Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “stratospheric”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,153 records · Page 64
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

Concentration of carbon monoxide in the upper stratosphere

The concentration of telluric carbon monoxide has been determined in the upper stratosphere from infrared solar spectra recorded by balloon in October 1978 and September 1979, over Texas. The average mixing ratios were found to be (2.1 plus or minus 3) x 10 to the -8th ppv and (3.7 plus or minus 0.4) x 10 the the -8th ppv above the float altitudes of 30.6 and 36.8 km, respectively. The concentration profile deduced from all the measurements indicates that the CO mixing ratio increases in the upper stratosphere, from (1 plus or minus 0.3) x 10 to the -8th ppv at 30.6 km, to about 4 x 10 to the -8th ppv above 41 km.

Zander, R.↗
NASA NTRS1981

Particles above the tropopause - Measurements and models of stratospheric aerosols, meteoric debris, nacreous clouds, and noctilucent clouds

An outline is presented of the present status of knowledge of stratospheric aerosols, meteoric debris, nacreous clouds, and noctilucent clouds. Considerable progress has been made in studies of these particles during the previous decade and it is appropriate to synthesize the information to provide a background for studies planned for the 1980s. Numerical models of the formation, growth, and evolution are considered and a description is given of the physical processes involved, taking into account aspects of nucleation, coagulation, condensational growth, sedimentation, and questions of dynamical transport. A schematic outline of the physical and chemical processes included in a model of stratospheric aerosols is provided.

Toon, O. B.↗
NASA NTRS1981

Natural variability of tropical upper stratospheric ozone inferred from the Atmosphere Explorer backscatter ultraviolet experiment

Analysis of backscattered ultraviolet radiances observed at tropical latitudes by the Atmosphere Explorer-E satellite reveals both annual and semiannual cycles in upper stratospheric ozone. The annual variation dominates the signal at wavelengths which sense ozone primarily above 45 km while below this, to the lowest altitude sensed, 35 km, the semiannual component has comparable amplitude. Comparison of radiance measurements taken with the same instrument at solar minimum during 1976 and solar maximum in 1979 show no significant differences. This suggests that variations in upper stratospheric ozone over the solar cycle are small, although the data presently available do not allow a definite conclusion.

Frederick, J. E.↗
NASA NTRS1981

Implications of smaller concentrations of stratospheric OH - A two-dimensional model study of ozone perturbations

There is growing observational evidence that stratospheric OH concentrations are smaller than models have been predicting. Using very recent HOx reaction rate coefficient measurements in a two-dimensional photochemical model, results which support these observations are obtained. As a consequence of smaller OH concentrations, we show that perturbations of stratospheric ozone by NOx (SST emissions and nitrogen fertilizers) may be larger than expected, while perturbations due to added water vapor and chlorine (SSTs and chlorofluoromethanes, respectively) may be smaller.

Whitten, R. C.↗
NASA NTRS1981

Measurement of heavy ozone in the stratosphere

The distribution of heavy ozone (molecular mass 50) has been measured for the first time in the stratosphere with a mass spectrometer system. During a balloon descent after midnight on September 4, 1980, a pronounced enhancement of heavy ozone was found. The maximum in the isotopic ratio, (O-18)(O-16)2/(O-16)3, occurred at 32 km where the enhancement of heavy ozone was over 40%. The ratio decreased toward higher and lower altitudes, and reached the standard value below 24 km. These measurements confirm an earlier prediction that there exists a preferred production mechanism for heavy ozone in the stratosphere.

Mauersberger, K.↗
NASA NTRS1981

Simultaneous spectroscopic determination of the latitudinal, seasonal, and diurnal variability of stratospheric N2O, NO, NO2, and HNO3

A program for the measurement of latitudinal, seasonal, and diurnal variations in stratospheric N2O, NO, NO2 and HNO3 is described, which uses airborne Fourier transform absorption spectroscopy to simultaneously determine columns, above 12 km, of the four molecules. The data may prove useful for comparison with two-dimensional models of stratospheric chemistry, since simultaneous measurement of several species with the same technique provides an inherently more reliable set for model comparisons, by eliminating uncorrelated atmospheric variability and reducing differences in instrumental biases.

Coffey, M. T.↗
NASA NTRS1981

Satellite and correlative measurements of the stratospheric aerosol. I An optical model for data conversions

A description is presented of an empirically based model of stratospheric aerosol optical properties (size distributions and refractive indices) and their variations. The need for such a model arose in the data validation and archival programs for two satellite sensors, SAM II and SAGE. These programs require the ability to convert measurements of a given aerosol macroproperty (e.g., volume extinction coefficient, volume backscatter coefficient, particle number or mass per unit volume) to best estimates of other aerosol macroproperties, and to assess quantitatively the uncertainties in the conversion process. The described model provides the information on size distributions, refractive indices and their variations necessary for these tasks, and also defines a procedure for combining the model information with empirical data in a way that facilitates automatic data processing. Although the model was developed for use in the satellite validation and archival programs, it also has proven useful in other studies of stratospheric aerosol.

Russell, P. B.↗
NASA NTRS1981

Satellite and correlative measurements of the stratospheric aerosol. II Comparison of measurements made by SAM II, dustsondes and airborne lidar

Results are shown from the first set of measurements conducted to validate extinction data from the Stratospheric Aerosol Measurement II (SAM II). Dustsonde-measured number density profiles and lidar-measured backscattering profiles for two days are converted to extinction profiles, and are shown to agree within their respective uncertainties at all heights above the tropopause. Near the tropopause, agreement depends on use of model size distributions with larger particles, having radii greater than 0.6 microns. The presence of such large particles is supported by measurements made elsewhere, is suggested by the in situ size distribution measurements reported, and is likely to have an important bearing on the radiative impact of the total stratospheric aerosol. It is concluded that the SAM II extinction data and uncertainty estimates are supported.

Russell, P. B.↗
NASA NTRS1981

Measurement of trace levels of chlorine in the stratosphere

Mathematical models of stratospheric ozone have predicted a reduction in the total ozone due to chlorofluoromethanes released into the atmosphere. Analytical procedures for the collection of air in the stratosphere and for analysis of these air samples for trace levels of chlorine, regardless of the state of chemical composition were developed. Calibration experiments are conducted in order to validate all methods and procedures. Results of neutron activation analysis calibration procedures using standard chlorine gases are included.

Warren, D. C.↗
NASA NTRS1981

Spectroscopic detection of stratospheric hydrogen cyanide

A number of features have been identified as absorption lines of hydrogen cyanide in infrared spectra of stratospheric absorption obtained from a high-altitude aircraft. Column amounts of stratospheric hydrogen cyanide have been derived from spectra recorded on eight flights. The average vertical column amount above 12 kilometers is 7.1 + or - 0.8 x 10 to the 14th molecules per square centimeter, corresponding to an average mixing ratio of 170 parts per trillion by volume.

Coffey, M. T.↗
NASA NTRS1981

Inversion technique for IR heterodyne sounding of stratospheric constituents from space platforms

The techniques which have been employed for inversion of IR heterodyne measurements for remote sounding of stratospheric trace constituents usually rely on either geometric effects based on limb-scan observations (i.e., onion peel techniques) or spectral effects by using weighting functions corresponding to different frequencies of an IR spectral line. An experimental approach and inversion technique are discussed which optimize the retrieval of concentration profiles by combining the geometric and the spectral effects in an IR heterodyne receiver. The results of inversions of some synthetic CIO spectral lines corresponding to solar occultation limb scans of the stratosphere are presented, indicating considerable improvement in the accuracy of the retrieved profiles. The effects of noise on the accuracy of retrievals are discussed for realistic situations.

Abbas, M. M.↗
NASA NTRS1981

Stratospheric measurements of continuous absorption near 2400 per cm

Measurements of continuous absorption near 2400 per cm by N2 and CO2 over long path lengths in the lower stratosphere are presented. The continua were measured in a stratospheric solar spectrum obtained during sunset with a balloon-borne Michelson interferometer in the 2380-2500 per cm region, and transmittances were calculated by ratioing the amplitudes to those of a high-sun spectrum in order to eliminate the wavelength dependence of the measured flux. Comparison of the measured transmittances with those calculated for a multilayered atmospheric model using laboratory absorption measurements results in a fair agreement, and reveals the primary component of the absorption throughout most of the range to be N2, with the CO2 contribution equal to that of N2 only at the CO2 band head. In this region, the shape of the continuum is very sensitive to the sub-Lorentzian line shape assumed in the calculations, and so, if the shape of the N2 continuum at low temperatures can be determined through laboratory measurements, may be used to infer air-broadened far-wing CO2 line shape.

Rinsland, C. P.↗
NASA NTRS1981

Solar UV variability - Effects on stratospheric ozone, trace constituents and thermal structure

The effect of long-term (11-year solar cycle) solar UV variability on stratospheric chemical and thermal structure has been studied using a time-dependent one-dimensional model. Previous studies have suggested substantial variations in local and total ozone, and in stratospheric thermal structure from solar minimum to solar maximum. It is shown that significant variations also occur in some of the trace constituents. Members of the HOx family and N2O exhibit the largest variations, and these changes, if detected, may provide additional means of verifying the presence of solar UV variability and its effects. Some of the species show large phase differences with the assumed solar flux variation. The role of chemical and transport time constants on the time variations of the trace species is examined. Comparisons with reported ozone and temperature data show reasonable agreement for the period 1960 to 1972.

Natarajan, M.↗
NASA NTRS1981

The transport of trace chemicals by planetary waves in the stratosphere. I Steady waves

When dissipation is present a forced planetary wave will interact with the zonal flow in the stratosphere and cause acceleration of the zonal wind, mean-zonal diabatic heating and net transport of trace chemicals. Quasi-geostrophic scaling is used to derive expressions relating the above quantities to each other and to wave statistics for steady-state conditions and Newtonian cooling. Numerical calculations are presented for stationary wavenumber 1 which indicate that in the stratosphere the effect of the wave on the mean-zonal quantities is 1/5 to 1/20 that required by observations and models. In the mesosphere the calculated value is roughly 1/20 the required size. Reasons for this discrepancy are discussed.

Kurzeja, R. J.↗
NASA NTRS1982

Solar irradiance in the stratosphere - Implications for the Herzberg continuum absorption of O2

A set of solar irradiance observations is analyzed that were performed from the third Solar Absorption Balloon Experiment (SABE-3) as the payload ascended through the stratosphere from 32 to 39 km. Comparison of these data with calculations of the attenuated irradiance based on simultaneous ozone and pressure measurements made from the payload suggests a refinement of the cross section values used in photochemical models. More ultraviolet radiation in the 200-210 nm spectral region reaches the middle stratosphere than is predicted by the absorption data presently available. It is suggested that significantly smaller values for the Herzberg continuum of O2 be used in future models.

Frederick, J. E.↗
NASA NTRS1982

Stratospheric measurements of collision-induced absorption by molecular oxygen

High-resolution stratospheric solar absorption spectra recorded at sunset with a balloon-borne interferometer, from an altitude of 33 km, are used in a study of collision-induced absorption by the fundamental vibration-rotation band of O2, whose continuum has been identified in the 1400-1700/cm region in spectra obtained at tangent altitudes below 22 km. It is found that transmittance measurements in intervals free of atmospheric line absorption agree with values calculated with the O2 absorption coefficients of Timofeyev and Tonkov (1978), and that the measurements indicate a 20% upper limit for the uncertainty of the available O2 absorption coefficients at lower stratospheric temperatures, on the order of 220 K.

Rinsland, C. P.↗
NASA NTRS1982

Temperature dependence of the formation of sulfate aerosols in the stratosphere

Classical nucleation theory is used in calculations of the temperature dependence of the characteristics and nucleation rates of sulfate aerosols in the binary H2SO4-H2O vapor mixture, in order to assess the influence of temperature on the formation of sulfate aerosols in the stratosphere, and to explore the possibility of new particle formation through homogeneous nucleation processes at regions where temperature is as low as -75 C, rather than the often-assumed -50 or -55 C. Calculation results indicate that the number of particles formed at a lower temperature is larger by several orders of magnitude than at higher temperatures, when water and sulfuric acid vapor concentrations are kept constant, and that large quantities of ultrafine particles which cannot be detected by conventional methods may exist at low-temperature stratospheric regions.

Yue, G. K.↗
NASA NTRS1982

Stratospheric aerosols - Observation and theory

Important chemical and physical roles of aerosols are discussed, and properties of stratospheric aerosols as revealed by experimental data are described. In situ measurements obtained by mechanical collection and scattered-light detection yield the overall size distribution of the aerosols, and analyses of preserved aerosol precursor gases by wet chemical, cryogenic and spectroscopic techniques indicate the photochemical sources of particle mass. Aerosol chemical reactions including those of gaseous precursors, those in aqueous solution, and those on particle surfaces are discussed, in addition to aerosol microphysical processes such as nucleation, condensation/evaporation, coagulation and sedimentation. Models of aerosols incorporating such chemical and physical processes are presented, and simulations are shown to agree with measurements. Estimates are presented for the potential aerosol changes due to emission of particles and gases by aerospace operations and industrial consumption of fossil fuels, and it is demonstrated that although the climatic effects of existing levels of stratospheric aerosol pollution are negligible, potential increases in those levels might pose a future threat.

Turco, R. P.↗