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NASA NTRS1983

Response of amphibian egg cytoplasm to novel gravity orientation and centrifugation

The effects of inversion and centrifugation on the compartmentalization of cytoplasm in Xenopus laevis eggs are investigated experimentally. The rearrangement of yolk-platelet compartments (YPC) characterized by morphology, density, and viscosity differences is studied in fertilized, unfertilized, and unfertilized electrically activated eggs in normal, and inverted positions and with and without centrifugation at 10-183 x g for 5 min. The eggs are fixed and embedded in plastic or paraffin prior to sagittal sectioning (0.5, 4, or 8 microns) and microscopic examination; the results are presented in a diagram and discussed. A density-compartment model combining both animal/vegetal and dorsal/ventral polarities is proposed: YPC determined without gravity orientation during oogenesis respond to both sperm entrance point and gravity after fertilization, and the response involves breaking of the radial symmetry of the egg. It is predicted that Xenopus eggs in a microgravity environment will encounter difficulties in establishing a primary embryonic axis.

Neff, A. W.↗

NASA NTRS2001

Cross Calibration of TOMS, SBUV/2 and Sciamachy Radiances from Ground Observations

Verification of a stratospheric ozone recovery remains a high priority for environmental research and policy definition. Models predict an ozone recovery at a much lower rate than the measured depletion rate observed to date. Therefore improved precision of the satellite and ground ozone observing systems are required over the long term to verify recovery. We have shown that validation of radiances is the most effective means for correcting absolute accuracy and long term drifts of backscatter type satellite measurements. This method by-passes the algorithms used for both satellite and ground based measurements which are normally used to validate and correct the satellite data. Validation of radiances will also improve all higher level data products derived from the satellite observations. Backscatter algorithms suffer from several errors such as unrepresentative a-priori data and air mass factor corrections. Radiance comparisons employ forward models but are inherently more accurate and than inverse (retrieval) algorithms. A new method for satellite validation is planned which will compliment measurements from the existing ground-based networks. This method will employ very accurate comparisons between ground based zenith sky radiances and satellite nadir radiances. These comparisons will rely heavily on the experience derived from the Shuttle SBUV (SSBUV) program which provided a reference standard of radiance measurements for SBUV/2, TOMS, and GOME. This new measurement program, called "Skyrad", employs two well established capabilities at the Goddard Space Flight Center, 1) the SSBUV calibration facilities and 2) the radiative transfer codes used for the TOMS and SBUV/2 algorithms and their subsequent refinements. Radiative transfer calculations show that ground based zenith sky and satellite nadir backscatter ultraviolet comparisons can be made very accurately under certain viewing conditions. The Skyrad instruments (SSBUV, Brewer spectrophotometers, and possibly others) will be calibrated and maintained to a precision of a few tenths of a percent. Skyrad data will then enable long term calibration of upcoming satellite instruments such as QuickTOMS. SBUV/2s and SCIAMACHY with a high degree of precision. This technique can be further employed to monitor the performance of future instruments such as GOME-2, OMI, and OMPS. Initial ground observations taken from Goddard Space Flight Center compared with radiative transfer calculations has indicated the feasibility of this method.

Hillsenrath, Ernest↗

NASA NTRS1987

Vector constraints on western U.S. deformation from space geodesy, neotectonics, and plate motions

The rate-of-slip vector on the San Andreas fault in central California estimated from geodetic and Holocene geological data is inconsistent with the prediction of rigid plate models such as RM2. This well-known 'San Andreas discrepancy' is diagnostic of plate deformation distributed both east of the fault in the Basin and Range and west of the fault along the California continental margin. Constraints on the integrated deformation rates across these two regions consistent with: (1) the kinematical boundary conditions imposed by the rigid plate model; (2) neotectonic and paleoseismic estimates of deformation rates; (3) ground-based geodetic measurements; and (4) rates of change observed by very long baseline interferometry along seven baselines to western U.S. sites are constructed. The space-geodetic data on Basin and Range extension taken over a 4-year interval are compatible with geological observations averaged over the Holocene; the best estimate of its integrated deformation rate, provided by the joint inversion of both data types, is 9.7 + or - 2.1 mm/yr, N 56 deg W + or - 10 deg, too small and in the wrong direction to account entirely for the San Andreas discrepancy. The integral of this deformation, estimated by subtracting the Basin and Range contribution from the discrepancy vector, requires significant right-lateral shear parallel to the San Andreas (13 + or - 5 mm/yr) and some compression perpendicular to it (9 + or - 3 mm/yr).

Minster, J. Bernard↗

NASA NTRS1993

Solar wind conditions in the outer heliosphere and the distance to the termination shock

The Plasma Science experiment on the Voyager 2 spacecraft has measured the properties of solar wind protons from 1 to 40.4 AU. We use these observations to discuss the probable location and motion of the termination shock of the solar wind. Assuming that the interstellar pressure is due to a 5 micro-G magnetic field draped over the upstream face of the heliopause, the radial variation of ram pressure implies that the termination shock will be located at an average distance near 89 AU. This distance scales inversely as the assumed field strength. There are also large variations in ram pressure on time scales of tens of days, due primarily to large variations in solar wind density at a given radius. Such rapid changes in the solar wind ram pressure can cause large perturbations in the location of the termination shock. We study the nonequilibrium location of the termination shock as it responds to these ram pressure changes. The results of this study suggest that the position of the termination shock can vary by as much as 10 AU in a single year, depending on the nature of variations in the ram pressure, and that multiple crossings of the termination shock by a given outer heliosphere spacecraft are likely. After the first crossing, such models of shock motion will be useful for predicting the timing of subsequent crossings.

Belcher, John W.↗

DOE OSTI2023

Insights into the Solvation Characteristics of Zwitterionic Deep Eutectic Solvents Using Multiple Polarity Scales

Deep eutectic solvents (DESs) formed by mixing zwitterionic hydrogen bond acceptors (HBAs) with diol- and organic acid-based hydrogen bond donors (HBDs) are popular sustainable solvents. In addition to possessing an amphiphilic character, zwitterionic DESs offer unique solvation properties, unlike those composed of halide-containing HBAs. While all other popular classes of DESs have been investigated, no study has attempted to characterize the solvation characteristics of zwitterionic DESs. In this study, the solvation properties of betaine [Bet]-, sulfobetaine-, and l-carnitine [l-Car]-based DESs were thoroughly investigated for the first time using solvatochromic dye methods and inverse gas chromatography (IGC). Herein, the Nile red polarity scale revealed that DESs composed of organic acids were generally more polar than diol-based DESs. Kamlet–Taft solvent parameters revealed that glycerol-based DESs offered exceptionally high hydrogen bond donating ability compared to those composed of 1,4-butane diol and triethylene glycol. The Abraham solvation parameter model revealed hydrogen bond basicity to be the most dominant interaction, and it was generally higher for diol-based HBDs compared to organic acid-based HBDs. Additionally, sulfobetaine HBAs possessing longer alkyl chains generally offered higher dispersive-type interactions and hydrogen bond basicity compared to [Bet] and [l-Car] salts. This is the first study to combine and compare results from solvatochromic dye methods and IGC in an attempt to comprehensively explain and predict the solvation characteristics of zwitterionic DESs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS2001

Particle Engulfment and Pushing (PEP): Past Micro-Gravity Experiments and Future Experimental Plan on the International Space Station (ISS)

The interaction of an insoluble particle with a growing solid-liquid interface (SLI) has been a subject of investigation for the four decades. For a metallurgist or a material scientist understanding the fundamental physics of such an interaction is relevant for applications that include distribution of reinforcement particles in metal matrix composites, inclusion management in castings, and distribution of Y2Ba1Cu1O5 (211) precipitates (flux pinning sites) in Y1Ba2Cu3O7 (123) superconducting crystals. The same physics is also applicable to other areas including geological applications (frost heaving in soils) and preservation of biological cells. Experimentally this interaction can be quantified in terms of a critical growth velocity, Vcr, of the SLI below which particles are pushed ahead of the advancing interface, and above which the particles are engulfed. Past experimental evidence suggests that this Vcr is an inverse function of the particle radius, R. In order to isolate the fundamental physics that governs such a relationship it is necessary to minimize natural convection at the SLI that is inherent in ground based experiments. Hence for the purpose of producing benchmark data (Vcr vs. R) PEP is a natural candidate for micro-gravity experimentation. Accordingly, experiments with pure Al containing a dispersion of ZrO2 particles and an organic analogue, succinonitrile (SCN) containing polystyrene particles have been performed on the LMS and USMP-4 mission respectively. In this paper we will summarize the experimental data that was obtained during these two micro-gravity missions and show that the results differ compared to terrestrial experiments. We will also discuss the basic elements of our analytical and numerical model and present a comparison of the predictions of these models against micro-gravity experimental data. Finally. we will discuss our future experimental plan that includes the ISS glovebox and MSRRl.

Sen, Subhayu↗

DOE OSTI2020

Linear and nonlinear optical responses in the chiral multifold semimetal RhSi

Chiral topological semimetals are materials that break both inversion and mirror symmetries. They host interesting phenomena such as the quantized circular photogalvanic effect (CPGE) and the chiral magnetic effect. In this work, we report a comprehensive theoretical and experimental analysis of the linear and nonlinear optical responses of the chiral topological semimetal RhSi, which is known to host multifold fermions. We show that the characteristic features of the optical conductivity, which display two distinct quasi-linear regimes above and below 0.4 eV, can be linked to excitations of different kinds of multifold fermions. The characteristic features of the CPGE, which displays a sign change at 0.4 eV and a large non-quantized response peak of around 160 μA/V 2 at 0.7 eV, are explained by assuming that the chemical potential crosses a flat hole band at the Brillouin zone center. Our theory predicts that, in order to observe a quantized CPGE in RhSi, it is necessary to increase the chemical potential as well as the quasiparticle lifetime. More broadly, our methodology, especially the development of the broadband terahertz emission spectroscopy, could be widely applied to study photogalvanic effects in noncentrosymmetric materials and in topological insulators in a contact-less way and accelerate the technological development of efficient infrared detectors based on topological semimetals.

Materials Science↗

DOE OSTI2025

Comprehensive Measurement of the Reactor Antineutrino Spectrum and Flux at Daya Bay

This Letter reports the precise measurement of the reactor antineutrino spectrum and flux based on the full dataset of 4.7 ×10 6 inverse-beta-decay candidates collected at Daya Bay near detectors. Expressed in terms of the inverse-beta-decay yield per fission, the antineutrino spectra from all reactor fissile isotopes and the specific 235 U and 239 Pu isotopes are measured with 1.3%, 3%, and 8% uncertainties, respectively, near the 3 MeV spectrum peak in reconstructed energy, reaching the best precision in the world. The total antineutrino flux and isotopic 235 U and 239 Pu fluxes are precisely measured to be 5.84 ± 0.07, 6.16 ± 0.12, and 4.16 ± 0.21 in units of 10 −43 cm 2 /fission. These measurements are compared with the Huber-Mueller model, the reevaluated conversion model based on the Kurchatov Institute measurement, and the latest summation model (SM2023). Furthermore, the Daya Bay flux shows good consistency with the Kurchatov Institute and SM2023 models but disagrees with the Huber-Mueller model. The Daya Bay spectrum, however, disagrees with all model predictions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

NASA NTRS2004

Automated Processing of ISIS Topside Ionograms into Electron Density Profiles

Modeling of the topside ionosphere has for the most part relied on just a few years of data from topside sounder satellites. The widely used Bent et al. (1972) model, for example, is based on only 50,000 Alouette 1 profiles. The International Reference Ionosphere (IRI) (Bilitza, 1990, 2001) uses an analytical description of the graphs and tables provided by Bent et al. (1972). The Alouette 1, 2 and ISIS 1, 2 topside sounder satellites of the sixties and seventies were ahead of their times in terms of the sheer volume of data obtained and in terms of the computer and software requirements for data analysis. As a result, only a small percentage of the collected topside ionograms was converted into electron density profiles. Recently, a NASA-funded data restoration project has undertaken and is continuing the process of digitizing the Alouette/ISIS ionograms from the analog 7-track tapes. Our project involves the automated processing of these digital ionograms into electron density profiles. The project accomplished a set of important goals that will have a major impact on understanding and modeling of the topside ionosphere: (1) The TOPside Ionogram Scaling and True height inversion (TOPIST) software was developed for the automated scaling and inversion of topside ionograms. (2) The TOPIST software was applied to the over 300,000 ISIS-2 topside ionograms that had been digitized in the fkamework of a separate AISRP project (PI: R.F. Benson). (3) The new TOPIST-produced database of global electron density profiles for the topside ionosphere were made publicly available through NASA s National Space Science Data Center (NSSDC) ftp archive at . (4) Earlier Alouette 1,2 and ISIS 1, 2 data sets of electron density profiles from manual scaling of selected sets of ionograms were converted fiom a highly-compressed binary format into a user-friendly ASCII format and made publicly available through nssdcftp.gsfc.nasa.gov. The new database for the topside ionosphere established as a result of this project, has stimulated a multitude of new studies directed towards a better description and prediction of the topside ionosphere. Marinov et al. (2004) developed a new model for the upper ion transition height (Oxygen to Hydrogen and Helium) and Bilitza (2004) deduced a correction term for the I N topside electron density model. Kutiev et al. (2005) used this data to develop a new model for the topside ionosphere scale height (TISH) as a function of month, local time, latitude, longitude and solar flux F10.7. Comparisons by Belehaki et al. (2005) show that TISH is in general agreement with scale heights deduced from ground ionosondes but the model predicts post-midnight and afternoon maxima whereas the ionosonde data show a noon maximum. Webb and Benson (2005) reported on their effort to deduce changes in the plasma temperature and ion composition from changes in the topside electron density profile as recorded by topside sounders. Limitations and possible improvements of the IRI topside model were discussed by Coisson et al. (2005) including also the possible use of the NeQuick model, Our project progressed in close collaboration and coordination with the GSFC team involved in the ISIS digitization effort. The digitization project was highly successful producing a large amount of digital topside ionograms. Several no-cost extensions of the TOPIST project were necessary to keep up with the pace and volume of the digitization effort.

Reinisch, bodo W.↗

NASA NTRS2007

Symmetry, Statistics and Structure in MHD Turbulence

Here, we examine homogeneous MHD turbulence in terms of truncated Fourier series. The ideal MHD equations and the associated statistical theory of absolute equilibrium ensembles are symmetric under P, C and T. However, the presence of invariant helicities, which are pseudoscalars under P and C, dynamically breaks this symmetry. This occurs because the surface of constant energy in phase space has disjoint parts, called components: while ensemble averages are taken over all components, a dynamical phase trajectory is confined to only one component. As the Birkhoff-Khinchin theorem tells us, ideal MHD turbulence is thus non-ergodic. This non-ergodicity manifests itself in low-wave number Fourier modes that have large mean values (while absolute ensemble theory predicts mean values of zero). Therefore, we have coherent structure in ideal MHD turbulence. The level of non-ergodicity and amount of energy contained in the associated coherent structure depends on the values of the helicities, as well as on the presence, or not, of a mean magnetic field and/or overall rotation. In addition to the well known cross and magnetic helicities, we also present a new invariant, which we call the parallel helicity, since it occurs when mean field and rotation axis are aligned. The question of applicability of these results to real (i.e., dissipative) MHD turbulence is also examined. Several long-time numerical simulations on a 64(exp 3) grid are given as examples. It is seen that coherent structure begins to form before decay dominates over nonlinearity. The connection of these results with inverse spectral cascades, selective decay, and magnetic dynamos is also discussed.

Shebalin, John V.↗

DOE OSTI2024

Gradient-based surface nuclear magnetic resonance for groundwater investigation

In medical magnetic resonance imaging, spatial localization (imaging) is based upon the application of controlled magnetic field gradients on top of the main magnetic field to spatially modulate the frequency and/or phase of the nuclear magnetic resonance (NMR) signal across the volume of investigation. In this work, we have applied similar physical principles to produce controlled magnetic field gradients during surface NMR-based groundwater investigations. In this approach, a gradient pulse of variable amplitude or duration is applied immediately after the excitation pulse to cause predictable phase encoding of the NMR signal as a function of depth. This approach is also applicable to emerging surface NMR detection methods that use a prepolarization field with fast nonadiabatic turn-off to generate detectable NMR signals from the shallow subsurface. In this case, the gradient pulse is applied after terminating the prepolarization field and provides a heretofore unavailable means of localizing the NMR response as a function of depth. The application of gradients can also be combined with tip-angle-based modulation to yield higher imaging resolution than can be achieved through either gradient- or tip-angle-based imaging alone. We implemented this new gradient-based capability into a surface NMR gradient generation accessory that is compatible with the GMR-Flex instrument and developed surface NMR-specific forward modeling and linear inverse models. We validated the accuracy of this novel gradient-based sNMR technology using computer simulations, experiments using a small pool filled with a discrete layer of bulk water, and field experiments at well-characterized groundwater test sites along Ebey Island, WA, and Larned, KS. The gradient-based sNMR imaging observations were compared with high-resolution direct push NMR results observed at these sites. The results of computer simulations and field experiments indicate improvements in both the detection (signal-to-noise ratio) and spatial resolution of shallow subsurface water content using gradient-based surface NMR, compared with traditional surface NMR imaging methods.

Geochemistry & Geophysics↗

DOE OSTI2025

Determination of confinement regime boundaries via separatrix parameters on Alcator C-Mod based on a model for interchange-drift-Alfvén turbulence

The separatrix operational space (SepOS) model (Eich and Manz 2021 Nucl. Fusion 61 086017) is shown to predict the L–H transition, the L-mode density limit, and the ideal magnetohydrodynamic ballooning limit in terms of separatrix parameters for a wide range of Alcator C-Mod plasmas. The model is tested using Thomson scattering measurements across a wide range of operating conditions on C-Mod, spanning $\overline{n}_{\mathrm{e}}$ = 0.3–5.5 $\times 10^{20}\,$m −3 , $B_{\mathrm{t}} = 2.5$–8.0 T, and $B_{\mathrm{p}}$= 0.1–1.2 T. An empirical regression for the electron pressure gradient scale length, $\lambda_{{p}_{\mathrm{e}}}$, against a turbulence control parameter, $\alpha_{\mathrm{t}}$, and the poloidal fluid gyroradius, $\rho_{\mathrm{s,p}}$, is constructed for H-modes and found to require positive exponents for both regression parameters, indicating turbulence widening of near-scrape-off layer widths at high $\alpha_{\mathrm{t}}$ and an inverse scaling with $B_{\mathrm{p}}$, consistent with results on ASDEX Upgrade. The SepOS model is also tested in the unfavorable drift direction and found to apply well to all three boundaries, including the L–H transition as long as a correction to the Reynolds energy transfer term, $\alpha_\mathrm{RS} \lt 1$ is applied. I-modes typically exist in the unfavorable drift direction for values of $\alpha_{\mathrm{t}} \lesssim 0.3$. Finally, an experiment studying the transition between the Type-I ELMy and EDA H-mode is analyzed using the same framework. It is found that a recently identified boundary $\alpha_{\mathrm{t}} = 0.55$ at excludes most EDA H-modes but that the balance of wavenumbers responsible for the L-mode density limit, namely $k_\mathrm{EM} = k_\mathrm{RBM}$, may better describe the transition on C-Mod. The ensemble of boundaries validated and explored is then applied to project regime access and limit avoidance for the SPARC primary reference discharge parameters.

ELM suppression↗

NASA NTRS2008

Improving the Optical Quality Factor of the WGM Resonator

Resonators usually are characterized with two partially dependent values: finesse (F) and quality factor (Q). The finesse of an empty Fabry-Perot (FP) resonator is defined solely by the quality of its mirrors and is calculated as F=piR(exp 1/2)/(1-R). The maximum up-to-date value of reflectivity R approximately equal to 1 - 1.6 x 10(exp -6) is achieved with dielectric mirrors. An FP resonator made with the mirrors has finesse F=1.9 x 10(exp 6). Further practical increase of the finesse of FP resonators is problematic because of the absorption and the scattering of light in the mirror material through fundamental limit on the reflection losses given by the internal material losses and by thermodynamic density fluctuations on the order of parts in 109. The quality factor of a resonator depends on both its finesse and its geometrical size. A one-dimensional FP resonator has Q=2 F L/lambda, where L is the distance between the mirrors and lambda is the wavelength. It is easy to see that the quality factor of the resonator is unlimited because L is unlimited. F and Q are equally important. In some cases, finesse is technically more valuable than the quality factor. For instance, buildup of the optical power inside the resonator, as well as the Purcell factor, is proportional to finesse. Sometimes, however, the quality factor is more valuable. For example, inverse threshold power of intracavity hyperparametric oscillation is proportional to Q(exp 2) and efficiency of parametric frequency mixing is proportional to Q(exp 3). Therefore, it is important to know both the maximally achievable finesse and quality factor values of a resonator. Whispering gallery mode (WGM) resonators are capable of achieving larger finesse compared to FP resonators. For instance, fused silica resonators with finesse 2.3 x 10(exp 6) and 2.8 x 10(exp 6) have been demonstrated. Crystalline WGM resonators reveal even larger finesse values, F=6.3 x 10(exp 6), because of low attenuation of light in the transparent optical crystals. The larger values of F and Q result in the enhancement of various nonlinear processes. Low-threshold Raman lasing, optomechanical oscillations, frequency doubling, and hyperparametric oscillations based on these resonators have been recently demonstrated. Theory predicts a possibility of nearly 10(exp 14) room-temperature optical Q-factors of optical crystalline WGM resonators, which correspond to finesse levels higher than 10(exp 9). Experiments have shown numbers a thousand times lower than that. The difference occurs due to media imperfections. To substantially reduce the optical losses caused by the imperfections, a specific, multi-step, asymptotic processing of the resonator is implemented. The technique has been initially developed to reduce microwave absorption in dielectric resonators. One step of the process consists of mechanical polishing performed after high temperature annealing. Several steps repeat one after another to lead to significant reduction in optical attenuation and, as a result, to the increase of Q-factor as well as finesse of the resonator which demonstrates a CaF2 WGM resonator with F greater than 10(exp 7) and Q greater than 10(exp 11).

Savchenkov, Anatoliy↗

NASA NTRS2004

An Evaluation of Quantitative Methods of Determining the Degree of Melting Experienced by a Chondrule

Many workers have considered the degree to which partial melting occurred in chondrules they have studied, and this has led to attempts to find reliable methods of determining the degree of melting. At least two quantitative methods have been used in the literature: a convolution index (CVI), which is a ratio of the perimeter of the chondrule as seen in thin section divided by the perimeter of a circle with the same area as the chondrule, and nominal grain size (NGS), which is the inverse square root of the number density of olivines and pyroxenes in a chondrule (again, as seen in thin section). We have evaluated both nominal grain size and convolution index as melting indicators. Nominal grain size was measured on the results of a set of dynamic crystallization experiments previously described, where aliquots of LEW97008(L3.4) were heated to peak temperatures of 1250, 1350, 1370, and 1450 C, representing varying degrees of partial melting of the starting material. Nominal grain size numbers should correlate with peak temperature (and therefore degree of partial melting) if it is a good melting indicator. The convolution index is not directly testable with these experiments because the experiments do not actually create chondrules (and therefore they have no outline on which to measure a CVI). Thus we had no means to directly test how well the CVI predicted different degrees of melting. Therefore, we discuss the use of the CVI measurement and support the discussion with X-ray Computed Tomography (CT) data.

Nettles, J. W.↗

NASA NTRS2016

A Computationally-Efficient Inverse Approach to Probabilistic Strain-Based Damage Diagnosis

This work presents a computationally-efficient inverse approach to probabilistic damage diagnosis. Given strain data at a limited number of measurement locations, Bayesian inference and Markov Chain Monte Carlo (MCMC) sampling are used to estimate probability distributions of the unknown location, size, and orientation of damage. Substantial computational speedup is obtained by replacing a three-dimensional finite element (FE) model with an efficient surrogate model. The approach is experimentally validated on cracked test specimens where full field strains are determined using digital image correlation (DIC). Access to full field DIC data allows for testing of different hypothetical sensor arrangements, facilitating the study of strain-based diagnosis effectiveness as the distance between damage and measurement locations increases. The ability of the framework to effectively perform both probabilistic damage localization and characterization in cracked plates is demonstrated and the impact of measurement location on uncertainty in the predictions is shown. Furthermore, the analysis time to produce these predictions is orders of magnitude less than a baseline Bayesian approach with the FE method by utilizing surrogate modeling and effective numerical sampling approaches.

Warner, James E.↗

NASA NTRS1975

Waveguide CO2 laser gain: Dependence on gas kinetic and discharge properties

Using a simple rate equation approach the gas kinetic and discharge properties of waveguide CO2 lasers were examined. The dependence was calculated of the population inversion and laser small signal gain on gas pressure, gas mixture, pumping rate (discharge current), tube bore diameter, and wall temperature. At higher pressures the gain is optimized by using more helium rich mixtures and smaller bore diameters. The dependence of laser tunability on the gas kinetic properties and cavity losses was determined, it was found that for loss cavities the laser tunability may substantially exceed the molecular fullwidth at half maximum. The more helium rich gas mixtures give greater tunability when cavity losses are small and less tunability when cavity losses are large. The role of the various gases in the waveguide CO2 laser is the same as that in conventional devices, by contrast with conventional lasers, the waveguide laser transition is homogeneously broadened. The dependence of gain on gas pressure and other kinetic and discharge properties differs substantially from that predicted by scaling results from conventional low pressure lasers.

Cohen, S. C.↗

NASA NTRS2005

Modeling Atmospheric CO2 Processes to Constrain the Missing Sink

We report on a NASA supported modeling effort to reduce uncertainty in carbon cycle processes that create the so-called missing sink of atmospheric CO2. Our overall objective is to improve characterization of CO2 source/sink processes globally with improved formulations for atmospheric transport, terrestrial uptake and release, biomass and fossil fuel burning, and observational data analysis. The motivation for this study follows from the perspective that progress in determining CO2 sources and sinks beyond the current state of the art will rely on utilization of more extensive and intensive CO2 and related observations including those from satellite remote sensing. The major components of this effort are: 1) Continued development of the chemistry and transport model using analyzed meteorological fields from the Goddard Global Modeling and Assimilation Office, with comparison to real time data in both forward and inverse modes; 2) An advanced biosphere model, constrained by remote sensing data, coupled to the global transport model to produce distributions of CO2 fluxes and concentrations that are consistent with actual meteorological variability; 3) Improved remote sensing estimates for biomass burning emission fluxes to better characterize interannual variability in the atmospheric CO2 budget and to better constrain the land use change source; 4) Evaluating the impact of temporally resolved fossil fuel emission distributions on atmospheric CO2 gradients and variability. 5) Testing the impact of existing and planned remote sensing data sources (e.g., AIRS, MODIS, OCO) on inference of CO2 sources and sinks, and use the model to help establish measurement requirements for future remote sensing instruments. The results will help to prepare for the use of OCO and other satellite data in a multi-disciplinary carbon data assimilation system for analysis and prediction of carbon cycle changes and carbodclimate interactions.

Kawa, S. R.↗

NASA NTRS2021

Assessing Relay Communications for Mars Sample Return Surface Mission Concepts

The Mars Sample Return (MSR) Campaign is a 3-mission campaign concept supported by NASA and ESA to return samples from the Mars surface. MSR will, for the firsttime ever, present a need to communicate with multiple surfaceassets that are co-located on Mars in a coordinated effort toaccomplish the unified objective of fetching, transporting, andreturning samples from Mars. Currently, Mars surface assetsrelay data to and from Earth using a number of orbiters inwhat’s known as the Mars Relay Network (MRN). This networkis characterized by a small number of surface assets distributedacross the Martian globe and a larger number of orbiters toprovide relay services. As of June 2020, there are two surfaceassets for which five orbiters are providing relay. During theMSR Campaign, there will be two rovers and a lander that allwill require relay communication from a small number of Marsorbiters to meet the aggressive MSR timeline. The inversion ofthe current MRN paradigm, a system of many surface assetsrequiring relay and few orbiters to provide relay, necessitatesthe unique challenge of optimally allocating relay passes tomaximize the operational capability of all assets. The allocationmust consider a large number of trade variables includingMars asset operational requirements and Earth ground systemconstraints, including staffing schedules, operations planningacross time zones, and more. To address these telecommunicationchallenges, the Mars Asset Relay Mission Link AllocationDesign Environment (MARMLADE) tool was developed. Itis a MATLAB-based tool to assign orbiter passes or Direct-From-Earth (DFE) links to each of the three surface assets andquantify the operational efficiency of each surface asset.MARMLADE uses a data set of simulated Mars relay orbitergeometry and telecommunication capabilities provided by JPL’sTelecom Orbit Analysis and Simulation Tool (TOAST) softwareto compute which asset should get each pass based on a seriesof heuristics and predictions of all assets’ states. WithinMARMLADE, the user can provide inputs including the optionfor time-based pass splitting, fixed FWD data rate capabilities,DFE communication capabilities, and link parameters allowingfor the assessment of complex operations and hardware tradesusing surface mission operational efficiency as a primary figureof merit. As the MSR mission concepts continue to mature,MARMLADE is being used to assess ability of all MSR elementsto meet the surface mission timeline requirements and to provide relay link allocations to each of the MSR surface assets.

Lee, Charles↗