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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,153 records · Page 64
All sourcesNASA NTRSDOE OSTI
NASA NTRS1988

Polymer powder prepregging: Scoping study

Early on, it was found that NEAT LARC-TPI thermoplastic polyimide powder behaved elastoplastically at pressures to 20 ksi and temperatures to 260 degrees celcius (below MP). At high resin assay, resin powder could be continuously cold-flowed around individual carbon fibers in a metal rolling mill. At low resin assay (2:1, C:TPI), fiber breakage was prohibitive. Thus, although processing of TPI below MP would be quite unique, it appears that the polymer must be melted and flowed to produce low resin assay prepreg. Fiber tow was spread to 75 mm using a venturi slot tunnel. This allowed intimate powder/fiber interaction. Two techniques were examined for getting room temperature powder onto the room temperature fiber surface. Electrostatic powder coating allows the charged powder to cling tenaciously to the fiber, even while heated with a hot air gun to above its melt temperature. A variant of the wet slurry coating process was also explored. The carbon fibers are first wetted with water. Then dry powder is sprinkled onto the wet tow and doctor-rolled between the fibers. The wet structure is then taken onto a heated roll, with hot air guns drying and sinter-melting the powder onto the fiber surfaces. In both cases SEM shows individual fibers coated with powder particles that have melted in place and flowed along the fiber surface via surface tension.

Throne, James L.↗
DOE OSTI2024

Temperature-Dependent Mechanical Anisotropy in Textured Zircaloy Cladding

This work evaluates deformation activity in textured zircaloy-4 cladding with the aim of elucidating the mechanisms that govern mechanical behavior across a temperature range anticipated in reactor service. In particular, the dependence of mechanical anisotropy on temperature and stress state (ratio of applied stresses) is examined via uniaxial and biaxial tensile experiments at room temperature and 400 °C. The mechanical behavior was interpreted based on micro-texture and dominant slip system activity. Thermal activation of basal systems is found as a key mechanism affecting mechanical behavior across the temperature range. The biaxial stress states produce resolved shear stresses contrasting to uniaxial stress states. As a result, mechanical testing and implications for reactor pellet-cladding mechanical interaction stress conditions are discussed.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2021

A Low-Temperature Structural Transition in Canfieldite, Ag 8 SnS 6 , Single Crystals

Canfieldite, Ag 8 SnS 6 , is a semiconducting mineral notable for its high ionic conductivity, photosensitivity, and low thermal conductivity. In this paper, we report the solution growth of large single crystals of Ag 8 SnS 6 of mass up to 1 g from a ternary Ag–Sn–S melt. On cooling from high temperature, Ag 8 SnS 6 undergoes a known cubic ($F\bar{4}3m$) to orthorhombic ($Pna2_1$) phase transition at ≈460 K. By studying the magnetization and thermal expansion between 5–300 K, we discover a second structural transition at ≈120 K. Single crystal X-ray diffraction reveals the low-temperature phase adopts a different orthorhombic structure with space group $Pmn2_1$ ($\textit{a}$ = 7.662 9(5) Å, $\textit{b}$ = 7.539 6(5) Å, $\textit{c}$ = 10.630 0(5) Å, Z = 2 at 90 K) that is isostructural to the room-temperature forms of the related Se-based compounds Ag 8 SnSe 6 and Ag 8 GeSe 6 . The 120 K transition is first-order and has a large thermal hysteresis. On the basis of the magnetization and thermal expansion data, the room-temperature polymorph can be kinetically arrested into a metastable state by rapidly cooling to temperatures below 40 K. We last compare the room- and low-temperature forms of Ag8SnS6 with its argyrodite analogues, Ag 8 TQ 6 ($\textit{T}$ = Si, Ge, Sn; $\textit{Q}$ = S, Se), and identify a trend relating the preferred structures to the unit cell volume, suggesting smaller phase volume favors the $Pna2_1$ arrangement. We support this picture by showing that the transition to the $Pmn2_1$ phase is avoided in Ge alloyed Ag 8 Sn 1–x Ge x S 6 samples as well as in pure Ag 8 GeS 6 .

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Organoammonium-Ion-based Perovskites Can Degrade to Pb 0 via Amine–Pb(II) Coordination

The degradation of alkylammonium Pb II halide perovskites, in the dark and upon irradiation near room temperature, involves coordinated amine as the dominant reducing agent to yield Pb o near room temperature, as determined by X-ray photoelectron spectroscopy (XPS). The reduction of Pb II first involves amine coordination, supported by 207 Pb nuclear magnetic resonance (NMR) analysis. It is shown that a Pb II –amide complex is the immediate precursor of Pb II reduction. Its oxidized counterpart, the imine, is formed and is characterized by NMR and gas chromatography–mass spectrometry. Here, the “redox” process requires a β-C–H bond of the alkylamine. Amine species devoid of this moiety do not similarly reduce Pb II to Pb o . The conversion of an alkylammonium moiety to the Pb II –amide is proposed to occur through a sequence of photoassisted proton-transfer reactions to a lead-coordinated ligand, which is substantiated through XPS-observed Pb II reduction in a family of lead bromide/iodide 2D perovskites.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Sound speed and refractive index of amorphous CaSiO3 upon pressure cycling to 40 GPa

Abstract Brillouin spectroscopy at room temperature and pressures up to 40 GPa documents nearly identical elasticity and refractive index of amorphous CaSiO3 created by two different methods: temperature-quenching the melt at ambient pressure and pressure-amorphizing crystalline wollastonite at room temperature. We find reproducible hysteresis of 0 to 8% on pressure cycling that is small relative to the 30 to 60% changes in shear and longitudinal wave velocities over this pressure range. Together with observed changes in refractive index and previous results from Raman spectroscopy, these measurements reveal a continuous and reversible change in atomic packing induced by pressure. Unlike many other silicate glasses, amorphous CaSiO3 exhibits highly reproducible properties, behaving smoothly and reversibly under pressure cycling and possessing similar structure and elasticity regardless of synthesis paths for the starting material, which suggests that the amorphous solid may mimic the liquid over the pressure range investigated.

Geochemistry & Geophysics↗
NASA NTRS1972

Compressive strength of titanium alloy skin-stringer panels selectively reinforced with boron-aluminum composite.

Description of a method of selectively reinforcing conventional titanium airframe structure with unidirectional boron-aluminum composite attached by brazing which has been successfully demonstrated based on compression tests of short skin-stringer panels. Improvements in structural performance exceeded 25% on an equivalent weight basis over the range from room temperature to 800 F, both in terms of initial buckling and maximum strengths. Room-temperature performance was not affected by prior exposure at 600 F for 1000 hours in air, or by 400 cycles between -65 and 600 F. The experimental results were generally predictable on the basis of existing analytical procedures. No evidence of failure was observed in the braze bond between the boron-aluminum composite and the titanium alloy.

Herring, H. W.↗
NASA NTRS1986

Tensile behavior of Fe-40Al alloys with B and Zr additions

Both Fe-40Al and Fe-40Al-0.1Zr with and without B were produced by the hot extrusion of powdered metal. Tensile properties were determined from room temperature to 1100 K in air. All of the materials possessed some ductility at room temperature, and addition of B caused an increase in ductility and a change in fracture mode from intergranular to transgranular cleavage. At high temperatures, failure was caused primarily by the formation of grain boundary cavities in all of the alloys. The effect of Zr addition was unclear because of the complexity of the various microstructures. Comparison of air and vacuum testing at high temperatures revealed that an apparent oxidation assisted mechanism reduced high temperature ductility in these alloys, especially at 900 K.

Gaydosh, D. J.↗
NASA NTRS1994

MODIS airborne simulator visible and near-infrared calibration, 1991 FIRE-Cirrus field experiment. Calibration version: FIRE King 1.1

Calibration of the visible and near-infrared channels of the MODIS Airborne Simulator (MAS) is derived from observations of a calibrated light source. For the 1991 FIRE-Cirrus field experiment, the calibrated light source was the NASA Goddard 48-inch integrating hemisphere. Laboratory tests during the FIRE Cirrus field experiment were conducted to calibrate the hemisphere and from the hemisphere to the MAS. The purpose of this report is to summarize the FIRE-Cirrus hemisphere calibration, and then describe how the MAS was calibrated from observations of the hemisphere data. All MAS calibration measurements are presented, and determination of the MAS calibration coefficients (raw counts to radiance conversion) is discussed. Thermal sensitivity of the MAS visible and near-infrared calibration is also discussed. Typically, the MAS in-flight is 30 to 60 degrees C colder than the room temperature laboratory calibration. Results from in-flight temperature measurements and tests of the MAS in a cold chamber are given, and from these, equations are derived to adjust the MAS in-flight data to what the value would be at laboratory conditions. For FIRE-Cirrus data, only channels 3 through 6 were found to be temperature sensitive. The final section of this report describes comparisons to an independent MAS (room temperature) calibration by Ames personnel using their 30-inch integrating sphere.

Arnold, G. Thomas↗
NASA NTRS2004

High-Accuracy Surface Figure Measurement of Silicon Mirrors at 80 K

This report describes the equipment, experimental methods, and first results at a new facility for interferometric measurement of cryogenically-cooled spherical mirrors at the Goddard Space Flight Center Optics Branch. The procedure, using standard phase-shifting interferometry, has an standard combined uncertainty of 3.6 nm rms in its representation of the two-dimensional surface figure error at 80, and an uncertainty of plus or minus 1 nm in the rms statistic itself. The first mirror tested was a concave spherical silicon foam-core mirror, with a clear aperture of 120 mm. The optic surface was measured at room temperature using standard absolute techniques; and then the change in surface figure error from room temperature to 80 K was measured. The mirror was cooled within a cryostat. and its surface figure error measured through a fused-silica window. The facility and techniques will be used to measure the surface figure error at 20K of prototype lightweight silicon carbide and Cesic mirrors developed by Galileo Avionica (Italy) for the European Space Agency (ESA).

Blake, Peter↗
NASA NTRS1985

Effect of hot isostatic pressing on the properties of sintered alpha silicon carbide

Two lots of alpha silicon carbide were isostatically hot-pressed under 138 MPa for 2 h in Ar at temperatures up to 2200 C. Nearly theoretically dense specimens resulted. Hot isostatic pressing increased both room-temperature strength and 1200 C strength, and resulted in improved reliability. One lot of material which was pressed at 2200 C showed increases of about 20 percent in room-temperature strength and about 50 percent in 1200 C flexural strength; the Weibull modulus improved about 100 percent.

Watson, G. K.↗
NASA NTRS2001

High Temperature Elastic Properties of Single Crystal Mullite (Approximately 2.5Al2O3.SiO2) by Brillouin Spectroscopy

The complete elastic tensor of mullite has been determined by brillouin spectroscopy at room temperature and elevated temperatures up to 1200C. Equivalent, isotropic moduli (bulk, shear, and Young's) have been calculated. The room temperature values obtained using Voigt-Reuss-Hill averaging are: K(sub VRH) = 173.5 + 6.9 GPa, G(sub VRH) = 88.0 + 3.5 GPa, E(sub VRH) = 225.9 + 9.0 GPa. All moduli show relatively gradual decreases with temperature. The temperature derivatives obtained for the equivalent, isotropic moduli are: dK(sub VRH)/dT = - 17.5 + 2.5 MPa/deg. C, dG(sub VRH)/dT = -8.8 + 1.4 MPa/deg. C, dE(sub VRH)/dT = -22.6 + 2.8 MPa/deg C. Substantial differences between bulk properties calculated from the single crystal measurements in this study and the properties reported in the literature for polycrystalline sintered mullite are identified, indicating the importance of factors such as microstructure, intergranular phases, and composition to the elasticity of mullite ceramics.

Palko, James W.↗
NASA NTRS1976

Observations on the relationship of structure to the mechanical properties of thin TD-NiCr sheet

A study of the relationship between structure and mechanical properties of thin TD-NiCr sheet indicated that the elevated temperature tensile, stress-rupture, and creep strength properties are dependent on grain aspect ratio and sheet thickness. In general, the strength properties increase with increasing grain aspect ratio and sheet thickness. Tensile testing revealed an absence of ductility at elevated temperatures (not less than 1144 K). Significant creep damage as determined by subsequent tensile testing at room temperature occurs after very small amounts (less than 0.1%) of prior creep deformation over the temperature range 1144-1477 K. A threshold stress for creep appears to exist. Creep exposure below the threshold stress at T not less than 1366 K results in almost full retention of room temperature tensile properties.

Whittenberger, J. D.↗
DOE OSTI2022

Thermal stability of antiferroelectric-like Al:HfO 2 thin films with TiN or Pt electrodes

HfO 2 -based antiferroelectric-like thin films are increasingly being considered for commercial devices. However, even with initial promise, the temperature sensitivity of electrical properties such as loss tangent and leakage current remains unreported. 50 nm thick, 4 at. % Al-doped HfO 2 thin films were synthesized via atomic layer deposition with both top and bottom electrodes being TiN or Pt. A study of their capacitance vs temperature showed that the Pt/Al:HfO 2 /Pt had a relative dielectric permittivity of 23.30 ± 0.06 at room temperature with a temperature coefficient of capacitance (TCC) of 78 ± 86 ppm/°C, while the TiN/Al:HfO 2 /TiN had a relative dielectric permittivity of 32.28 ± 0.14 at room temperature with a TCC of 322 ± 41 ppm/°C. The capacitance of both devices varied less than 6% over 1 to 1000 kHz from –125 to 125 °C. Both capacitors maintained loss tangents under 0.03 and leakage current densities of 10 –9 –10 –7 A/cm 2 between –125 and 125 °C. The TiN/Al:HfO 2 /TiN capacitor maintained an energy storage density (ESD) of 18.17 ± 0.79 J/cm 3 at an efficiency of 51.79% ± 2.75% over the –125 to 125 °C range. The Pt/Al:HfO 2 /Pt capacitor also maintained a stable ESD of 9.83 ± 0.26 J/cm 3 with an efficiency of 62.87% ± 3.00% over the same temperature range. Finally, such low losses in both capacitors along with their thermal stability make antiferroelectric-like, Al-doped HfO 2 thin films a promising material for temperature-stable microelectronics.

36 MATERIALS SCIENCE↗
NASA NTRS1992

Emittance measurements of RCG coated Shuttle tiles

The spectral and total normal emittance of the Reaction Cured Glass (RCG) coating used on Shuttle tiles has been measured for surface temperatures of 300 to 1905 K. These measurements were made on two virgin and two flown Shuttle tile samples. Room temperature directional emittance data were also obtained and used to determine the total hemispherical emittance of RCG as a function of temperature. The data obtained from this calculation indicate that the total hemispherical emittance decreases from a room temperature value of 0.83 to a value of 0.76 at 1905 K. The flown Shuttle tiles exhibited a change in the spectral distribution of emittance compared to that of the virgin tile, but no significant trends in the total emittance from a virgin to a flown tile could be established.

Bouslog, Stanley A.↗
NASA NTRS1987

B2 aluminides for high temperature applications

The structure, phase composition, and mechanical properties of B2 FeAl and NiAl aluminides are investigated. It is noted that, in both alloys, the room temperature brittleness is of primary concern. In the case of FeAl, significant tensile ductilities of up to 8 percent have been obtained at room temperature in iron-rich alloys. In the case of polycrystalline NiAl, attempts to improve ductility have not so far been successfull. Possible solutions to this problem are examined.

Vedula, K.↗
DOE OSTI2024

Cu(II) Stability and UV-Induced Electron Transfer in a Metal–Organic Hybrid: An EPR, DFT, and Crystallographic Characterization of Copper-Doped Zinc Creatininium Sulfate

Single-crystal X-ray diffraction and electron paramagnetic resonance (EPR) spectroscopic experiments, complemented by quantum chemical DFT calculations, were carried out on the copper-doped metal–organic hybrid and Tutton salt analogue zinc creatininium sulfate to determine its crystal structure, to characterize the electronic structure of the doped Cu(II) binding site, and to propose a pathway for an excited-state, proton-coupled electron transfer (PCET) process in UV-exposed crystals. The crystal structure is isomorphous to that of cadmium creatininium sulfate, which has the transition ion, not in direct coordination with the creatinine, but forming a hexahydrate complex, which is bridged to a creatininium through an intervening sulfate ion. The EPR g (2.446, 2.112, 2.082) and copper hyperfine (A Cu : -327, -59.6, 10.8 MHz) tensor parameters are consistent with doped copper replacing host zinc in the metal–hexahydrate complex. These parameters are similar to those observed for copper hexahydrate in doped Tutton salt systems at low temperature, where the unpaired electron occupies mainly the copper 3d x 2 –y 2 orbital. At room temperature in the Tutton systems, vibration couplings stemming from a dynamic Jahn–Teller effect cause tensor averaging which results in a reduction in their maximum g-tensor and hyperfine tensor values. However, like for the doped isomorphous Cd creatinine crystal, the Cu(II) EPR exhibits little, or no room temperature averaging compared to its low temperature pattern. Samples exposed to 254 nm UV light generate a carbon-centered free radical species, characterized by an isotropic g-tensor (g = 2.0029) and an alpha-proton hyperfine coupling (-24 -14 +4 G). These parameters identify it as a creatinine radical cation formed by the oxidative release of one of its C2 methylene hydrogens. DFT calculations confirm the unpaired electronic structures of both the Cu(II) site and free radical. The growth in radical concentration with an increase in the UV exposure time coincides with a decrease in the copper EPR signal, indicating a coupled light-induced oxidation reduction process. A comparison of the crystal structure with the EPR parameters and DFT results provides evidence for a UV-induced PCET.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Vertical gradient freeze growth of detector grade CdZnTeSe single crystals

Here, we report the growth of detector grade Cd 0.9 Zn 0.1 Te 0.97 Se 0.03 (CZTS) single crystals, a recently discovered quaternary semiconductor for room temperature radiation detection, by a vertical gradient freeze (VGF) method. VGF is a comparatively low-temperature growth method and avoids relative motion between the heater and the ampoule containing the precursor materials which minimizes any thermal drift or temperature fluctuations. As a result, CZTS single crystals with superior charge transport properties has been obtained. Growth of detector-grade CZTS single crystals using VGF method has not been reported yet. X-ray spectroscopy based elemental analysis showed that the grown crystals demonstrated the desired stoichiometry required for high resolution radiation detection. Planar detectors fabricated by deposition of gold contacts (~0.07 cm 2 ) demonstrated high bulk resistivity ~10 10 Ω-cm and a very low leakage current density of 2.8 × 10 –8 A/cm 2 at a bias of 100 V when measured at room temperature. The detectors showed excellent radiation response with 100 % charge collection efficiency when exposed to 5486 keV alpha particles. The electron mobility-lifetime (μτ) product was measured to be 3 × 10 –3 cm 2 /V using a single polarity Hecht analysis which is at par with the recently reported values measured in CZTS grown using conventional Bridgman or travelling heater method. The electron mobility has been calculated to be 964 cm 2 V –1 s –1 using a time-of-flight (TOF) method, a substantial improvement over that obtained from conventionally grown CZTS single crystals.

36 MATERIALS SCIENCE↗
NASA NTRS1997

Elevated Temperature Ballistic Impact Testing of PBO and Kevlar Fabrics for Application in Supersonic Jet Engine Fan Containment Systems

Ballistic impact tests were conducted on fabric made from both Poly(phenylene benzobizoxazole) (PBO) and Kevlar 29 which were selected to be similar in weave pattern, areal density, and fiber denier. The projectiles were 2.54-cm- (1-in.-) long aluminum cylinders with a diameter of 1.27 cm (0.5 in.). The fabric specimens were clamped on four sides in a 30.5-cm- (12-in.-) square frame. Tests on PBO were conducted at room temperature and at 260 C (500 F). A number of PBO specimens were aged in air at 204 and 260 C (400 and 500 F) before impact testing. Kevlar specimens were tested only at room temperature and with no aging. The PBO absorbed significantly more energy than the Kevlar at both room and elevated temperatures. However, after aging at temperatures of 204 C (400 F) and above, the PBO fabric lost almost all of its energy absorbing ability. It was concluded that PBO fabric is not a feasible candidate for fan containment system applications in supersonic jet engines where operating temperatures exceed this level.

Pereira, J. Michael↗