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At least 1,153 records · Page 64
All sourcesNASA NTRSDOE OSTI
NASA NTRS2024

Evolving Particles in the 2022 Hunga-Tonga Hunga-Ha’apai Volcano Eruption Plume

The Multi-angle Imaging SpectroRadiometer (MISR) aboard NASA’s Terra satellite observed the Hunga Tonga—Hunga Ha’apai (HTHH) 15 January eruption plume on eight occasions between 15 and 23 January 2022. From the MISR multi-angle, multi-spectral imagery we retrieve aerosol plume height geometrically, along with plume-level motion vectors, and derive radiometrically constraints on particle effective size, shape, and light-absorption properties. Parts of two downwind aerosol layers were observed in different places and times, one concentrated in the upper troposphere (11-18 km ASL), and a mid-stratosphere layer~23 –30+ km ASL. After the initial day (1/15), the retrievals identified only spherical, non-light-absorbing particles, typical of volcanic sulfate/water particles. The near-tropopause plume particles show constant, medium-small (several tenths of a micron) effective size over four days. The mid-stratosphere particles were consistently smaller, but retrieved effective particle size increased between 1/17 and 1/23, though they might have decreased slightly on 1/22. As a vast amount of water was also injected into the stratosphere by this eruption, models predicted relatively rapid sulfate particle growth from the modest amounts of SO2 gas injected by the eruption to high altitudes along with the water (Zhu et al, 2022). MISR observations up to ten days after the eruption are consistent with these model predictions. The possible decrease in stratospheric particle size after initial growth was likely caused by evaporation, as the plume mixed with drier, ambient air. Particles in the lower-elevation plume observed on 1/15 were larger than all the downwind aerosols and contained significant non-spherical (likely ash) particles.

aerosol plume height↗
NASA NTRSDate not supplied

Tracking the Hunga Tonga-Hunga Ha’apai Eruption Stratospheric Aerosol and Trace Gas Plumes Using Machine Learning

The Hunga Tonga-Hunga Ha’apai (HTHH) submarine volcano had an explosive eruption phase on January 15, 2022, that thrusted ash, gases, and water vapor through the troposphere and into the stratosphere. The stratospheric volcanic plume included aerosol precursor gases such as SO2 and H2S as well as anomalously high water vapor concentrations due to the submarine oceanic origin. With these atmospheric constituents, the sulfuric gases and water vapor formed sulfate (SO4) particles via gas-to-particle reactions and these aerosols likely increased in size due to hygroscopic growth within anomalously humid regions. Strong easterlies and gravity waves propagated the volcanic impacts throughout the stratosphere. Orbital and suborbital passive sensor retrievals detected changes in the aerosol and trace gas characteristics within the atmospheric column for cloud-free regions over the southern hemisphere. While the CALIPSO lidar can detect aerosol layers in the stratosphere, passive sensors such as MODIS retrieved the total column aerosol abundance and characteristics. Previous studies used manual tracking methods to determine volcanic plume positions and compared them to ground observations. In this study, we examine the machine learning (ML) approaches including segmentation, object detection, and object tracking to identify and track aerosol and trace gas plumes using orbital and suborbital sensor data. This ML implementation strives to provide a more systematic approach to separate total column effects from those of the stratosphere. Similar ML tracking may be useful for stratospheric impact events observed historically by CALIPSO and in the future with EarthCare and the Atmosphere Observing System (AOS) lidar-capable missions.

Rhys Leahy↗
DOE OSTI2011

FY 2011 4th Quarter Metric: Estimate of Future Aerosol Direct and Indirect Effects

The global and annual mean aerosol direct and indirect effects, relative to 1850 conditions, estimated from CESM simulations are 0.02 W m-2 and -0.39 W m-2, respectively, for emissions in year 2100 under the IPCC RCP8.5 scenario. The indirect effect is much smaller than that for 2000 emissions because of much smaller SO2 emissions in 2100; the direct effects are small due to compensation between warming by black carbon and cooling by sulfate.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2012

Electrochemical Membrane for Carbon Dioxide Separation and Power Generation

uelCell Energy, Inc. (FCE) has developed a novel system concept for separation of carbon dioxide (CO2) from greenhouse gas (GHG) emission sources using an electrochemical membrane (ECM). The salient feature of the ECM is its capability to produce electric power while capturing CO2 from flue gas, such as from an existing pulverized coal (PC) plant. Laboratory scale testing of the ECM has verified the feasibility of the technology for CO2 separation from simulated flue gases of PC plants as well as combined cycle power plants and other industrial facilities. Recently, FCE was awarded a contract (DE-FE0007634) from the U.S. Department of Energy to evaluate the use of ECM to efficiently and cost effectively separate CO2 from the emissions of existing coal fired power plants. The overarching objective of the project is to verify that the ECM can achieve at least 90% CO2 capture from flue gas of an existing PC plant with no more than 35% increase in the cost of electricity (COE) produced by the plant. The specific objectives and related activities planned for the project include: 1) conduct bench scale tests of a planar membrane assembly consisting of ten or more cells of about 0.8 m2 area each, 2) develop the detailed design for an ECM-based CO2 capture system applied to an existing PC plant, and 3) evaluate the effects of impurities (pollutants such as SO2, NOx, Hg) present in the coal plant flue gas by conducting laboratory scale performance tests of the membrane. The results of this project are anticipated to demonstrate that the ECM is an advanced technology, fabricated from inexpensive materials, based on proven operational track records, modular, scalable to large sizes, and a viable candidate for >90% carbon capture from existing PC plants. In this paper, the fundamentals of ECM technology including: material of construction, principal mechanisms of operation, carbon capture test results and the benefits of applications to PC plants will be presented.

Jolly, Stephen↗
DOE OSTI2015

A Community Emissions Data System (CEDS) for Historical Emissions

Historical emission estimates for anthropogenic aerosol and precursor compounds are key data needed for Earth system models, climate models, and atmospheric chemistry and transport models; both for general analysis and assessment and also for model validation through comparisons with observations. Current global emission data sets have a number of shortcomings, including timeliness and transparency. Satellite and other earth-system data are increasingly available in near real-time, but global emission estimates lag by 5-10 years. The CEDS project will construct a data-driven, open source framework to produce annually updated emission estimates. The basic methodologies to be used for this system have been used for SO2 (Smith et al. 2011, Klimont, Smith and Cofala 2013), and are designed to complement existing inventory efforts. The goal of this system is to consistently extend current emission estimates both forward in time to recent years and also back over the entire industrial era. The project will produce improved datasets for global and (potentially) regional model, allow analysis of trends across time, countries, and sectors of emissions and emission factors, and facilitate improved scientific analysis in general. Consistent estimation of uncertainty will be an integral part of this system. This effort will facilitate community evaluation of emissions and further emission-related research more generally.

Smith, Steven J.↗
DOE OSTI2015

Synthesis and characterization of low viscosity carbon dioxide binding organic liquids for flue gas clean up

Climate change is partly attributed to global anthropogenic carbon dioxide (CO2) emission to the atmosphere. These environmental effects can be mitigated by CO2 capture, utilization and storage. Alkanolamine solvents, such as monoethanolamine (MEA), which bind CO2 as carbamates or bicarbonate salts are used for CO2 capture in niche applications. These solvents consist of approximately 30 wt% of MEA in water, exhibiting a low, CO2-rich viscosity, fast kinetics and favorable thermodynamics. However, these solvents have low CO2 capacity and high heat capacity of water, resulting in prohibitively high costs of thermal solvent regeneration. Effective capture of the enormous amounts of CO2 produced by coal-fired plants requires a material with high CO2 capacity and low regeneration energy requirements. To this end, several water-lean transformational solvents systems have been developed in order to reduce these energy penalties. These technologies include nano-material organic hybrids (NOHMs), task-specific, protic and conventional ionic liquids, phase change solvents. As part of an ongoing program in our group, we have developed new water lean transformational solvents known as CO2 binding organic liquids (CO2BOLs) which have the potential to be energy efficient CO2 capture solvents. These solvents, also known as switchable ionic liquids meaning, are organic solvents that can reversibly transform from non- ionic to ionic form and back. The zwitterionic state in these liquids is formed when low polarity non-ionic alkanolguanidines or alkanolamidines react with CO2 or SO2 to form ionic liquids with high polarity. These polar ionic liquids can be thermally converted to the less polar non-ionic solvent by releasing CO2.

Koech, Phillip K.↗
DOE OSTI2018

Impacts of Future Electricity Generation on Greenhouse Gases and Air Quality in the Rocky Mountain Region

This study shows that emissions from the future scenarios for the Rocky Mountain region vary in space and time, with important implications for local air quality. In scenarios with expensive natural gas or GHG fees to promote renewable energy, wind energy plays a key role in emissions reductions in the fall and spring seasons when the wind resources are abundant and competitive to fossil fuels. The greenhouse gas fees scenario reduces annual emissions of CO2, SO2, and NOx by around 40% on an annual basis. However, emissions in the summer do not change as much between scenarios mainly because of high electricity demand and reduced wind energy resources. The impacts of emissions due to the electricity generation scenarios for summertime ozone can be significant in areas near coal power plants depending on the day, but overall changes are smaller in the summer compared to other seasons.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2018

Is Every kWh the Same? How Do Energy Efficiency Measures Stack Up Across Regions?

The U.S. residential building sector is responsible for thirty-eight percent of electricity use, as well as for 49%, 8%, 19% and 2% of U.S. SO2, NOx, CO2 and PM2.5 emissions, respectively. The residential building sector is also a key target of customer funded energy efficiency programs, which have typically been designed to reduce energy consumption (kWh). Today, energy efficiency is also being used to meet air emissions goals. However, not every kWh saved has the same mitigation potential. The goal of this work is to evaluate energy efficiency potential in the U.S. residential building sector and determine how energy conservation measures (ECMs) that reduce electricity consumption correlate to air emissions reductions. To assess energy efficiency potential, this analysis uses Scout, a software program developed by the U.S. Department of Energy that estimates the energy and CO2 impact potential of various ECMs on the U.S. residential and commercial building sectors. Here, Scout is first used to assess the total long term national energy (electricity, gas, and oil), CO2, and cost savings of deploying residential ECM portfolios. Then, electricity savings results from Scout in 2021 are used to assess the regional differences in emissions reductions with the Avoided Emissions and geneRation Tool (AVERT) model from different end uses. Better understanding the relationship between ECMs and cost-effective emission reductions will enable states, municipalities and other interested parties to meet multiple policy objectives through energy efficiency.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2020

Environmental impact of national and subnational carbon policies in China based on a multi-regional dynamic CGE model

Carbon policies are important not only for mitigating global climate change, but also for controlling local and regional air pollution. The large regional disparities in economic development and air pollution across China calls for regionally differentiated policies. Previous studies have not systematically investigated the environmental impacts of regional carbon policies in China covering different spatial scales. This study constructs a multi-regional dynamic computable general quilibrium (CGE) model covering 30 provinces of China to assess the impacts of national and subnational carbon polices on CO2 emissions and co-emitted air pollutants from 2020 to 2050. We consider one national carbon policy which aims to achieve China’s 2030 national CO2 abatement target, as well as three regional policies with the same policy stringency as the national one but only applied to eastern China (EP), the Jiangsu-Shanghai-Zhejiang area (JSZP), and the Beijing-Tianjin-Hebei area (BTHP), respectively. We find that regional policies (EP, JSZP, and BTHP) are as effective in reducing CO2 emissions in their targeted regions as the national policy. However, they lead to an increase in CO2 emissions in untargeted regions (the so-called “emissions leakage”). The CO2 leakage rates, which depend on the policy spatial coverage, are 4%, 13%, and 65% for EP, JSZP, and BTHP, respectively, in 2050. Compared with CO2, changes in air pollutant emissions, including sulfur dioxide (SO2), nitrogen oxides (NOx), volatile organic compounds (VOC), and fine particulate matter (PM2.5), exhibit a similar pattern under all policy scenarios, but the magnitude of change is significantly smaller. Transportation, thermal power, and some energy intensive industries are the three largest contributors to CO2 and air pollutant emission reductions. Our results suggest that regional carbon policy is effective in reducing CO2 and air pollutant emissions in the targeted regions, and extending the spatial coverage or increasing policy stringency can largely inhibit emissions leakage.

Zhang, Wenwen↗
DOE OSTI2015

A Community Emissions Data System (CEDS) for Historical Emissions

Historical emission estimates for anthropogenic aerosol and precursor compounds are key data needed for Earth system models, climate models, and atmospheric chemistry and transport models; both for general analysis and assessment and also for model validation through comparisons with observations. Current global emission data sets have a number of shortcomings, including timeliness and transparency. Satellite and other earth-system data are increasingly available in near real-time, but global emission estimates lag by 5-10 years. The CEDS project will construct a data-driven, open source framework to produce annually updated emission estimates. The basic methodologies to be used for this system have been used for SO2 (Smith et al. 2011, Klimont, Smith and Cofala 2013), and are designed to complement existing inventory efforts. The goal of this system is to consistently extend current emission estimates both forward in time to recent years and also back over the entire industrial era. The project will produce improved datasets for global and (potentially) regional model, allow analysis of trends across time, countries, and sectors of emissions and emission factors, and facilitate improved scientific analysis in general. Consistent estimation of uncertainty will be an integral part of this system. This effort will facilitate community evaluation of emissions and further emission-related research more generally.

Smith, Steven J.↗
DOE OSTI2021

SO3/H2SO4 continuous real-time sensor demonstration at a power plant

We present results from field testing of a new, innovative sensor developed to measure SO3/H2SO4 continuously and in real time at a coal-fired power plant. The system utilizes the sensitivity, specificity, and real-time capabilities of mid-infrared (Mid-IR) laser-based sensor technology, along with a heated, close-coupled cell mounted directly to a power plant duct. Measurements were made by the laser sensor over a 2-day period and compared to results from the accepted method, EPA 8A, which requires a 30-minute collection, labor intensive processing, and off-site analysis at a lab. In contrast to the condensation method, the laser sensor continuously samples flue gas and reports measurements of the concentration of SO3/H2SO4, SO2 ever second with unattended operation. This initial demonstration proved the sensor concept and paves the way for its use for optimizing sorbent injection used to neutralize SO3/H2SO4. Optimized sorbent injection will enable significant cost savings associated with efforts to mitigate the presence and effects of SO3/H2SO4 such as “Blue Plume”, air heater fouling, and duct corrosion. In particular, the real-time, actionable information will enable better control of additive injection in flex conditions and variable fuels.

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2022

Hazmat Incident in New Mexico: Sulfur Dioxide Alarm

Sandia National Laboratories (SNL) is a multimission laboratory located in Albuquerque, New Mexico, and is one of three National Nuclear Security Administration research and development laboratories located in the United States. Recently, SNL’s Emergency Response Team (ERT) responded to an incident involving a sulfur dioxide (SO2)-fixed monitor, setting off the alarm inside a laboratory and in the adjacent hallway. The potential sources for the alarm were various experiments involving batteries and an uninterrupted power supply (UPS) in the immediate area.

99 GENERAL AND MISCELLANEOUS↗
DOE OSTI2023

Computationally Guided Design of Multiple Impurities Tolerant Cathode for Solid Oxide Fuel Cell Applications

Solid oxide fuel cells (SOFCs) have been recognized as promising candidates in the demand of reducing the dependence on fossil fuels, which is one of the solutions to the threat of global warming. It was reported that the direct chemical-to-electrical energy conversion in SOFCs comes with negligible emission of greenhouse gases and up to 60% working efficiency. SOFC has unique advantages over traditional power generation technologies and other types of fuel cells due to the use of relatively inexpensive materials, low sensitivity to poisoning impurities in fuels, relatively high conversion efficiency, and fuel flexibility (like carbon-based fuels). However, during the SOFC operation, the cathode is exposed to intrinsic and extrinsic airborne contaminants at high temperatures (600–900°C), leading to their reaction with electrode materials, irreversible chemical and structural changes, and electrochemical performance degradation. of which CO2, SO2, Cr6+ and H2O are known to be concerns. Thus, developing a comprehensive understanding of the multiple impurities poisoning of SOFC cathodes in the presence of single or multiple impurities is necessary to address the long-term degradation of the SOFC cathode systems at operating conditions. An integrated computational and experimental approach has been utilized in the current work aiming at the comprehensive investigation of the cathode materials under single or multiple impurities poisoning effects, understanding the multiple impurities poisoning mechanism(s), and improving the long-term durability of the SOFC cathodes to develop better performing impurity-tolerant cathode materials. We first examined the agreement between the simulation approach and the experimental observations at various atmospheric and temperature conditions to confirm the reliability of CALPHAD for poisoning simulations in these cathodes. Then, using this approach, we investigated the accelerated testing protocol, which has become the standard method for conducting impurity poisoning experiments involving these cathode materials. We found our simulation approach is able to predict in which systems, i.e., cathode material and treatment environment, the accelerated testing protocols reflect actual operating conditions. Finally, in-depth simulations were done for these three candidate cathodes under different experimental conditions and suggested directions toward alternative cathode materials that have superior impurity tolerance.

36 MATERIALS SCIENCE↗
DOE OSTI2025

A Framework for Assessing Economic and Environmental Trade-offs of Internalized Emission Costs in ERCOT Grid Planning

The power grid is on the cusp of a massive transition driven by three major areas: 1) the growth in demand for electricity, 2) efforts to decarbonize the United States economy, and 3) a desire to mitigate social disparities from the impact of electricity generation on local populations. However, most studies of the electricity sector do not include equity impacts in their models. This study seeks to do so by developing a comprehensive and generalizable model tailored to the Electric Reliability Council of Texas (ERCOT) grid, designed to incorporate the equity impacts of electricity generation in a decarbonized and resilient framework. To integrate equity into our research, we incorporate environmental externalities into our capacity expansion model of ERCOT. Specifically, we factor in intermediate-level local marginal damages of precursor pollutants (NH3, NOx, primary PM2.5, SO2, and VOC) and global pollutant CO2 into the cost of generating electricity. We do this by taking into account county population, county ambient pollution concentration, and generator emission rates. Leveraging open-source modeling tools, such as PowerGenome, pyGRETA, and GenX we construct a county-level model to account for these costs. We integrate these marginal damages into the variable operations and maintenance costs of generators, for both existing and potential future builds. This study’s findings suggest that the value of a dynamic social cost of carbon (SSC) will cover criteria pollutant marginal damages within the ERCOT grid and solar and wind is expected to increase out to 2035. Key metrics evaluated within this research include fuel mix distribution across technologies, transmission and grid infrastructure costs, CO2 emissions, local pollutants marginal damages, and the variation in generation capacity built by the model. These results and framework can be used to support grid decisions that explicitly include distributional and procedural equity within a decarbonized and sustainable grid framework.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2012

aosso2

ARM Instrument: Sulfur Dioxide Monitor

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

A {Ni 12 }-Wheel-Based Metal-Organic Framework for Coordinative Binding of Sulphur Dioxide and Nitrogen Dioxide

Air pollution by SO 2 and NO 2 has caused significant risks on the environment and human health. Understanding the mechanism of active sites within capture materials is of fundamental importance to the development of new clean-up technologies. We report the crystallographic observation of reversible coordinative binding of SO 2 and NO 2 on open Ni II sites in a metal-organic framework (NKU-100) incorporating unprecedented {Ni 12 }-wheels; each wheel exhibits six open Ni II sites on desolvation. Immobilised gas molecules are further stabilised by cooperative host-guest interactions comprised of hydrogen bonds, π∙∙∙π interactions and dipole interactions. At 298 K and 1.0 bar, NKU-100 shows adsorption uptakes of 6.21 and 5.80 mmol g -1 for SO 2 and NO 2 , respectively. Dynamic breakthrough experiments have confirmed the selective retention of SO 2 and NO 2 at low concentrations under dry conditions. This work will inspire the future design of efficient sorbents for the capture of SO 2 and NO 2 .

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2017

Performance of density functionals for modeling vapor liquid equilibria of CO 2 and SO 2

Vapor liquid equilibria (VLE) and condensed phase properties of carbon dioxide and sulfur dioxide are calculated using first principles Monte Carlo (FPMC) simulations to assess the performance of several density functionals, notably PBE-D3, BLYP-D3,PBE0-D3, M062X-D3, and rVV10. GGA functionals were used to compute complete vapor liquid coexistence curves (VLCCs) to estimate critical properties, while the hybrid and nonlocal vander Waals functionals were used only for computing density at a single state point due to the high computational cost. Our results show that the BLYP-D3 functional performs well in predicting VLE properties for both molecules when compared with other functionals. In the liquid phase, pair correlation functions reveal that there is not a significant difference in the location of the peak for the first solvation shell while the peak heights are different for different functionals. Altogether, theBLYP-D3 functional is a good choice for modeling VLE of acidic gases with significant environmental implications such as CO 2 and SO 2 .

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗