterization of Photon-Counting Detector Responsivity for Non-Linear Two-Photon Absorption Process

Sub-band absorption at 1550 nm has been demonstrated and characterized on silicon Geiger mode detectors which normally would be expected to have no response at this wavelength. We compare responsivity measurements to singlephoton absorption for wavelengths slightly above the bandgap wavelength of silicon (approx. 1100 microns). One application for this low efficiency sub-band absorption is in deep space optical communication systems where it is desirable to track a 1030 nm uplink beacon on the same flight terminal detector array that monitors a 1550 nm downlink signal for pointingcontrol. The currently observed absorption at 1550 nm provides 60-70 dB of isolation compared to the response at 1064 nm, which is desirable to avoid saturation of the detector by scattered light from the downlink laser.

Geiger mode detector↗

NASA NTRS2016

Growth Mechanism of Nanowires: Binary and Ternary Chalcogenides

Semiconductor nanowires exhibit very exciting optical and electrical properties including high transparency and a several order of magnitude better photocurrent than thin film and bulk materials. We present here the mechanism of nanowire growth from the melt-liquid-vapor medium. We describe preliminary results of binary and ternary selenide materials in light of recent theories. Experiments were performed with lead selenide and thallium arsenic selenide systems which are multifunctional material and have been used for detectors, acousto-optical, nonlinear and radiation detection applications. We observed that small units of nanocubes and elongated nanoparticles arrange and rearrange at moderate melt undercooling to form the building block of a nanowire. Since we avoided the catalyst, we observed self-nucleation and uncontrolled growth of wires from different places. Growth of lead selenide nanowires was performed by physical vapor transport method and thallium arsenic selenide nanowire by vapor-liquid-solid (VLS) method. In some cases very long wires (>mm) are formed. To achieve this goal experiments were performed to create situation where nanowires grew on the surface of solid thallium arsenic selenide itself.

Singh, N. B.↗

NASA NTRS2016

Growth Mechanism of Nanowires: Ternary Chalcogenides

In the past two decades there has been a large rise in the investment and expectations for nanotechnology use. Almost every area of research has projected improvements in sensors, or even a promise for the emergence of some novel device technologies. For these applications major focuses of research are in the areas of nanoparticles and graphene. Although there are some near term applications with nanowires in photodetectors and other low light detectors, there are few papers on the growth mechanism and fabrication of nanowire-based devices. Semiconductor nanowires exhibit very favorable and promising optical properties, including high transparency and a several order of magnitude better photocurrent than thin film and bulk materials. We present here an overview of the mechanism of nanowire growth from the melt, and some preliminary results for the thallium arsenic selenide material system. Thallium arsenic selenide (TAS) is a multifunctional material combining excellent acousto-optical, nonlinear and radiation detection properties. We observed that small units of (TAS) nanocubes arrange and rearrange at moderate melt undercooling to form the building block of a nanowire. In some cases very long wires (less than mm) are formed. Since we avoided the catalyst, we observed self-nucleation and uncontrolled growth of wires from different places.

Singh, N. B.↗

NASA NTRS2018

Land Surface Reflectances from Geostationary Sensors

GEONEX is a processing pipeline that produces a suite of satellite land surface products using data streams from the latest geostationary (GEO) sensors including the GOES016/ABI and the Himawari-8/AHI. The suite, created collaboratively by scientists from NASA and NOAA, includes top-of-atmosphere (TOA) reflectances, land surface reflectances (LSRs), vegetation indices, LAI/fPAR, and other downstream products. As a key component of the GEONEX product processing, we have adapted the Multi-Angle Implementation of Atmospheric Correction (MAIAC) algorithm to produce LSRs from the TOA data. Because the algorithm depends on building "stacks" of images, we first run internal geo-registration checks to ensure geo-spatial accuracy and consistency of the input (L1B) data before transferring them from the geostationary projection into a tile system in geographic grids. Scan-time is inferred from metadata and applied to calculate the sun-sensor angles for each grid cell. The MAIAC algorithm is run to detect clouds/shadows, estimate aerosol optical thickness (AOT), perform atmospheric corrections, and generate LSRs. We have processed 18-months (from 2016/04 onward) of AHI data over East Asia and Oceania at a 10-minute time step and 10-months (from 2018/01 onward) of ABI data over North and South Americas at a 15-minute time step. As a verification measure, we compare the GEONEX (AHI/ABI) surface reflectances with the standard MODIS products (MOD09GA) and the MODIS MAIAC products over pixels that have similar sun-view geometries. The results indicate general linear relationships between GEONEX and corresponding MODIS LSRs. In particular, the RMSEs between GEONEX and MOD09 data are comparable to those between MOD09 and MODIS MAIAC products, suggesting that the uncertainties of GEONEX LSRs fall into an acceptable range. However, direct comparisons of LSRs over pixels with different sun-view angles are not as straightforward and require more modeling efforts to correct the directional effects. Evaluation of such angular influences on the downstream products (e.g., vegetation indices) is also under investigation.

Geostationary satellite; Remote Sensing; Atmospher↗

NASA NTRS2019

A Radar Investigation of Precipitation Properties During Discrepancies Between GOES-16 GLM and LMA Observed Flash Rates in the Skyline Alabama Supercell of 22 April 2017

Conclusions: GLM (Geostationary Lightning Mapper) flash rates were 2 to 5 times lower than LMA (Lightning Mapping Array) in an Alabama supercell that was tracked using a combination of GLM flash initiation density and VIL (Vertically Integrated Liquid); Since most lightning was initiating at 8-9 kilometers (and not at low levels) according to LMA, flash height does not appear to be a primary factor in low GLM flash rates; When (LMA-GLM) flash rate differences were largest, the LMA observed flash areas were relatively small (and vice versa); Flash size may be a primary factor in low GLM flash rates due to detectability and/or flash clustering issues with small flashes within the coarse 8 kilometers by 8 kilometers resolution; High cloud liquid water droplet concentrations were inferred indirectly from riming necessary for large radar MESH (Maximum Expected Size of Hail), VIL and hail/graupel volumes. High cloud water droplet concentrations in supercells may decrease GLM detection efficiency due to optical extinction of near IR (near Infrared) emitted by lightning as it moves through cloud; Despite large flash rate differences, GLM & LMA lightning jumps during robust supercell generally agreed with each other and radar trends in HID (Radar Reflectivity and Hydrometeor Identification), MESH and VIL.However, more LMA jumps (than GLM) in developing supercell and more GLM jumps (than LMA) in weak to decaying supercell. Future work: improve GLM tracking.

GLM↗

NASA NTRS2019

The HST Lightcurve of (486958) 2014 MU69

We report Hubble Space Telescope (HST) lightcurve observations of the New Horizons spacecraft encounter Kuiper Belt object (KBO) (486958) 2014 MU69 acquired near opposition in July 2017. In order to plan the optimum flyby sequence the New Horizons mission planners needed to learn as much as possible about the target in advance of the encounter. Specifically, from lightcurve data, encounter timing could be adjusted to accommodate a highly elongated, binary, or rapidly rotating target. HST astrometric (Porter et al., 2018) and stellar occultation (Buie et al., 2018) observations constrained MU69's orbit and diameter (21–41 km for an albedo of 0.15–0.04), respectively. Photometry from the astrometric dataset suggested a variability of ≥0.3 mags, but they did not determine the period or provide shape information. To that end we strategically spaced 24 HST orbits over 9 days to investigate rotation periods from approximately 2–100 h and to better constrain the lightcurve amplitude. Until New Horizons detected MU69 in its optical navigation images beginning in August 2018, this HST lightcurve campaign provided the most accurate photometry to date. The mean variation in our data is 0.15 magnitudes which suggests that MU69 is either nearly spherical (a:b axis ratio of 1:1.15), or its pole vector is pointed near the line of sight to Earth; this interpretation does not preclude a near-contact binary or bi-lobed object. However, image stacks do conclude that MU69 does not have a binary companion ≥2000 km with a sensitivity to 29th magnitude (an object a few km in size for an albedo of 0.04–0.15). Our data are not of sufficient signal to noise to uniquely determine the period or amplitude, however, they did provide the necessary information for spacecraft planning. We report with confidence that MU69 is not both rapidly rotating and highly elongated (which we define as a lightcurve amplitude ≥ 0.5 magnitude). Since this paper is being published post fly-by, we note that our results are consistent with the fly-by imagery and orientation of MU69 (Stern et al., 2019). The combined dataset also suggests that within the KBO lightcurve literature there are likely other objects which share a geometric configuration like MU69 resulting in an underestimate of the contact binary fraction for the Cold Classical Kuiper Belt.

S D Benecchi↗

NASA NTRS2020

CubeSat Array for Detection of RF Emissions from Exoplanets using Inter-Satellite Optical Communications

UNKNOWN

Velazco, Jose↗

NASA NTRS2021

Central America Disasters: Using Earth Observations to Map Flooding for Disaster Monitoring, Inform Potential Risk, and Prepare for Possible Response

In November 2020, Hurricanes Eta and Iota hit Central America within weeks of each other, causing severe flooding, landslides, and widespread damage. NASA DEVELOP partnered with Comité Regional de Recursos Hidráulicos (CRRH), Centro de Coordinación para la Prevención de los Desastres en América Central y República Dominicana (CEPREDENAC), and Sistema de la Integración Centroamericana (SICA) to better understand how flooding throughout Central America has impacted and will continue to affect communities, focusing on sites in Guatemala, Honduras, El Salvador, Belize, Nicaragua, western Panama, and eastern Costa Rica from January 2015 to October 2021. The team utilized surface reflectance data from Landsat 7 Enhanced Thematic Mapper Plus (ETM+), Landsat 8 Operational Land Imager (OLI), Sentinel-2 MultiSpectral Instrument (MSI), Suomi National Polar-orbiting Partnership (NPP) Visible Infrared Imaging Radiometer Suite (VIIRS), and Terra Moderate Resolution Imaging Spectroradiometer (MODIS). This project also utilized backscatter data from Sentinel-1 C-band Synthetic Aperture Radar (C-SAR) and elevation data from the Shuttle Radar Topography Mission (SRTM). Incorporating these Earth observations in NASA SERVIR’s Hydrologic Remote Sensing Analysis for Floods (HYDRAFloods) tool run on Google Earth Engine (GEE), the team produced historical surface water maps, a case study analysis of the two hurricanes, and a code tutorial. These results indicated that surface water increased in priority sites from 2015 to 2021, optical and SAR imagery detected similar flood patterns and extent after the hurricanes, and rainfall was concentrated on the east coast of the region. These products allow partners to make informed decisions around flooding preparation and disaster mitigation.

Caroline Williams↗

DOE OSTI2023

Fast image acquisition system and method using pulsed light illumination and sample scanning to capture optical micrographs with sub-micron features

An optical inspection system for detecting sub-micron features on a sample component. The system may have a controller, a camera responsive to the controller for capturing images, an objective lens able to capture submicron scale features on the sample component, and a pulsed light source. The pulsed light source may be used to generate light pulses. The camera may be controlled to acquire images, using the objective lens, only while the pulsed light source is providing light pulses illuminating a portion of the sample component. Relative movement between the sample component and the objective lens is provided to enable at least one of a desired subportion or an entirety of the sample component to be scanned with the camera.

Yoo, Jae Hyuck↗