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At least 1,171 records · Page 65
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Modeling and Investigations on Surface Colors of Wings on the Performance of Albatross-Inspired Mars Drones and Thermoelectric Generation Capabilities

Thermal effects of wing color for Albatross-inspired drones performing in the Martian atmosphere are investigated during the summer and winter seasons. This study focuses on two useful consequences of the thermal effects of wing color: the drag reduction and the thermoelectric generation of power. According to its color, each wing side has a certain temperature affecting the drag. Investigations of various configurations have shown that the thermal effect on the wing boundary layer skin drag is insignificant because of the low atmospheric pressure. However, the total drag varies as much as 12.8% between the highest performing wing color configuration and the lowest performing configuration. Additionally, the large temperature differences between the top and the bottom wing surfaces show great potential for thermoelectric power generation. The maximum temperature differences between the top and bottom surfaces for the summer and winter seasons are, respectively, 65 K and 30 K. The drag reduction and the power generation via thermoelectric generators both contribute to enhancing the endurance of drones. Future drone designs will benefit from increased endurance through optimizing the wing color configuration.

Rice, Devyn↗
DOE OSTI2022

Occurrence of Low-Level Jets over the Eastern U.S. Coastal Zone at Heights Relevant to Wind Energy

Two years of high-resolution simulations conducted with the Weather Research and Forecasting (WRF) model are used to characterize the frequency, intensity and height of low-level jets (LLJ) over the U.S. Atlantic coastal zone. Meteorological conditions and the occurrence and characteristics of LLJs are described for (i) the centroids of thirteen of the sixteen active offshore wind energy lease areas off the U.S. east coast and (ii) along two transects extending east from the U.S. coastline across the northern lease areas (LA). Flow close to the nominal hub-height of wind turbines is predominantly northwesterly and southwesterly and exhibits pronounced seasonality, with highest wind speeds in November, and lowest wind speeds in June. LLJs diagnosed using vertical profiles of modeled wind speeds from approximately 20 to 530 m above sea level exhibit highest frequency in LA south of Massachusetts, where LLJs are identified in up to 12% of hours in June. LLJs are considerably less frequent further south along the U.S. east coast and outside of the summer season. LLJs frequently occur at heights that intersect the wind turbine rotor plane, and at wind speeds within typical wind turbine operating ranges. LLJs are most frequent, intense and have lowest core heights under strong horizontal temperature gradients and lower planetary boundary layer heights.

17 WIND ENERGY↗
DOE OSTI2022

Numerical and Experimental Investigations on the Ignition Behavior of OME

On the path towards climate-neutral future mobility, the usage of synthetic fuels derived from renewable power sources, so-called e-fuels, will be necessary. Oxygenated e-fuels, which contain oxygen in their chemical structure, not only have the potential to realize a climate-neutral powertrain, but also to burn more cleanly in terms of soot formation. Polyoxymethylene dimethyl ethers (PODE or OMEs) are a frequently discussed representative of such combustibles. However, to operate compression ignition engines with these fuels achieving maximum efficiency and minimum emissions, the physical-chemical behavior of OMEs needs to be understood and quantified. Especially the detailed characterization of physical and chemical properties of the spray is of utmost importance for the optimization of the injection and the mixture formation process. The presented work aimed to develop a comprehensive CFD model to specify the differences between OMEs and dodecane, which served as a reference diesel-like fuel, with regards to spray atomization, mixing and auto-ignition for single- and multi-injection patterns. The simulation results were validated against experimental data from a high-temperature and high-pressure combustion vessel. The sprays’ liquid and vapor phase penetration were measured with Mie-scattering and schlieren-imaging as well as diffuse back illumination and Rayleigh-scattering for both fuels. To characterize the ignition process and the flame propagation, measurements of the OH* chemiluminescence of the flame were carried out. Significant differences in the ignition behavior between OMEs and dodecane could be identified in both experiments and CFD simulations. Liquid penetration as well as flame lift-off length are shown to be consistently longer for OMEs. Zones of high reaction activity differ substantially for the two fuels: Along the spray center axis for OMEs and at the shear boundary layers of fuel and ambient air for dodecane. Additionally, the transient behavior of high temperature reactions for OME is predicted to be much faster.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2022

Curled-Skewed Wakes behind Yawed Wind Turbines Subject to Veered Inflow

This work presents a new engineering analytical model that predicts the effect of both the turbine yaw misalignment and the inflow wind veer on the wake flow distribution downwind of a wind turbine. To consider the veered inflow, two methods were examined. In the first method, the curled shape of the wake due to the yaw offset is initially modelled. The wake shape is then laterally skewed at each height due to the wind veer based on the assumption that the turbine wake is transported downstream by the incoming flow. The second method is a more realistic approach that accounts for the effect of wind veer on the wind velocity direction and the yaw angle seen by the wind turbine. This models the wake region in a local coordinate system defined based on the wind direction at each height. A coordinate transformation is then performed to represent the wake flow distribution in the global coordinate system attached to the ground. The results show that while the two methods provide similar outputs for small variations in the wind direction across the rotor, the difference becomes more evident with an increase in wind veer. High-fidelity simulations for a turbine subject to a neutral atmospheric boundary layer were employed to validate model predictions for different operating conditions.

17 WIND ENERGY↗
DOE OSTI2024

Power Production, Inter- and Intra-Array Wake Losses from the U.S. East Coast Offshore Wind Energy Lease Areas

There is an urgent need to develop accurate predictions of power production, wake losses and array–array interactions from multi-GW offshore wind farms in order to enable developments that maximize power benefits, minimize levelized cost of energy and reduce investment uncertainty. New, climatologically representative simulations with the Weather Research and Forecasting (WRF) model are presented and analyzed to address these research needs with a specific focus on offshore wind energy lease areas along the U.S. east coast. These, uniquely detailed, simulations are designed to quantify important sources of wake-loss projection uncertainty. They sample across different wind turbine deployment scenarios and thus span the range of plausible installed capacity densities (ICDs) and also include two wind farm parameterizations (WFPs; Fitch and explicit wake parameterization (EWP)) and consider the precise WRF model release used. System-wide mean capacity factors for ICDs of 3.5 to 6.0 MWkm−2 range from 39 to 45% based on output from Fitch and 50 to 55% from EWP. Wake losses are 27–37% (Fitch) and 11–19% (EWP). The discrepancy in CF and wake losses from the two WFPs derives from two linked effects. First, EWP generates a weaker ‘deep array effect’ within the largest wind farm cluster (area of 3675 km2), though both parameterizations indicate substantial within-array wake losses. If 15 MW wind turbines are deployed at an ICD of 6 MWkm−2 the most heavily waked wind turbines generate an average of only 32–35% of the power of those that experience the freestream (undisturbed) flow. Nevertheless, there is no evidence for saturation of the resource. The wind power density (electrical power generation per unit of surface area) increases with ICD and lies between 2 and 3 Wm−2. Second, EWP also systematically generates smaller whole wind farm wakes. Sampling across all offshore wind energy lease areas and the range of ICD considered, the whole wind farm wake extent for a velocity deficit of 5% is 1.18 to 1.38 times larger in simulations with Fitch. Over three-quarters of the variability in normalized wake extents is attributable to variations in freestream wind speeds, turbulent kinetic energy and boundary layer depth. These dependencies on meteorological parameters allow for the development of computationally efficient emulators of wake extents from Fitch and EWP.

17 WIND ENERGY↗
DOE OSTI2024

Three-Dimensional Aerodynamics and Vortex-Shedding Characteristics of Wind Turbine Airfoils over 360-Degree Angles of Attack

In this work, we present the first three-dimensional (3D) computational investigation of wind turbine airfoils over 360° angles of attack to predict unsteady aerodynamic loads and vortex-shedding characteristics. To this end, static–airfoil simulations are performed for the FFA-W3 airfoil family at a Reynolds number of 107 with the Improved Delayed Detached Eddy Simulation turbulence model. Aerodynamic forces reveal that the onset of boundary-layer instabilities and flow separation does not necessarily coincide with the onset of stall. In addition, a comparison with two-dimensional simulation data and flat plate theory extension of airfoil polars, suggest that, in the deep stall regime, 3D effects remain critical for predicting both the unsteady loads and the vortex-shedding dynamics. For all airfoils, the vortex-shedding frequencies are found to be inversely proportional to the wake width. In the case of slender airfoils, the frequencies are nearly independent of the airfoil thickness, and their corresponding Strouhal number St is approximately 0.15. Based on the calculated St, the potential for shedding frequencies to coincide with the natural frequencies of the International Energy Agency 15 MW reference wind turbine blades is investigated. The analysis shows that vortex-induced vibrations occur primarily at angles of attack of around ±90° for all airfoils.

17 WIND ENERGY↗
DOE OSTI2023

Measurements and Prediction of Ash Deposition in a Cyclone-Fired Boiler Operating under Variable Load Conditions

Measurements of ash deposition rates were made between the secondary superheater and reheater sections of a 450 MW cyclone-fired lignite boiler as the operational load varied from 33 to 100%. Significant reductions in deposition rates with a decrease in operational load were observed. To uncover the causative mechanisms behind these observations, operational data from the power plant were used to carry out computational fluid dynamic (CFD) simulations of the boiler. After ascertaining that the gas temperatures and velocities at various sections within the boiler were being represented adequately, decoupled simulations of the ash deposition process on the deposit probe were carried out using a finely resolved boundary layer mesh. Fly ash particle size distribution (PSD) and its concentration for the decoupled calculations were determined from stand-alone cyclone barrel simulations. The ash partitioning (mass %) between the fly ash and slag was found to be ~50:50, which was in line with previous field observations, and it did not vary significantly across different cyclone loads. The predicted PSD of the deposit ash was concentrated in the size range 10–30 microns, which was in agreement with cross-sectional images of the deposit obtained from the measurements. At lower loads, sharp variations in the deposition rates were predicted in the gas temperature range 950–1150 K. The particle kinetic energy—particle viscosity-based capture methodology utilized in this study in conjunction with appropriate ash compositions, ash viscosity models and gas temperature estimates can help estimate slagging propensities at different loads reasonably well in these systems.

Krishnamoorthy, Gautham (ORCID:0000000255205092)↗
DOE OSTI2023

Detailed Simulations of a Three-Stage Supercritical Carbon Dioxide Axial Compressor with a Focus on the Shrouded Stator Cavities Flow

This paper describes the findings of detailed simulations performed to investigate the impact of seal teeth cavity leakage flow on the aerodynamic and thermal performance of a three-stage supercritical CO 2 axial compressor. The study compares a shrouded stator configuration (with cavities) to a cantilevered stator configuration (without cavities) to highlight their differences. High-fidelity computational fluid dynamics simulations were performed using non-linear harmonic (NLH) and mixing plane assumptions, considering various possible rotor/stator interface configurations for mixing plane calculations. The key performance parameters for each case were compared, and the best-performing configuration selected for further analysis. The individual stage performance parameters are also examined and compared between the cantilevered and shrouded configurations. It was observed that in the shrouded case, the leakage flow enters the cavity downstream of the stator trailing edge and gets entrained into the primary flow upstream of the stator, leading to boundary layer changes at the hub and degradation of stator and downstream rotor performance. Vortical flow structures were also observed in the stator wells, which tended to change the flow angles around the region, thereby affecting mixing and velocity distribution, resulting in a slight deterioration of compressor performance. Additionally, the study examines windage heating due to shear work from rotating walls, including the seal teeth surface. The amount of shear work done on the leakage flow and the corresponding rise in fluid temperature were quantified, tabulated, and further compared with a simple analytical model, showing good agreement between them and, hence, validating the numerical approach used.

42 ENGINEERING↗
DOE OSTI2023

Sizing and Selection of Pressure Relief Valves for High-Pressure Thermal–Hydraulic Systems

This study covers the critical concerns related to the sizing, selection, installation, maintenance, and testing of pressure safety valves (PSVs). The aim is to ensure the safety of pressurized systems, hydrostatic transmission systems, and hydraulic plants, including process plants, thermal power plants, and nuclear reactor systems. PSVs are devices that ensure the safety and reliability of pressurized vessels, lines, and systems during overpressure events. The task of selecting which PSV features are of greatest value for a specific purpose is complex—especially in the design of a high-pressure experimental thermal–hydraulic facility for hydrostatic and transient testing of the reactor system—when the systems are in the design and development phases and require qualification and demonstration to prove that they have reached a given level of technological readiness. The present study highlights the required steps for users to follow the associated rules, guidelines, and recommendations. As a part of this research, case studies are presented to help readers better understand the applicable strategy and standards. A discussion and a review of PSV performance degradation and failure are summarized to provide a better understanding of varied process applications and conditions, including fluid flow dynamics, boundary-layer formation and pressure drops, gas bubble formation and collapse, geometric configurations, inlet/outlet piping, abrupt pressure fluctuations, and acoustic resonance. Moreover, this study discusses the servicing and testing of PSVs in a multiphase pressurized system. Overall, it provides a basic overview of how PSVs ensure the safety of pressurized systems, supported by case studies and industrial practices.

02 PETROLEUM↗
DOE OSTI2022

A Novel Machine Learning Algorithm for Cloud Detection Using AERI Measurement Data

Infrared hyperspectral remote sensing has been widely used in the field of meteorology. Many scientists have carried out research on inversion methods of meteorological elements such as thermodynamic profile, boundary layer height, cloud base height, etc. In this study, a method based on machine learning for cloud detection using ground-based infrared hyperspectral radiation data is proposed. The features of outliers, the cloudy and cloud-free data of Atmospheric Emitted Radiance Interferometer (AERI) radiation are extracted. The “reference values” of cloudy and cloud-free are determined based on the observation data of Vaisala CL31 ceilometer within the time range of 8 min before the corresponding time of AERI. A support vector machine (SVM) algorithm is used for training. The dataset comes from the Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) site and North Slope Alaska (NSA) site from 2015 to 2017, and the ARM West Antarctic Radiation Experiment (AWARE) site in 2016 is also analyzed. The instruments used in this paper include AERI, ceilometer, etc. The experimental results reveal that the agreement of cloud detection results between the proposed algorithm and ceilometer is about 93% at each site. However, for high clouds or optically thin clouds, the agreement will decrease.

47 OTHER INSTRUMENTATION↗
DOE OSTI2022

Synergistic Retrieval of Temperature and Humidity Profiles from Space-Based and Ground-Based Infrared Sounders Using an Optimal Estimation Method

The atmospheric temperature and humidity profiles of the troposphere are generally measured by radiosondes and satellites, which are essential for analyzing and predicting weather. Nevertheless, the insufficient observation frequencies and low detection accuracy of the boundary layer restricts the description of atmospheric state changes by the temperature and humidity profiles. Therefore, this work focus on retrieving the temperature and humidity profiles using observations of the FengYun-4 (FY-4) Geostationary Interferometric Infrared Sounder (GIIRS) combined with ground-based infrared spectral observations from the Atmospheric Emitted Radiance Interferometer (AERI), which are more accurate than space-based individual retrieval results and have a wider effective retrieval range than ground-based individual retrieval results. Based on the synergistic observations, which are made by matching the space-based and ground-based data with those of different spatial and temporal resolutions, a synergistic retrieval process is proposed to obtain the temperature and humidity profiles at a high frequency under clear-sky conditions based on the optimal estimation method. In this research, using the line-by-line radiative transfer model (LBLRTM) as the forward model for observing simulations, a retrieval experiment was carried out in Qingdao, China, where an AERI is situated. Taking radiosonde data as a reference for comparing the retrieval results of the temperature and humidity profiles of the troposphere, the root-mean-square error (RMSE) of the synergistic retrieval algorithm below 400 hPa is within 2 K for temperature and within 12% for relative humidity. Compared with the GIIRS individual retrieval, the RMSE of temperature and relative humidity for the synergistic method is reduced by 0.13–1.5 K and 2.7–4.4% at 500 hPa, and 0.13–2.1 K and 2.5–7.2% at 900 hPa. Moreover, the forecast index (FI) calculated from the retrieval results shows reasonable consistency with the FIs calculated from the ERA5 reanalysis and from radiosonde data. The synergistic retrieval results have higher temporal resolution than space-based retrieval results and can reflect the changes in the atmospheric state more accurately. Overall, the results demonstrated the promising potential of the synergistic retrieval of temperature and humidity profiles at high accuracy and high temporal resolution under clear-sky conditions from FY-4/GIIRS and AERI.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Acoustic Tomography of the Atmosphere: A Large-Eddy Simulation Sensitivity Study

Accurate measurement of atmospheric turbulent fluctuations is critical for understanding environmental dynamics and improving models in applications such as wind energy. Advanced remote sensing technologies are essential for capturing instantaneous velocity and temperature fluctuations. Acoustic tomography (AT) offers a promising approach that utilizes sound travel times between an array of transducers to reconstruct turbulence fields. This study presents a systematic evaluation of the time-dependent stochastic inversion (TDSI) algorithm for AT using synthetic travel-time measurements derived from large-eddy simulation (LES) fields under both neutral and convective atmospheric boundary-layer conditions. Unlike prior work that relied on field observations or idealized fields, the LES framework provides a ground-truth atmospheric state, enabling quantitative assessment of TDSI retrieval reliability, sensitivity to travel-time measurement noise, and dependence on covariance model parameters and temporal data integration. A detailed sensitivity analysis was conducted to determine the best-fit model parameters, identify the tolerance thresholds for parameter mismatch, and establish a maximum spatial resolution. The TDSI algorithm successfully reconstructed large-scale velocity and temperature fluctuations with root mean square errors ( RMSE s) below 0.35 m/s and 0.12 K, respectively. Spectral analysis established a maximum spatial resolution of approximately 1.4 m, and reconstructions remained robust for travel-time measurement uncertainties up to 0.002 s. These findings provide critical insights into the operational limits of TDSI and inform future applications of AT for atmospheric turbulence characterization and system design.

17 WIND ENERGY↗
DOE OSTI2024

LES simulations of a vacuum membrane distillation channel with geometric alterations

3D LES simulations were carried out to study the performance of a vacuum membrane distillation module. A wiggly wall profile with/without embedded stiffeners was considered to alleviate axial and radial temperature polarization, the cause of performance decrease in membrane distillation. Results of the flow field show the wiggles create unsteady vortex shedding inducing intense mixing in the channel. Vortex shedding intensity increases as the Reynolds number increases or stiffeners are added. 3D results show a 56% improvement in flux when moving from a flat sheet membrane to a wiggly membrane with stiffeners at a constant Reynolds number, corresponding to an improvement from 11.7 to 41.7 in the Nusselt number, showing that the alterations improved the flux performance by enhancing the heat transfer along the membrane surface and therefore alleviating temperature polarization, a critical bottleneck in membrane distillation systems. Further, a merit criterion was defined based on the Nusselt number and friction factor, and a 40% increase in merit was shown switching from a flat to a wiggly channel, while a 97% merit increase was seen going from flat to wiggly with stiffeners. A 42% enhancement in the flux was also seen moving from a straight channel to a wiggly channel at a higher Reynolds number which highlights the importance of strategically choosing the mass flow rate, as well as inducing flow separation and vortex shedding in the channel to promote mixing and dissipate the thermal boundary layer. The variation in results between the wiggly module with stiffeners and the wiggly module at high Reynolds numbers suggests enhancing mixing structures can be more impactful on flux for this geometry than increasing the flow rate to a turbulent/transitional regime. However, both are preferable for peak system flux performance. Furthermore, a 2D approximation was used to perform simulations on more extended channels to examine the length degradation. The modules with wiggly channels performed at the same flux level with a doubling of the length. On the other hand, the flat sheet modules experienced length degradation by temperature polarization and dropped in flux yield by around 13% of the short-channel value. This work illustrates that modeling the system and understanding how the performance decreases as the membrane surface area increases are critical for a larger module (scaling up from a lab to a prototype module) to maintain high flux performance.

42 ENGINEERING↗
DOE OSTI2021

Large Eddy Simulation of the Southern Ocean

The data set contains seven Large Eddy Simulations (LES) at the Southern Ocean Flux Site for studies of deep turbulent ocean boundary layers, with and without surface wave effects, and with both idealized and observed forcing by wind, surface buoyancy flux and Stokes drift profiles. There are 20 days of hourly statistics computed every half-hour of turbulence quantities; namely, the vertical fluxes of buoyancy (temperature) and momentum, buoyancy and velocity variances, and the turbulent kinetic energy, its production terms and its dissipation.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2019

Quantifying aerosol size distributions and their temporal variability in the Southern Great Plains, USA

A quality-controlled, 5-year dataset of aerosol number size distributions (particles with diameters (Dp) from 7 nm through 14 µm) was developed using observations from a scanning mobility particle sizer, aerodynamic particle sizer, and a condensation particle counter at the Department of Energy's Southern Great Plains (SGP) site. This data set was used for two purposes. First, typical characteristics of the aerosol size distribution (number, surface area, and volume) were calculated for the SGP site, both for the entire dataset and on a seasonal basis, and size distribution lognormal fit parameters are provided. While the median size distributions generally had similar shapes (four lognormal modes) in all the seasons, there were some significant differences between seasons. These differences were most significant in the smallest particles(Dp<30 nm) and largest particles (Dp>800 nm).Second, power spectral analysis was conducted on this long-term dataset to determine key temporal cycles of total aerosol concentrations, as well as aerosol concentrations in specified size ranges. The strongest cyclic signal was associated with a diurnal cycle in total aerosol number concentrations that was driven by the number concentrations of the smallest particles(Dp<30 nm). This diurnal cycle in the smallest particles occurred in all seasons in ~50% of the observations,suggesting a persistent influence of new particle formation events on the number concentrations observed at the SGP site. This finding is in contrast with earlier studies that suggest new particle formation is observed primarily in the springtime at this site. The timing of peak concentrations associated with this diurnal cycle was shifted by several hours depending on the season,which was consistent with seasonal differences in insolation and boundary layer processes. Significant diurnal cycles in number concentrations were also found for particles with Dp between 140 and 800 nm, with peak concentrations occurring in the overnight hours, which were primarily associated with both nitrate and organic aerosol cycles. Weaker cyclic signals were observed for longer timescales (days to weeks) and are hypothesized to be related to the timescales of synoptic weather variability. The strongest periodic signals (3.5–5 and 7 d cycles) for these longer timescales varied depending on the season, with no cyclic signals and the lowest variability in the summer.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Radiative heating rate profiles over the southeast Atlantic Ocean during the 2016 and 2017 biomass burning seasons

Marine boundary layer clouds, including the transition from stratocumulus to cumulus, are poorly represented in numerical weather prediction and general circulation models. Further uncertainties in the cloud structure arise in the presence of biomass burning carbonaceous aerosol, as is the case over the southeast Atlantic Ocean, where biomass burning aerosol is transported from the African continent. As the aerosol plume progresses across the southeast Atlantic Ocean, radiative heating within the aerosol layer has the potential to alter the thermodynamic environment and therefore the cloud structure; however, limited work has been done to quantify this along the trajectory of the aerosol plume in the region. The deployment of the first Atmospheric Radiation Measurement (ARM) Mobile Facility (AMF1) in support of the Layered Atlantic Smoke Interactions with Clouds field campaign provided a unique opportunity to collect observations of cloud and aerosol properties during two consecutive biomass burning seasons during July through October of 2016 and 2017 over Ascension Island (7.96° S, 14.35° W). Using observed profiles of temperature, humidity, and clouds from the field campaign alongside aerosol optical properties from Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA-2), as input for the Rapid Radiation Transfer Model (RRTM), profiles of the radiative heating rate due to aerosols and clouds were computed. Radiative heating is also assessed across the southeast Atlantic Ocean using an ensemble of back trajectories from the Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model. Idealized experiments using the RRTM with and without aerosols and a range of values for the single-scattering albedo (SSA) demonstrate that shortwave (SW) heating within the aerosol layer above Ascension Island can locally range between 2 and 8 K d -1 depending on the aerosol optical properties, though impacts of the aerosol can be felt elsewhere in the atmospheric column. When considered under clear conditions, the aerosol has a cooling effect at the TOA, and based on the observed cloud properties at Ascension Island, the cloud albedo is not large enough to overcome this. Shortwave radiative heating due to biomass burning aerosol is not balanced by additional longwave (LW) cooling, and the net radiative impact results in a stabilization of the lower troposphere. However, these results are extremely sensitive to the single-scattering albedo assumptions in models.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Vertical profiles of light absorption and scattering associated with black carbon particle fractions in the springtime Arctic above 79° N

Despite the potential importance of black carbon (BC) for radiative forcing of the Arctic atmosphere, vertically resolved measurements of the particle light scattering coefficient (σ sp ) and light absorption coefficient (σ ap ) in the springtime Arctic atmosphere are infrequent, especially measurements at latitudes at or above 80° N. Here, relationships among vertically distributed aerosol optical properties (σap, σsp and single scattering albedo or SSA), particle microphysics and particle chemistry are examined for a region of the Canadian archipelago between 79.9 and 83.4° N from near the surface to 50 hPa. Airborne data collected during April 2015 are combined with ground-based observations from the observatory at Alert, Nunavut and simulations from the Goddard Earth Observing System (GEOS) model, GEOS-Chem, coupled with the TwO-Moment Aerosol Sectional (TOMAS) model (collectively GEOS-Chem–TOMAS; Kodros et al., 2018) to further our knowledge of the effects of BC on light absorption in the Arctic troposphere. The results are constrained for σsp less than 15 Mm -1 , which represent 98% of the observed σsp, because the single scattering albedo (SSA) has a tendency to be lower at lower σsp, resulting in a larger relative contribution to Arctic warming. At 18.4 m 2 g -1 , the average BC mass absorption coefficient (MAC) from the combined airborne and Alert observations is substantially higher than the two averaged modelled MAC values (13.6 and 9.1 m2 g -1 ) for two different internal mixing assumptions, the latter of which is based on previous observations. The higher observed MAC value may be explained by an underestimation of BC, the presence of small amounts of dust and/or possible differences in BC microphysics and morphologies between the observations and model. In comparing the observations and simulations, we present σap and SSA, as measured, and σ ap 2 and the corresponding SSA to encompass the lower modelled MAC that is more consistent with accepted MAC values. Median values of the measured σap, rBC and the organic component of particles all increase by a factor of 1.8±0.1, going from near-surface to 750 hPa, and values higher than the surface persist to 600 hPa. Modelled BC, organics and σap agree with the near-surface measurements but do not reproduce the higher values observed between 900 and 600 hPa. The differences between modelled and observed optical properties follow the same trend as the differences between the modelled and observed concentrations of the carbonaceous components (black and organic). Model-observation discrepancies may be mostly due to the modelled ejection of biomass burning particles only into the boundary layer at the sources. For the assumption of the observed MAC value, the SSA range between 0.88 and 0.94, which is significantly lower than other recent estimates for the Arctic, in part reflecting the constraint of σsp<15 Mm -1 . The large uncertainties in measuring optical properties and BC, and the large differences between measured and modelled values here and in the literature, argue for improved measurements of BC and light absorption by BC and more vertical profiles of aerosol chemistry, microphysics and other optical properties in the Arctic.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Model bias in simulating major chemical components of PM 2.5 in China

High concentrations of PM 2.5 (particulate matter with an aerodynamic diameter less than 2.5 µm) in China have caused severe visibility degradation. Accurate simulations of PM 2.5 and its chemical components are essential for evaluating the effectiveness of pollution control strategies and the health and climate impacts of air pollution. In this study, we compared the GEOS-Chem model simulations with comprehensive datasets for organic aerosol (OA), sulfate, nitrate, and ammonium in China. Model results are evaluated spatially and temporally against observations. The new OA scheme with a simplified secondary organic aerosol (SOA) parameterization significantly improves the OA simulations in polluted urban areas, highlighting the important contributions of anthropogenic SOA from semivolatile and intermediate-volatility organic compounds. The model underestimates sulfate and overestimates nitrate for most of the sites throughout the year. More significant underestimation of sulfate occurs in winter, while the overestimation of nitrate is extremely large in summer. The model is unable to capture some of the main features in the diurnal pattern of the PM 2.5 chemical components, suggesting inaccuracies in the presented processes. Potential model adjustments that may lead to a better representation of the boundary layer height, the precursor emissions, hydroxyl radical concentrations, the heterogeneous formation of sulfate and nitrate, and the wet deposition of nitric acid and nitrate have been tested in the sensitivity analysis. The results show that uncertainties in chemistry perhaps dominate the model biases. The proper implementation of heterogeneous sulfate formation and the good estimates of the concentrations of sulfur dioxide, hydroxyl radical, and aerosol liquid water are essential for the improvement of the sulfate simulation. The update of the heterogeneous uptake coefficient of nitrogen dioxide significantly reduces the modeled concentrations of nitrate. However, the large overestimation of nitrate concentrations remains in summer for all tested cases. The possible bias in the chemical production and the wet deposition of nitrate cannot fully explain the model overestimation of nitrate, suggesting issues related to the atmospheric removal of nitric acid and nitrate. A better understanding of the atmospheric nitrogen budget, in particular, the role of the photolysis of particulate nitrate, is needed for future model developments. Moreover, the results suggest that the remaining underestimation of OA in the model is associated with the underrepresented production of SOA.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗