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At least 1,153 records · Page 64

Wind tunnel investigation of the interaction and breakdown characteristics of slender wing vortices at subsonic, transonic, and supersonic speeds

The vortex dominated aerodynamic characteristics of a generic 65 degree cropped delta wing model were studied in a wind tunnel at subsonic through supersonic speeds. The lee-side flow fields over the wing-alone configuration and the wing with leading edge extension (LEX) added were observed at M (infinity) equals 0.40 to 1.60 using a laser vapor screen technique. These results were correlated with surface streamline patterns, upper surface static pressure distributions, and six-component forces and moments. The wing-alone exhibited vortex breakdown and asymmetry of the breakdown location at the subsonic and transonic speeds. An earlier onset of vortex breakdown over the wing occurred at transonic speeds due to the interaction of the leading edge vortex with the normal shock wave. The development of a shock wave between the vortex and wing surface caused an early separation of the secondary boundary layer. With the LEX installed, wing vortex breakdown asymmetry did not occur up to the maximum angle of attack in the present test of 24 degrees. The favorable interaction of the LEX vortex with the wing flow field reduced the effects of shock waves on the wing primary and secondary vortical flows. The direct interaction of the wing and LEX vortex cores diminished with increasing Mach number. The maximum attainable vortex-induced pressure signatures were constrained by the vacuum pressure limit at the transonic and supersonic speeds.

Erickson, Gary E.↗

Quantifying the Effect of Cosmic Ray Showers on the X-IFU Energy Resolution

The X-ray Integral Field Unit (X-IFU) will operate an array of more than 3000 Transition Edge Sensor pixels at 90 mK with an unprecedented energy resolution of 2.5 eV at 7 keV. In space, primary cosmic rays and secondary particles produced in the instrument structure will continuously deposit energy on the detector wafer and induce fluctuations on the pixels’ thermal bath. We have investigated through simulations of the X-IFU readout chain how these fluctuations eventually influence the energy measurement of X-ray photons. Realistic timelines of thermal bath fluctuations at different positions in the array are generated as a function of a thermal model and the expected distribution of the deposited energy of the charged particles. These are then used to model the TES response to these thermal perturbations and their influence on the onboard energy reconstruction process. Overall, we show that with adequate heatsinking, the main energy resolution degradation effect remains minimal and within the associated resolution allocation of 0.2 eV. We further study how a dedicated triggering algorithm could be put in place to flag the rarer large thermal events.

P. Peille↗

Permafrost on Mars: distribution, formation, and geological role

The morphology of channels, valleys, chaotic and fretted terrains and many smaller features on Mars is consistent with the hypothesis that localized deterioration of thick layers of ice-rich permafrost was a dominant geologic process on the Martian surface. Such ground ice deterioration gave rise to large-scale mass movement, including sliding, slumping and sediment gravity flowage, perhaps also catastropic floods. In contrast to Earth, such mass movement processes on Mars lack effective competition from erosion by surface runoff. Therefore, Martian features due to mass movement grew to reach immense size without being greatly modified by secondary erosional processes. The Viking Mission to Mars in 1976 provided adequate measurements of the relevant physical parameters to constrain models for Martian permafrost.

Nummedal, D.↗

Aircraft laser derived chlorophyll distribution across the Iceland-Faeroe front

The ocean surface color (water-leaving radiances) and thermal structure across the Iceland-Faeroe Front under both clear and cloudy conditions were measured from a NASA research aircraft on 25 May 1989. The measurements were made along four north-south lines that were 125 km in length and spaced 35 km apart. The color measurements were made with a 14 channel, non-polarized Multispectral Airborne Radiometer System (MARS) while the thermal data were collected by a thermal radiometer and aircraft bathythermographs. The satellite imagery (NOAA AVHRR) sequence show the development of meanders through the frontal region. These aircraft ocean color and thermal data characterize the biological distribution and are closely coupled to the physical processes occurring in the frontal systems. The ratio of several channels of the ocean color data are used to determine the surface chlorophyll. The retrieved data correlate well with laser-induced chlorophyll fluorescence obtained at the same time and historical chlorophyll data. The observed chlorophyll patchiness appearing across the Iceland-Faeroe Front is believed to be directly and indirectly related to primary and secondary circulation processes in ocean frontal systems. High chlorophyll concentrations were observed on the north side of the front and are inferred to be the result from the advection of Icelandic Coastal Water into the region. The sharp chlorophyll decline at and south of the thermal frontal boundary is clearly related to the subsurface thermal structure.

Arnone, Robert A.↗

Isotopic constraints on the origin of meteoritic organic matter

Salient features of the isotopic distribution of H, C and N in the organic material found in carbonaceous meteorites are noted. Most organic fractions are strongly enriched in D with respect to the D/H ratio characteristic of H2 in the protosolar system; substantial variations in C-13/C-12 ratio are found among different molecular species, with oxidised species tending to be C-13 enriched relative to reduced species; some homologous series reveal systematic decrease in C-13/C-12 with increasing C number; considerable variation in N-15/N-14 ratio is observed within organic matter, though no systematic pattern to its distribution has yet emerged; no interelement correlations have been observed between isotope enrichments for the different biogenic elements. The isotopic complexity echoes the molecular diversity observed in meteoritic organic matter and suggests that the organic matter was formed by multiple processes and/or from multiple sources. However, existence of a few systematic patterns points towards survival of isotopic signatures characteristic of one or more specific processes. The widespread D enrichment implies either survival of many species of interstellar molecule or synthesis from a reservoir containing a significant interstellar component. Several of the questions raised above can be addressed by more detailed determination of the distribution of the H, C and N isotopes among different well-characterized molecular fractions. Thus, the present study is aimed at discovering whether the different amino acids have comparable D enrichments, which would imply local synthesis from a D-enriched reservoir, or very viable D enrichments, which would imply survival of some interstellar amino acids. The same approach is also being applied to polycyclic aromatic hydrocarbons. Because the analytical technique employed (secondary ion mass spectrometry) can acquire data for all three isotopic systems from each molecular fraction, any presently obscured interelement isotopic correlation should also be revealed, which will aid in identifying pertinent synthetic processes.

Kerridge, J. F.↗

Overexpanded Performance of Conical Nozzles with Area Ratios of 6 and 9 With and Without Supersonic External Flow

An investigation of the thrust characteristics and internal pressure distributions of two convergent-divergent 15 deg. half-angle exhaust nozzles having area ratios of 6 and 9 was made in the NASA Lewis 10- by 10-foot supersonic wind tunnel. The tests were conducted at free-stream Mach numbers of 0, 2.0, 2.5, 3.0, and 3.5 over a range of nozzle pressure ratios from 3 to 105. Attempts were made to induce separation of the overexpanded nozzle flow using secondary airflow and a wedge. Nozzle flow expansion under all free-stream conditions followed one-dimensional theory until separation from the nozzle wall occurred. In quiescent air the nozzle flow expanded to a pressure approximately one-half the base pressure before separation. When the nozzles were tested with supersonic external flow at the same effective pressure ratios, the nozzle flow separated with negligible expansion below the base pressure. The effect of a supersonic stream on internal nozzle flow separation characteristics was well defined only at a free-stream Mach number of 2.0. Thrust data at supersonic free-stream conditions indicate that only a small percentage of the ideal nozzle thrust will be available at nozzle pressure ratios below design. However, the overexpanded primary nozzle thrust loss was decreased by injecting large quantities of secondary air near the nozzle exit. In most cases no net gain in thrust resulted from secondary-air injection when the nozzle thrust was compared with the ideal thrust of both the primary and secondary airflows.

Musial, Norman T.↗

Preliminary Geological Findings on the BP-1 Simulant

A waste material from an aggregate producing quarry has been used to make an inexpensive lunar simulant called BP-1. The feedstock is the Black Point lava flow in northern Arizona. Although this is part of the San Francisco volcanic field, which is also the source of the JSC-1 series feedstock, BP-1 and JSC-1 are distinct. Chemically, the Black Point flow is an amygdaloidal nepheline-bearing basalt. The amygdules are filled with secondary minerals containing opaline silica, calcium carbonate, and ferric iron minerals. X-ray diffraction (XRD) detected approximately 3% quartz, which is in line with tests done by the Kennedy Space Center Industrial Hygiene Office. Users of this material should use appropriate protective equipment. XRD also showed the presence of significant halite and some bassanite. Both are interpreted to be evaporative residues due to recycling of wash water at the quarry. The size distribution of BP-1 may be superior to some other simulants for some applications.

Stoeser, D. B.↗

Field reversal in low pressure, unmagnetized radio frequency capacitively coupled argon plasma discharges

In general, the radio frequency (rf) electric field within a sheath points toward the metal electrode in low pressure, unmagnetized rf electropositive capacitively coupled plasma (CCP) glow discharges. This is due to the large ratio of electron to ion mobility and the formation of an ion sheath. In this work, we studied, using fully kinetic particle-in-cell simulations, a reversed electric field induced by the strong secondary electron emission during the phase of sheath collapse in a high-voltage rf-driven low pressure CCP glow discharge. We explored the transition behavior of the formation of field reversal as a function of driving voltage amplitude and found that field reversal starts to form at around 750 V, for a discharge with an electrode spacing of 4 cm at 10 mTorr argon pressure driven at 13.56 MHz. Accordingly, the energy distribution function of electrons incident on the electrode shows peaks from around 3 to 10 eV while varying the driving voltage from 150 to 2000 V, showing potentially beneficial effects in plasma material processing where relatively directional electrons are preferred to solely thermal diffusion electrons.

Physics↗

The energy dependence of the ratios of secondary to primary elements in the cosmic radiation

The secondary to primary ratios B/C, N/O and (Sc-Mn)/Fe in the galactic cosmic rays have been measured in the overall energy interval 30-180 MeV/n with the University of Chicago cosmic ray telescope on board the satellite IMP-8 during the period 1974-1978. These results, together with the values of the same ratios measured at higher energies, have been compared to the results of cosmic ray propagation calculations using different pathlength distributions (PLD) and different levels of solar modulation, in order to select a single set of parameters consistent with all the measured ratios.

Garcia-Munoz, M.↗

Mechanistic studies on reduced exercise performance and cardiac deconditioning with simulated zero gravity

The primary purpose of this research is to study the physiological mechanisms associated with the exercise performance of rats subjected to conditions of simulated weightlessness. A secondary purpose is to study related physiological changes associated with other systems. To facilitate these goals, a rodent suspension model was developed (Overton-Tipton) and a VO2 max testing procedure was perfected. Three methodological developments occurred during this past year deserving of mention. The first was the refinement of the tail suspension model so that (1) the heat dissipation functions of the caudal artery can be better utilized, and (2) the blood flow distribution to the tail would have less external constriction. The second was the development on a one-leg weight bearing model for use in simulated weightlessness studies concerned with change in muscle mass, muscle enzyme activity, and hind limb blood flow. The chemical body composition of 30 rats was determined and used to develop a prediction equation for percent fat using underwater weighing procedures to measure carcass specific gravity and to calculate body density, body fat, and fat free mass.

Tipton, Charles M.↗

Improving Separation Assurance Stability Through Trajectory Flexibility Preservation

New information and automation technologies are enabling the distribution of tasks and decisions from the service providers to the users of the air traffic system, with potential capacity and cost benefits. This distribution of tasks and decisions raises the concern that independent user actions will decrease the predictability and increase the complexity of the traffic system, hence inhibiting and possibly reversing any potential benefits. One such concern is the adverse impact of uncoordinated actions by individual aircraft on the stability of separation assurance. For example, individual aircraft performing self-separation may resolve predicted losses of separation or conflicts with some traffic, only to result in secondary conflicts with other traffic or with the same traffic later in time. In answer to this concern, this paper proposes metrics for preserving user trajectory flexibility to be used in self-separation along with other objectives. The hypothesis is that preserving trajectory flexibility will naturally reduce the creation of secondary conflicts by bringing about implicit coordination between aircraft. The impact of using these metrics on improving self-separation stability is investigated by measuring the impact on secondary conflicts. The scenarios analyzed include aircraft in en route airspace with each aircraft meeting a required time of arrival in a twenty minute time horizon while maintaining separation from the surrounding traffic and using trajectory flexibility metrics to mitigate the risk of secondary conflicts. Preliminary experiments showed promising results in that the trajectory flexibility preservation reduced the potential for secondary conflicts.

Idris, Husni↗

Validation of SMAP Surface Soil Moisture Products with Core Validation Sites

The NASA Soil Moisture Active Passive (SMAP) mission has utilized a set of core validation sites as the primary methodology in assessing the soil moisture retrieval algorithm performance. Those sites provide well calibrated in situ soil moisture measurements within SMAP product grid pixels for diverse conditions and locations.The estimation of the average soil moisture within the SMAP product grid pixels based on in situ measurements is more reliable when location specific calibration of the sensors has been performed and there is adequate replication over the spatial domain, with an up-scaling function based on analysis using independent estimates of the soil moisture distribution. SMAP fulfilled these requirements through a collaborative CalVal Partner program.This paper presents the results from 34 candidate core validation sites for the first eleven months of the SMAP mission. As a result of the screening of the sites prior to the availability of SMAP data, out of the 34 candidate sites 18 sites fulfilled all the requirements at one of the resolution scales (at least). The rest of the sites are used as secondary information in algorithm evaluation. The results indicate that the SMAP radiometer-based soil moisture data product meets its expected performance of 0.04 cu m/cu m volumetric soil moisture (unbiased root mean square error); the combined radar-radiometer product is close to its expected performance of 0.04 cu m/cu m, and the radar-based product meets its target accuracy of 0.06 cu m/cu m (the lengths of the combined and radar-based products are truncated to about 10 weeks because of the SMAP radar failure). Upon completing the intensive CalVal phase of the mission the SMAP project will continue to enhance the products in the primary and extended geographic domains, in co-operation with the CalVal Partners, by continuing the comparisons over the existing core validation sites and inclusion of candidate sites that can address shortcomings.

SMAP↗

High power, extended temperature range-capable, highly abuse overcharge and discharge tolerant rechargeable battery cell and pack

Provided are electrochemical secondary cells that exhibit excellent abuse tolerance, deep discharge and overcharge conditions including at extreme temperatures and remain robust and possess excellent performance. Cells as provided herein include: a cathode a polycrystalline cathode electrochemically active material including the formula Li1+xMO2+y, wherein −0.9≤x≤0.3, −0.3≤y≤0.3, and wherein M includes Ni at 80 atomic percent or higher relative to total M, the cathode electrochemically active material comprising a non-uniform distribution of Co; an anode including an anode electrochemically active material of the formula Li4+aTi5O12+b wherein −0.3≤a≤3.3, −0.3≤b≤0.3; and wherein the anode and the cathode each independently include a current collector substrate comprising aluminium.

Sahin, Kenan↗

Use of Microgravity to Control the Microstructure of Eutectics

This grant began in June of 1996. Its long term goal is to be able to control the microstructure of directionally solidified eutectic alloys, through an improved understanding of the influence of convection. The primary objective of the present projects is to test hypotheses for the reported influence of microgravity on the microstructure of three fibrous eutectics (MnBi-Bi, InSb-NiSb, Al3Ni-Al). A secondary objective is to determine the influence of convection on the microstructure of other eutectic alloys. Two doctoral students and a masters student supported as a teaching assistant were recruited for this research. Techniques were developed for directional solidification of MnBi-Bi eutectics with periodic application of current pulses to produce an oscillatory freezing rate. Image analysis techniques were developed to obtain the variation in MnBi fiber spacing, which was found to be normally distributed. The mean and standard deviation of fiber spacing were obtained for several freezing conditions. Eighteen ampoules were prepared for use in the gradient freeze furnace QUELD developed at Queen's University for use in microgravity. Nine of these ampoules will be solidified soon at Queen's in a ground-based model. We hope to solidify the other nine in the QUELD that is mounted on the Canadian Microgravity Isolation Mount on MIR. Techniques are being developed for directional solidification of the Al-Si eutectic at different freezing rates, with and without application of accelerated crucible rotation to induce convection. For the first time, theoretical methods are being developed to analyze eutectic solidification with an oscillatory freezing rate. In a classical sharp-interface model, we found that an oscillatory freezing rate increases the deviation of the average interfacial composition from the eutectic, and increases the undercooling of the two phases by different amounts. This would be expected to change the volume fraction solidifying and the fiber spacing. Because of difficulties in tracking the freezing interfaces of the two solid phases, a phase-field model is also being developed. A paper demonstrating application of phase field methods to periodic structures has been submitted for publication.

Wilcox, William R.↗

Fe-Ni Mobilization in Primitive Co Chondrites: Implications for Progressive Aqueous Alteration in the Parent Body

Chondrites that escaped significant secondary alteration are essential for investigating isotopic signatures of the protosolar nebula and constraining early solar system chronology. Telus et al. showed that fluid-induced Fe and Ni mobilization occurred even in the most unequilibrated ordinary chondrites (UOCs), both falls and finds. CO3.0s are more pristine than ordinary chondrites of the same petrologic type, based on presolar silicate grain abundances [2]. Here, we extend the study of [1] by analyzing the Fe and Ni distributions in CO3.0s, ALHA 77307, DOM 08006, DOM 10104, and MIL 090038, and Acfer 094 (ungrouped C3.0) to better characterize the alteration history of these primitive chondrites. We are especially interested in whether these chondrites are good candidates for studying the Fe-60-Ni-60 systematics of chondrules.

M Telus↗

Understanding the Applicability of Gas/Particle Partitioning Theory to SOA using Novel Chemically-Speciated Partitioning Measurements (Final Report)

The main objective of this research grant project was to investigate the physical-chemical processes and properties of particles and partitioning gases that influence gas/particle (G/P) partitioning and timescales for equilibration, to directly determine the conditions under which equilibrium G/P partitioning theory can be applied to secondary organic aerosol (SOA). SOA constitutes a major component of submicron particles in the atmosphere, which have important implications for air quality, human and ecosystem health, radiation balance, and climate; however SOA formation, evolution and losses are not well understood. Use of novel on-line measurements of chemically-speciated partitioning measurements of both gas-phase and particle-phase components was a central component to advancing these scientific goals. The key approach was to conduct environmental chamber studies with systems of increasing complexity to determine G/P partitioning rates and equilibrium states for chemically-speciated SOA components. The project builds on our previous work on gas-wall partitioning that must be understood in order to study G/P partitioning in chambers, and to help extrapolate the results to be atmospherically relevant. The goal was to employ measurements and modeling to systematically determine when G/P partitioning theory accurately describes the distribution of oxidized organic compounds in the gas and aerosol phases, and when and why it does not (e.g., aerosol phase-state kinetic limitations, non-ideal mixing, phase separation, oligomer formation,), for chemical and physical conditions typically found throughout the continental boundary layer.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

CO 2 Capture Characteristics of Hyperbranched Poly(alkylene imine): A Molecular Dynamics Simulation Approach

This study explores the CO 2 capture characteristics of hyperbranched poly(ethylenimine) (HB-PEI) and poly- (propyleneimine) (HB-PPI) through molecular dynamics simulations using density functional theory-calibrated force fields. Key features such as density, free volume, glass transition temperature, CO 2 /H 2 O distribution, and molecular diffusion are systematically investigated to elucidate structure−function relationships under dry and hydrated conditions. HB-PEI demonstrates a slightly higher density and lower free volume compared to HB-PPI yet shows superior CO 2 capture due to the high amine concentration. Glass transition analysis indicates a higher thermal mobility in HBPEI, enhancing the CO 2 diffusivity. Pair correlation and coordination analyses confirm a stronger affinity of CO 2 with primary and secondary amines, particularly in hydrated environments where water competes with CO 2 for binding sites. Despite its more compact structure, HB-PEI outperformed HB-PPI in CO 2 and H 2 O transport, as confirmed by higher diffusion coefficients across all hydration levels. These findings highlight a critical balance among polymer architecture, amine accessibility, and hydration in designing next-generation solid amine sorbents for efficient direct air capture applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Photodissociation of iso-propoxy (i-C 3 H 7 O) radical at 248 nm

Photodissociation of the i-C 3 H 7 O radical is investigated using fast beam photofragment translational spectroscopy. Neutral i-C 3 H 7 O radicals are produced through the photodetachment of a fast beam of i-C 3 H 7 O - anions and are subsequently dissociated at 248 nm (5.0 eV). Furthermore, the dominant product channels are CH 3 + CH 3 CHO and OH + C 3 H 6 with some contribution from H + C 3 H 6 O. The CH 3 and H loss channels are attributed to dissociation on the ground electronic state of i-C 3 H 7 O, but in a nonstatistical manner because calculated RRKM dissociation rates exceed the rate of energy randomization. Translational energy and angular distributions for OH loss are consistent with ground state dissociation, but the branching ratio for this channel is considerably higher than predicted from RRKM rate calculations. Additionally, i-C 3 H 7 O undergoes three-body fragmentation to CH 3 + CH 3 + HCO and CH 3 + CH 4 + CO. These three-body channels are attributed to dissociation of i-C 3 H 7 O to CH 3 + CH 3 CHO, followed by secondary dissociation of CH 3 CHO on its ground electronic state.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗