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At least 1,153 records · Page 64

Global, seasonal surface variations from satellite radiance measurements

Global, daily, visible, and infrared radiance measurements from the NOAA-5 Scanning Radiometer (SR) are analyzed for the months of January, April, July, and October 1977 to infer surface radiative properties. A radiative transfer model that simulates the spectral and angular characteristics of the NOAA-5 SR measurements is used to retrieve monthly mean surface visible reflectances and temperature at 25 km resolution. These surface properties were found sufficiently accurate for simulation of clear sky radiances to determine global, seasonal variations in cloudiness. Further comparisons of these results with other data highlight the analysis difficulties and radiative model shortcomings that must be overcome to monitor regional and seasonal variations of earth's surface. These preliminary results also provide an estimate of the magnitude of these variations.

Rossow, William B.↗

Forced convection and flow boiling with and without enhancement devices for top-side-heated horizontal channels

The effect of enhancement devices on flow boiling heat transfer in coolant channels, which are heated either from the top side or uniformly was studied. Studies are completed of the variations in the local (axial and circumferential) and mean heat transfer coefficients in horizontal, top-heated coolant channels with smooth walls and internal heat transfer enhancement devices. The working fluid is freon-11. The objectives are to: (1) examine the variations in both the mean and local (axial and circumferential) heat transfer coefficients for a circular coolant channel with either smooth walls or with both a twisted tape and spiral finned walls; (2) examine the effect of channel diameter (and the length-to-diameter aspect ratio) variations for the smooth wall channel; and (3) develop and improved data reduction analysis. The case of the top-heated, horizontal flow channel with smooth wall (1.37 cm inside diameter, and 122 cm heated length) was completed. The data were reduced using a preliminary analysis based on the heated hydraulic diameter. Preliminary examination of the local heat transfer coefficient variations indicated that there are significant axial and circumferential variations. However, it appears that the circumferential variation is more significant than the axial ones. In some cases, the circumferential variations were as much as a factor of ten. The axial variations rarely exceeded a factor of three.

Boyd, Ronald D., Sr.↗

Development of a sensitivity analysis technique for multiloop flight control systems

This report presents the development and application of a sensitivity analysis technique for multiloop flight control systems. This analysis yields very useful information on the sensitivity of the relative-stability criteria of the control system, with variations or uncertainties in the system and controller elements. The sensitivity analysis technique developed is based on the computation of the singular values and singular-value gradients of a feedback-control system. The method is applicable to single-input/single-output as well as multiloop continuous-control systems. Application to sampled-data systems is also explored. The sensitivity analysis technique was applied to a continuous yaw/roll damper stability augmentation system of a typical business jet, and the results show that the analysis is very useful in determining the system elements which have the largest effect on the relative stability of the closed-loop system. As a secondary product of the research reported here, the relative stability criteria based on the concept of singular values were explored.

Vaillard, A. H.↗

Observation of daily and annular variations in the {sup 214}Po half-life

Results: of the analysis of a time series of values of the half-life (τ) of the {sup 214}Po nucleus with a different time step obtained from the TAU-1 (354 days) and TAU-2 (973 days) installations are presented. The annual variation with an amplitude of (9.8 ± 0.6) × 10{sup −4} and daily variations in the solar, lunar, and sidereal times with amplitudes of (5.3 ± 0.3) × 10{sup −4}, (6.9 ± 2.0) × 10{sup −4}, and (7.2 ± 1.2) × 10{sup −4}, respectively, are found in the series of τ values. It is shown that variations in microclimatic parameters cannot be a cause of τ variations.

07 ISOTOPE AND RADIATION SOURCES↗

The Discovery of the Long-Period, Eccentric Planet Kepler-88 d and System Characterization with Radial Velocities and Photodynamical Analysis

We present the discovery of Kepler-88 d (P{sub d} = 1403±14 days, Msini{sub d}=965±44 M{sub ⊕}=3.04±0.13 M{sub J}, e{sub d}=0.41±0.03) based on six years of radial velocity (RV) follow-up from the W. M. Keck Observatory High Resolution Echelle Spectrometer spectrograph. Kepler-88 has two previously identified planets. Kepler-88 b (KOI-142.01) transits in the NASA Kepler photometry and has very large transit timing variations (TTVs). Nesvorný et al. performed a dynamical analysis of the TTVs to uniquely identify the orbital period and mass of the perturbing planet (Kepler-88 c), which was later was confirmed with RVs from the Observatoire de Haute-Provence (OHP). To fully explore the architecture of this system, we performed photodynamical modeling on the Kepler photometry combined with the RVs from Keck and OHP and stellar parameters from spectroscopy and Gaia. Planet d is not detectable in the photometry, and long-baseline RVs are needed to ascertain its presence. A photodynamical model simultaneously optimized to fit the RVs and Kepler photometry yields the most precise planet masses and orbital properties yet for b and c: P{sub b}=10.91647±0.00014 days, M{sub b}=9.5±1.2 M{sub ⊕}, P{sub c}=22.2649±0.0007 days, and M{sub c}=214.0±5.3 M{sub ⊕}. The photodynamical solution also finds that planets b and c have low eccentricites and low mutual inclination, are apsidally anti-aligned, and have conjunctions on the same hemisphere of the star. Continued RV follow-up of systems with small planets will improve our understanding of the link between inner planetary system architectures and giant planets.

79 ASTRONOMY AND ASTROPHYSICS↗

Statistical analysis of pulsed-neutron well logs in monitoring injected carbon dioxide

Pulsed-neutron well logs (PNLs) were acquired to monitor CO 2 storage associated with enhanced oil recovery. This work quantifies the precision of repeat PNLs using data from four wells and 15 repeat PNLs. Root-mean-square (RMS) precision for the repeat PNLs was less than 3%, indicating good agreement between the baseline and repeat PNLs. Evaluations of scaled relative difference (Scaled-D) showed variation in precision among individual wells and formations. Analysis of false-positive rates (FPRs) across the entire data set showed that a Scaled-D threshold in sandstone formations of approximately ±8% resulted in a 1% FPR. These Scaled-D precision thresholds were used to estimate the value of CO 2 saturation able to be confidently distinguished from baseline. The detection limit for CO 2 is lowest for high-porosity formations filled with saline water and is highest for low-porosity formations filled with fresh water. Thus, detection of vertical out-of-zone CO 2 migration using repeat PNLs is a function of instrument precision, petrophysical properties, and hydrology, all of which must be taken into account as part of the monitoring program. Here, the results of this work provide insight into how PNLs may be included within monitoring plans to detect vertical out-of-zone CO 2 migration along a wellbore or instances of wellbore failure and provide a quantitative basis for establishing detection limits of repeat PNLs to distinguish change from baseline conditions.

54 ENVIRONMENTAL SCIENCES↗

Increased inflammation as well as decreased endoplasmic reticulum stress and translation differentiate pancreatic islets from donors with pre-symptomatic stage 1 type 1 diabetes and non-diabetic donors

Aims/hypothesis Progression to type 1 diabetes is associated with genetic factors, the presence of autoantibodies and a decline in beta cell insulin secretion in response to glucose. Very little is known regarding the molecular changes that occur in human insulin-secreting beta cells prior to the onset of type 1 diabetes. Herein, we applied an unbiased proteomics approach to identify changes in proteins and potential mechanisms of islet dysfunction in islet-autoantibody-positive organ donors with pre-symptomatic stage 1 type 1 diabetes (HbA1c ≤42 mmol/mol [6.0%]). We aimed to identify pathways in islets that are indicative of beta cell dysfunction. Methods Multiple islet sections were collected through laser microdissection of frozen pancreatic tissues from organ donors positive for single or multiple islet autoantibodies (AAb + , n=5), and age (±2 years)- and sex-matched non-diabetic (ND) control donors (n=5) obtained from the Network for Pancreatic Organ donors with Diabetes (nPOD). Islet sections were subjected to MS-based proteomics and analysed with label-free quantification followed by pathway and functional annotations. Results Analyses resulted in ~4500 proteins identified with low false discovery rate (<1%), with 2165 proteins reliably quantified in every islet sample. We observed large inter-donor variations that presented a challenge for statistical analysis of proteome changes between donor groups. We therefore focused on only the donors with stage 1 type 1 diabetes who were positive for multiple autoantibodies (mAAb + , n=3) and genetic risk compared with their matched ND controls (n=3) for the final statistical analysis. Approximately 10% of the proteins (n=202) were significantly different (unadjusted p<0.025, q<0.15) for mAAb + vs ND donor islets. The significant alterations clustered around major functions for upregulation in the immune response and glycolysis, and downregulation in endoplasmic reticulum (ER) stress response as well as protein translation and synthesis. The observed proteome changes were further supported by several independent published datasets, including a proteomics dataset from in vitro proinflammatory cytokine-treated human islets and single-cell RNA-seq datasets from AAb + individuals. Conclusions/interpretation In situ human islet proteome alterations in stage 1 type 1 diabetes centred around several major functional categories, including an expected increase in immune response genes (elevated antigen presentation/HLA), with decreases in protein synthesis and ER stress response, as well as compensatory metabolic response. The dataset serves as a proteomics resource for future studies on beta cell changes during type 1 diabetes progression and pathogenesis. Data availability The LC-MS raw datasets that support the findings of this study have been deposited in the online repository: MassIVE (https://massive.ucsd.edu/ProteoSAFe/static/massive.jsp) with accession no. MSV000090212.

Autoantibody-positive↗

Zinc concentration affects the functional groups of microbial communities in sugarcane-cultivated soil

The addition of zinc (Zn) to the soil has significant gains in sugarcane productivity. The understanding of the consequences of zinc application requires insight into ecological aspects of changes in soil microbial communities. Here, we evaluated the effects of zinc application on richness, diversity, evenness and structure of microbial functional genes in sugarcane-cultivated soil, and response thresholds of abundance for groups of microbial functional genes on different zinc concentrations added to the soil (0, 5, 10 and 20 kg Zn ha -1 ) in two sugarcane fields in the Northeastern São Paulo state, Brazil. Using a high-density functional gene array termed GeoChip 5.0, which contains 101,796 distinct probes belonging to gene categories involved in zinc transport, secondary metabolism, stress, virulence and nutrient cycling, differences were observed in the functional gene structure of microbial communities and abundance of specific gene families with a threshold between 5 and 10 kg Zn ha -1 . However, the richness, diversity and evenness of functional genes did not differ across the zinc gradients in soil. Cluster analysis based on microbial functional subcategories revealed variation in abundances across the gradient of zinc concentrations in soil mainly for virulence, stress, secondary metabolism, and carbon- and phosphorus-cycling-related gene families. A threshold in abundance was observed between 5 and 10 kg Zn ha -1 with high abundance of microbial gene families associated with zinc transporter proteins, antioxidant enzymes, exoenzymes associated with infection, secretion proteins, virulence regulatory genes, carbon fixation, and phosphorus utilization in soils supplemented with up to 5 kg Zn ha -1 . In these same soils, reduced abundance was observed for gene families associated with methanogenesis, metabolism of halogen and carotenoid, and antiphagocytosis compared with soil supplements with 10 or 20 kg Zn ha -1 . The results suggest that changes in microbial functional gene structure and abundance could be used to evaluate the impact of soil management practices on soil microbial communities in sugarcane production fields.

54 ENVIRONMENTAL SCIENCES↗

A thin-walled composite beam model for light-weighted structures interacting with fluids

A thin-walled beam model is proposed for structures of variable cross-section, which can be either open or closed and includes multicellular cross-sections with either isotropic or orthotropic materials. The proposed model does not require any priori definition of cross-sectional warping which instead results from the solution of the problem. To achieve that a special deformation pattern is superimposed on the bending deformation described by Euler–Bernoulli beam theory. All sectional properties are automatically incorporated in the analysis as a result of the usual variational formulation of the system of equations. The proposed model is specifically designed to simulate the dynamics of wind/hydrokinetic turbine blade with low computational cost, especially in fluid–structure interaction (FSI) simulation. A number of test cases have been carried out to validate the proposed structural model which show good agreement between the results obtained her e and the solutions available in literature. Finally, FSI simulation of a hydrokinetic blade under field condition is carried out to illustrate the capability of the current thin-walled beam model in practice.

42 ENGINEERING↗

Tracking seasonal variability in plant traits from spaceborne PRISMA and NEON AOP across forest types and ecoregions

Plant traits serve as critical indicators of how plants adapt to environmental changes and influence ecosystem functions. While airborne hyperspectral remote sensing effectively maps plant traits through detailed reflectance properties, it is limited by cost and scale, making large-scale and temporal studies challenging. The recently launched spaceborne hyperspectral imager, PRecursore IperSpettrale della Missione Applicativa (PRISMA), offers frequent, large scale and high-fidelity observations on a spatial resolution of 30 m and a revisit time of around 29 days, making it suitable for large-scale seasonal trait mapping. However, their potential remains largely unexplored. This study developed a multi-stage framework by leveraging the PRISMA spaceborne hyperspectral data and National Ecological Observatory Network (NEON) Airborne Observation Platform (AOP) hyperspectral data to investigate the seasonal dynamics of four key plant traits — chlorophyll content, carotenoid content, equivalent water thickness, and nitrogen content — across eleven NEON sites representing diverse forest types and ecoregions in the contiguous U.S. Our results demonstrated that PRISMA hyperspectral data can reliably track seasonal variability in plant traits, achieving overall R 2 values ranging from 0.78 to 0.88 and normalized root mean square error (NRMSE) values ranging from 5.4% to 8.4% for the four traits. Seasonal patterns revealed bell-shaped trajectories for chlorophyll and carotenoids, while equivalent water thickness decreased steadily across most sites, driven by structural changes during leaf maturation and senescence. Nitrogen content exhibited less pronounced seasonal variation but followed expected nutrient resorption patterns. Analysis of environmental drivers showed that seasonal variability is primarily controlled by solar radiation and day length in northern sites, vapor pressure in semi-arid regions, and temperature in mid-southeastern sites. Spatial variability, meanwhile, was primarily driven by soil properties, particularly during the peak growing season. However, the influence of soil variables slightly declines toward the end of the season at several sites, as climatic factors become more prominent. This study highlights the capability of PRISMA, and potentially other similar spaceborne hyperspectral data for large-scale, time-series plant trait mapping and provides valuable insights into the interactions between plant traits and environmental factors. In conclusion, these findings contribute to advancing our understanding of plant functional ecology and improving predictions of ecosystem responses to environmental changes.

Environmental drivers↗

Long-term excess nitrogen fertilizer increases sensitivity of soil microbial community to seasonal change revealed by ecological network and metagenome analyses

Nitrogen (N) fertilizer has often been generously applied to increase crop biomass yield. Although the influences of inorganic N fertilizer on soil microbial communities have been widely studied, the effect of N fertilizer on microbial co-occurrence networks and its metagenome is largely unknown. Further, seasonal changes in microbial community responses to N addition have rarely been reported. In this study, three N fertilizer rates (0, 56, 196 kg N/ha) were applied annually in switchgrass (Panicum virgatum L.) grown for bioenergy production in the upper Midwest, USA. The soil microbiome was affected by both fertilizer and low pH in the 7th year of fertilization treatments. The microbial community structures were relatively stable during the growing season for each N fertilizer rate. However, the excess N fertilizer (196N) increased the seasonal variation of bacterial and fungal communities. Network analysis showed that the microbial interactions at the 196N treatment were more intense, with decreased bacteria-fungal interactions compared to 56N and 0N. Furthermore, this suggests that the microbial community became more sensitive to environmental change under the influence of long-term excess N fertilizer. Metagenomic analysis showed that the long-term excess N fertilizer promoted many metabolic processes, especially carbohydrate and amino acid related metabolism and Archaea mediated ammonia oxidation. However, N fertilizer also reduced many other traits, especially N 2 fixation and signal transduction, the latter of which may contribute to the decreased interactions between bacteria and fungi.

54 ENVIRONMENTAL SCIENCES↗

Scalable and Tunable Carbide-Phosphide Composite Catalyst System for the Thermochemical Conversion of Biomass

We have prepared composite materials of hexagonal nickel phosphide and molybdenum carbide (Mo2C) utilizing a simple and scalable two-stage synthesis method comprised of carbothermic reduction followed by hydrothermal incubation. We observe the monophasic hexagonal phosphide Ni2P in the composite at low phosphide-to-carbide (P:C) ratios. Upon increasing the proportion of P:C, the carbide surface becomes saturated, and we detect the emergence of a second hexagonal nickel phosphide phase (Ni5P4) upon annealing. We demonstrate that vapor-phase upgrading (VPU) of whole biomass via catalytic fast pyrolysis is achievable using the composite material as a catalyst, and we monitor the resulting product slates using pyrolysis gas chromatography/mass spectrometry. Our analysis of the product vapors indicates that variation of the P:C molar ratio in the composite material affords product slates of varying complexity and composition, which is indicated by the number of products and their relative proportions in the product slate. Our results demonstrate that targeted vapor product composition can be obtained, which can potentially be utilized to tune the composition of the bio-oil downstream.

09 BIOMASS FUELS↗

A microphysiological model of human trophoblast invasion during implantation

Abstract Successful establishment of pregnancy requires adhesion of an embryo to the endometrium and subsequent invasion into the maternal tissue. Abnormalities in this critical process of implantation and placentation lead to many pregnancy complications. Here we present a microenigneered system to model a complex sequence of orchestrated multicellular events that plays an essential role in early pregnancy. Our implantation-on-a-chip is capable of reconstructing the three-dimensional structural organization of the maternal-fetal interface to model the invasion of specialized fetal extravillous trophoblasts into the maternal uterus. Using primary human cells isolated from clinical specimens, we demonstrate in vivo-like directional migration of extravillous trophoblasts towards a microengineered maternal vessel and their interactions with the endothelium necessary for vascular remodeling. Through parametric variation of the cellular microenvironment and proteomic analysis of microengineered tissues, we show the important role of decidualized stromal cells as a regulator of extravillous trophoblast migration. Furthermore, our study reveals previously unknown effects of pre-implantation maternal immune cells on extravillous trophoblast invasion. This work represents a significant advance in our ability to model early human pregnancy, and may enable the development of advanced in vitro platforms for basic and clinical research of human reproduction.

60 APPLIED LIFE SCIENCES↗

Mapping Critical Vulnerabilities in Natural Gas Pipeline Systems through Network Centrality and GIS Analytics

Natural gas plays a central role in the US energy landscape, providing 43% of electricity generation in 2023. Its exclusive recovery ability on pipelines for transmission underscores the importance of understanding the disruption recovery ability of this infrastructure. This study employs a network-based analytical framework integrating geographic information systems (GIS) with multiple centrality measures—betweenness, closeness, degree, and eigenvector—to pinpoint key segments and evaluate the structural robustness of the national pipeline network. Pipelines are grouped by System ID and Operator ID to capture variations across organizational and physical structures. The analysis reveals uneven patterns of network influence, where certain pipelines function as critical connectors or dominant hubs. Spatial mapping highlights geographic dependencies and potential chokepoints, offering a clear view of where targeted risk prevention measures would be most effective. The findings provide practical guidance for prioritizing maintenance, enhancing system robustness, and mitigating risks to ensure a stable and secure energy supply. Future research will expand the framework to incorporate dynamic operational data and real-time network behavior.

Peterson, Steven [ORNL] (ORCID:0000000287672998)↗

Theory of critical balance in plasma turbulence

Critical balance, a statement of the approximate equality of a timescale of motion parallel to the magnetic field with a timescale of turbulent motion perpendicular to the field, is analyzed from a statistical description of the relative motion of two particles consistent with two-point correlation in a nonlinear gyrokinetic system with collisions. Critical balance is understood from a premise that the fastest time to any spatial scale that encounters decorrelated motions sets an overall correlation time for both perpendicular and parallel scales. For a regime of weak collisionality, this leads to the approximate equality of the parallel streaming time and the perpendicular turbulent correlation time, which is a standard statement of critical balance. These two timescales are only approximately equal because of effects in parallel streaming dynamics and collisions, the former producing deviations tied to variations of perpendicular and parallel wavenumbers. Finally, analysis of a collisional regime shows that critical balance also applies in that limit with a modified relation between parallel and perpendicular spatial scales.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

An intermediate model for fitting triplet–triplet annihilation in phosphorescent organic light emitting diode materials

Triplet–triplet annihilation (TTA) is one of the primary contributors to efficiency roll-off and permanent material degradation in phosphorescent organic light-emitting diodes. Here, the two limiting case models typically used to quantify this quenching mechanism are multi-step Dexter and single-step Förster, which, respectively, assume ideal Fickian diffusion or perfect trapping of triplet excitons. For device-relevant guest doping levels (typically 5–12 vol. %), both significant diffusion of excitons and trapping due to spatial and energetic disorder exist, so neither conventional model fits experimental data well. We develop and validate an intermediate TTA model, which is a weighted average of the limiting cases of pure radiative decay (no TTA) and multi-step Dexter based TTA that returns an effective TTA rate constant and a parameter quantifying the portion of well-isolated excitons. Kinetic Monte-Carlo simulations and time-resolved photoluminescence measurements of an archetype host–guest system demonstrate that our intermediate model provides significantly improved fits with more realistic physical values, is more robust to variations in experimental conditions, and provides an analysis framework for the effects of trapping on TTA.

30 DIRECT ENERGY CONVERSION↗

Probing pre-inflationary anisotropy with directional variations in the gravitational wave background

We perform a detailed analysis on a primordial gravitational-wave background amplified during a Kasner-like pre-inflationary phase allowing for general triaxial anisotropies. It is found that the predicted angular distribution map of gravitational-wave intensity on large scales exhibits topologically distinctive patterns according to the degree of the pre-inflationary anisotropy, thereby serving as a potential probe for the pre-inflationary early universe with future all-sky observations of gravitational waves. We also derive an observational limit on the amplitude of such anisotropic gravitational waves from the B -mode polarisation of the cosmic microwave background.

79 ASTRONOMY AND ASTROPHYSICS↗