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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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This paper describes MEXEC, an implemented micro executive that compiles a device model into an interal structure. Not only does this structure facilitate computing the most likely current device mode from n sets of sensor measurements, but it also facilitates generating an n step reconfiguration plan that is most likely not to result in reaching a target mode - if such a plan exists.
Security is one of the most if not the most important areas today. After the several attacks on the United States, security everywhere has heightened from airports to communication among the military branches legionnaires. With advanced persistent threats (APTs) on the rise following Stuxnet, government branches and agencies are required, more than ever, to follow several standards, policies and procedures to reduce the likelihood of a breach. Attack vectors today are very advanced and are going to continue to get more and more advanced as security controls advance. This creates a need for networks and systems to be in an updated, patched and secured state in a launch control system environment. Attacks on critical systems are becoming more and more relevant and frequent. Nation states are hacking into critical networks that might control electrical power grids or water dams as well as carrying out advanced persistent threat (APTs) attacks on government entities. NASA, as an organization, must protect its self from attacks from all different types of attackers with different motives. Although the International Space Station was created, there is still competition between the different space programs. With that in mind, NASA might get attacked and breached for various reasons such as espionage or sabotage. My project will provide a way for NASA to complete an in house penetration test which includes: asset discovery, vulnerability scans, exploit vulnerabilities and also provide forensic information to harden systems. Completing penetration testing is a part of the compliance requirements of the Federal Information Security Act (FISMA) and NASA NPR 2810.1 and related NASA Handbooks. This project is to demonstrate how in house penetration testing can be conducted that will satisfy all of the compliance requirements of the National Institute of Standards and Technology (NIST), as outlined in FISMA. By the end of this project, I hope to have carried out the tasks stated above as well as gain an immense knowledge about compliance, security tools, networks and network devices, as well as policies and procedures.
The cost of sending large spacecraft to orbit makes them undesirable for carrying out smaller scientific missions. Small spacecraft are more economical and can be tailored for missions where specific tasks need to be carried out, the Maraia capsule is such a spacecraft. Maraia will allow for samples of experiments conducted on the International Space Station to be returned to earth. The use of balloons to conduct experiments at the edge of space is a practical approach to reducing the large expense of using rockets. E-MIST is a payload designed to fly on a high altitude balloon. It can maintain science experiments in a controlled manner at the edge of space. The work covered here entails the integration of hardware onto each of the mentioned systems and the code associated with such work. In particular, the resistance temperature detector, pressure transducers, cameras, and thrusters for Maraia are discussed. The integration of the resistance temperature detectors and motor controllers to E-MIST is described. Several issues associated with sensor accuracy, code lock-up, and in-flight reset issues are mentioned. The solutions and proposed solutions to these issues are explained.
Thr prospect of highly autonomous spacecraft and rovers is exciting for what they can do with onboard decision making, but also troubling for what they might do [improperly] without human-in-the-loop oversight.
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This work is the first report of a molybdenum carbide-based electrocatalyst for sulfur-based sodium metal batteries (SMBs/NMBs). MoC/Mo 2 C is in-situ grown on nitrogen-doped carbon nanotubes in parallel with formation of extensive nanoporosity. Sulfur impregnation (50 wt% S) results in unique triphasic architecture termed MoC/Mo 2 C@PCNT-S. Quasi-solid-state phase transformation to Na 2 S is promoted in carbonate electrolyte, with in-situ time-resolved Raman, XPS and optical analysis demonstrating minimal soluble polysulfides. MoC/Mo 2 C@PCNT-S cathodes delivered among the most promising rate performance characteristics in literature, achieving 987 mAh g -1 at 1 Ag -1 , 818 mAh g -1 at 3 A g -1 , and 621 mAh g -1 at 5 A g -1 . The cells deliver superior cycling stability, retaining 650 mAh g -1 after 1000 cycles at 1.5 Ag -1 , corresponding to 0.028% capacity decay per cycle. High mass loading cathodes (64 wt% S, 12.7 mg cm -2 ) also show cycling stability, with anode degradation due to deep plating/stripping driving capacity decay. Density functional theory (DFT) demonstrates that formation energy of Na 2 S x (1 ≤ x ≤ 4) on surface of MoC/Mo 2 C is significantly lowered compared to analogous redox in liquid. Strong binding of Na 2 S x (1 ≤ x ≤ 4) on MoC/Mo 2 C surfaces results from charge transfer between the sulfur and Mo sites on carbides' surface.
Suppressing the photon energy loss (E loss ), especially the non-radiative loss, is of importance to further improve the device performance of organic solar cells (OSCs). However, typical π-conjugated semiconductors possess a large singlet–triplet energy gap (ΔE ST ), leading to a lower triplet state than charge transfer state and contributing to a non-radiative loss channel of the photocurrent by the triplet state. Herein, a series of triplet polymer donors are developed by introducing a BNIDT block into the PM6 polymer backbone. Further, the high electron affinity of BNIDT and the opposite resonance effect of the B—N bond in BNIDT results in a lowered highest occupied molecular orbital (HOMO) and a largely reduced ΔE ST . Moreover, the morphology of the active blends is also optimized by fine-tuning the BNIDT content. Therefore, non-radiative recombination via the terminal triplet loss channels and morphology traps is effectively suppressed. The PNB-3 (with 3% BNIDT):L8-BO device exhibits both small ΔE ST and optimized morphology, favoring more efficient charge transfer and transport. Finally, the simultaneously enhanced V oc of 0.907 V, J sc of 26.59 mA cm –2 , and FF of 78.86% contribute to a champion PCE of 19.02%. Therefore, introducing B—N bonds into benchmark polymers is a possible avenue toward higher-performance of OSCs.
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Integration of nanoscale photonic and plasmonic components on Si substrates is a critical step toward Si-based integrated nanophotonic devices. Herein, a set of unique complex 3D metamaterials with intercalated nanolayered and nanopillar structures with tunable plasmonic and optical properties on Si substrates is designed. More specifically, the 3D metamaterials combine metal (Au) nanopillars and alternating metal-nitride (Au-TiN and Au-TaN) nanolayers, epitaxially grown on Si substrates. The ultrafine Au nanopillars ( d ≈ 3 nm) continuously grow throughout all the nanolayers with high epitaxial quality. Novel optical properties, such as highly anisotropic optical property, high absorbance covering the entire visible spectrum regime, and hyperbolic property in the visible regime, are demonstrated. Furthermore, a waveguide based on a silicon nitride (Si 3 N 4 ) ridge with a multilayer structure is successfully fabricated. The demonstration of 3D nanoscale metamaterial design integrated on Si opens up a new route toward tunable metamaterials nanostructure designs with versatile material selection for various optical components in Si integrated photonics.
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Abstract Development of inexpensive and efficient oxygen evolution reaction (OER) catalysts in acidic environment is very challenging, but it is important for practical proton exchange membrane water electrolyzers. A molecular iron–nitrogen coordinated carbon nanofiber is developed, which is supported on an electrochemically exfoliated graphene (FeN 4 /NF/EG) electrocatalyst through carbonizing the precursor composed of iron ions absorbed on polyaniline‐electrodeposited EG. Benefitting from the unique 3D structure, the FeN 4 /NF/EG hybrid exhibits a low overpotential of ≈294 mV at 10 mA cm −2 for the OER in acidic electrolyte, which is much lower than that of commercial Ir/C catalysts (320 mV) as well as all previously reported acid transitional metal‐derived OER electrocatalysts. X‐ray absorption spectroscopy coupled with a designed poisoning experiment reveals that the molecular FeN 4 species are identified as active centers for the OER in acid. The first‐principles‐based calculations verify that the FeN 4 –doped carbon structure is capable of reducing the potential barriers and boosting the electrocatalytic OER activity in acid.
Lanthanide (Ln) group elements have been attracting considerable attention owing to the distinct optical properties. The crystal-field surroundings of Ln ions in the host materials can determine their energy level splitting, which is of vital importance to tailor their optical properties. 2D MoS 2 single crystals were utilized as the host material to embed Eu 3+ and energy-level splitting was achieved for tuning its photoluminescence (PL). The high anisotropy of the 2D host materials makes them distort the degenerate orbitals of the Ln ions more efficiently than the symmetrical bulk host materials. A significant red-shift of the PL peak for Eu 3+ was observed. The strategy for tailoring the energy level splitting of Ln ions by the highly designable 2D material crystal field provides a new method to extend their optical properties.
Abstract A porous organic cage composed of six iron tetraphenylporphyrins was used as a supramolecular catalyst for electrochemical CO 2 ‐to‐CO conversion. This strategy enhances active site exposure and substrate diffusion relative to the monomeric catalyst, resulting in CO generation with near‐quantitative Faradaic efficiency in pH 7.3 water, with activities reaching 55 250 turnovers. These results provide a starting point for the design of supramolecular catalysts that can exploit the properties of the surrounding matrix yet retain the tunability of the original molecular unit.
A dicopper(II)-paddle-wheel-based metal-organic framework (PCN-80, see picture) with a rare (3,3,4)-connected topology has been synthesized by using a unique octatopic ligand featuring 90° bridging-angle dicarboxylate moieties. PCN-80 has Brunauer-Emmett-Teller (BET) and Langmuir surface areas of 3850 and 4150 m 2 g -1 , respectively. It exhibits high gas-uptake capacity for H 2 and large adsorption selectivity of CO 2 over N 2 .
Lanthanide (Ln) group elements have been attracting considerable attention owing to the distinct optical properties. The crystal-field surroundings of Ln ions in the host materials can determine their energy level splitting, which is of vital importance to tailor their optical properties. 2D MoS 2 single crystals were utilized as the host material to embed Eu 3+ and energy-level splitting was achieved for tuning its photoluminescence (PL). The high anisotropy of the 2D host materials makes them distort the degenerate orbitals of the Ln ions more efficiently than the symmetrical bulk host materials. A significant red-shift of the PL peak for Eu 3+ was observed. The strategy for tailoring the energy level splitting of Ln ions by the highly designable 2D material crystal field provides a new method to extend their optical properties.
Here, a porous organic cage composed of six iron tetraphenylporphyrins was used as a supramolecular catalyst for electrochemical CO 2 -to-CO conversion. This strategy enhances active site exposure and substrate diffusion relative to the monomeric catalyst, resulting in CO generation with near-quantitative Faradaic efficiency in pH 7.3 water, with activities reaching 55 250 turnovers. These results provide a starting point for the design of supramolecular catalysts that can exploit the properties of the surrounding matrix yet retain the tunability of the original molecular unit.
Abstract Confined single metal atoms in graphene‐based materials have proven to be excellent catalysts for several reactions and promising gas sensing systems. However, whether the chemical activity arises from the specific type of metal atom or is a direct consequence of the confinement itself remains unclear.
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