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At least 1,153 records · Page 64

Research experiences on materials science in space aboard Salyut and Mir

From 1980 through 1991 approximately 500 materials processing experiments were performed aboard the space stations Salyut 6, Salyut 7 and Mir. This includes work on catalysts, polymers, metals and alloys, optical materials, superconductors, electronic crystals, thin film semiconductors, super ionic crystals, ceramics, and protein crystals. Often the resulting materials were surprisingly superior to those prepared on earth. The Soviets were the first to fabricate a laser (CdS) from a crystal grown in space, the first to grow a heterostructure in space, the first super ionic crystal in space, the first crystals of CdTe and its alloys, the first zeolite crystals, the first protein crystals, the first chromium disilicide glass, etc. The results were used to optimize terrestrial materials processing operations in Soviet industry. The characteristics of these three space stations are reviewed, along with the advantages of a space station for materials research, and the problems encountered by the materials scientists who used them. For example, the stations and the materials processing equipment were designed without significant input from the scientific community that would be using them. It is pointed out that successful results have been achieved also by materials processing at high gravity in large centrifuges. This research is also continuing around the world, including at Clarkson University. It is recommended that experiments be conducted in centrifuges in space, in order to investigate the acceleration regime between earth's gravity and the microgravity achieved in orbiting space stations. One cannot expect to understand the influence of gravity on materials processing from only two data points, earth's gravity and microgravity. One must also understand the influence of fluctuations in acceleration on board space stations, the so-called 'g-jitter.' This paper is presented in outline and graphical form.

Regel, Liya L.↗

Space Environmental Effects on Additively Manufactured (AM) Parts on MISSE-9/10

The Materials on International Space Station Experiment (MISSE) experiments have made a continuous presence on the ISS and allowed for testing of performance and durability of materials exposed to the Low Earth Orbit (LEO) space environment. Additive Manufacturing (AM) has been included on several MISSE flights, and many companies (Made in Space and Stratasys) and NASA centers wanted to test various AM material samples. The goal of studying Space Environmental Effects on AM Parts with MISSE 9/10 was to fly promising metal and polymer AM material samples (dogbones) that could have future manufacturing capabilities in space and conduct post-flight analysis of these materials via mechanical and optical properties. On these flights, MISSE-9 contained three Inconel and 12 polymer samples and MISSE-10 included three Inconel and 16 polymer samples. Before flying to the ISS, all the samples underwent thermal vacuum bakeout (at 60°C for 24 hours and 10-6 torr). After bakeout, control and flight experiments were weighed, and optical properties were taken. Optical properties such as solar absorptance and infrared emittance were taken on the control samples and the flight samples (preflight and postflight). To understand more about the mechanical properties of the AM samples, tensile testing was conducted on the samples to determine the yield and ultimate tensile strength of the dogbone samples against the control. Lastly, the torque on the fasteners securing the dogbone samples were loosened and measured using a torque wrench, and they were compared to their preflight torque specification required. Optical properties and masses were recorded before flight, and the postflight results were recorded and collected in June 2022 to study the effects. With the postflight analysis, NASA engineers can now better characterize how UV radiation and thermal cycling affect the material properties.

Materials on International Space Station Experimen↗

Laboratory studies of fast oxygen atom interactions with materials

A pulsed 8 km/s oxygen atom source was used to perform a number of measurements of material interactions of interest to low Earth orbit applications. A system to measure the scattering distribution resulting from 8 km/s oxygen atoms impinging on selected spacecraft materials was developed. Data for scattering from glass and black and clear anodized aluminum are presented. Results on the fast atom oxidation mechanism for thin silver films, the O-atom velocity dependent erosion rates for selected materials, and the oxidation dependence on material temperature are presented.

Caledonia, George E.↗

Calculational investigation of impact cratering dynamics - Early time material motions

Early time two-dimensional finite difference calculations of laboratory-scale hypervelocity (6 km/sec) impact of 0.3 g spherical 2024 aluminum projectiles into homogeneous plasticene clay targets were performed and the resulting material motions analyzed. Results show that the initial jetting of vaporized target material is qualitatively similar to experimental observation. The velocity flow field developed within the target is shown to have features quite similar to those found in calculations of near-surface explosion cratering. Specific application of Maxwell's analytic Z-Model (developed to interpret the flow fields of near-surface explosion cratering calculations), shows that this model can be used to describe the flow fields resulting from the impact cratering calculations, provided that the flow field center is located beneath the target surface, and that application of the model is made late enough in time that most of the projectile momentum has been dissipated.

Thomsen, J. M.↗

Performance Testing of Molten Regolith Electrolysis with Transfer of Molten Material for the Production of Oxygen and Metals on the Moon

Previously, we have demonstrated the production of oxygen by electrolysis of molten regolith simulants at temperatures near 1600 C. Using an inert anode and suitable cathode, direct electrolysis (no supporting electrolyte) of the molten silicate is carried out, resulting in the production of molten metallic products at the cathode and oxygen gas at the anode. Initial direct measurements of current efficiency have confirmed that the process offer potential advantages of high oxygen production rates in a smaller footprint facility landed on the moon, with a minimum of consumables brought from Earth. We now report the results of a scale-up effort toward the goal of achieving production rates equivalent to 1 metric ton O2/year, a benchmark established for the support of a lunar base. We previously reported on the electrochemical behavior of the molten electrolyte as dependent on anode material, sweep rate and electrolyte composition in batches of 20-200g and at currents of less than 0.5 A. In this paper, we present the results of experiments performed at currents up to 10 Amperes) and in larger volumes of regolith simulant (500 g - 1 kg) for longer durations of electrolysis. The technical development of critical design components is described, including: inert anodes capable of passing continuous currents of several Amperes, container materials selection, direct gas analysis capability to determine the gas components co-evolving with oxygen. To allow a continuous process, a system has been designed and tested to enable the withdrawal of cathodically-reduced molten metals and spent molten oxide electrolyte. The performance of the withdrawal system is presented and critiqued. The design of the electrolytic cell and the configuration of the furnace were supported by modeling the thermal environment of the system in an effort to realize a balance between external heating and internal joule heating. We will discuss the impact these simulations and experimental findings have on the design of a suitable prototype for lunar applications

Sibille, Laurent↗

Robotics in a controlled, ecological life support system

Controlled, Ecological Life Support Systems (CELSS) that utilize plants to provide food, water and oxygen could consume considerable amounts of labor unless crop production, recovery and processing are automated. Robotic manipulators equipped with special end-effectors and programmed to perform the sensing and materials handling tasks would minimize the amount of astronaut labor required. The Human Rated Test Facility (HRTF) planned for Johnson Space Center could discover and demonstrate techniques of crop production which can be reliably integrated with machinery to minimize labor requirements. Before the physical components (shelves, lighting fixtures, etc.) can be selected, a systems analysis must be performed to determine which alternative processes should be followed and how the materials handling tasks should be automated. Given that the current procedures used to grow crops in a CELSS may not be the best methods to automate, then what are the alternatives? How may plants be grown, harvested, processed for food, and the inedible components recycled? What commercial technologies current exist? What research efforts are underway to develop new technologies which might satisfy the need for automation in a CELSS? The answers to these questions should prove enlightening and provide some of the information necessary to perform the systems analysis. The planting, culturing, gathering, threshing and separation, food processing, and recovery of inedible portions of wheat were studied. The basic biological and materials handling processes of each task are defined and discussed. Current practices at Johnson Space Center and other NASA centers are described and compared to common production practices in the plant production industry. Technologies currently being researched which might be applicable are identified and illustrated. Finally, based on this knowledge, several scenarios are proposed for automating the tasks for wheat.

Miles, Gaines E.↗

Study of micrometeroid orbital debris

Knowing the impact effects of the space environment on engineering materials is critical if we are to build space hardware which will last for the duration of the mission. This study will perform measurements on impacted materials in order to determine the effects of the high velocity impacts on structures which are planned for long duration in space.

Workman, Gary L.↗

Advanced Materials and Manufacturing for Low-Cost, High-Performance Liquid Rocket Combustion Chambers

A document describes the low-cost manufacturing of C103 niobium alloy combustion chambers, and the use of a high-temperature, oxidation-resistant coating that is superior to the standard silicide coating. The manufacturing process involved low-temperature spray deposition of C103 on removable plastic mandrels produced by rapid prototyping. Thin, vapor-deposited platinum-indium coatings were shown to substantially improve oxidation resistance relative to the standard silicide coating. Development of different low-cost plastic thrust chamber mandrel materials and prototyping processes (selective laser sintering and stereolithography) yielded mandrels with good dimensional accuracy (within a couple of mils) for this stage of development. The feasibility of using the kinetic metallization cold-spray process for fabrication of free-standing C1O3 thrusters on removable plastic mandrels was also demonstrated. The ambient and elevated temperature mechanical properties of the material were shown to be reasonably good relative to conventionally processed C103, but the greatest potential benefit is that coldsprayed chambers require minimal post-process machining, resulting in substantially lower machining and material costs. The platinum-iridium coating was shown to provide greatly increased oxidation resistance over the silicide when evaluated through oxyacetylene torch testing to as high as 300 F (= 150 C). The iridium component minimizes reaction with the niobium alloy chamber at high temperatures, and provides the high-temperature oxidation resistance needed at the throat.

Williams, Brian E.↗

Furnace and support equipment for space processing

A core facility capable of performing a majority of materials processing experiments is discussed. Experiment classes are described, the needs peculiar to each experiment type are outlined, and projected facility requirements to perform the experiments are treated. Control equipment (automatic control) and variations of the Czochralski method for use in space are discussed.

Mazelsky, R.↗

Importance of numerosity and distribution of articulations within the digits, wrists, and arms of telemanipulators confronted with dextrous assembly tasks

This study was conducted to evaluate the impact of successive exclusion of degrees-of-freedom within digits (thumb and index finger) and wrist when performing tasks demanding varying degrees of end effector kinematic complexity. The analysis was performed by successive constraining articulations in the fingers (thumb and index) and wrists or human subjects via splints, and then timing performance of part movement, positioning, and assembly operations requiring different levels of kinematic freedom. Analysis of performance times showed that transferring degrees-of-freedom, or articulations, from the digits to the wrist and arm had little or no material affect upon manipulation performance times if wrist and arm kinematics were unrestricted. If wrist and arm kinematics are not constrained and are of high-quality, our findings show that transferring kinematic freedom from the digits to the wrist and arms or remote end effectors offers limited or no consequence in terms of remote assembly operations. The importance of such findings, in terms of development and implementation of commercially attractive telemanipulators, is discussed.

Wiker, Steven F.↗

Materials, Processes, and Environmental Engineering Network

Attention is given to the Materials, Processes, and Environmental Engineering Network (MPEEN), which was developed as a central holding facility for materials testing information generated by the Materials and Processes Laboratory of NASA-Marshall. It contains information from other NASA centers and outside agencies, and also includes the NASA Environmental Information System (NEIS) and Failure Analysis Information System (FAIS) data. The data base is NEIS, which is accessible through MPEEN. Environmental concerns are addressed regarding materials identified by the NASA Operational Environment Team (NOET) to be hazardous to the environment. The data base also contains the usage and performance characteristics of these materials.

White, Margo M.↗

Correlation of design with performance of primary lithium-sulfur oxyhalide cells

Results and assessments of a focused literature review of primary lithium sulfur oxyhalide cells are presented. Major emphasis is placed on the effect of component materials and designs on performance (energy density and rate capability), safety, and storage life of these cells. This information is a reference guide for the design of high energy batteries for future use on NASA missions.

Frank, H. A.↗

LWIR HgCdTe: Innovative detectors in an incumbent technology

HgCdTe is the current material of choice for high performance imagers operating at relatively high temperatures. Its lack of technological maturity compared with silicon and wide-band gap III-V compounds is more than offset by its outstanding IR sensitivity and by the relatively benign effect of its materials defects. This latter property has allowed non-equilibrium growth techniques, metal oxide chemical vapor deposition (MOCVD) and molecular beam epitaxy (MBE), to produce device quality long wavelength infrared (LWIR) HgCdTe even on common substrates like GaAs and GaAs/Si. Detector performance in these exotic materials structures is comparable in many ways with devices in equilibrium-grown material. Lifetimes are similar. RoA values at 77K as high as several hundred have been seen in HgCdTe/GaAs/Si with 9.5 micron cut-off wavelength. HgCdTe/GaAs layers with approx. 15 micron cut-off wavelengths have given average 77K RoAs of greater than 2. Hybrid focal plane arrays have been evaluated with excellent operability.

Tennant, William E.↗

An Exploratory Exercise in Taguchi Analysis of Design Parameters: Application to a Shuttle-to-space Station Automated Approach Control System

The chief goals of the summer project have been twofold - first, for my host group and myself to learn as much of the working details of Taguchi analysis as possible in the time allotted, and, secondly, to apply the methodology to a design problem with the intention of establishing a preliminary set of near-optimal (in the sense of producing a desired response) design parameter values from among a large number of candidate factor combinations. The selected problem is concerned with determining design factor settings for an automated approach program which is to have the capability of guiding the Shuttle into the docking port of the Space Station under controlled conditions so as to meet and/or optimize certain target criteria. The candidate design parameters under study were glide path (i.e., approach) angle, path intercept and approach gains, and minimum impulse bit mode (a parameter which defines how Shuttle jets shall be fired). Several performance criteria were of concern: terminal relative velocity at the instant the two spacecraft are mated; docking offset; number of Shuttle jet firings in certain specified directions (of interest due to possible plume impingement on the Station's solar arrays), and total RCS (a measure of the energy expended in performing the approach/docking maneuver). In the material discussed here, we have focused on single performance criteria - total RCS. An analysis of the possibility of employing a multiobjective function composed of a weighted sum of the various individual criteria has been undertaken, but is, at this writing, incomplete. Results from the Taguchi statistical analysis indicate that only three of the original four posited factors are significant in affecting RCS response. A comparison of model simulation output (via Monte Carlo) with predictions based on estimated factor effects inferred through the Taguchi experiment array data suggested acceptable or close agreement between the two except at the predicted optimum point, where a difference outside a rule-of-thumb bound was observed. We have concluded that there is most likely an interaction effect not provided for in the original orthogonal array selected as the basis for our experimental design. However, we feel that the data indicates that this interaction is a mild one and that inclusion of its effect will not alter the location of the optimum.

Deal, Don E.↗

Experimental characterization of nonlinear, rate-dependent behavior in advanced polymer matrix composites

In order to support materials selection for the next-generation supersonic civilian-passenger transport aircraft, a study has been undertaken to evaluate the material stress/strain relationships needed to describe advanced polymer matrix composites under conditions of high load and elevated temperature. As part of this effort, this paper describes the materials testing which was performed to investigate the viscoplastic behavior of graphite/thermoplastic and graphite/bismaleimide composites. Test procedures, results and data-reduction schemes which were developed for generating material constants for tension and compression loading, over a range of useful temperatures, are explained.

Gates, Thomas S.↗

Compatibility Studies of Hydrogen Peroxide and a New Hypergolic Fuel Blend

Several preliminary materials compatibility studies have been conducted to determine the practicality of a new hypergolic fuel system. Hypergolic fuel ignites spontaneously as the oxidizer decomposes and releases energy in the presence of the fuel. The bipropellant system tested consists of high-test hydrogen peroxide (HTP) and a liquid fuel blend consisting of a hydrocarbon fuel, an ignition enhancer and a transition metal catalyst. In order for further testing of the new fuel blend to take place, some basic materials compatibility and HTP decomposition studies must be accomplished. The thermal decomposition rate of HTP was tested using gas evolution and isothermal microcalorimetry (IMC). Materials were analyzed for compatibility with hydrogen peroxide including a study of the affect welding has on stainless steel elemental composition and its relation to HTP decomposition. Compatibility studies of valve materials in the fuel blend were performed to determine the corrosion resistance of the materials.

Baldridge, Jennifer↗

Use of reinforced inorganic cement materials for spark wire and drift chamber wire frames

The results of a survey, materials test, and analysis study directed toward the development of an inorganic glass-fiber reinforced cement material for use in the construction of space qualified spark wire frames and drift chamber frames are presented. The purpose for this research was to evaluate the feasibility of using glass fiber reinforced cement (GFRC) for large dimensioned structural frames for supporting a number of precisely located spark wires in multiple planes. A survey of the current state of the art in fiber reinforced cement materials was made; material sample mixes were made and tested to determine their laboratory performances. Tests conducted on sample materials showed that compressive and flexural strengths of this material could approach values which would enable fabrication of structural spark wire frames.

Source record↗

Electric Motors for Non-Cryogenic Hybrid Electric and Turboelectric Propulsion

NASA Glenn Research Center is investigating hybrid electric and turboelectric propulsion concepts for future aircraft to reduce fuel burn, emissions, and noise. Systems studies show that the weight and efficiency of the electric system components need to be improved for this concept to be feasible. However, advances in motor component materials such as soft magnetic materials, hard magnetic materials, conductors, thermal insulation, and structural materials are expected in the coming years, and should improve motor performance. This study investigates several motor types for a one megawatt application, and projects the motor performance benefits of new component materials that might be available in the coming decades.

Hybrid propulsion↗