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TbHg2 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Tb is bonded in a 10-coordinate geometry to ten equivalent Hg atoms. There are a spread of Tb–Hg bond distances ranging from 3.18–3.36 Å. Hg is bonded in a 8-coordinate geometry to five equivalent Tb and three equivalent Hg atoms. There are two shorter (3.01 Å) and one longer (3.18 Å) Hg–Hg bond lengths.
TbPr3 is Magnesium-derived structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Tb is bonded to twelve equivalent Pr atoms to form TbPr12 cuboctahedra that share corners with six equivalent TbPr12 cuboctahedra, corners with twelve equivalent PrTb4Pr8 cuboctahedra, edges with eighteen equivalent PrTb4Pr8 cuboctahedra, faces with eight equivalent TbPr12 cuboctahedra, and faces with twelve equivalent PrTb4Pr8 cuboctahedra. All Tb–Pr bond lengths are 3.69 Å. Pr is bonded to four equivalent Tb and eight equivalent Pr atoms to form PrTb4Pr8 cuboctahedra that share corners with four equivalent TbPr12 cuboctahedra, corners with fourteen equivalent PrTb4Pr8 cuboctahedra, edges with six equivalent TbPr12 cuboctahedra, edges with twelve equivalent PrTb4Pr8 cuboctahedra, faces with four equivalent TbPr12 cuboctahedra, and faces with sixteen equivalent PrTb4Pr8 cuboctahedra. There are two shorter (3.67 Å) and six longer (3.71 Å) Pr–Pr bond lengths.
TbScSb is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. The structure is three-dimensional. Tb is bonded in a 5-coordinate geometry to five equivalent Sb atoms. There are four shorter (3.15 Å) and one longer (3.18 Å) Tb–Sb bond lengths. Sc is bonded to four equivalent Sb atoms to form a mixture of distorted edge and corner-sharing ScSb4 cuboctahedra. All Sc–Sb bond lengths are 3.08 Å. Sb is bonded in a 9-coordinate geometry to five equivalent Tb and four equivalent Sc atoms.
LiTbIn2 is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Li is bonded in a body-centered cubic geometry to eight equivalent In atoms. All Li–In bond lengths are 3.16 Å. Tb is bonded in a body-centered cubic geometry to eight equivalent In atoms. All Tb–In bond lengths are 3.16 Å. In is bonded in a body-centered cubic geometry to four equivalent Li and four equivalent Tb atoms.
TbTeO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Tb is bonded to twelve equivalent O atoms to form TbO12 cuboctahedra that share corners with twelve equivalent TbO12 cuboctahedra, faces with six equivalent TbO12 cuboctahedra, and faces with eight equivalent TeO6 octahedra. All Tb–O bond lengths are 3.02 Å. Te is bonded to six equivalent O atoms to form TeO6 octahedra that share corners with six equivalent TeO6 octahedra and faces with eight equivalent TbO12 cuboctahedra. The corner-sharing octahedral tilt angles are 0°. All Te–O bond lengths are 2.14 Å. O is bonded to four equivalent Tb and two equivalent Te atoms to form a mixture of distorted edge, face, and corner-sharing OTb4Te2 octahedra. The corner-sharing octahedra tilt angles range from 0–60°.
Tb3Hg is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Tb is bonded in a distorted square co-planar geometry to four equivalent Hg atoms. All Tb–Hg bond lengths are 3.41 Å. Hg is bonded to twelve equivalent Tb atoms to form a mixture of face and corner-sharing HgTb12 cuboctahedra.
Tb4Co is Iron carbide-like structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Tb4Co clusters. Tb is bonded in a single-bond geometry to one Co atom. The Tb–Co bond length is 2.48 Å. Co is bonded in a tetrahedral geometry to four equivalent Tb atoms.
TbB12 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Tb is bonded in a 1-coordinate geometry to twenty-four equivalent B atoms. All Tb–B bond lengths are 2.79 Å. B is bonded in a 7-coordinate geometry to two equivalent Tb and five equivalent B atoms. There is one shorter (1.72 Å) and four longer (1.79 Å) B–B bond length.
ErTbRh2 is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Er is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Er–Rh bond lengths are 2.97 Å. Tb is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Tb–Rh bond lengths are 2.97 Å. Rh is bonded in a body-centered cubic geometry to four equivalent Er and four equivalent Tb atoms.
TbBi2Bi crystallizes in the orthorhombic Cmmm space group. The structure is two-dimensional and consists of two bismuth molecules and one TbBi2 sheet oriented in the (0, 0, 1) direction. In the TbBi2 sheet, Tb is bonded in a distorted rectangular see-saw-like geometry to four equivalent Bi atoms. All Tb–Bi bond lengths are 3.06 Å. Bi is bonded in a linear geometry to two equivalent Tb atoms.
(TbSn)2ZnSn crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one 7440-31-5 molecule, two TbSn clusters, and one zinc molecule. In each TbSn cluster, Tb is bonded in a single-bond geometry to one Sn atom. The Tb–Sn bond length is 2.94 Å. Sn is bonded in a single-bond geometry to one Tb atom.
Tb4Cu4P7Cu crystallizes in the tetragonal I4mm space group. The structure is three-dimensional and consists of two copper molecules and one Tb4Cu4P7 framework. In the Tb4Cu4P7 framework, there are three inequivalent Tb3+ sites. In the first Tb3+ site, Tb3+ is bonded in a 8-coordinate geometry to eight P3- atoms. There are four shorter (2.92 Å) and four longer (3.03 Å) Tb–P bond lengths. In the second Tb3+ site, Tb3+ is bonded in a 8-coordinate geometry to eight P3- atoms. There are four shorter (2.84 Å) and four longer (2.88 Å) Tb–P bond lengths. In the third Tb3+ site, Tb3+ is bonded in a 6-coordinate geometry to six P3- atoms. All Tb–P bond lengths are 2.91 Å. Cu+1.80+ is bonded in a distorted trigonal non-coplanar geometry to three P3- atoms. There are two shorter (2.37 Å) and one longer (2.41 Å) Cu–P bond lengths. There are three inequivalent P3- sites. In the first P3- site, P3- is bonded in a 6-coordinate geometry to four Tb3+ and two equivalent P3- atoms. Both P–P bond lengths are 2.37 Å. In the second P3- site, P3- is bonded in a 8-coordinate geometry to four equivalent Tb3+ and four equivalent Cu+1.80+ atoms. In the third P3- site, P3- is bonded in a 8-coordinate geometry to four Tb3+ and four equivalent Cu+1.80+ atoms.
TbHg2 crystallizes in the trigonal P-3m1 space group. The structure is three-dimensional. Tb is bonded to twelve equivalent Hg atoms to form a mixture of distorted edge and face-sharing TbHg12 cuboctahedra. There are six shorter (3.33 Å) and six longer (3.38 Å) Tb–Hg bond lengths. Hg is bonded in a 9-coordinate geometry to six equivalent Tb and three equivalent Hg atoms. All Hg–Hg bond lengths are 2.87 Å.
TbEu3 is beta Cu3Ti-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Tb is bonded to twelve equivalent Eu atoms to form TbEu12 cuboctahedra that share corners with six equivalent TbEu12 cuboctahedra, corners with twelve equivalent EuTb4Eu8 cuboctahedra, edges with eighteen equivalent EuTb4Eu8 cuboctahedra, faces with eight equivalent TbEu12 cuboctahedra, and faces with twelve equivalent EuTb4Eu8 cuboctahedra. There are six shorter (3.79 Å) and six longer (3.83 Å) Tb–Eu bond lengths. Eu is bonded to four equivalent Tb and eight equivalent Eu atoms to form EuTb4Eu8 cuboctahedra that share corners with four equivalent TbEu12 cuboctahedra, corners with fourteen equivalent EuTb4Eu8 cuboctahedra, edges with six equivalent TbEu12 cuboctahedra, edges with twelve equivalent EuTb4Eu8 cuboctahedra, faces with four equivalent TbEu12 cuboctahedra, and faces with sixteen equivalent EuTb4Eu8 cuboctahedra. There are a spread of Eu–Eu bond distances ranging from 3.76–3.91 Å.
TbHg2Cd is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Tb is bonded in a body-centered cubic geometry to eight equivalent Hg atoms. All Tb–Hg bond lengths are 3.13 Å. Hg is bonded in a body-centered cubic geometry to four equivalent Tb and four equivalent Cd atoms. All Hg–Cd bond lengths are 3.13 Å. Cd is bonded in a distorted body-centered cubic geometry to eight equivalent Hg atoms.
TbVO2 crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional. Tb is bonded in a distorted hexagonal planar geometry to six equivalent O atoms. There are two shorter (2.27 Å) and four longer (2.46 Å) Tb–O bond lengths. V is bonded in a linear geometry to two equivalent O atoms. Both V–O bond lengths are 1.88 Å. O is bonded to three equivalent Tb and one V atom to form a mixture of distorted corner and edge-sharing OTb3V tetrahedra.
CaTbHg2 is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Ca is bonded in a body-centered cubic geometry to eight equivalent Hg atoms. All Ca–Hg bond lengths are 3.25 Å. Tb is bonded in a body-centered cubic geometry to eight equivalent Hg atoms. All Tb–Hg bond lengths are 3.25 Å. Hg is bonded in a body-centered cubic geometry to four equivalent Ca and four equivalent Tb atoms.
TbGdRh2 is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Tb is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Tb–Rh bond lengths are 2.99 Å. Gd is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Gd–Rh bond lengths are 2.99 Å. Rh is bonded in a body-centered cubic geometry to four equivalent Tb and four equivalent Gd atoms.