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At least 1,171 records · Page 65
All sourcesNASA NTRSDOE OSTI
NASA NTRSDate not supplied

Comparison between Hayabusa 2 Spectral Measurements and Simulations

This paper compares recent Hayabusa 2 spectral measurements with state-of-the-art shock-layer radiation simulations resulting from the LAURA/HARA code suite. These simulations include coupled ablation, which accounts for the injection of ablation products into the flowfield, and coupled radiation, which accounts for radiative energy loss in the flowfield. To enable the coupled ablation simulations, a best-estimate model is developed for Hayabusa’s carbon-phenolic ablator, based on the limited available published information. The comparison between the simulations and measurements focuses on two atomic nitrogen lines and two atomic oxygen lines, as well as the CN Violet band system. For the atomic lines, the measurements and simulations agree within 25% over most of the trajectory. This excellent agreement is unprecedented for observed radiation measurements of atomic lines, where previous Stardust and Hayabusa 1 comparisons were significantly worse. The improved agreement for these Hayabusa 2 comparisons is both the result of improved measurement quality and enhanced flowfield/radiation modeling. To provide a link between these observed radiation measurements and the radiative heating to a vehicle surface, the recently developed flowfield property binning approach is used to identify flowfield properties that provide the dominant emission contribution to the measured spectrum. These identified flowfield properties are then shown to match those for the surface radiative heating to the currently developed Mars Sample Return (MSR) Earth Entry System (EES) at a specific trajectory point and surface location. This matching of flowfield properties indicates that this EES radiative heating and Hayabusa 2 observed radiation simulations are equivalent radiation problems. Therefore, the excellent agreement between Hayabusa 2 measurements and simulations may be leveraged to inform the radiation heating margin for the MSR EES.

Christopher O Johnston↗
NASA NTRS2021

The Use of Astronomy VLBA Campaign MOJAVE for Geodesy

We investigated the suitability of the astronomical 15 GHz VLBA observing program MOJAVE-5 for estimation of geodetic parameters, such as station coordinates and Earth orientation parameters. We processed contemporary geodetic dual-band RV and CN experiments observed at 2.3 GHz and 8.6 GHz starting on September 2016 through July 2020 as reference dataset. We showed that the baseline length repeatability from MOJAVE-5 experiments is only a factor of 1.5 greater than from the dedicated geodetic dataset and still below 1 ppb. The wrms of the difference of estimated EOP with respect to the reference IERS C04 time series are a factor of 1.3 to 1.8 worse. We isolated three major differences between the datasets in terms their possible impact on the geodetic results, i.e. the scheduling approach, treatment of the ionospheric delay, and selection of target radio sources. We showed that the major factor causing discrepancies in the estimated geodetic parameters is the different scheduling approach of the datasets. We conclude that systematic errors in MOJAVE-5 dataset are low enough for these data to be used as an excellent testbed for further investigations on the radio source structure effects in geodesy and astrometry.

Hana Krasna↗
NASA NTRS2021

A Deep Search for Five Molecules in the 49 Ceti Debris Disk

Surprisingly strong CO emission has been observed from more than a dozen debris disks around nearby main-sequence stars. The origin of this CO is unclear, in particular whether it is left over from the protoplanetary disk phase or is second-generation material released from collisions between icy bodies like debris dust. The primary unexplored avenue for distinguishing the origin of the material is understanding its molecular composition. Here we present a deep search for five molecules (CN, HCN, HCO+, SiO, and CH3OH) in the debris disk around 49 Ceti. We take advantage of the high sensitivity of the Atacama Large Millimeter/submillimeter Array at Band 7 to integrate for 3.2 hr at modest spatial (1′′) and spectral (0.8 km s−1) resolution. Our search yields stringent upper limits on the flux of all surveyed molecular lines, which imply abundances relative to CO that are orders of magnitude lower than those observed in protoplanetary disks and solar system comets, and also those predicted in outgassing models of second-generation material. However, if CI shielding is responsible for extending the lifetime of any CO produced in second-generation collisions as proposed by Kral et al., then the line ratios do not reflect true ice phase chemical abundances but rather imply that CO is shielded by its own photodissociation product, CI, and other molecules are rapidly photodissociated by the stellar and interstellar radiation field.

Debris disks↗
NASA NTRS2023

The Mid-Infrared Molecular Inventory Towards Orion IRc2

We present the first high spectral resolution mid-infrared survey in the Orion BN/KL region, covering 7.2 to 28.3μm. With SOFIA/EXES we target the enigmatic source Orion IRc2. While this is in the most prolifically studied massive star-forming region, longer wavelengths and molecular emission lines dominated previous spectral surveys. The mid-infrared observations in this work access different components and molecular species in unprecedented detail. We unambiguously identify two new kinematic components, both chemically rich with multiple molecular absorption lines. The “blue clump” has ν LSR = −7.1 ± 0.7 km s −1 and the “red clump” 1.4 ± 0.5 km s −1 . While the blue and red clump shave similar temperatures and line widths, molecular species in the blue clump have higher column densities. They are both likely linked to pure rotational H 2 emission also covered by this survey. This work provides evidence for the scenario that the blue and red clumps are distinct components unrelated to the classic components in the Orion BN/KL region. Comparison to spectroscopic surveys towards other infrared targets in the region show that the blue clump is clearly extended. We analyze, compare, and present in depth findings on the physical conditions of C 2 H 2 , 13 CCH 2 , CH 4 , CS, H 2 O, HCN, H 13 CN, HNC, NH 3 , and SO 2 absorption lines and an H 2 emission line associated with the blue and red clumps. We also provide limited analysis of H 2 O and SiO molecular emission lines towards Orion IRc2 and the atomic forbidden transitions [FeII], [SI], [SIII], and [NeII].

Atomic spectroscopy↗
NASA NTRS2023

Direct Analyses of Aqueous Fluids from C-Class Asteroid 162173 Ryugu

Imaging using X-ray absorption contrast by synchrotron nano-computed tomography (47.4 nm/voxel, 7keV) of a Ryugu pyrrhotite crystal revealed probable fluid inclusions. The inclusions were completely encapsuled in pyrrhotite, suggesting the fluids were trapped in the early stages of crystal growth, and filled with low-Z material. We performed Time-of Flight-Secondary Ion Mass Spectrometry (TOF-SIMS) depth profiling and high-resolution mapping at -120°C to exposure and measure the composition of the trapped fluids in a frozen state. These measurements revealed that the ancient, trapped fluids on Ryugu’s parent asteroid were saline aqueous solutions containing H2O, CO2, sulfur species, and nitrogen- and chlorine-bearing organic compounds identified by representative secondary ion species including O(-), OH(-), CO(-), S(-), Cl(-), C2(-), C2H(-), and CN(-). The inferred presence of CO2 indicates formation of the sulfides, and by implication the Ryugu parent body, beyond the H2O and CO2 snow lines of the early solar system, i.e. > 3-4 au from the Sun.

M Zolensky↗
NASA NTRSDate not supplied

Simulation of etch pit formation through active sites in carbon fiber micro-structures

Erosion of carbon due to oxidation does not occur uniformly but through localized etch pit formation as a result of active surface sites. In this work we demonstrate a newly developed capability to capture pitting of carbon fiber microstructures such as FiberForm, which is commonly used as the base material for NASA’s spacecraft ablative thermal protection systems (TPS). The simulations are performed at the meso-scale in order to capture the pit formation and growth using direct simulation Monte Carlo (DSMC), specifically using the Stochastic PArallel Rarefied-gas Time-accurate Analyzer (SPARTA) code. Legacy and latest models both assume uniform reactivity of carbon surface sites with oxygen even at the meso-scale level. However, in reality the carbon surface has locally different reaction rates due to the presence of defects at the atomic scale. The defective nature of these sites enhances their reactivity with atmospheric gases compared to the non-defective sites (2-3 orders of magnitude) and are termed as “active sites”. Thus, these sites tend to be the first to react and eventually get removed through the formation of gasses such as CO, CO2, and CN. Their removal results in all the neighboring atoms becoming defective, thus leading to chain reaction of localized carbon removal and formation of etch pits. Capturing the formation of pits during the ablation simulation of carbon micro-structures is critical to predicting their structural failure. Recently a detailed surface chemistry framework was developed in SPARTA, capable of incorporating various reaction mechanisms such as adsorption, desorption, Eley-Rideal (ER) and Langmuir-Hinshelwood (LH) mechanisms. We have implemented the capability of a single surface having multiple site sets with different reactivities within this framework. We have used this feature to model the presence of active sites on carbon surfaces, whose reactivity is orders of magnitude higher than that of the passive sites due to the presence of defects. The active site fraction is a property of surface elements within SPARTA and is directly proportional to the local reactivity of each surface element. By introducing an initial distribution of the active site fraction across the carbon surface and propagating it in a manner that mimics the evolution of real reacting carbon surfaces, we can capture the formation and growth of etch pits as a result of surface consumption reactions such as oxidation.

DSMC↗
NASA NTRSDate not supplied

Simulation of Etch Pit Formation in DSMC Through Active Sites in Carbon Fiber Micro-Structures

Erosion of carbon due to oxidation does not occur uniformly but through localized etch pit formation because of active surface sites. In this work we demonstrate a newly developed capability to capture pitting of carbon fiber microstructures such as FiberForm, which is commonly used as the base material for NASA’s spacecraft ablative thermal protection systems (TPS). The simulations are performed at the meso-scale in order to capture the pit formation and growth using direct simulation Monte Carlo (DSMC), specifically using the Stochastic PArallel Rarefied-gas Time-accurate Analyzer (SPARTA) code. Legacy and latest models both assume uniform reactivity of carbon surface sites with oxygen even at the meso-scale level. However, in reality the carbon surface has locally different reaction rates due to the presence of defects at the atomic scale. The defective nature of these sites enhances their reactivity with atmospheric gases compared to the non-defective sites (2-3 orders of magnitude) and are termed as “active sites”. Thus, these sites tend to be the first to react and eventually get removed through the formation of gases such as CO, CO2, and CN. Their removal results in all the neighboring atoms becoming defective, thus leading to chain reaction of localized carbon removal and formation of etch pits. Capturing the formation of pits during the ablation simulation of carbon micro-structures is critical to predicting their structural failure. Recently a detailed surface chemistry framework was developed in SPARTA, capable of incorporating various detailed surface reaction mechanisms. We have implemented the capability of a single surface having multiple site sets with different reactivities within this framework. We have used this feature to model the presence of active sites on carbon surfaces, whose reactivity is orders of magnitude higher than that of the passive sites due to the presence of defects. The active site fraction is a property of surface elements within SPARTA and is directly proportional to the local reactivity of each surface element. By introducing an initial distribution of the active site fraction across the carbon surface and propagating it in a manner that mimics the evolution of real reacting carbon surfaces, we can capture the formation and growth of etch pits as a result of surface consumption reactions such as oxidation.

DSMC↗
NASA NTRSDate not supplied

Dragonfly Entry Aerosciences Measurements (DrEAM) Suite Science Objectives

NASA Ames and Langley are partnering with DLR to propose a comprehensive instrumentation suite known as the Dragonfly Entry Aerosciences Measurements (DrEAM). DrEAM will provide key aerothermodynamic data and performance analysis for Dragonfly’s forebody and backshell Thermal Protection System (TPS), and also includes a DLR-provided Data Acquisition System (DAS). Titan's atmosphere predominantly consists of nitrogen (~ 98% by mole) with small amounts of methane (~ 2% by mole). CN is a strong radiator and is found in nonequilibrium concentrations for Titan entry, the modeling of which has proven to be a difficult task. The DrEAM instrumentation suite will significantly advance the state-of-the-art not only by documenting the environment and performance of Dragonfly’s entry system but also by making key measurements in Titan’s atmosphere for the first time, thus providing new benchmark data applicable to entry science more generally.

Aaron Brandis↗
NASA NTRSDate not supplied

DSMC Simulation of Etch Pit Formation Through Active Sites in Carbon Fiber Micro-Structures

Erosion of carbon due to oxidation does not occur uniformly but through localized etch pit formation because of active surface sites. In this work we demonstrate a newly developed capability to capture pitting of carbon fiber microstructures such as FiberForm, which is commonly used as the base material for NASA’s spacecraft ablative thermal protection systems (TPS). The simulations are performed at the meso-scale in order to capture the pit formation and growth using direct simulation Monte Carlo (DSMC), specifically using the Stochastic PArallel Rarefied-gas Time-accurate Analyzer (SPARTA) code. Legacy and latest models both assume uniform reactivity of carbon surface sites with oxygen even at the meso-scale level. However, in reality the carbon surface has locally different reaction rates due to the presence of defects at the atomic scale. The defective nature of these sites enhances their reactivity with atmospheric gases compared to the non-defective sites (2-3 orders of magnitude) and are termed as “active sites”. Thus, these sites tend to be the first to react and eventually get removed through the formation of gases such as CO, CO2, and CN. Their removal results in all the neighboring atoms becoming defective, thus leading to chain reaction of localized carbon removal and formation of etch pits. Capturing the formation of pits during the ablation simulation of carbon micro-structures is critical to predicting their structural failure. Recently a detailed surface chemistry framework was developed in SPARTA, capable of incorporating various detailed surface reaction mechanisms. We have implemented the capability of a single surface having multiple site sets with different reactivities within this framework. We have used this feature to model the presence of active sites on carbon surfaces, whose reactivity is orders of magnitude higher than that of the passive sites due to the presence of defects. The active site fraction is a property of surface elements within SPARTA and is directly proportional to the local reactivity of each surface element. By introducing an initial distribution of the active site fraction across the carbon surface and propagating it in a manner that mimics the evolution of real reacting carbon surfaces, we can capture the formation and growth of etch pits as a result of surface consumption reactions such as oxidation.

DSMC↗
NASA NTRSDate not supplied

Coupled Material Response Simulations of Dragonfly Capsule and DrEAM Reconstruction

Icarus is a three-dimensional, unstructured, finite-volume material response solver developed at NASA Ames Research Center and has been recently used to analyze the material response of the Dragonfly capsule for a variety of problems. Since the Dragonfly capsule will be instrumented in a similar manner to the Mars 2020 and MSL capsules, it is important to assess how our current simulation tools can aid in understanding Dragonfly Entry Aerosciences Measurements (DrEAM). In this presentation, the Ares multi-physics tool that couples Icarus to the flow and radiation physics of the aerothermal environment will be used to better understand how modeling sensitivities might affect environment reconstructions and our understanding of measured data. Ares couples Icarus to the US3D flow solver and NERO, a reduced-order, finite-volume radiation transport solver and uses a customized time-scale management to enable coupled simulations for a large portion of the Dragonfly trajectory. As a result of the coupling, a more accurate and consistent assessment of modelling sensitivities to aerothermal reconstruction can be assessed. For example, the radiometer is sensitive to the quantity of CN in the flow, which is a byproduct of the free-stream methane but also the pyrolysis gas products injected into the boundary layer due to ablation of the heatshield. Ares will be used to conduct a simulation of the full Dragonfly capsule for 50 seconds of the trajectory. The different aerothermal and material response models will be discussed and the key results will be presented in terms of the simulated thermocouple and radiometer measurements on the backshell.

Ablation↗
NASA NTRS2024

Measurements of Titan’s Stratospheric Winds during the 2009 Equinox with the eSMA

Saturn’s moon Titan possesses stratospheric zonal winds that places it among a sparse class of planetary bodies known to have superrotation in their atmospheres. Few measurements have been made of these speeds in the upper stratosphere, leaving their seasonal variations still not well understood. We examined observations made with the extended Submillimeter Array in 2009 March ( L s = 355°) and 2010 February ( L s = 5°), shortly before and after Titanʼs northern spring equinox. Cassini observations and atmospheric models find equinoctial periods to be especially dynamic. Zonal wind calculations, derived from the Doppler frequency shift of CH 3 CN near 349.4 GHz, yielded speeds of 128 ± 27 m s −1 in 2009 and 209 ± 48 m s −1 in 2010. We estimated the measured emission to originate from vertical altitudes of 336 +112 - 88 km, equivalent to pressures of 3.8 +19.2 -3.4 Pa, commensurate with Titan’s upper stratosphere/lower mesosphere. This suggests a possible increase in zonal speeds during this period. The results are then compared to those from previous Cassini-inferred and direct-interferometric observations of winds, as well as general circulation model simulations, to form a more complete picture of the seasonal cycle of stratospheric zonal winds.

Siobhan Light↗
NASA NTRSDate not supplied

Characterization of Titan Entry Radiative Heating in the Low Density Electric Arc Shock Tube

Prediction of aftbody radiative heating for Dragonfly’s entry at Titan requires accurate models to inform the design of its thermal protection systems. Previously reported investigations of shock layer aftbody radiation in the Electric Arc Shock Tube (EAST) at NASA Ames Research Center focused on the lower altitude/higher density part of the trajectory. This paper presents the first optical emission spectroscopy measurements of an ongoing test series in the new aluminum Low Density Shock Tube (LDST), recently installed at EAST, focusing on the radiative heating characterization through the higher altitude portion of Dragonfly’s entry path. Experimental data collected at a fill pressure of 0.1 Torr and shock velocities between 5.2 and 6.2 km/s show favorable agreement to similar conditions previously tested in the 4" High-Velocity Shock Tube, as well as improvements in the signal to noise ratio and available test time. Simulations employing DPLR and NEQAIR underpredict the experimental radiance, with increasing discrepancy from the NIR towards the UV wavelength range, thus motivating further efforts in improving the current non-Boltzmann model for the CN molecule.

A Fagnani↗
DOE OSTI2020

Low Temperature Oxidation of Methylpropyl Ether

Ethers are potential high-performance fuels that can be produced from renewable carbon sources such as biomass, but their combustion properties are not clearly understood. The cetane numbers (CN) for ethers, a measure of autoignition tendency, can range from less than 10 to greater than 100, and predictive tools based upon the molecular structures are desirable in order to focus fuel development research. In this study, we used molecular modeling, chemical kinetic modeling, and experimental measurements to understand the important reactions that lead to the autoignition of methylpropyl ether (MPE), a model for ethers containing alkyl chains long enough for intramolecular hydrogen transfer. These reactions are known to be important in the autoignition of alkanes and ethers and we propose to investigate the relationship between alkyl and ether reaction pathways. A reaction mechanism for MPE was created using MIT's Reaction Mechanism Generator (RMG) and G4 quantum calculation results and models were tested using the ChemKin Pro suite of software. Results from atmospheric pressure, flow tube reactor experiments and rapid compression machine (RCM) experiments were used to test the kinetic model and suggest refinements.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2020

Surface-modified cyanide-based transition metal compounds

A system, method, and articles of manufacture for a surface-modified transition metal cyanide coordination compound (TMCCC) composition, an improved electrode including the composition, and a manufacturing method for the composition which may include multiple chelation species (Che_x). The composition, compound, device, and uses thereof according to AxMn(y-k)Mjk[Mnm(CN)(6-p-q)(NC)p(Che_I)rq]z.CHE_GROUP (Vac)(1-z).nH2O, wherein CHE_GROUP includes one or more chelation materials selected from the group consisting of (Che_I)rw, (Che_II)sv, and combinations thereof, and wherein 0 < j≤4, 0≤k≤0.1, 0≤(p+q)≤6, 0 < x≤4, 0 < y≤1, 0 < z≤1, 0 < w≤0.2; −3≤r≤3; 0 < v≤0.2; −3≤s≤3; and 0≤n≤6; wherein x+2(y−k)+jk+(m+(r+1)q−6)z+wr+vs=0.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Surface-modified cyanide-based transition metal compounds

A system, method, and articles of manufacture for a surface-modified transition metal cyanide coordination compound (TMCCC) composition, an improved electrode including the composition, and a manufacturing method for the composition which may include multiple chelation species (Che_x). The composition, compound, device, and uses thereof according to AxMn(y-k)Mjk[Mnm(CN)(6-p-q)(NC)p(Che_I)rq]z. CHE_GROUP (Vac)(1-z).nH2O, wherein CHE_GROUP includes one or more chelation materials selected from the group consisting of (Che_I)rw, (Che_II)sv, and combinations thereof, and wherein 0 < j≤4, 0≤k≤0.1, 0≤(p+q)≤6, 0 < x≤4, 0 < y≤1, 0 < z≤1, 0 < w≤0.2; −3≤r≤3; 0 < v≤0.2; −3≤s≤3; and 0≤n≤6; wherein x+2(y−k)+jk+(m+(r+1)q−6)z+wr+vs=0.

36 MATERIALS SCIENCE↗
DOE OSTI2020

AGR-5/6/7 Capsule Leach Station Hardware Qualification - Phase 1

Procedural changes to this document shall be logged and justified using the EQP Change Log below. Typographical errors do not need to be logged, but do require the Lead Engineers initials and date. Each entry shall be numbered (i.e., CN #1) for identification in the left-hand margin of the table. Each entry may include individual or groups of related procedural changes. Changes to the EQP shall made by pen and ink and/or addition of additional pages depending on the extent of the change.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2026

Millimeter-wave Detections of Symbiotic Stars in SPT and ACT Data

We present the results of a joint targeted search of candidate symbiotic stars at millimeter wavelengths using the South Pole Telescope (SPT) and the Atacama Cosmology Telescope (ACT). Candidates are selected from the New Online Database of Symbiotic Variables, restricting to objects that are within either the SPT-3G or ACT~DR6 footprint, covering most of the southern hemisphere and up to a declination of $+20^\circ$. Forced photometry on the 828 candidate symbiotic star locations in SPT and ACT data results in 31 unique objects detected with more than a $3σ$ significance using two frequency bands: 18 confirmed and 13 suspected symbiotic stars. We provide the SPT and ACT 95/98, 150, and 220~GHz light curves, along with optical and infrared light curves from 2016--2026, as well as spectral energy distributions, physical parameters from the literature, and brief summaries regarding the nature of each individual object. Using Herschel SPIRE data from 2013, we place upper limits on millimeter flux for CN Cha near the beginning of the optical rise in its 2012/2013 nova, which suggests a strong variability and lag at millimeter wavelengths and results in a rare observance of a Galactic millimeter slow transient. In addition, we provide coadded thumbnails and light curves for the remaining 797 candidate symbiotic stars that did not pass our detection thresholds. Millimeter-wave emission from symbiotic stars is primarily a combination of free-free emission of the ionization region and optically thick blackbody emission of the cooler dust components of the system. When combined with contemporaneous multi-wavelength observations, millimeter-wave observations can be used to test binary models of symbiotic stars and provide insight on the geometry and physical properties of these systems.

Tandoi, C. [Illinois U., Urbana, Astron. Dept.] (O↗