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At least 1,171 records · Page 65

Oscillator Strengths of Allowed and Intercombination Transitions in Neutral Sulfur

We have calculated oscillator strengths and transition probabilities of electric-dipole allowed and intercombination transitions from fine-structure levels of the ground 3s(sup 2)3p(sup 4) configuration to the levels belonging to configurations 3s(sup 2)3p(sup 3)4s, 3s(sup 2) 3p(sup 3)5s, 3(sup 2)3p(sup 3)3d, 3s(sup 2)3p(sup 3)4d of neutral sulfur. Extensive configuration-interaction wave functions are used to represent these levels. The relativistic corrections have been included through the Breit-Pauli Hamiltonian. The results are compared with previous theoretical calculations and with measurements.

Tayal, S. S.↗

Atomic interferometer measurements of Berry and Aharonov-Anandan phases for isolated spins S>(1/2) nonlinearly coupled to external fields

In a recent paper we have studied the peculiar features of the Berry and Aharonov-Anandan geometric phases for isolated spins S{>=}1. We have assumed that they are submitted to a dipole and quadrupole coupling to external E and B fields with the mild restriction E{center_dot}B=0. This implies discrete symmetries leading to remarkable simplifications of the geometry and algebra involved. The aim of the present work is to describe realistic proposals, within the realm of atomic physics, for the verification of some of our most significant theoretical predictions. There are several challenges to be overcome. For alkali-metal atoms, most commonly used in atomic interferometers, the only practical way to generate quadrupole coupling, with a strength comparable to the dipole one, is the ac Stark effect induced by a nearly resonant light beam. One then has to face the instability of the 'dressed' atom hyperfine (hf) level, a candidate for our isolated spin. One deleterious effect is the apparition of an imaginary part in the quadrupole to dipole coupling strength ratio, {lambda}. Fortunately we have found a simple way to get rid of I({lambda}) by an appropriate detuning. We are left with an unstable isolated spin. This implies an upper bound to the quantum cycle duration T{sub c}. In the case of the Berry's phase, T{sub c} has a lower bound due to the necessity of keeping the nonadiabatic corrections below a predefined level. We have found a compromise in the case of the F=2,m=0 {sup 87}Rb ground-state hf level. This is our candidate for the measurement of the somewhat ''exotic'' Berry's phase acquired by the S=2,m=0 state at the end of a quantum cycle involving a rotation of {pi} of the E field--in practice, the linear polarization of the dressing beam --about the B field direction. We have found a way to implement, in a Ramsey-type interferometric measurement, the procedures aimed at controlling the nonadiabatic corrections, as described in detail in our previous theoretical paper. A numerical simulation of our experimental proposal shows that a 0.1% accurate determination of Berry's phase, free of nonadiabatic corrections, can be achieved. Measurements could also be considered for cold {sup 52}Cr chromium atoms with S=3, where values of {lambda}{approx_equal}1 can be obtained with an instability smaller than in the {sup 87}Rb case, due to a more favorable spectroscopic structure. The F=1,m=1 hf level of the {sup 87}Rb ground state offers the opportunity to extend the measurement of Aharonov-Anandan's phases beyond the case S=(1/2). We construct, using 'light shift', the Hamiltonian H{sub ||}(t) generating a closed circuit in the density-matrix space which satisfies at any time the 'parallel transport' condition, thus making the quantum cycle free from the adiabaticity condition. We also consider the case of half-integer spins (e.g., {sup 201}Hg, {sup 135}Ba, and {sup 137}Ba), with their own specific features. We show how the difference of Berry's phases for states S=(3/2) and S=(1/2), with m=(1/2), can be exploited to achieve a holonomic maximum entanglement of three qubits.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Depth-dependent Vertical-to-Horizontal (V/H) Ratios of Free-Field Ground Motion Response Spectra for Deeply Embedded Nuclear Structures

This report documents the results of a study to determine the depth-dependent V/H ratios of ground motion response spectra in the free field. The V/H ratios reported herein were developed from a worldwide database of surface and downhole acceleration recordings obtained from 45 vertical array stations. This database was specifically compiled for this project, and includes information from a diversity of active tectonic regions (California, Alaska, Taiwan, Japan), site conditions (rock to soft soil), ground motion intensity levels (PGAs between 0.01 g and 0.50 g), magnitudes (between ML 2.78 and JMA 8.1), epicentral distances (between 3.2 km and 812 km), and source depths (between 1.2 km and 112 km), as well as sensors at surface and at a wide range of depths relevant to the project. To study the significance of the depth effect, V/H ratios from all the records were sorted into a number of depth bins relevant to the project, and statistics (average, standard deviation, coefficient of variation, 16th, 50th, and 84th percentiles) of the V/H ratios within each bin were computed. Similar analyses were repeated, controlling for different site conditions, ground motion intensity levels, array locations, and source depths, to study their relative effect on the V/H ratios. Our findings confirm the importance of the depth effect on the V/H ratios. The research findings in this report can be used to provide guidance on the significance of the depth effect, and the extent to which this effect should be considered in the seismic design of deeply embedded SMR structures and NPP structures in general.

42 ENGINEERING↗

Dismantling the nuclear research reactor Thetis

The research reactor Thetis, in service since 1967 and stopped in 2003, is part of the laboratories of the institution of nuclear science of the University of Ghent. The reactor, of the pool-type, was used as a neutron-source for the production of radio-isotopes and for activation analyses. The reactor is situated in a water pool with inner diameter of 3 m. and a depth of 7.5 m. The reactor core is situated 5.3 m under water level. Besides the reactor, the pool contains pneumatic loops, handling tools, graphite blocks for neutron moderation and other experimental equipment. The building houses storage rooms for fissile material and sources, a pneumatic circuit for transportation of samples, primary and secondary cooling circuits, water cleaning resin circuits, a ventilation system and other necessary devices. Because of the experimental character of the reactor, laboratories with glove boxes and other tools were needed and are included in the dismantling program. The building is in 3 levels with a crawl-space. The ground-floor contains the ventilation installation, the purification circuits with tanks, cooling circuits and pneumatic transport system. On the first floor, around the reactor hall, the control-room, visiting area, end-station for pneumatic transport, waste-storage room, fuel storage room and the labs are located. The second floor contains a few laboratories and end stations of the two high speed transfer tubes. The lowest level of the pool is situated under ground level. The reactor has been operated at a power of 150 kW and had a max operating power of 250 kW. Belgoprocess has been selected to decommission the reactor, the labs, storage halls and associated circuits to free release the building for conventional reuse and for the removal of all its internals as legal defined. Besides the dose-rate risk and contamination risk, there is also an asbestos risk of contamination. During construction of the installation, asbestos-containing materials were used, which must be removed in controlled conditions. The ventilation system is considered free from nuclear contamination but it contains asbestos. This paper covers the organization of the dismantling work, the technical execution aspect and conclusions already known (dismantling is ongoing as this is written). (authors)

07 ISOTOPE AND RADIATION SOURCES↗

Three-dimensional numerical simulation of near-surface flows over the Martian north polar cap

Measurements made by Viking Lander VL-2 (48 N) have shown that the near-surface wind and temperature regime on Mars displays striking similarities to terrestrial counterparts. The diurnal radiative cycle is responsible for establishment of a well-defined thermal circulation in which downslope (Katabatic) flows prevail during the nighttime hours and weak upslope (anabatic) conditions prevail during the daytime. Previous work has indicated that the slope flows are much like those found on Earth, particularly the Katabatic winds, which show striking similarities to drainage flows observed over Antarctica. The low-level wind regime appears to be an important factor in the scouring of the martian landscape. The north polar cap shows evidence of eolian features such as dunes, frost streaks, and grooves from Viking imagery. The direction of the prevailing wind can in cases be inferred from the eolian features. We examine the thermally induced flows that result from the radiative heating and cooling of the martian north polar region using a comprehensive three-dimensional atmospheric mesoscale numerical model. The same model has been used previously for simulation of Antarctic Katabatic winds. The model equations are written in terrain-following coordinates to allow for irregular terrain; prognostic equations include the flux forms of the horizontal momentum equations, temperature, continuity. A surface energy budget equation is also incorporated in which the surface temperature is determined. Explicit parameterization of both terrestrial (longwave) and solar (shortwave) radiation is included. Turbulent transfer of heat and momentum in the martian atmosphere is assumed to follow the similarity expressions in the surface boundary layer on Earth. The terrain heights for the martian north polar region have been obtained from the U.S. Geological Survey map and digitized onto a 57x57 grid with a spacing of 75 km. The resulting terrain map is shown in Fig. 1. The vertical grid consists of 15 levels (delta equals 0.998, 0.99, 0.98, 0.97, 0.96, 0.94, 0.92, 0.90, 0.85, 0.775, 0.70, 0.60, 0.50, 0.30, 0.10). The high resolution in the lower atmosphere is necessary to capture details of the boundary layer flows. The lowest level corresponds to a height of approximately 20 m above the ground, the seconds level 100 m.

Parish, Thomas R.↗

Selective reabsorption leading to multiple oscillations in the 8446-A atomic-oxygen laser.

Laser oscillation of atomic oxygen at 8446 A occurs in four closely spaced lines with peculiar intensity ratios, all detuned from the atomic center frequencies of the three fine-structure transitions. These anomalies are caused by the selective reabsorption of resonance radiation from the lower laser level by ground-state oxygen atoms. The selectivity results from the fact that the velocity distribution of the laser levels is considerably wider than that of the ground state, because of the dissociative mode of production of excited oxygen atoms. Possible extension of this mechanism to the atomic-hydrogen system is discussed.

Feld, M. S.↗

Copper fine-structure K-shell electron impact ionization cross sections for fast-electron diagnostic in laser-solid experiments

The K-shell electron impact ionization (EII) cross section, along with the K-shell fluorescence yield, is one of the key atomic parameters for fast-electron diagnostic in laser-solid experiments through the K-shell emission cross section. In addition, copper is a material that has been often used in those experiments because it has a maximum total K-shell emission yield. Furthermore, in a campaign dedicated to the modeling of the K lines of astrophysical interest (Palmeri et al., 2012), the K-shell fluorescence yields for the K-vacancy fine-structure atomic levels of all the copper isonuclear ions have been calculated. In this study, the K-shell EII cross sections connecting the ground and the metastable levels of the parent copper ions to the daughter ions K-vacancy levels considered in Palmeri et al. (2012) have been determined. The relativistic distorted-wave (DW) approximation implemented in the FAC atomic code has been used for the incident electron kinetic energies up to 10 times the K-shell threshold energies. Moreover, the resulting DW cross sections have been extrapolated at higher energies using the asymptotic form proposed by Davies et al. (2013)

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Probing cis-trans isomerization in the S{sub 1} state of C{sub 2}H{sub 2} via H-atom action and hot band-pumped IR-UV double resonance spectroscopies

We report novel experimental strategies that should prove instrumental in extending the vibrational and rotational assignments of the S{sub 1} state of acetylene, C{sub 2}H{sub 2}, in the region of the cis-trans isomerization barrier. At present, the assignments are essentially complete up to ∼500 cm{sup −1} below the barrier. Two difficulties arise when the assignments are continued to higher energies. One is that predissociation into C{sub 2}H + H sets in roughly 1100 cm{sup −1} below the barrier; the resulting quenching of laser-induced fluorescence (LIF) reduces its value for recording spectra in this region. The other difficulty is that tunneling through the barrier causes a staggering in the K-rotational structure of isomerizing vibrational levels. The assignment of these levels requires data for K values up to at least 3. Given the rotational selection rule K′ − ℓ{sup ′′} = ± 1, such data must be obtained via excited vibrational levels of the ground state with ℓ{sup ′′} > 0. In this paper, high resolution H-atom resonance-enhanced multiphoton ionization spectra are demonstrated to contain predissociated bands which are almost invisible in LIF spectra, while preliminary data using a hyperthermal pulsed nozzle show that ℓ{sup ′′} = 2 states can be selectively populated in a jet, giving access to K′ = 3 states in IR-UV double resonance.

74 ATOMIC AND MOLECULAR PHYSICS↗

System-Level Performance Evaluation of ATD-1 Ground-Based Technologies

A series of large-scale human-in-the-loop simulations were conducted in the Airspace Operations Laboratory (AOL) at NASA Ames Research Center to evaluate the system-level performance of NASA Air Traffic Management Technology Demonstration-1 (ATD-1) ground-based technologies. The ATD-1 ground-based technologies are the Traffic Management Advisor for Terminal Metering (TMA-TM) and Controller-Managed Spacing (CMS) tools. The simulations compared current operations to ATD-1 operations for peak-period arrivals to Phoenix Sky Harbor International Airport (PHX). Results indicate that controllers new to ATD-1 operations can increase the use of Performance-Based Navigation (PBN) in complex arrival flows without undue increases in workload.

Callantine, Todd J.↗

Energy levels of a quantum particle on a cylindrical surface with non-circular cross-section in electric and magnetic fields

We calculate the energy levels of a quantum particle on a cylindrical surface with non-circular cross-section in uniform electric and magnetic fields. Using separation of variables method and a change of independent variable, we show that the problem can be reduced to a one-dimensional Schrödinger equation for a periodic potential. The effects of varying the shape of the cross-section while keeping the same perimeter and the strengths of the electric and magnetic fields are investigated for elliptical, corrugated, and nearly-rectangular tubes with radial dimensions of the order of a nanometer. The geometric potential has minima at the angular positions where there is a significant amount of curvature. For the elliptical and corrugated tubes, it is shown that as the tube departs from the circular shape of cross-section the double-degeneracy between the energy levels is lifted. For the nearly-rectangular tube, it is shown that energy level crossings occur as the horizontal dimension of the tube is varied while keeping the same perimeter and radius of circular corners. The interplay between the curvature and the strength of the electric and magnetic fields determines the overall behavior of the energy levels. As the strength of the electric field increases, the overall potential gets skewed creating a potential well on the side corresponding to the more negative electric potential. The energy levels of the first few excited states approach more positive values while the ground state energy level approaches a more negative value. For large electric fields, all bound state energy levels tend to more negative values. The contribution of weak magnetic fields to the overall potential behaves in the same way as the electric field contribution but with its sign depending on the direction of the component of the momentum parallel to the cylindrical axis. Large magnetic fields lead to pairing of energy levels reminiscent of 2D Landau levels for the elliptical and nearly-rectangular tubes.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Atomic lifetime measurements of Ne-like Fe ions in a magnetic field

Among the lowest excited levels in Ne-like ions, that is, of configuration 2p 5 3s, there is a J = 0 level that in a field-free environment decays by a magnetic dipole (M1) transition to the lower J = 1 level of the same configuration only. In the presence of a magnetic field, this level can also decay to the ground configuration J = 0 level. In the course of the first measurement of the 2p 5 3s J = 0 level lifetime and the M1 transition rate the magnetically induced transition (MIT) appeared as a complication that was then turned into a tool. The technical details of the measurement in an electron beam ion trap have been described elsewhere. As a result, we illuminate the physics aspects of the two transition rate measurements and show how the results compare to computations.

74 ATOMIC AND MOLECULAR PHYSICS↗

Sub-Doppler infrared spectroscopy of resonance-stabilized hydrocarbon intermediates: ν 3 / ν 4 CH stretch modes and CH 2 internal rotor dynamics of benzyl radical

Highly reactive benzyl radicals are generated by electron dissociative attachment to benzyl chloride doped into a neon–hydrogen–helium discharge and immediately cooled to T rot = 15 K in a high density, supersonic slit expansion environment. The sub-Doppler spectra are fit to an asymmetric-top rotational Hamiltonian, thereby yielding spectroscopic constants for the ground (v = 0) and first excited (v = 1, ν 3 , ν 4 ) vibrational levels of the ground electronic state. The rotational constants obtained for the ground state are in good agreement with previous laser induced fluorescence measurements (LIF), with vibrational band origins (ν 3 = 3073.2350 ± 0.0006 cm –1 , ν 4 = 3067.0576 ± 0.0006 cm –1 ) in agreement with anharmonically corrected density functional theory calculations. Furthermore, to assist in detection of benzyl radical in the interstellar medium, we have also significantly improved the precision of the ground state rotational constants through combined analysis of the ground state IR and LIF combination differences. Of dynamical interest, there is no evidence in the sub-Doppler spectra for tunneling splittings due to internal rotation of the CH 2 methylene subunit, which implies a significant rotational barrier consistent with partial double bond character in the CC bond. This is further confirmed with high level ab initio calculations at the CCSD(T)-f12b/ccpVdZ-f12 level, which predict a zero-point energy corrected barrier to internal rotation of ΔE tun ≈ 11.45 kcal mol –1 or 4005 cm –1 . In summary, the high-resolution infrared spectra are in excellent agreement with simple physical organic chemistry pictures of a strongly resonance-stabilized benzyl radical with a nearly rigid planar structure due to electron delocalization around the aromatic ring.

Kortyna, A.↗

Flying-qualities criteria for wings-level-turn maneuvering during an air-to-ground weapon delivery task

A moving-base simulator experiment conducted at Ames Research Center demonstrated that a wings-level-turn control mode improved flying qualities for air-to-ground weapons delivery compared with those of a conventional aircraft. Evaluations of criteria for dynamic response for this system have shown that pilot ratings correlate well on the basis of equivalent time constant of the initial response. Ranges of this time constant, as well as digital-system transport delays and lateral-acceleration control authorities that encompassed Level I through Level III handling qualities, were determined.

Sammonds, R. I.↗

Sound propagation elements in evaluation of en route noise of advanced turbofan aircraft

Cruise noise from an advanced turboprop aircraft is reviewed on the basis of available wind tunnel data to estimate the aircraft noise signature at the source. Available analytical models are used to evaluate the sound levels at the ground. The analysis allows reasonable estimates to be made of the community noise levels that might be generated during cruise by such aircraft, provides the basis for preliminary comparisons with available data on noise of existing aircraft during climb and helps to identify the dominant elements of the sound propagation models applicable to this situation.

Sutherland, Louis C.↗

The Low-Lying Electronic States of LiB

The spectroscopic constants for the triplet and singlet states of LiB below about 30 000/ cm are determined using an internally contracted multireference configuration interaction approach in conjunction with [6s 5p 3d 2f] atomic natural orbital basis sets. The ground state is (sup 3)Pi as found in previous work. No excited triplet states are found to be ideal for characterizing the ground state; the (1)(sup 3)Sigma(sup -) state has a transition energy that is too small for many experimental approaches and the (2)(sup 3)Pi and (3)(sup 3)Pi states have bond lengths that are significantly longer than the ground state, resulting in transition intensities that are spread out over many vibrational levels of the ground state.

Ricca, Alessandra↗

Quadrupole splittings in the near-infrared spectrum of 14 NH 3

Sub-Doppler, saturation dip, spectra of lines in the v 1 + v 3 , v 1 + 2v 4 and v 3 + 2v 4 bands of 14 NH 3 have been measured by frequency comb-referenced diode laser absorption spectroscopy. The observed spectral line widths are dominated by transit time broadening, and show resolved or partially-resolved hyperfine splittings that are primarily determined by the 14 N quadrupole coupling. Modeling of the observed line shapes based on the known hyperfine level structure of the ground state of the molecule shows that, in nearly all cases, the excited state level has hyperfine splittings similar to the same rotational level in the ground state. The data provide accurate frequencies for the line positions and easily separate lines overlapped in Doppler-limited spectra. The observed hyperfine splittings can be used to make and confirm rotational assignments and ground state combination differences obtained from the measured frequencies are comparable in accuracy to those obtained from conventional microwave spectroscopy. Furthermore, several of the measured transitions do not show the quadrupole hyperfine splittings expected based on their existing rotational assignments. Either the assignments are incorrect or the upper levels involved are perturbed in a way that affects the nuclear hyperfine structure.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Spectroscopic prescription for optimal stimulated Raman transfer of ultracold heteronuclear molecules to the lowest rovibronic level

We show that the multiplicative product of a molecular-beam excitation spectrum and an ultracold-molecule excitation spectrum, with a frequency offset appropriate to the initial ultracold-molecule level, provides the relative rate of stimulated Raman transfer (SRT) from a given high rovibrational level to the lowest rovibronic level, i.e., the v{sup ''}=0,J{sup ''}=0 level of the ground electronic state for photoassociated (and magnetoassociated) ultracold molecules. This product spectrum clearly indicates the optimal pathways for SRT, even when the two component spectra are completely unassigned. We illustrate this specifically for the case of KRb.

74 ATOMIC AND MOLECULAR PHYSICS↗