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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,153 records · Page 64
All sourcesNASA NTRSDOE OSTI
NASA NTRS1993

Comparison of Stratospheric Aerosol and Gas Experiment II and balloon-borne stratospheric water vapor measurements

The Stratospheric Aerosol and Gas Experiment II has one channel at 940 nm related to water vapor. Two inversion procedures were developed independently in order to obtain the water vapor profile: the Chahine method by the Langley Research Center, and the Mill method by the Laboratoire d'Optique Atmospherique. Comparisons were made between these two algorithms and some results are presented at midlatitudes (about 45 deg N) and tropical latitudes (12-25 deg S). They are compared with in situ frost point hygrometer data provided by balloon experiments from the Laboratoire de Meteorologie Dynamique. At +/- 0.5 ppmv, agreement between the inversion results and the experimental results was obtained in the altitude range from 18-19 to 26-27 km. Below 18-19 km and above 26-27 km the error is larger (sometimes 1 ppmv and more).

Pruvost, P.↗
NASA NTRS1991

Growth of thin films of organic nonlinear optical materials by vapor growth processes - An overview and examination of shortfalls

Research on the growth of second- and third-order nonlinear optical (NLO) organic thin film by vapor deposition is reviewed. Particular attention is given to the experimental methods for growing thin films of p-chlorophenylurea, diacetylenes, and phthalocyanines; characteristics of the resulting films; and approaches for advancing thin film technology. It is concluded that the growth of NLO thin films by vapor processes is a promising method for the fabrication of planar waveguides for nonlinear optical devices. Two innovative approaches are proposed including a method of controlling the input beam frequency to maximize nonlinear effects in thin films and single crystals, and the alternate approach to the molecular design of organic NLO materials by increasing the transition dipole moment between ground and excited states of the molecule.

Frazier, D. O.↗
NASA NTRS1993

Absorption coefficients for water vapor at 193 nm from 300 to 1073 K

Measurements of the water absorption coefficient at 193 nm from 300 to 1073 K are reported. The measurements were made using broadband VUV radiation and a monochromator-based detection system. The water vapor was generated by a saturator and metered into a flowing, 99 cm absorption cell via a water vapor mass flow meter. The 193 nm absorption coefficient measurements are compared to room temperature and high temperature shock tube measurements with good agreement. The absorption can be parameterized by a nu3 vibrational mode reaction coordinate and the thermal population of the nu3 mode.

Kessler, W. J.↗
NASA NTRS1992

Millimeter-wave imaging radiometer for cloud, precipitation and atmospheric water vapor studies

A millimeter-wave imaging radiometer (MIR) developed by NASA Goddard Space Flight Center is described. The MIR is a nine-channel total power radiometer developed for atmospheric research. Three dual-pass band channels are centered about the strongly opaque 183-GHz water vapor absorption line; the frequencies are 183 +/- 1, +/- 3, and +/- 7 GHz. Another channel is located on the wing of this band at 150 GHz. These four channels have varying degrees of opacity from which the water vapor profile can be inferred. The design and salient characteristics of this instrument are discussed, together with its expected benefits.

Racette, P. E.↗
NASA NTRS1993

Effects of detailed droplet heating models on turbulent sprays vaporization behavior

The effects of three different droplet heating models on the vaporization history and internal structure of turbulent liquid fuel sprays were investigated. The models considered were the infinite-diffusion, diffusion-limit, and effective-conductivity models. A numerical solution for the models was developed and implemented in the KIVA-II computer code. Low temperature and relatively high temperature numerical studies were conducted. The low temperature computations were compared with existing experimental data. The comparisons showed that while the infinite-diffusion and diffusion-limit models respectively overpredicted and underpredicted the fuel vapor peak concentration and distribution in the combustor, the effective-conductivity model gave results that were in better agreement with measurements. A limited study for the high temperature case was performed due to lack of experimental data and predictions using the three models were compared with each other.

Mawid, M. A.↗
NASA NTRS1993

One-parameter scaling and exponential-sum fitting for water vapor and CO2 infrared transmission functions

A medium-sized band model for water vapor and CO2 absorption is developed using the one-parameter scaling approximation. The infrared spectrum is divided into 10 bands. The Planck-weighted diffuse transmittance is reduced to a function dependent only upon the scaled absorber amount and fit by an exponential sum. By selecting specific sets of absorption coefficients for exponential-sum fitting, computations of fluxes and cooling rate are made very fast. Compared to a broadband model, the accuracy, speed, and versatility are all enhanced. With absorption due to water vapor line, continuum, CO2 as well as O3 included, the parameterization introduces an error of less than 1.5 W/sq m in fluxes and less than 0.15 C/day in the tropospheric and lower stratospheric cooling rates.

Chou, Ming-Dah↗
NASA NTRS1993

A comparison of observed (HALOE) and modeled (CCM2) methane and stratospheric water vapor

Recent measurements (21 September-15 October 1992) of methane and water vapor by the Halogen Occultation Experiment (HALOE) on the Upper Atmosphere Research Satellite (UARS) are compared with model results for the same season from a troposphere-middle atmosphere version of the National Center for Atmospheric Research (NCAR) Community Climate Model (CCM2). Several important features of the two constituent fields are well reproduced by the CCM2, despite the use of simplified methane photochemistry in the CCM2 and some notable differences between the model's zonal mean circulation and climatology. Observed features simulated by the model include the following: 1) subsidence over a deep layer in the Southern Hemisphere polar vortex; 2) widespread dehydration in the polar vortex; and 3) existence of a region of low water vapor mixing ratios extending from the Antarctic into the Northern Hemisphere tropics, which suggests that Antarctic dehydration contributes to midlatitude and tropical dryness in the stratosphere.

Mote, Philip W.↗
NASA NTRS1991

Chemical vapor deposition coatings for oxidation protection of titanium alloys

Results of an experimental investigation of the oxidation protection afforded to Ti-14Al-21Nb and Ti-14Al-23Nb-2V titanium aluminides and Ti-17Mo-3Al-3Nb titanium alloy by aluminum-boron-silicon and boron-silicon coatings are presented. These coatings are applied by a combination of physical vapor deposition (PVD) and chemical vapor deposition (CVD) processes. The former is for the application of aluminum, and the latter is for codeposition of boron and silicon. Coating thickness is in the range of 2 to 7 microns, and coating weights are 0.6 to 2.0 mg/sq cm. Oxidation testing was performed in air at temperatures to 1255 K in both static and hypersonic flow environments. The degree of oxidation protection provided by the coatings is determined from weight change measurements made during the testing and post test compositional analyses. Temperature-dependent total normal emittance data are also presented for four coating/substrate combinations. Both types of coatings provided excellent oxidation protection for the exposure conditions of this investigation. Total normal emittances were greater than 0.80 in all cases.

Cunnington, G. R.↗
NASA NTRS1932

Preliminary Tests on the Vaporization of Fuel Sprays

High-speed motion pictures were taken of fuel sprays injected into the combustion chamber of the N.A.C.A. combustion apparatus. Three fuels, ethyl alcohol, gasoline, and fuel oil, which differed considerably in volatility were tested. By maintaining the engine temperature below that required for ignition the spray could be studied from soon after the start of injection until 130 crank degrees later. The results show that the sprays vaporize appreciably so that it is possible for the ignition in high speed compression-ignition engines to take place from the vapor phase.

Rothrock, A M↗
NASA NTRS1955

Performance of a single fuel-vaporizing combustor with six injectors adapted for gaseous hydrogen

The combustor was operated over a range of inlet-air pressures from 5.3 to 24.0 inches of mercury absolute and inlet-air reference velocities from 60 to 100 feet per second. The combustion efficiencies obtained with the six configurations varied from about 65 to 95 percent for a combustor temperature-rise range of 200 degrees to 1400 degrees F. At a temperature rise of 1200 degrees F (near-rated engine conditions), the spread in efficiencies of the six configurations was about 5 percent. Efficiencies in the range of 65 to 85 percent were obtained at operating conditions beyond the burning range of conventional jet fuels. A fuel-injector configuration that fed only gaseous hydrogen fuel into the standard liquid-fuel-vaporizing tubes generally gave the highest efficiencies. This configuration minimizes the possibility of combustion in the fuel-vaporizing tubes and could be easily adapted to the full-scale engine combustor.

Wear, Jerrold D↗
NASA NTRS1926

Experimental investigation of the physical properties of medium and heavy oils, their vaporization and use in explosion engines. Part IV

This report presents a theoretical treatment of the vaporization process of medium and heavy oils. The results of this investigation, which were mostly obtained from the lighter components of the heavy fuels, require a 10- or 16-fold vaporization in comparison with gasoline. We must attain a still finer degree of atomization, in order to include the heavier components.

OILS↗
NASA NTRS1994

Comparison Of Measurments Of Atmospheric Water Vapor

Report presents experimental intercomparison among measurements by four spectrometric instruments for determining concentration of atmospheric water vapor. Three instruments ground-based and needed to provide independent data to calibrate and validate measurements taken by fourth instrument, which is airborne visible/infrared imaging spectrometer (AVIRIS). Remote down-looking instruments like AVIRIS increases accuracy and coverage of water-vapor measurements.

Bruegge, Carol J.↗
NASA NTRS1993

Impact melting and vaporization in planetary regoliths

The thermal phenomena attending high-velocity impact have profound effects on virtually every aspect of the physical, chemical, and optical evolution of planetary regoliths. Not only do impacts pulverize, redistribute, and mix the various components of a regolith, but they also fuse and vaporize them - changing crystalline material to glass, releasing trapped or implanted gases, and spreading vaporized products across the planet's surface, among many other things. Those wishing to understand the details of regolith evolution must incorporate the effects of impact into their approach to the problem. Derived from a more extensive contribution, a short summary of the thermal processes accompanying impact into planetary regoliths, with the immediate acknowledgment that it is neither exhaustive in its consideration of the existing literature nor exact in any of its treatments, is presented. The reader desiring more information is directed to the relevant papers cited at the end; should they fail to provide satisfaction, he or she is then heartily encouraged to attack the problem immediately.

Cintala, Mark J.↗
NASA NTRS1992

Separation of cirrus cloud from clear surface from AVIRIS data using the 1.38 micron water vapor band

Cirrus clouds play an important role in climate systems because of their large area coverage, persistence, and radiative effects. Thin cirrus clouds are difficult to detect in visible images and infrared images in the 10-12 micron atmospheric window region, particularly over land, because these clouds are partially transparent. Ackerman recently developed a method for detecting cirrus clouds using three narrow channels centered near 8, 11, and 12 microns, respectively, based on the analysis of IR emission spectra measured with a high spectral resolution interferometer. Barton also described a method for estimating cirrus cloud height and amount from measurements with two narrow channel radiometers of the Selective Chopper Radiometer on Nimbus 5. Both channels are located within the strong 2.7 micron water vapor band absorption region. One of the channels includes additional carbon dioxide absorption. A differential absorption technique with sets of empirical coefficients was used in the estimation of cirrus cloud heights and amounts. A technique using narrow channels in the strong 1.38 micron water vapor band absorption region for detecting cirrus clouds from spectral imaging data acquired by the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) on 5 Dec. 1991 during the FIRE (The First International Satellite Cloud Climatology Project (ISCCP) Regional Experiment) Phase 2 Field Experiment is described.

Gao, Bo-Cai↗
NASA NTRS1992

Analysis of satellite-derived ozone and water vapor measurements

Research under this grant has involved analyses of satellite-derived measurements of water vapor and total ozone. Upper tropospheric water vapor data from the Nimbus 7 temperature-humidity infrared radiometer (THIR) 6.7 micron channel were analyzed by Fourier transformation to provide wavenumber spectra for a case of an upper level system over Europe. The power law spectrum for horizontal scales from 60 to several hundred km suggests that when convective cloud energy sources are not present, the enstrophy-cascading process (with variance proportional to the minus three power of wavenumber) may hold to much smaller scales than previously thought. Several investigations of the middle atmosphere (stratosphere and mesosphere) were also conducted. Slow atmospheric oscillations with periods of 1-2 months were investigated in total ozone measurements and in ionospheric data. Using one-point correlation maps and total ozone mapping spectrometer (TOMS) data, strong statistical evidence was found for the planetary-scale oscillations at these periods. A dipole-like pattern in the tropical equatorial Indian ocean-western Pacific region was documented, along with wavetrain-like patterns emanating into the extratropics. While attempting to follow the oscillations upward above stratosphere, oscillations were studied in ionospheric data (D-region radio wave absorption, in the upper mesosphere, around 80-90 km altitude). Cross-spectral analyses with solar flux data revealed that much of the observed 1-2 month variance in the ionospheric D-region was well correlated to solar variations. Further research has involved investigations of the photochemical lifetime of greenhouse gases methane and nitrous oxide. Using Nimbus 7 satellite data, a new analysis technique was employed to determine the lifetime of these gases in situ in the upper stratosphere. The lifetimes are found to be in good agreement with theoretical estimates.

Stanford, John L.↗
NASA NTRS1993

Growth of zinc selenide single crystals by physical vapor transport in microgravity

The goals of this research were the optimization of growth parameters for large (20 mm diameter and length) zinc selenide single crystals with low structural defect density, and the development of a 3-D numerical model for the transport rates to be expected in physical vapor transport under a given set of thermal and geometrical boundary conditions, in order to provide guidance for an advantageous conduct of the growth experiments. In the crystal growth studies, it was decided to exclusively apply the Effusive Ampoule PVT technique (EAPVT) to the growth of ZnSe. In this technique, the accumulation of transport-limiting gaseous components at the growing crystal is suppressed by continuous effusion to vacuum of part of the vapor contents. This is achieved through calibrated leaks in one of the ground joints of the ampoule. Regarding the PVT transport rates, a 3-D spectral code was modified. After introduction of the proper boundary conditions and subroutines for the composition-dependent transport properties, the code reproduced the experimentally determined transport rates for the two cases with strongest convective flux contributions to within the experimental and numerical error.

Rosenberger, Franz↗
NASA NTRS1993

LOX droplet vaporization in a supercritical forced convective environment

Modern liquid rocket engines often use liquid oxygen (LOX) and liquid hydrogen (LH2) as propellants to achieve high performance, with the engine operational conditions in the supercritical regimes of the propellants. Once the propellant exceeds its critical state, it essentially becomes a puff of dense fluid. The entire field becomes a continuous medium, and no distinct interfacial boundary between the liquid and gas exists. Although several studies have been undertaken to investigate the supercritical droplet behavior at quiescent conditions, very little effort has been made to address the fundamental mechanisms associated with LOX droplet vaporization in a supercritical, forced convective environment. The purpose is to establish a theoretical framework within which supercritical droplet dynamics and vaporization can be studied systematically by means of an efficient and robust numerical algorithm.

Hsiao, Chia-Chun↗