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At least 1,171 records · Page 65

Assessment of SNPP VIIRS VIS NIR Radiometric Calibration Stability Using Aqua MODIS and Invariant Surface Targets

The first Visible Infrared Imaging Radiometer Suite (VIIRS) is onboard the Suomi National Polar-orbiting Partnership (SNPP) satellite. As a primary sensor, it collects imagery and radiometric measurements of the land, atmosphere, cryosphere, and oceans in the spectral regions from visible (VIS) to long-wave infrared. NASA's National Polar-orbiting Partnership (NPP) VIIRS Characterization Support Team has been actively involved in the VIIRS radiometric and geometric calibration to support its Science Team Principal Investigators for their independent quality assessment of VIIRS Environmental Data Records. This paper presents the performance assessment of the radiometric calibration stability of the VIIRS VIS and NIR spectral bands using measurements from SNPP VIIRS and Aqua MODIS simultaneous nadir overpasses and over the invariant surface targets at the Libya-4 desert and Antarctic Dome Concordia snow sites. The VIIRS sensor data records (SDRs) used in this paper are reprocessed by the NASA SNPP Land Product Evaluation and Analysis Tool Element. This paper shows that the reprocessed VIIRS SDRs have been consistently calibrated from the beginning of the mission, and the calibration stability is similar to or better than MODIS. Results from different approaches indicate that the calibrations of the VIIRS VIS and NIR spectral bands are maintained to be stable to within 1% over the first three-year mission. The absolute calibration differences between VIIRS and MODIS are within 2%, with an exception for the 0.865-m band, after correction of their spectral response differences.

Wu, Aisheng↗

TPSAS-NF1676L-12168-DND

The Federal Aviation Administration’s Surveillance and Broadcast Services Program Office considers Interval Management (IM) to be one of the three key, near-term applications to make use of ADS-B-In, the receiving and processing of Automatic Dependent Surveillance – Broadcast data on-board an aircraft. Interval Management is used to describe a wide range of operational applications and uses of airborne spacing technology. Interval Management makes use of improved scheduling and sequencing capabilities for the air traffic controllers (ATC) and precise, relative spacing of aircraft, to improve airport throughput, increase the use of Optimized Profile Descents (OPD), and reduce tactical controller workload. The IM applications are subdivided into two categories: one where the flight crew is authorized to manage their speed to achieve the IM goal while the controller retains separation responsibility and a second where the flight crew takes responsibility for both managing speed but also for separation from the specified target aircraft. The former is referred to as Interval Management-Spacing (IM-S) and the latter as Interval Management-Delegated Separation (IM-DS). For the past 10 years NASA has been working on a specific IM application called Airborne Precision Spacing (APS). This concept has focused on increasing runway throughput while enabling OPDs. It is seen as a specific application within the IM class of applications. This talk will present the current state of the APS concept including support for dependent parallel runway operations and how NASA is working to have APS support the broader IM activities. Planned development and testing of APS, including extensions to support IM-DS and FAA-planned flight trials will be presented along with several up-coming simulations.

Bryan E Barmore↗

TPSAS-NF1676L-12329-DND

The Federal Aviation Administration’s Surveillance and Broadcast Services Program Office considers Interval Management (IM) to be one of the three key, near-term applications to make use of ADS-B-In, the receiving and processing of Automatic Dependent Surveillance – Broadcast data on-board an aircraft. Interval Management is used to describe a wide range of operational applications and uses of airborne spacing technology. Interval Management makes use of improved scheduling and sequencing capabilities for the air traffic controllers (ATC) and precise, relative spacing of aircraft, to improve airport throughput, increase the use of Optimized Profile Descents (OPD), and reduce tactical controller workload. The IM applications are subdivided into two categories: one where the flight crew is authorized to manage their speed to achieve the IM goal while the controller retains separation responsibility and a second where the flight crew takes responsibility for both managing speed but also for separation from the specified target aircraft. The former is referred to as Interval Management-Spacing (IM-S) and the latter as Interval Management-Delegated Separation (IM-DS). For the past 10 years NASA has been working on a specific IM application called Airborne Precision Spacing (APS). This concept has focused on increasing runway throughput while enabling OPDs. It is seen as a specific application within the IM class of applications. This talk will present the current state of the APS concept including support for dependent parallel runway operations and how NASA is working to have APS support the broader IM activities. Planned development and testing of APS, including extensions to support IM-DS and FAA-planned flight trials will be presented along with several up-coming simulations.

Brian T Baxley↗

Marshall Space Flight Center Propulsion Systems Department (PSD) KM Initiative

NASA Marshall Space Flight Center s Propulsion Systems Department (PSD) is four months into a fifteen month Knowledge Management (KM) initiative to support enhanced engineering decision making and analyses, faster resolution of anomalies (near-term) and effective, efficient knowledge infused engineering processes, reduced knowledge attrition, and reduced anomaly occurrences (long-term). The near-term objective of this initiative is developing a KM Pilot project, within the context of a 3-5 year KM strategy, to introduce and evaluate the use of KM within PSD. An internal NASA/MSFC PSD KM team was established early in project formulation to maintain a practitioner, user-centric focus throughout the conceptual development, planning and deployment of KM technologies and capabilities with in the PSD. The PSD internal team is supported by the University of Alabama's Aging Infrastructure Systems Center Of Excellence (AISCE), Intergraph Corporation, and The Knowledge Institute. The principle product of the initial four month effort has been strategic planning of PSD KM implementation by first determining the "as is" state of KM capabilities and developing, planning and documenting the roadmap to achieve the desired "to be" state. Activities undertaken to support the planning phase have included data gathering; cultural surveys, group work-sessions, interviews, documentation review, and independent research. Assessments and analyses have been performed including industry benchmarking, related local and Agency initiatives, specific tools and techniques used and strategies for leveraging existing resources, people and technology to achieve common KM goals. Key findings captured in the PSD KM Strategic Plan include the system vision, purpose, stakeholders, prioritized strategic objectives mapped to the top ten practitioner needs and analysis of current resource usage. Opportunities identified from research, analyses, cultural/KM surveys and practitioner interviews include: executive and senior management sponsorship, KM awareness, promotion and training, cultural change management, process improvement, leveraging existing resources and new innovative technologies to align with other NASA KM initiatives (convergence: the big picture). To enable results based incremental implementation and future growth of the KM initiative, key performance measures have been identified including stakeholder value, system utility, learning and growth (knowledge capture, sharing, reduced anomaly recurrence), cultural change, process improvement and return-on-investment. The next steps for the initial implementation spiral (focused on SSME Turbomachinery) have been identified, largely based on the organization and compilation of summary level engineering process models, data capture matrices, functional models and conceptual-level systems architecture. Key elements include detailed KM requirements definition, KM technology architecture assessment, evaluation and selection, deployable KM Pilot design, development, implementation and evaluation, and justifying full implementation (estimated Return-on-Investment). Features identified for the notional system architecture include the knowledge presentation layer (and its components), knowledge network layer (and its components), knowledge storage layer (and its components), User Interface and capabilities. This paper provides a snapshot of the progress to date, the near term planning for deploying the KM pilot project and a forward look at results based growth of KM capabilities with-in the MSFC PSD.

Caraccioli, Paul↗

Activation of N 2 on Manganese Nitride-Supported Ni 3 and Fe 3 Clusters and Relevance to Ammonia Formation

Dual-site models were constructed to represent manganese nitride (Mn 4 N)-supported Ni 3 and Fe 3 clusters for NH 3 synthesis. Density functional theory calculations produced an energy barrier of approximately 0.55 eV for N–N bond activation at the interfacial nitrogen vacancy sites (N v ); also, the hydrogenation and removal of interfacial N is promoted by earth-abundant Ni and Fe metals. Steady-state microkinetic modeling revealed that the turnover frequencies of NH 3 production follow an order of Fe 3 @Mn 4 N ≈ Ni 3 @Mn 4 N > Mn 4 N > Fe >> Ni. Moreover, we present clear evidence that, before NH 3 formation, NH migrates from N v onto the metallic sites. Using N binding energy (BE N ) and the transition-state energy of N 2 activation (E TS ) as descriptors, we concluded that the beneficial effects owing to interfacial N v sites are the most pronounced when BE N is either too strong or too weak while E TS is high; otherwise, excessive N v sites may hinder catalyst performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Micrometeoroid and Orbital Debris (MMOD) Testing, Ballistic Limit Equation Definition and Risk Assessment of the Exploration Extravehicular Mobility Unit (xEMU)

A well-known hazard associated with exposure to the space environment is the risk of failure due to an impact from a micrometeoroid and orbital debris (MMOD) particle. As NASA prepares to return astronauts to the moon with the Artemis program, the next generation of spacesuit is in development to support future extravehicular activities (EVAs.) An MMOD impact to the spacesuit is of great concern as a large leak could prevent an astronaut from safely reaching an airlock in time resulting in a loss of life. The exploration extravehicular mobility unit (xEMU) must meet MMOD requirements for multiple environments including those in low earth orbit (LEO) as well as the meteoroid and secondary lunar regolith ejecta environments found on the lunar surface. The subject of this paper is an internal xEMU configuration design developed by NASA Johnson Space Center (JSC) personnel. This paper will expand on the hypervelocity impact (HVI) testing and ballistic limit equation (BLE) definition work that was partially presented at the 2nd International Orbital De-bris (IOC-II) Conference held in Sugar Land, TX in December 2023. The xEMU shares similarities with the legacy Extravehicular Mobility Unit (EMU) spacesuit that is currently used for ISS EVAs, however differences in the layup (e.g., materials, thicknesses, and layers) of the fabric environmental protection garment (EPG), portable life support system (xPLSS) and helmet required an extensive test program to determine ballistic performance. Over 100 hypervelocity impact (HVI) tests were performed by the NASA/JSC HVIT and White Sands Test Facility (WSTF) teams on the xEMU EPG, xPLSS and helmet to generate ballistic limit equations (BLEs) for MMOD impacts. Additionally, over 50 low speed tests (< 1km/s) were performed by the NASA/JSC HVIT and Southwest Research Institute (SwRI) teams on the xEMU EPG, xPLSS and helmet to generate BLEs for lunar ejecta impacts. Post testing, ballistic limit equations used to define the performance of the various regions on the xEMU spacesuit were developed from a generic set of BLEs. The HVI and low speed testing was performed to establish a physical basis for the equations with the co-efficients and exponents of the generic BLEs adjusted to fit the test data. The xEMU BLEs were added to the NASA/JSC software application used for space-craft MMOD risk assessments (BUMPER-3). A finite element model (FEM) of the xEMU spacesuit, which defines the size and shape of the spacesuit as well as the locations of the various shielding configurations, was created based on a solid model provided by the xEMU program office. Using the FEM file and added xEMU BLEs, BUMPER-3 assessments of the xEMU spacesuit for probability of no penetration (PNP) were performed. For the LEO assessment of a typical ISS EVA, the orbital debris and meteoroids environments were defined using the latest engineering models, ORDEM 3.2 and MEM-3 respectively. The lunar sur-face assessment again used the MEM-3 engineering model to define the meteoroid environ-ment along with the current released lunar surface ejecta model, NASA SP-8013 (developed during the Apollo Program). The Space Team in the Natural Environments Branch at Mar-shall Space Flight Center (MSFC) will soon release the new Lunar Meteoroid Ejecta Engineering Model (LMEEM), at which time the xEMU lunar surface EVA will be reassessed. Assessment of the MMOD risk for an 8-hour, 2-person EVA in both LEO and on the lunar surface showed that the xEMU spacesuit meets the program technical requirement of 1 in 2500 failure odds. Similar to the legacy EMU spacesuit, the majority of the MMOD risk (96% of the LEO EVA risk and 99% of the lunar surface EVA risk) is concentrated in regions of xEMU that are comprised primarily of softgoods (arms, legs, and gloves) rather than the hardgoods (xPLSS, hard upper torso and helmet).

Micrometeoroid↗

Nickel foam supported porous copper oxide catalysts with noble metal-like activity for aqueous phase reactions

Contiguous metal foams offer a multitude of advantages over conventional powders as supports for nanostructured heterogeneous catalysts; most critically a preformed 3-D porous framework ensuring full directional coverage of supported catalyst, and intrinsic ease of handling and recyclability. Nonetheless, metal foams remain comparatively underused in thermal catalysis compared to more conventional supports such as amorphous carbon, metal oxides, zeolites and more recently MOFs. Herein, we demonstrate a facile preparation of highly-reactive, robust, and easy to handle Ni foam-supported Cu-based metal catalysts. The highly sustainable synthesis requires no specialized equipment, no surfactants or additive redox reagents, uses water as solvent, and CuCl 2 (H 2 O) 2 as precursor. The resulting material seeds as well-separated micro-crystalline Cu 2 (OH) 3 Cl evenly covering the Ni foam. Calcination above 400 °C transforms the Cu 2 (OH) 3 Cl to highly porous CuO. All materials display promising activity towards the reduction of 4-nitrophenol and methyl orange. Notably, our leading CuO-based material displays 4-nitrophenol reduction activity comparable with very reactive precious-metal based systems. Furthermore, recyclability studies highlight the intrinsic ease of handling for the Ni foam support, and our results point to a very robust, highly recyclable catalyst system.

36 MATERIALS SCIENCE↗

Verification of the PERSENT Software

Ongoing commercial design activities require a thorough verification of the Argonne Reactor Computation codes be performed. DIF3D is central to this system and substantial work has been done to verify its accuracy on several identified commercial needs. This manuscript details the verification work done on PERSENT which relies upon the DIF3D code for its forward and adjoint flux solution. Previous work identified the PERSENT features required to be verified to support commercial design activities, features of which are generally applicable to hexagonal-Z fast reactor designs. The scope of this verification effort includes verifying PERSENT’s ability to correctly calculate four key quantities: perturbation worth distributions, kinetics parameters, sensitivity coefficients, and cross section uncertainty quantification. This manuscript provides the verification tasks and their results with respect to these quantities needed for commercial design activities. For the perturbation worth distributions, hand calculations are deployed to verify the PERSENT calculated results. Similarly, hand calculation of the PERSENT computed kinetics parameters is also used to verify the PERSENT results. In both of these, the input to PERSENT is manipulated to ensure the hand calculation exactly matches the equations PERSENT is calculating. The sensitivity coefficients involve calculating the derivatives of a parameter (such as reactivity worth), with respect to the cross section data. Direct finite difference calculations with DIF3D are used to verify the PERSENT calculated results. For the uncertainty quantification, manufactured input to PERSENT is used to allow an exact hand calculation to reproduce the PERSENT calculated results. The work detailed in this report verified that significant issues were identified for earlier versions of PERSENT for sensitivity coefficients which were corrected in this work and thus version 12.1.0 of PERSENT must be used to reproduce all of the verified work in this report.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

High Electron Mobility Transistor Structures on Sapphire Substrates Using CMOS Compatible Processing Techniques

System-on-a-chip (SOC) processes are under intense development for high-speed, high frequency transceiver circuitry. As frequencies, data rates, and circuit complexity increases, the need for substrates that enable high-speed analog operation, low-power digital circuitry, and excellent isolation between devices becomes increasingly critical. SiGe/Si modulation doped field effect transistors (MODFETs) with high carrier mobilities are currently under development to meet the active RF device needs. However, as the substrate normally used is Si, the low-to-modest substrate resistivity causes large losses in the passive elements required for a complete high frequency circuit. These losses are projected to become increasingly troublesome as device frequencies progress to the Ku-band (12 - 18 GHz) and beyond. Sapphire is an excellent substrate for high frequency SOC designs because it supports excellent both active and passive RF device performance, as well as low-power digital operations. We are developing high electron mobility SiGe/Si transistor structures on r-plane sapphire, using either in-situ grown n-MODFET structures or ion-implanted high electron mobility transistor (HEMT) structures. Advantages of the MODFET structures include high electron mobilities at all temperatures (relative to ion-implanted HEMT structures), with mobility continuously improving to cryogenic temperatures. We have measured electron mobilities over 1,200 and 13,000 sq cm/V-sec at room temperature and 0.25 K, respectively in MODFET structures. The electron carrier densities were 1.6 and 1.33 x 10(exp 12)/sq cm at room and liquid helium temperature, respectively, denoting excellent carrier confinement. Using this technique, we have observed electron mobilities as high as 900 sq cm/V-sec at room temperature at a carrier density of 1.3 x 10(exp 12)/sq cm. The temperature dependence of mobility for both the MODFET and HEMT structures provides insights into the mechanisms that allow for enhanced electron mobility as well as the processes that limit mobility, and will be presented.

Mueller, Carl↗

The Need for Vendor Source Code at NAS

The Numerical Aerodynamic Simulation (NAS) Facility has a long standing practice of maintaining buildable source code for installed hardware. There are two reasons for this: NAS's designated pathfinding role, and the need to maintain a smoothly running operational capacity given the widely diversified nature of the vendor installations. NAS has a need to maintain support capabilities when vendors are not able; diagnose and remedy hardware or software problems where applicable; and to support ongoing system software development activities whether or not the relevant vendors feel support is justified. This note provides an informal history of these activities at NAS, and brings together the general principles that drive the requirement that systems integrated into the NAS environment run binaries built from source code, onsite.

Carter, Russell↗

System with buffer for lateral flow on a porous membrane

Systems are described, based on a primary binding compound and a secondary binding compound used in combination with a support to detect a target in a sample. The systems includes at least one support structure, at least one small primary support portion containing at least one molecule covalently bound to a visual colloidal marker, a plurality of secondary support portions comprising secondary binding compounds that are covalently bound to the support portions and chemically active, at least one pH litmus indicator, at least one pH strip, a buffer for lateral flow on the porous membrane support that allows preservation and activity of binding compounds.

Bearinger, Jane P.↗

Report on FY 2020 Testing in Support of the Development and Extension of ASME Code Rules for Grade 91

This report summarizes the FY 2020 research and activities at Oak Ridge National Laboratory in support of the ASME code rule development and code extension for Grade 91 (Gr. 91) steel. Incorporation of the Gr. 91 temperature-dependent fatigue curves in Section III Division 5 was one major task, and the associated major aspects brought up during the course of the ASME balloting process are documented in this report. Experiments and analysis continued on the development of the alternative creep-fatigue evaluation based on elastic–perfectly plastic (EPP) plus simplified model test (SMT) methodology. The focus of the study in FY 2020 was the evaluation of the hold-time effect at high cycle and low strain range region. Baseline testing in support of the evaluation of hold time effects was started and will continue in FY 2021. Major on-going experiments and activities in support of the ASME code development and extension of Gr. 91 will be completed in FY 2021.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Studies and analyses of the space shuttle main engine

The primary objectives were to: evaluate ways to maximize the information yield from the current Space Shuttle Main Engine (SSME) condition monitoring sensors, identify additional sensors or monitoring capabilities which would significantly improve SSME data, and provide continuing support of the Main Engine Cost/Operations (MECO) model. In the area of SSME condition monitoring, the principal tasks were a review of selected SSME failure data, a general survey of condition monitoring, and an evaluation of the current engine monitoring system. A computerized data base was developed to assist in modeling engine failure information propagations. Each of the above items is discussed in detail. Also included is a brief discussion of the activities conducted in support of the MECO model.

Tischer, Alan E.↗

A bioinspired cobalt catalyst based on a tripodal imidazole/pyridine platform capable of water reduction and oxidation

The prototypical drug carrier [Co II (L 1 )Cl]PF 6 (1), where L 1 is a tripodal amine bound to pyridine and methyl-imidazoles, had its electrocatalytic water splitting activity studied under different pH conditions. This species contains a high-spin 3d 7 Co II metal center, and is capable of generating both H 2 from water reduction and O 2 from water oxidation. Turnover numbers reach 390 after 3 h for water reduction. Initial water oxidation activity is molecular, with TONs of 71 at pH 7 and 103 at pH 11.5. The results reveal that species 1 can undergo several redox transformations, including reduction to the 3d 8 Co I species that precedes a LS 3d 6 hydride for water reduction, as well as nominal Co IV $=$O and Co III -OOH species required for water oxidation. Finally, post-catalytic analyses confirm the molecular nature of reduction and support initial molecular activity for oxidation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Energy migration and scintillation kinetics in compositionally complex (Gd 1/4 Y 1/4 Tb 1/4 Lu 1/4 ) 3 Al 5 O 12 :Ce single crystal scintillator

It is well-established that compositional tuning through binary admixture can improve scintillation performance in several materials systems, including Ce-activated garnets. Although recent work on ternary or quaternary cation admixture shows promise, the impact of this increased compositional complexity on thermal stability and carrier-defect dynamics has not been addressed. Here, we investigate a compositionally complex garnet, (Gd 1/4 Y 1/4 Tb 1/4 Lu 1/4 ) 3 Al 5 O 12 :Ce (GYTLAG), grown by the Czochralski method using temperature-dependent photoluminescence (PL), PL decay, and thermoluminescence (TL). PL and PL decay measurements support a thermally activated Tb 3+ -Ce 3+ energy transfer, where Tb 3+ emission dominates below 60 K, but Ce 3+ emission increases from 20-300 K. Thermal quenching of Ce 3+ emission occurs around T 50 = 508 K, with an activation energy of 0.6 eV. TL and wavelength-resolved TL spectra from 20–500 K show that GYTLAG contains similar trap groups to LuAG but with a broader distribution of glow peaks below room temperature, possibly caused by quaternary cation mixing. A combination of dose dependence, partial cleaning and initial rise, and glow curve fitting to a first order continuous Gaussian distribution model are used to understand the contribution of electronic point defects to scintillation decay and afterglow at room temperature. Furthermore, these results inform how increased compositional complexity influences recombination dynamics in garnet scintillators.

Compositionally complex↗

Utilizing a TDRS satellite for direct broadcast satellite-radio propagation experiments and demonstrations

The NASA/VOA Direct Broadcast Satellite-Radio (DBS-R) Program will be using a NASA Tracking Data Relay Satellite (TDRS) satellite at 62 deg. West longitude to conduct live satellite S-band propagation experiments and demonstrations of satellite sound broadcasting over the next two years (1993-1994). The NASA/VOA DBS-R program has applied intensive effort to garner domestic and international support for the DBS-R concept. An S-band DBS-R allocation was achieved for Region 2 at WARC-92 held in Spain. With this allocation, the DBS-R program now needs to conduct S-band propagation experiments and systems demonstrations that will assist in the development of planning approaches for the use of Broadcast Satellite Service (Sound) frequency bands prior to the planning conference called for by WARC-92. These activities will also support receiver concept development applied to qualities ranging from AM to Monophonic FM, Stereophonic FM, Monophonic CD, and Stereophonic CD quality.

Hollansworth, James E.↗

Utilizing a TDRS satellite for direct broadcast satellite-radio propagation experiments and demonstrations

The NASA/VOA Direct Broadcast Satellite - Radio (DBS-R) Program will be using a NASA Tracking Data Relay Satellite (TDRS) at 62 deg West longitude to conduct live satellite S-band propagation experiments and demonstrations of satellite sound broadcasting over the next two years (1993-1994). The NASA/VOA DBS-R program has applied intensive effort to garner domestic and international support for the DBS-R concept. An S-band DBS-R allocation was achieved for Region 2 at WARC-92 held in Spain. With this allocation, the DBS-R program now needs to conduct S-band propagation experiments and systems demonstrations that will assist in the development of planning approaches for the use of Broadcast Satellite Service (Sound) frequency bands prior to the planning conference called for by WARC-92. These activities will also support receiver concept development applied to qualities ranging from AM to Monophonic FM, Stereophonic FM, Monophonic CD, and Stereophonic CD quality.

Hollansworth, James E.↗