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At least 1,171 records · Page 65

Resolving the Valence of Iron Oxides by Resonant Photoemission Spectroscopy

Precisely determining the oxidation states of metal cations within variable-valence transition metal oxides remains a significant challenge, yet it is crucial for understanding and predicting the properties of these technologically important materials. Iron oxides, in particular, exhibit a remarkable diversity of electronic structures due to the variable valence states of iron (Fe 2+ and Fe 3+ ). A quantitative analysis using conventional X-ray photoelectron spectroscopy (XPS) is challenging because of the strong overlap of the Fe 2p XPS peaks from different oxidation states. Here, in this study, we show how this problem can be resolved using Resonant Photoemission Spectroscopy (ResPES), which unambiguously distinguishes Fe oxidation states and spectroscopically estimates the composition ratio of Fe cation valence states in the complex Fe oxides. We demonstrate this in the model case of a FeO 2 monolayer film on Pt(111), showing that the FeO 2 film consists of an equal mixture of Fe 2+ and Fe 3+ cations, yielding an average valence of +2.5, contrary to the +3 valence proposed based on density functional theory (DFT).

Chen, Hao [Lawrence Berkeley National Laboratory (↗

Synthesis of hover autopilots for rotary-wing VTOL aircraft

The practical situation is considered where imperfect information on only a few rotor and fuselage state variables is available. Filters are designed to estimate all the state variables from noisy measurements of fuselage pitch/roll angles and from noisy measurements of both fuselage and rotor pitch/roll angles. The mean square response of the vehicle to a very gusty, random wind is computed using various filter/controllers and is found to be quite satisfactory although, of course, not so good as when one has perfect information (idealized case). The second part of the report considers precision hover over a point on the ground. A vehicle model without rotor dynamics is used and feedback signals in position and integral of position error are added. The mean square response of the vehicle to a very gusty, random wind is computed, assuming perfect information feedback, and is found to be excellent. The integral error feedback gives zero position error for a steady wind, and smaller position error for a random wind.

Hall, W. E.↗

Singular perturbation, state aggregation and nonlinear filtering

Consideration is given to a state process evolving in R(n), whose motion is that of a pure jump process in R(n) in the 0(1) time scale, upon which is superimposed a continuous motion along the orbits of a gradient-like vector field g in R(n) in the 0(1/epsilon) time scale. The infinitesimal generator of the state process is, in other words, of the form L + (1/epsilon)g. It follows from the main results presented that the projected filters converge to the finite state Wonham filter corresponding to the problem of estimating the finite state process in the presence of additive white noise.

Hijab, O.↗

Error analysis for a reduced-order discrete adaptive observer

The Kreisselmeier discrete adaptive observer is analyzed for the case in which the observer order is less than that of the plant. The state and parameter estimates from the observer are compared to the states and parameters for an arbitrary reduced-order model (ROM) of the plant, where the observer and ROM are of equal dimension. Conditions sufficient for ultimate boundedness of the observation errors are given, and expressions for the error bounds are derived.

Lilly, J. H.↗

In-flight inertial guidance alignment

This work reports on an extension of a recent work by Goshen-Meskin and Bar-Itzhack (1988). That work dealt with the observability analysis of inertial-navigation systems during in-flight alignment. The work was confined to the analysis of altitude damped systems; hence, the error model considered was a two-channel model. The present work deals with an undamped three-channel error model. An analysis similar to the previous one is carried out. It is shown that it is possible to fully observe, and thus estimate, all the states of the system. This is in contrast to the previous two-channel system, in which it is impossible to fully observe and estimate all the states of the system. The conclusions of the analysis presented in this paper are verified through covariance simulation which yields identical results.

Bar-Itzhack, I. Y.↗

Observability studies of inertial navigation systems

The present work deals with an undamped three-channel inertial-navigation-system error model. It is shown that it is possible to fully observe, and thus estimate, all the states of the system. This is in contrast to a previous two-channel system, in which it was impossible to fully observe and estimate all the states of the system. The conclusions of the analysis are verified through covariance simulation, which yields identical results.

Bar-Itzhack, I. Y.↗

Sequential Filtering in the Presence of Uniform Measurement Errors

This paper presents a sequential filtering strategy using observations corrupted with uniform measurement noise. While the Kalman filter remains the best linear estimator of the state, other filtering techniques provide minimum variance optimal estimates, a trait only enjoyed by the Kalman filter when the underlying noises are, in fact, Gaussian. This work develops a new approximate optimal estimator for uniform measurement noises. The resulting recursion requires just slightly more computational time to complete a measurement update than the Kalman filter, which generally cannot be claimed by other optimal strategies such as the particle or Gaussian mixture filters.

James S. McCabe↗

Sequential Filtering in the Presence of Uniform Measurement Errors

This paper presents a sequential filtering strategy using observations corrupted with uniform measurement noise. While the Kalman filter remains the best linear estimator of the state, other filtering techniques provide minimum variance optimal estimates, a trait only enjoyed by the Kalman filter when the underlying noises are, in fact, Gaussian. This work develops a new approximate optimal estimator for uniform measurement noises. The resulting recursion requires just slightly more computational time to complete a measurement update than the Kalman filter, which generally cannot be claimed by other optimal strategies such as the particle or Gaussian mixture filters.

James S McCabe↗

Estimation With Range Dependent Sensor Model

This paper focuses on the improvement of target tracking accuracy taking into account the sensor’s reading degradation as the relative range increases. The approach is based on the assumption that range measurement error depends on the actual range. Specifically, we model the measurement error as a proportional to the actual range term plus a zero-mean, Gaussian distributed, and uncorrelated process. We present two approaches to tracking a target with constant velocity model. The first approach uses Extended Kalman Filter (EKF) framework to estimate target's states and the unknown proportionality coefficient with linearization on the observation model on the predicted states at each time step. The second one uses a measurement conversion method to estimate the target's scaled by the unknown constant term states, which is shown to be unbiased. This conversion results in linear state and observation models, hence the standard Kalman filter can be applied. The actual target state is computed by application of back scaling with the estimate of unknown scale factor. We evaluate the approaches in desktop simulations.

Target tracking↗

Time-Varying Output Delay Compensation-A Model-Free Approach and its Application on Cooperative On-Ramp Merging

This paper presents a model-free approach to compensate for time-varying output delay in networked control systems. The proposed architecture combines a model-free observer and the Smith predictor. The model-free observer estimates the current state while handling modeling errors and uncertainties of the system. The Smith predictor moves the effect of time delay outside the control closed-loop using the estimated delayed output and the actual output of the plant. The proposed method is applied to a cooperative on-ramp merging problem. First, an ultra-local model predictive control is implemented to provide a computationally efficient online speed planner agnostic to the vehicle dynamics. After that, a model-free observer is designed to estimate the current state. Finally, the proposed architecture is tested against a time-varying output delay with an upper bound of 200 milliseconds. The results demonstrate the effectiveness of the proposed method with improved tracking of intervehicle distance.

Waleed khan, Muhammad [The University of Texas at ↗

Analytic Steady-State Accuracy of a Spacecraft Attitude Estimator

This paper extends Farrenkopf's analysis of a single-axis spacecraft attitude estimator using gyro and angle sensor data to include the angle output white noise of a rate-integrating gyro. Analytic expressions are derived for the steady-state pre-update and post-update angle and drift bias variances and for the state update equations. It is shown that only part of the state update resulting from the angle sensor measurement is propagated to future times.

Markley, F. Landis↗

Local flow structures defined by kinematic events in isotropic turbulence

The spatial structure of turbulent motion in incompressible isotropic turbulence is investigated using a conditional average in which the conditional event specifies the local deformation tensor in addition to the local velocity vector. This average gives the best estimate of the flow field around a fixed point x given the kinematic state at x. Estimates are calculated for various kinematic states in isotropic turbulence, including pure translation, pure shear, plane strain, axisymmetric strain, and pure rotation. It is demonstrated that the large-scale motion is dominated by a vortex ring structure associated with the translational component, except at critical points of the velocity vector field.

Adrian, R. J.↗

Design considerations for flight test of a fault inferring nonlinear detection system algorithm for avionics sensors

The modifications to the design of a fault inferring nonlinear detection system (FINDS) algorithm to accommodate flight computer constraints and the resulting impact on the algorithm performance are summarized. An overview of the flight data-driven FINDS algorithm is presented. This is followed by a brief analysis of the effects of modifications to the algorithm on program size and execution speed. Significant improvements in estimation performance for the aircraft states and normal operating sensor biases, which have resulted from improved noise design parameters and a new steady-state wind model, are documented. The aircraft state and sensor bias estimation performances of the algorithm's extended Kalman filter are presented as a function of update frequency of the piecewise constant filter gains. The results of a new detection system strategy and failure detection performance, as a function of gain update frequency, are also presented.

Caglayan, A. K.↗

Design considerations for flight test of a fault inferring nonlinear detection system algorithm for avionics sensors

This paper summarizes the modifications made to the design of a fault inferring nonlinear detection system (FINDS) algorithm to accommodate flight computer constraints and the resulting impact on the algorithm performance. An overview of the flight data-driven FINDS algorithm is presented. This is followed by a brief analysis of the effects of modifications to the algorithm on program size and execution speed. Significant improvements in estimation performance for the aircraft states and normal operating sensor biases, which have resulted from improved noise design parameters and a new steady-state wind model, are documented. The aircraft state and sensor bias estimation performances of the algorithm's extended Kalman filter are presented as a function of update frequency of the piecewise constant filter gains. The results of a new detection system strategy and failure detection performance, as a function of an update frequency, are also presented.

Caglayan, A. K.↗

An estimation of aerodynamic forces and moments on an airplane model under steady state spin conditions

The problem of estimating the aerodynamic characteristics of a wing body configuration of a spinning airplane at extreme angles of attack and spin rates is approached by the application of strip theory. Semiempirical methods are used to estimate the aerodynamic force distributions over each component using static, nonrotational wind-tunnel test data. To these predictions, corrections are applied to account for the primary rotational flow effects which are significant at large spin rates. The results of this modified strip theory are shown to be in good agreement with spin tunnel rotary balance test data.

Pamadi, B. N.↗

Aerodynamic parameters of the Navion airplane extracted from flight

An iterative method, which is characterized as a maximum-likelihood minimum-variance technique, was used to extract the aerodynamic parameters of a Navion airplane from flight data. The purposes were to compare the results with parameters obtained from wind-tunnel tests and with results obtained by analog matching the same data, and to develop techniques for application of the parameter extraction program. Results from the study showed that the parameter-extraction program can produce aerodynamic parameters which will permit close estimation of the aircraft time histories used in the extraction process. The program determined an estimate of the standard deviations of the states and parameters. These estimates were used to indicate how well the calculated states fit the flight data and the confidence in the values of the estimated parameters. The study also showed that the values of the parameters were affected by the data and mathematical model used during the extraction process. Because of the lack of confidence in the parameters extracted by use of some of the sets of data, several parameters were estimated by other methods. By using a combination of methods, a set of parameters which gave a fit to the data was obtained.

Suit, W. T.↗

Equilibrium Core Model for Micro Pebble Bed Reactors Using OpenMC

Estimating the equilibrium state for pebble bed reactors (PBRs) presents complex challenges as it requires simultaneous consideration of changes in the pebbles’ movement as well as their fuel compositions. Whereas traditional approaches use multigroup diffusion codes for neutronics calculations of PBRs’ equilibrium state, the double-heterogeneity of PBRs complicates neutron cross-section generation. Continuous-energy Monte Carlo (MC) methods are better suited for detailed PBR analysis because of their natural handling of double-heterogeneity, but they demand substantially more computational resources. Here, this study introduces a novel method for efficiently estimating the equilibrium state in small and micro PBRs with reduced computational cost. The method is anticipated to accelerate the processes of core design and performing parametric studies for utilizing advanced fuel and structural materials. The HTR-10 reactor design was used for validating the method’s predictions and evaluating its computational efficiency. When compared to reference calculation values from the literature, criticality (k-effective) was predicted to be approximately within the margin of error of the MC transport calculation, average core power density (in megawatts per cubic meter) was predicted within 2.5% relative error, and maximum thermal flux (10 13 n/cm 2 .s −1 ) was predicted within 1.8% relative error. The calculated inventory of fission products and fuel composition in the equilibrium core were within 15% and 16.6%, respectively, when compared to reported values from the literature. The difference is attributed to variance in the considered values of the core temperature, which was found to significantly affect the depletion analyses.

Equilibrium core↗