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All sourcesNASA NTRSDOE OSTI
NASA NTRS2026

A Review of Pump Package Assembly Anomalies and Demonstration to Gain Motor Controller Replacement Capability

The International Space Station (ISS) generates heat within the US modules from systems used to operate the station, maintain crew health, and conduct science experiments in the orbiting laboratory. The Internal Thermal Control System (ITCS) collects this heat in water loops and transfers it to the external ammonia system for rejection to space. The ITCS uses six Pump Package Assemblies (PPA) as the motive force to circulate the water within the Lab, Node 2, and Node 3 (Node 1 is parasitic to the Lab and Node 3 ITCS loops). In the life of ISS, 3 PPAs have had to be replaced and 2 PPAs are currently showing signs of degradation. The first PPA to fail in 2003 was due to early coolant chemistry issues; the remaining pump failures and current pump degradations are determined to be related to the Pump/Fan Motor Controller (PFMC), with their individual signatures all being unique to this point. The PFMC of one of the failed PPAs was returned and testing confirmed its sub-components to be the root cause of the PPA failure. Due to the relative size and weight of the standalone PFMC in comparison to the integrated assembly, it is desired, from a launch and on-orbit stowage perspective, to replace the PFMC component of the degraded PPA instead of the entire PPA. The PPA was not designed for this capability, so on the ground demonstrations are planned using crew tools to show that the PFMC can be replaced on-orbit while maintaining full functionality. This paper will focus on the signatures of the two most recent PPA failures and the two PPAs showing signs of degradation, in addition to presenting the findings from the PFMC demonstration effort.

Aaron Rodriguez↗
NASA NTRS2005

System Design and Performance of the Two-Gyro Science Mode For the Hubble Space Telescope

For fifteen years, the science mission of the Hubble Space Telescope (HST) required using at least three of the six on-board rate gyros for attitude control. Failed gyros were eventually replaced through Space Shuttle Servicing Missions. The tragic loss of the Space Shuttle Columbia has resulted in the cancellation of all planned Shuttle based missions to HST. While a robotic servicing mission is currently being planned instead, controlling with alternate sensors to replace failed gyros can extend the HST science gathering until a servicing mission can be performed, and also extend science at HST's end of life. Additionally, sufficient performance may allow a permanent transition to operations with less than 3 gyros (by intentionally turning off working gyros saving them for later use) allowing for an even greater science mission extension. To meet this need, a Two Gyro Science (TGS) mode has been designed and implemented using magnetometers (Magnetic Sensing System - MSS), Fixed Head Star Trackers (FHSTs), and Fine Guidance Sensors (FGSs) to control vehicle rate about the missing gyro input axis. The development of the TGS capability is the largest re-design of HST operations undertaken, since it affects several major spacecraft subsystems, the most heavily being the Pointing Control System (PCS) and Flight Software (FSW). Additionally, and equally important, are the extensive modifications and enhancements of the Planning and Scheduling system which must now be capable of scheduling science observations while taking into account several new constraints imposed by the TGS operational modes (such as FHST availability and magnetic field geometry) that will impact science gathering efficiency and target availability. This paper discusses the systems engineering design, development, and performance of the TGS mode, now in its final stages of completion.

Prior, Michael↗
NASA NTRS2004

High Power Density Motors

With the growing concerns of global warming, the need for pollution-free vehicles is ever increasing. Pollution-free flight is one of NASA's goals for the 21" Century. , One method of approaching that goal is hydrogen-fueled aircraft that use fuel cells or turbo- generators to develop electric power that can drive electric motors that turn the aircraft's propulsive fans or propellers. Hydrogen fuel would likely be carried as a liquid, stored in tanks at its boiling point of 20.5 K (-422.5 F). Conventional electric motors, however, are far too heavy (for a given horsepower) to use on aircraft. Fortunately the liquid hydrogen fuel can provide essentially free refrigeration that can be used to cool the windings of motors before the hydrogen is used for fuel. Either High Temperature Superconductors (HTS) or high purity metals such as copper or aluminum may be used in the motor windings. Superconductors have essentially zero electrical resistance to steady current. The electrical resistance of high purity aluminum or copper near liquid hydrogen temperature can be l/lOO* or less of the room temperature resistance. These conductors could provide higher motor efficiency than normal room-temperature motors achieve. But much more importantly, these conductors can carry ten to a hundred times more current than copper conductors do in normal motors operating at room temperature. This is a consequence of the low electrical resistance and of good heat transfer coefficients in boiling LH2. Thus the conductors can produce higher magnetic field strengths and consequently higher motor torque and power. Designs, analysis and actual cryogenic motor tests show that such cryogenic motors could produce three or more times as much power per unit weight as turbine engines can, whereas conventional motors produce only 1/5 as much power per weight as turbine engines. This summer work has been done with Litz wire to maximize the current density. The current is limited by the amount of heat it generates. By increasing the heat transfer out of the wire, the wires can carry a larger current and therefore produce more force. This was done by increasing the surface area of the wire to allow more coolant to flow over it. Litz wire was used because it can carry high frequency current. It also can be deformed into configurations that would increase the surface area. The best configuration was determined by heat transfer and force plots that were generated using Maxwell 2D. Future work will be done by testing and measuring the thrust force produced by the wires in a magnetic field.

Kascak, Daniel J.↗
NASA NTRS2005

System Design and Performance of the Two-Gyro Science Mode For the Hubble Space Telescope

For fifteen years, the science mission of the Hubble Space Telescope (HST) required using at least three of the six on-board rate gyros for attitude control. Failed gyros were eventually replaced through Space Shuttle Servicing Missions. The tragic loss of the Space Shuttle Columbia has resulted in the cancellation of all planned Shuttle based missions to HST. While a robotic servicing mission is currently being planned instead, controlling with alternate sensors to replace failed gyros can extend the HST science gathering until a servicing mission can be performed, and also extend science at HST s end of life. Additionally, sufficient performance may allow a permanent transition to operations with less than 3 gyros (by intentionally turning off working gyros saving them for later use) allowing for an even greater science mission extension. To meet this need, a Two Gyro Science (TGS) mode has been designed and implemented using magnetometers (Magnetic Sensing System - MSS), Fixed Head Star Trackers (FHSTs), and Fine Guidance Sensors (FGSs) to control vehicle rate about the missing gyro input axis. The development of the TGS capability is the largest re-design of HST operations undertaken, since it affects several major spacecraft subsystems, the most heavily being the Pointing Control System (PCS) and Flight Software (FSW). Additionally, and equally important, are the extensive modifications and enhancements of the Planning and Scheduling system which must now be capable of scheduling science observations while taking into account several new constraints imposed by the TGS operational modes (such as FHST availability and magnetic field geometry) that will impact science gathering efficiency and target availability. This paper discusses the systems engineering design, development, and performance of the TGS mode, now in its final stages of completion.

Prior, Michael↗
NASA NTRS2005

Shuttle Orbiter Contingency Abort Aerodynamics: Real-Gas Effects and High Angles of Attack

An important element of the Space Shuttle Orbiter safety improvement plan is the improved understanding of its aerodynamic performance so as to minimize the "black zones" in the contingency abort trajectories [1]. These zones are regions in the launch trajectory where it is predicted that, due to vehicle limitations, the Orbiter will be unable to return to the launch site in a two or three engine-out scenario. Reduction of these zones requires accurate knowledge of the aerodynamic forces and moments to better assess the structural capability of the vehicle. An interesting aspect of the contingency abort trajectories is that the Orbiter would need to achieve angles of attack as high as 60deg. Such steep attitudes are much higher than those for a nominal flight trajectory. The Orbiter is currently flight certified only up to an angle of attack of 44deg at high Mach numbers and has never flown at angles of attack larger than this limit. Contingency abort trajectories are generated using the data in the Space Shuttle Operational Aerodynamic Data Book (OADB) [2]. The OADB, a detailed document of the aerodynamic environment of the current Orbiter, is primarily based on wind-tunnel measurements (over a wide Mach number and angle-of-attack range) extrapolated to flight conditions using available theories and correlations, and updated with flight data where available. For nominal flight conditions, i.e., angles of attack of less than 45deg, the fidelity of the OADB is excellent due to the availability of flight data. However, at the off-nominal conditions, such as would be encountered on contingency abort trajectories, the fidelity of the OADB is less certain. The primary aims of a recent collaborative effort (completed in the year 2001) between NASA and Boeing were to determine: 1) accurate distributions of pressure and shear loads on the Orbiter at select points in the contingency abort trajectory space; and 2) integrated aerodynamic forces and moments for the entire vehicle and the control surfaces (body flap, speed brake, and elevons). The latter served the useful purpose of verification of the aerodynamic characteristics that went into the generation of the abort trajectories.

Prabhu, Dinesh K.↗
NASA NTRS2010

Agricultural Productivity Forecasts for Improved Drought Monitoring

Water stresses on agricultural crops during critical phases of crop phenology (such as grain filling) has higher impact on the eventual yield than at other times of crop growth. Therefore farmers are more concerned about water stresses in the context of crop phenology than the meteorological droughts. However the drought estimates currently produced do not account for the crop phenology. US Department of Agriculture (USDA) and National Oceanic and Atmospheric Administration (NOAA) have developed a drought monitoring decision support tool: The U.S. Drought Monitor, which currently uses meteorological droughts to delineate and categorize drought severity. Output from the Drought Monitor is used by the States to make disaster declarations. More importantly, USDA uses the Drought Monitor to make estimates of crop yield to help the commodities market. Accurate estimation of corn yield is especially critical given the recent trend towards diversion of corn to produce ethanol. Ethanol is fast becoming a standard 10% ethanol additive to petroleum products, the largest traded commodity. Thus the impact of large-scale drought will have dramatic impact on the petroleum prices as well as on food prices. USDA's World Agricultural Outlook Board (WAOB) serves as a focal point for economic intelligence and the commodity outlook for U.S. WAOB depends on Drought Monitor and has emphatically stated that accurate and timely data are needed in operational agrometeorological services to generate reliable projections for agricultural decision makers. Thus, improvements in the prediction of drought will reflect in early and accurate assessment of crop yields, which in turn will improve commodity projections. We have developed a drought assessment tool, which accounts for the water stress in the context of crop phenology. The crop modeling component is done using various crop modules within Decision Support System for Agrotechnology Transfer (DSSAT). DSSAT is an agricultural crop simulation system, which integrates the effects of soil, crop phenotype, weather, and management options. It has been in use for more than 15 years by researchers, growers and has become a de-facto standard in crop modeling communities spanning over 100 countries. The meteorological forcings to DSSAT are provided by NASA s National Land Data Assimilation System (NLDAS) datasets. NLDAS is a framework that incorporates atmospheric forcing and land parameter values along with land surface models to diagnose and predict the state of the land surface.

Limaye, Ashutosh↗
DOE OSTI2025

Optimizing Facility Operations by Applying Machine Learning to the Army Reserve Enterprise Building Control System (Final Report)

Thousands of U.S. Department of Defense (DoD) buildings have building automation systems (BASs) and/or advanced meters. Although these systems have a wealth of data, performance optimization requires time and expertise to review and act on that information. Machine learning (ML) can provide automated and actionable insights to controls operators. This demonstration implemented proven ML methods on the Army Reserve Enterprise Building Control System. ML refers to algorithms that “learn” from data and improve their performance on a given task over time. In the buildings domain these tasks range from predicting future energy consumption, to identifying operational issues before faults occur, to optimizing control decisions. To learn, ML requires input data, which – for buildings – typically consists of instrument data such as energy consumption data and subsystem controls information such as set-point temperatures, and context data consisting of information such as the physical location of the building, the area of the building, and the weather. ML models use the relationships learned from the input data to make predictions with new, previously unseen, data. The team was able to investigate and successfully implement the following ML use cases: labeling consumption data as anomalous or non-anomalous; baseline whole-building load prediction (unknown fault status); fault detection (validation not possible); and site prioritization for energy-related projects. Due to the constraints of the project, interventions were not able to be implemented during the demonstration; therefore, assessments of operational cost savings and maintenance avoided could not be performed. The project has been presented at two leading national building conferences and two additional publications to peer-reviewed journals are currently in preparation.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
NASA NTRS1993

Concept report: Experimental vector magnetograph (EXVM) operational configuration balloon flight assembly

The observational limitations of earth bound solar studies has prompted a great deal of interest in recent months in being able to gain new scientific perspectives through, what should prove to be, relatively low cost flight of the magnetograph system. The ground work done by TBE for the solar balloon missions (originally planned for SOUP and GRID) as well as the rather advanced state of assembly of the EXVM has allowed the quick formulation of a mission concept for the 30 cm system currently being assembled. The flight system operational configuration will be discussed as it is proposed for short duration flight (on the order of one day) over the continental United States. Balloon hardware design requirements used in formulation of the concept are those set by the National Science Balloon Facility (NSBF), the support agency under NASA contract for flight services. The concept assumes that the flight hardware assembly would come together from three development sources: the scientific investigator package, the integration contractor package, and the NSBF support system. The majority of these three separate packages can be independently developed; however, the computer control interfaces and telemetry links would require extensive preplanning and coordination. A special section of this study deals with definition of a dedicated telemetry link to be provided by the integration contractor for video image data for pointing system performance verification. In this study the approach has been to capitalize to the maximum extent possible on existing hardware and system design. This is the most prudent step that can be taken to reduce eventual program cost for long duration flights. By fielding the existing EXVM as quickly as possible, experience could be gained from several short duration flight tests before it became necessary to commit to major upgrades for long duration flights of this system or of the larger 60 cm version being considered for eventual development.

Source record↗
NASA NTRS1998

The Software Design for the Wide-Field Infrared Explorer Attitude Control System

The Wide-Field Infrared Explorer (WIRE), currently scheduled for launch in September 1998, is the fifth of five spacecraft in the NASA/Goddard Small Explorer (SMEX) series. This paper presents the design of WIRE's Attitude Control System flight software (ACS FSW). WIRE is a momentum-biased, three-axis stabilized stellar pointer which provides high-accuracy pointing and autonomous acquisition for eight to ten stellar targets per orbit. WIRE's short mission life and limited cryogen supply motivate requirements for Sun and Earth avoidance constraints which are designed to prevent catastrophic instrument damage and to minimize the heat load on the cryostat. The FSW implements autonomous fault detection and handling (FDH) to enforce these instrument constraints and to perform several other checks which insure the safety of the spacecraft. The ACS FSW implements modules for sensor data processing, attitude determination, attitude control, guide star acquisition, actuator command generation, command/telemetry processing, and FDH. These software components are integrated with a hierarchical control mode managing module that dictates which software components are currently active. The lowest mode in the hierarchy is the 'safest' one, in the sense that it utilizes a minimal complement of sensors and actuators to keep the spacecraft in a stable configuration (power and pointing constraints are maintained). As higher modes in the hierarchy are achieved, the various software functions are activated by the mode manager, and an increasing level of attitude control accuracy is provided. If FDH detects a constraint violation or other anomaly, it triggers a safing transition to a lower control mode. The WIRE ACS FSW satisfies all target acquisition and pointing accuracy requirements, enforces all pointing constraints, provides the ground with a simple means for reconfiguring the system via table load, and meets all the demands of its real-time embedded environment (16 MHz Intel 80386 processor with 80387 coprocessor running under the VRTX operating system). The mode manager organizes and controls all the software modules used to accomplish these goals, and in particular, the FDH module is tightly coupled with the mode manager.

Anderson, Mark O.↗
NASA NTRS2016

Proximity Link Design and Performance Options for a Mars Areostationary Relay Satellite

Current and near-term Mars relay telecommunications services are provided by a set of NASA and ESA Mars science orbiters equipped with UHF relay communication payloads employing operationally simple low gain antennas. These have been extremely successful in supporting a series of landed Mars mission, greatly increasing data return relative to direct-to-Earth lander links. Yet their relay services are fundamentally constrained by the short contact times available from the selected science orbits. Future Mars areostationary orbiters, flying in circular, equatorial, 1- sol orbits, offer the potential for continuous coverage of Mars landers and rovers, radically changing the relay support paradigm. Achieving high rates on the longer slant ranges to areostationary altitude will require steered, high-gain links. Both RF and optical options exist for achieving data rates in excess of 100 Mb/s. Several point designs offer a measure of potential user burden, in terms of mass, volume, power, and pointing requirements for user relay payloads, as a function of desired proximity link performance.

telecommunications↗
NASA NTRS2009

Failure modes and low temperature performance of DC/DC converters

Several standard tests to evaluate key (direct current) DC/DC converter parameters were performed on different models of hybrid radiation-hard DC/DC converters. These tests were done to assess both performance and reliability during space applications that operate the converters at temperatures below the lower military range of -5°C. One of the converters failed near -110°C, but another DC/DC converter model started normally at temperatures as low as 140°C. The latter showed acceptable performance during turn-on, load transient, and synchronization tests even though some minor anomalies were observed. These results show good promise for its use in applications where the DC/DC converters will be operated at lower temperatures. An application circuit was also built and preliminary tests were performed on a commercial (low drop out) LDO type of DC to DC converter with adjustable output voltage. These can be used in point of load (POL) applications. This latter device functioned properly on the few tests that were performed; however, more testing is needed to identify potential issues with space use of this and similar devices.

Leon, Rosa↗
DOE OSTI2023

Ocean Energy: Markets - Currency - Impact. Dimension of & Choices in the Technology Development Space: Preprint

This paper presents considerations of the employment of ocean wave energy to support different energy demand side applications. The key aspect in these considerations is the wave energy supported achievable positive impact and associated tangible contribution in service of common societal good and of the natural commons. The level of impact that can be delivered is dependent on both, the level of contribution of the supported energy use application, and the compatibility and unique suitability of the wave energy resource and its characteristics with the needs of the application. Thus, a variety of ocean wave energy markets, the key value indicators or "currency' in which these markets trade the value delivered and the achievable positive impact, are reflected upon. Ocean wave energy supported acquisition of high quality ocean system data across a wide spectrum of system properties is identified as a highly impactful application enabling and/or improving a comprehensive range of impactful ocean system activities. The technology development process towards these markets and desired impacts requires relevant technology development progress guidance and metrics. Going beyond technology readiness levels and technology performance levels, the notion of further technology development progress scales towards high impact and high contribution are proposed. These scales and the associated technology properties can be regarded as additional technology development dimensions to span-up the technology development space in which desired system capability and functional requirement choices and subsequent ideation, innovation, research and technology development decisions can and are to be made.

data market↗
NASA NTRS2011

Dynamic Loads Generation for Multi-Point Vibration Excitation Problems

A random-force method has been developed to predict dynamic loads produced by rocket-engine random vibrations for new rocket-engine designs. The method develops random forces at multiple excitation points based on random vibration environments scaled from accelerometer data obtained during hot-fire tests of existing rocket engines. This random-force method applies random forces to the model and creates expected dynamic response in a manner that simulates the way the operating engine applies self-generated random vibration forces (random pressure acting on an area) with the resulting responses that we measure with accelerometers. This innovation includes the methodology (implementation sequence), the computer code, two methods to generate the random-force vibration spectra, and two methods to reduce some of the inherent conservatism in the dynamic loads. This methodology would be implemented to generate the random-force spectra at excitation nodes without requiring the use of artificial boundary conditions in a finite element model. More accurate random dynamic loads than those predicted by current industry methods can then be generated using the random force spectra. The scaling method used to develop the initial power spectral density (PSD) environments for deriving the random forces for the rocket engine case is based on the Barrett Criteria developed at Marshall Space Flight Center in 1963. This invention approach can be applied in the aerospace, automotive, and other industries to obtain reliable dynamic loads and responses from a finite element model for any structure subject to multipoint random vibration excitations.

Shen, Lawrence↗
NASA NTRS2016

Proximity Link Design and Performance Options for a Mars Areostationary Relay Satellite

Current and near-term Mars relay telecommunications services are provided by a set of NASA and ESA Mars science orbiters equipped with UHF relay communication payloads employing operationally simple low-gain antennas. These have been extremely successful in supporting a series of landed Mars mission, greatly increasing data return relative to direct-to-Earth lander links. Yet their relay services are fundamentally constrained by the short contact times available from the selected science orbits. Future Mars areostationary orbiters, flying in circular, equatorial, 1- sol orbits, offer the potential for continuous coverage of Mars landers and rovers, radically changing the relay support paradigm. Achieving high rates on the longer slant ranges to areostationary altitude will require steered, high-gain links. Both RF and optical options exist for achieving data rates in excess of 100 Mb/s. Several point designs offer a measure of potential user burden, in terms of mass, volume, power, and pointing requirements for user relay payloads, as a function of desired proximity link performance.

telecommunications↗
NASA NTRS2019

Creating Data-Driven Vector Visualizations of Satellite Orbit Tracks Using NASA GIBS and Worldview

NASA Earth Observing System (EOS) currently operates dozens of remote sensing satellites, many of which can be viewed directly in NASA’s open-source Worldview application. Much of this satellite imagery can be viewed in near-real time as it is processed and served by NASA’s Global Imagery Browse Service (GIBS). To better educate users on the time and location of imagery, GIBS serves orbit track specific layers for each satellite. Worldview has historically served these layers as raster images but recent updates have enabled the application to now serve these layers using vector tiles. With the release of Worldview v3.0, orbit track layers can be displayed using mapbox vector tiles (MVT). This visualization format allows users to not only view and change the color of orbit track layers, as they could do previously with rasters, but also inspect individual vector points and filter layers by specific parameters such as time. The data contained within a MVT is further enhanced in Worldview with the combination of a JSON description file served from GIBS used to describe the MVT data. This presentation will provide an overview of the process of consuming orbit track vector tiles and data files from GIBS using a pipeline to configure, build and ultimately display the orbit tracks in Worldview. Furthermore, the presentation aims to describe how others can leverage our open-source code to display and enhance vector layers in their own applications.

Rice, Zachary↗
NASA NTRS2020

Airborne Science Mission Capabilities of the NASA DC-8 and Possible Alternative Aircraft

Age-related concerns associated with operating the 50-year-old NASA Airborne Science Program DC-8 Flying Laboratory aircraft are raising concerns about the prospects of someday retiring the NASA DC-8. Given that eventuality, this study examines how current and anticipated science requirements can be incorporated with aeronautical performance and cost metrics for assessing, comparing, and down-selecting candidate replacement aircraft. A literature review of NASA DC-8 missions and interviews with current DC-8 science users provides context for the initial phase of this study and offers a pathway for collecting aircraft specifications. Performance models are developed and calibrated against published range-payload data for various mission fuel and payload weight combinations. The models are extended to three airborne science missions, with payload weights ranging from 30,000-52,000 lb and mission ranges up to 5,050 nmi. Results point towards the 767-200ER aircraft as a top contender offering a bit more experimenter floor-space, payload capacity, and range than the NASA DC-8, and to the U.S. Navy P-8 aircraft as a viable option offering perhaps not too much less of those items, with the relative benefit of using less fuel per mission.

Thomas A Ozoroski↗
DOE OSTI2024

Demonstration of Temperature Compensation Techniques for SPNDs Operating in High Temperatures

This report presents the testing results of rhodium-based self-powered neutron detectors (Rh-SPND) irradiated in a furnace dry tube from ambient temperature to 850°C at the Ohio State University Research Reactor. The purpose of the experiment is to demonstrate the technique and application of a temperature compensation technique for the Rh-SPND. This is performed by characterizing the temperature effects observed in past experiments—a displacement current and a stabilized dark current—of the Rh-SPND as a function of temperature under the models of shifting space charges as a product of photoconductivity properties. Low-power irradiation at the OSURR was performed with stabilized temperatures of ambient, 550, 575, 600, 625, 650, 675, and 700°C were first performed to obtain the curve fit parameters that describes the temperature effects. The results provided further insight for the behavior of the SPND at high temperatures in accordance with available insulation conductivity models. Transition points from photoconductivity to ionic conductivity were identified in the range of 550–600°C. Additionally, transition points ionic to electric conductivity were observed in the range of 675–700°C, however, the data was not able to fully capture the transition and did not have enough resolution to provide predictive compensation based only on temperature readings.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2024

Pure-Water-Fed Forward-Bias Bipolar Membrane CO 2 Electrolyzer

Coupling renewable electricity to reduce carbon dioxide (CO 2 ) electrochemically into carbon feedstocks offers a promising pathway to produce chemical fuels sustainably. While there has been success in developing materials and theory for CO 2 reduction, the widespread deployment of CO 2 electrolyzers has been hindered by challenges in the reactor design and operational stability due to CO 2 crossover and (bi)carbonate salt precipitation. Herein, we design asymmetrical bipolar membranes assembled into a zero-gap CO 2 electrolyzer fed with pure water, solving both challenges. By investigating and optimizing the anion-exchangelayer thickness, cathode differential pressure, and cell temperature, the forward-bias bipolar membrane CO 2 electrolyzer achieves a CO faradic efficiency over 80% with a partial current density over 200 mA cm –2 at less than 3.0 V with negligible CO 2 crossover. In addition, this electrolyzer achieves 0.61 and 2.1 mV h –1 decay rates at 150 and 300 mA cm –2 for 200 and 100 h, respectively. Postmortem analysis indicates that the deterioration of catalyst/polymer– electrolyte interfaces resulted from catalyst structural change, and ionomer degradation at reductive potential shows the decay mechanism. Furthermore, all these results point to the future research direction and show a promising pathway to deploy CO 2 electrolyzers at scale for industrial applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗