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At least 1,171 records · Page 65

Degradation of the Crystalline Structure of ZnS Ceramics under Abrasive Damage

Stability of optical elements based on ZnS ceramics to dust and rain erosion is usually estimated from the loss of material mass in a directional flow of solid particles or atmospheric precipitates. In this case, the mechanism of degradation and fracture of the surface layer of an optical element is not considered. The photoluminescence (PL) method was used for investigating the crystal lattice response to the abrasive action and the formation of cleavage in ZnS ceramics, which differ in manufacturing technology and, accordingly, in the grain size by two orders of magnitude. It is shown that during abrasive treatment of samples, their spectra exhibit changes typical of degradation of the crystal lattice of material grains. The PL spectra of cleavage surfaces reveal almost complete degradation of the structure of crystallite grains with a size from 1–2 to 100–200 μm.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Radio emission and the hot interstellar medium of early-type galaxies

The results of an analysis of a sample of 84 elliptical and S0 galaxies, observed in X-rays with the Einstein Observatory and in radio continuum at 5 GHz, are reported. Radio flux densities result in some of the lowest radio powers yet reported for early-type galaxies. Radio structures extending beyond the optical radius are found only in galaxies with 5 GHz radio power greater than about 10 exp 29.5 ergs/s/Hz. Radio and X-ray luminosities are correlated, although with large intrinsic scatter, suggesting that more than one mechanism may be involved. A correlation between core radio power and the X-ray-to-optical ratio suggests a connection between the hot ISM and nuclear radio sources and points to accreting cooling flows as the fuel for the radio sources. For the same radio core power, extended radio lobes tend to be associated with galaxies with relatively smaller X-ray-to-optical ratios, pointing to the importance of the hot ISM in disrupting the radio jets and confining extended radio structures.

Fabbiano, G.↗

Gas temperature measurements using the dual-line detection Rayleigh scattering technique

A new laser-induced Rayleigh scattering method is presented for the improved temperature diagnostics of gas flows. In the present technique, the two lines of a copper vapor laser are used to obtain the time and space resolved temperature. A single set of optics is used to form the optical probe and to collect the signal simultaneously from both the 510 nm and the 578 nm lines. The dual-line detection allows for the determination and removal of surface-scattered laser light from a Rayleigh signal thereby improving the applicability of Rayleigh scattering to near wall flows with a high degree of glare. An optical system using the dual-line detection technique is built, calibrated and tested in a hot air jet under various levels of background contamination. The results indicate that highly accurate temperature measurements are possible even when the laser-line background intensity, captured by the collecting optics, is five times that of the Rayleigh signal.

Otugen, M. Volkan↗

Gas temperature measurements using the dual-line detection Rayleigh scattering technique

A new laser-induced Rayleigh scattering method is presented for the improved temperature diagnostics of gas flows. In the present technique, the two lines of a copper vapor laser are used to obtain the time and space resolved temperature. A single set of optics is used to form the optical probe and to collect the signal simultaneously from both the 510 nm and the 578 nm lines. The dual-line detection allows for the determination and removal of surface-scattered laser light from a Rayleigh signal thereby improving the applicability of Rayleigh scattering to near wall flows with a high degree of glare. An optical system using the dual-line detection technique is built, calibrated and tested in a hot air jet under various levels of background contamination. The results indicate that highly accurate temperature measurements are possible even when the laser-line background intensity, captured by the collecting optics, is five times that of the Rayleigh signal.

Otugen, M. V.↗

Multisensor Instrument for Real-Time Biological Monitoring

The figure schematically depicts an instrumentation system, called a fiber optic-based integration system (FOBIS), that is undergoing development to enable real-time monitoring of fluid cell cultures, bioprocess flows, and the like. The FOBIS design combines a micro flow cytometer (MFC), a microphotometer (MP), and a fluorescence-spectrum- or binding-force-measuring micro-sensor (MS) in a single instrument that is capable of measuring multiple biological parameters simultaneously or sequentially. The fiber-optic-based integration system is so named because the MFC, the MP, and the MS are integrated into a single optical system that is coupled to light sources and photometric equipment via optical fibers. The optical coupling components also include a wavelength-division multiplexer and diffractive optical elements. The FOBIS includes a laserdiode- and fiber-optic-based optical trapping subsystem (optical tweezers ) with microphotometric and micro-sensing capabilities for noninvasive confinement and optical measurement of relevant parameters of a single cell or other particle. Some of the measurement techniques implemented together by the FOBIS have long been used separately to obtain basic understanding of the optical properties of individual cells and other organisms, the optical properties of populations of organisms, and the interrelationships among these properties, physiology of the organisms, and physical processes that govern the media that surround the organisms. For example, flow cytometry yields information on numerical concentrations, cross-sectional areas, and types of cells or other particles. Micro-sensing can be used to measure pH and concentrations of oxygen, carbon dioxide, glucose, metabolites, calcium, and antigens in a cell-culture fluid, thereby providing feedback that can be helpful in improving control over a bioprocess. Microphotometry (including measurements of scattering and fluorescence) can yield further information about optically trapped individual particles. In addition to the multifunctionality not previously available in a single biological monitoring system, the FOBIS offers advantages of low mass, sensitivity, accuracy, portability, low cost, compactness (the overall dimensions of the fully developed FOBIS sensor head are expected to be less than 1 by 1 by 2 cm), and immunity to electromagnetic interference at suboptical frequencies. FOBIS could be useful in a variety of laboratory and field settings in such diverse endeavors as medical, veterinary, and general biological research; medical and veterinary diagnosis monitoring of industrial bioprocesses; and analysis of biological contaminants in air, water, and food.

Zhang, Sean (Zhanxiang)↗

Investigating the Origins of Cyclic Variability in Internal Combustion Engines Using Wall-Resolved Large Eddy Simulations

Modern internal combustion engines (ICE) operate at the ragged edge of stable operation characterized by high cycle-to-cycle variations (CCV). A key scientific challenge for ICE is the understanding, modeling, and control of CCV in engine performance, which can contribute to partial burns, misfire, and knock. The objective of this study is to use high-fidelity numerical simulations to improve the understanding of the causes of CCV. Nek5000, a leading high-order spectral element, open source code, is used to simulate the turbulent flow in the engine combustion chamber. Multicycle, wall-resolved large-eddy simulations (LESs) are performed for the General Motors (GM), Transparent Combustion Chamber (TCC-III) optical engine under motored operating conditions. The mean and root-mean-square (rms) of the in-cylinder flow fields at various piston positions are validated using particle image velocimetry (PIV) measurements during the intake and compression strokes. The large-scale flow structures, including the swirl and tumble flow patterns, are analyzed in detail and the causes for cyclic variabilities in these flow features are explained. The energy distribution across the different scales of the flow are quantified using one-dimensional (1D) energy spectra, and the effect of the tumble breakdown process on the energy distribution is examined. Finally, the insights from this study can help us develop improved engine designs with reduced cyclic variabilities in the in-cylinder flow leading to enhanced engine performance.

33 ADVANCED PROPULSION SYSTEMS↗

CONSTRAINTS ON THE VISCOSITY AND MAGNETIC FIELD IN HOT ACCRETION FLOWS AROUND BLACK HOLES

The magnitude of the viscosity and magnetic field parameters in hot accretion flows is investigated in low luminosity active galactic nuclei (LLAGNs). Theoretical studies show that a geometrically thin, optically thick disk is truncated at mass accretion rates less than a critical value by mass evaporated vertically from the disk to the corona, with the truncated region replaced by an advection dominated accretion flow (ADAF). The critical accretion rate for such a truncation is a function of the viscosity and magnetic field. Observations of X-ray photon indices and spectral fits of a number of LLAGNs published in the literature provide an estimate of the critical rate of mass accretion and the truncation radius, respectively. By comparing the observational results with theoretical predictions, the viscosity and magnetic field parameters in the hot accretion flow region are estimated. Specifically, the mass accretion rates inferred in different sources constrain the viscosity parameter, whereas the truncation radii of the disk, as inferred from spectral fits, further constrain the magnetic field parameter. It is found that the value of the viscosity parameter in the corona/ADAF ranges from 0.17 to 0.5, with values clustered about 0.2-0.3. Magnetic pressure is required by the relatively small truncation radii for some LLAGNs and is found to be as high as its equipartition value with the gas pressure. The inferred values of the viscosity parameter are in agreement with those obtained from the observations of non-stationary accretion in stellar mass black hole X-ray transients. This consistency provides support for the paradigm that a geometrically thin disk is truncated by means of a mass evaporation process from the disk to the corona at low mass accretion rates.

79 ASTRONOMY AND ASTROPHYSICS↗

Optical measurement systems

Some of the areas of research conducted at Lewis on optical measurement techniques are described. Two laser anemometer systems developed at Lewis are used to illustrate the special instrumentation needs encountered in aeropropulsion research. Velocity measurements to be made through small viewing ports, close to surfaces within the propulsion system components, and in turbulent or highly-accelerating flows are some of the significant challenges. The application to research facilities of two advanced optical systems, the rainbow schlieren and the combustor viewing system, is presented. The calibration and verification of commercial optical measuring systems, such as droplet sizing systems, are also discussed. Calibration techniques capable of simulating moving droplets for flight-type sizing systems are being developed at Lewis. The presentation concludes with a brief look at the forces driving future research on optical instrumentation.

Lesco, Daniel J.↗

Continuous precipitation‐filtration process for initial capture of a monoclonal antibody product using a four‐stage countercurrent hollow fiber membrane washing step

The significant increase in product titers, coupled with the growing focus on continuous bioprocessing, has renewed interest in using precipitation as a low‐cost alternative to Protein A chromatography for the primary capture of monoclonal antibody (mAb) products. In this work, a commercially relevant mAb was purified from clarified cell culture fluid using a tubular flow precipitation reactor with dewatering and washing provided by tangential flow microfiltration. The particle morphology was evaluated using an inline high‐resolution optical probe, providing quantitative data on the particle size distribution throughout the precipitation process. Data were obtained in both a lab‐built 2‐stage countercurrent washing system and a commercial countercurrent contacting skid that provided 4 stages of continuous washing. The processes were operated continuously for 2 h with overall mAb yield of 92 ± 3% and DNA removal of nearly 3 logs in the 4‐stage system. The high DNA clearance was achieved by selective redissolution of the mAb using a low pH acetate buffer. Host cell protein clearance was 0.59 ± 0.08 logs, comparable to that based on model predictions. The process mass intensity was slightly better than typical Protein A processes and could be significantly improved by preconcentration of the antibody feed material.

59 BASIC BIOLOGICAL SCIENCES↗

Dynamics of the chemo-optical response of supported films of nematic liquid crystals

We report a study that elucidates key physicochemical phenomena that underlie the dynamics of adsorbate-induced ordering transitions in micrometer-thick films of nematic liquid crystals (LCs) supported on chemically functionalized surfaces. By flowing a gas containing dimethyl methylphosphonate (DMMP) over a film of nematic 4-cyano-4'-pentylbiphenyl (5CB) supported on a surface decorated with aluminum perchlorate, we quantify the dynamics of the optical response (intensity of transmitted light) of the LC film as a function of key experimental parameters, including linear flow rate of the gas over the surface of the film and the concentration of the DMMP within the gas. Building from prior infrared spectroscopic analysis revealing that the optical response of the LC is due to an ordering transition triggered by competitive ligand-exchange reactions at the chemically functionalized surface (i.e., between the phosphonate and nitrile groups of the DMMP and LC, respectively, with the aluminum perchlorate-decorated surface), we interpret the measurements reported herein within the framework of a simple model of mass transport. The model reveals that the rate-limiting process underlying the response of the LC is the mass transport of the DMMP across the concentration boundary layer formed on the vapor side of the LC–vapor interface, and not the mass transport of DMMP across the LC film nor the intrinsic ligand exchange kinetics. The analysis also reveals that the response of the LC is triggered once the concentration of DMMP within the LC film rises to approximately 0.25 mM. By flowing a stream of gas free of DMMP over a LC film pre-exposed to DMMP, we established that the relaxation of the LC film to the initial state is also largely controlled by mass transport of the DMMP across the vapor side of the LC–vapor interface. Analysis of the relaxation of the system leads to an estimate of the sensitivity of the supported LC film to the concentration of DMMP in the gas phase (approximately 150 ppb for the non-optimized system reported in this paper). These results and others reported in this paper identify key physical phenomena that dictate the dynamics of adsorbate-induced ordering transitions in LC systems, and provide important guidance to the design of LCs as chemo-responsive materials for use in sensors.

dimethyl methylphosphonate↗

Microstructural Characterization and High Strain Rate Plastic Flow Behavior of SMAW Armox500T Steel Joints from Spherical Indentation Experiments

Static indentation and uniaxial compression tests have been conducted on Armox500T steel and its weldments to predict the constraint factor (CF), i.e., ratio of Meyer’s hardness to uniaxial flow stress. Series of dynamic indentation experiments were carried out at impact velocities ranging from 5 to 300 m/s to estimate dynamic hardness as a function of average strain. Subsequently, dynamic indentation (DI) test data and CF determined under static indentation conditions have been used to study the high strain rate plastic flow behavior of Armox500T weldments in comparison with the base metal. It was observed that flow stress for Armox500T and its weldments under dynamic loading conditions (10{sup 4} s{sup −1}) are significantly higher than flow stress measured under static loading conditions (10{sup −3} s{sup −1}). The plastic flow behavior computed from DI is in good agreement with the data evaluated through conventional split Hopkinson pressure bar technique. Further, the study of the microstructure of base metal and weldments by optical microscopy and SEM revealed a considerable variation in the microstructure.

36 MATERIALS SCIENCE↗

A long-range laser velocimeter

A long-range laser velocimeter (LV) developed for remote operation from within the flow fields of large wind tunnels is described. Emphasis is placed on recent improvements in optical hardware as well as recent additions to data acquisition and processing techniques. The method used for data reduction of photon resolved signals is outlined in detail, and measurement accuracy is discussed. To study the performance of the LV and verify the measurement accuracy, laboratory measurements were made in the flow field of a 10-cm-diameter, 30-m/s axisymetric jet. The measured velocity and turbulence intensity surveys are compared with measurements made with a hot-wire anemometer. Additionally, the LV was used during the flow calibration of the 80-ft x 120-ft wind tunnel to measure the test-section boundary-layer thickness at the maximum wind tunnel speed of 51.5 m/s. The requirements and techniques used to seed the flow are discussed, and boundary-layer surveys of mean velocity and turbulence intensity of the streamwise component and the component normal to the surface are presented. The streamwise component of mean velocity is compared with data obtained with a total pressure rake.

Reinath, Michael S.↗

A simple growth method for Nb 2 O 5 films and their optical properties

A simple method for the synthesis of Nb₂O₅ films of thicknesses ranging from tens to several hundreds of nanometers on amorphous silicon dioxide or quartz substrates is presented. Nb₂O₅ films were formed by annealing the sputter deposited Nb films under an Ar flow and without oxygen plasma in a quartz tube within a furnace at 850 °C. The structural, compositional, optical, and vibrational properties were characterized by grazing incidence X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, ultraviolet visible spectroscopy, and Raman scattering. Each of the Nb₂O₅ films is polycrystalline with an orthorhombic crystal structure. We observed vibrational modes including longitudinal optical, transverse optical, and triply degenerate modes, and measured the indirect optical band gap to be ~3.65 eV. The transmittance spectrum of the ~20 nm thick Nb₂O₅ film shows over 90% transmittance below the band gap energy in the visible wavelength range and decreases to less than 20% in the ultraviolet regime. As a result, the optical properties of the films in the UV-vis range show potential applications as UV detectors.

36 MATERIALS SCIENCE↗

Annual Report: Innovative Process Technologies (30 September 2013)

Innovative Process Technologies is concerned with the development of innovative cost-effective technologies that promote efficiency, environmental performance, availability of advanced energy systems, and the development of computational tools that shorten development timelines of advanced energy systems. The project is focused on five distinct research tasks: (1) Sensors and Controls, (2) Power Electronics and Energetic Materials, (3) Innovative Energy Concepts (IEC), (4) Computational Materials, and (5) Multiphase Flow.

20 FOSSIL-FUELED POWER PLANTS↗

A survey of irradiated pillars, globules, and jets in the Carina nebula

We present wide-field, deep narrowband H{sub 2}, Brγ, Hα, [S ii], [O iii], and broadband I- and K-band images of the Carina star formation region. The new images provide a large-scale overview of all the H{sub 2} and Brγ emission present in over a square degree centered on this signature star-forming complex. By comparing these images with archival Hubble Space Telescope and Spitzer images we observe how intense UV radiation from O and B stars affects star formation in molecular clouds. We use the images to locate new candidate outflows and identify the principal shock waves and irradiated interfaces within dozens of distinct areas of star-forming activity. Shocked molecular gas in jets traces the parts of the flow that are most shielded from the intense UV radiation. Combining the H{sub 2} and optical images gives a more complete view of the jets, which are sometimes only visible in H{sub 2}. The Carina region hosts several compact young clusters, and the gas within these clusters is affected by radiation from both the cluster stars and the massive stars nearby. The Carina Nebula is ideal for studying the physics of young H ii regions and photodissociation region (PDR), as it contains multiple examples of walls and irradiated pillars at various stages of development. Some of the pillars have detached from their host molecular clouds to form proplyds. Fluorescent H{sub 2} outlines the interfaces between the ionized and molecular gas, and after removing continuum, we detect spatial offsets between the Brγ and H{sub 2} emission along the irradiated interfaces. These spatial offsets can be used to test current models of PDRs once synthetic maps of these lines become available.

79 ASTRONOMY AND ASTROPHYSICS↗

Universal spin-momentum locked optical forces

Evanescent electromagnetic waves possess spin-momentum locking, where the direction of propagation (momentum) is locked to the inherent polarization of the wave (transverse spin). We study the optical forces arising from this universal phenomenon and show that the fundamental origin of recently reported non-trivial optical chiral forces is spin-momentum locking. For evanescent waves, we show that the direction of energy flow, the direction of decay, and the direction of spin follow a right hand rule for three different cases of total internal reflection, surface plasmon polaritons, and HE{sub 11} mode of an optical fiber. Furthermore, we explain how the recently reported phenomena of lateral optical force on chiral and achiral particles are caused by the transverse spin of the evanescent field and the spin-momentum locking phenomenon. Finally, we propose an experiment to identify the unique lateral forces arising from the transverse spin in the optical fiber and point to fundamental differences of the spin density from the well-known orbital angular momentum of light. Our work presents a unified view on spin-momentum locking and how it affects optical forces on chiral and achiral particles.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Sensor for Boundary Shear Stress in Fluid Flow

The formation of scour patterns at bridge piers is driven by the forces at the boundary of the water flow. In most experimental scour studies, indirect processes have been applied to estimate the shear stress using measured velocity profiles. The estimations are based on theoretical models and associated assumptions. However, the turbulence flow fields and boundary layer in the pier-scour region are very complex and lead to low-fidelity results. In addition, available turbulence models cannot account accurately for the bed roughness effect. Direct measurement of the boundary shear stress, normal stress, and their fluctuations are attractive alternatives. However, most direct-measurement shear sensors are bulky in size or not compatible to fluid flow. A sensor has been developed that consists of a floating plate with folded beam support and an optical grid on the back, combined with a high-resolution optical position probe. The folded beam support makes the floating plate more flexible in the sensing direction within a small footprint, while maintaining high stiffness in the other directions. The floating plate converts the shear force to displacement, and the optical probe detects the plate s position with nanometer resolution by sensing the pattern of the diffraction field of the grid through a glass window. This configuration makes the sensor compatible with liquid flow applications.

Bao, Xiaoqi↗

AOI 1 — Computational Energy Sciences: Multiphase Flow Research: High-fidelity multi-phase radiation module for modern coal combustion systems (Final Scientific/Technical Report)

The effects of radiation in particle-laden flows were the object of the present research. The presence of particles increases optical thickness substantially, making the use of the “optically thin” approximation in most cases a very poor assumption. However, since radiation fluxes peak at intermediate optical thicknesses, overall radiative effects may not necessarily be stronger than in gas combustion. Also, the spectral behavior of particle radiation properties is much more benign, making spectral models simpler (and making the assumption of a gray radiator halfway acceptable, at least for fluidized beds when gas radiation is not large). On the other hand, particles scatter radiation, making the radiative transfer equation (RTE) much more di fficult to solve. The research carried out in this project encompassed three general areas: (i) assessment of relevant radiation properties of particle clouds encountered in fluidized bed and pulverized coal combustors, (ii) development of proper spectral models for gas–particulate mixtures for various types of two-phase combustion flows, and (iii) development of a Radiative Transfer Equation (RTE) solution module for such applications. The resulting models were validated against artificial cases since open literature experimental data were not available. The final models are in modular form tailored toward maximum portability, and were incorporated into two research codes: (i) the open-source CFD code OpenFOAM, which we have extensively used in our previous work, and (ii) the open-source multi-phase flow code MFIX, which is maintained by NETL.

42 ENGINEERING↗