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At least 1,153 records · Page 64
All sourcesNASA NTRSDOE OSTI
NASA NTRS2001

Thermal Expansion and Diffusion Coefficients of Carbon Nanotube-Polymer Composites

Classical molecular dynamics (MD) simulations employing Brenner potential for intra-nanotube interactions and van der Waals forces for polymer-nanotube interface have been used to investigate thermal expansion and diffusion characteristics of carbon nanotube-polyethylene composites. Addition of carbon nanotubes to polymer matrix is found to significantly increase the glass transition temperature Tg, and thermal expansion and diffusion coefficients in the composite above Tg. The increase has been attributed to the temperature dependent increase of the excluded volume for the polymer chains, and the findings could have implications in the composite processing, coating and painting applications.

Wei, Chengyu↗
NASA NTRS2002

Computational Nanomechanics of Carbon Nanotubes and Composites

Nanomechanics of individual carbon and boron-nitride nanotubes and their application as reinforcing fibers in polymer composites has been reviewed with interplay of theoretical modeling, computer simulations and experimental observations. The emphasis in this work is on elucidating the multi-length scales of the problems involved, and of different simulation techniques that are needed to address specific characteristics of individual nanotubes and nanotube polymer-matrix interfaces. Classical molecular dynamics simulations are shown to be sufficient to describe the generic behavior such as strength and stiffness modulus but are inadequate to describe elastic limit and nature of plastic buckling at large strength. Quantum molecular dynamics simulations are shown to bring out explicit atomic nature dependent behavior of these nanoscale materials objects that are not accessible either via continuum mechanics based descriptions or through classical molecular dynamics based simulations. As examples, we discus local plastic collapse of carbon nanotubes under axial compression and anisotropic plastic buckling of boron-nitride nanotubes. Dependence of the yield strain on the strain rate is addressed through temperature dependent simulations, a transition-state-theory based model of the strain as a function of strain rate and simulation temperature is presented, and in all cases extensive comparisons are made with experimental observations. Mechanical properties of nanotube-polymer composite materials are simulated with diverse nanotube-polymer interface structures (with van der Waals interaction). The atomistic mechanisms of the interface toughening for optimal load transfer through recycling, high-thermal expansion and diffusion coefficient composite formation above glass transition temperature, and enhancement of Young's modulus on addition of nanotubes to polymer are discussed and compared with experimental observations.

Srivastava, Deepak↗
NASA NTRS1997

Factors Influencing Residual Stresses in Yttria Stabilized Zirconia Thermal Barrier Coatings

To improve gas turbine and diesel engine performance using thermal barrier coatings (TBC's) requires an understanding of the factors that influence the in-service behavior of thermal barrier coatings. One of the many factors related to coating performance is the state of stress in the coating. The total stress state is composed of the stresses due to the in-service loading history and the residual stresses. Residual stresses have been shown to affect TBC life, the bond strength of thermal spray coatings, and the fatigue life of tungsten carbide coatings. Residual stresses are first introduced in TBC's by the spraying process due to elevated temperatures during processing and the difference in coefficients of thermal expansion of the top coat, bond coat, and substrate. Later, the residual stresses can be changed by the in-service temperature history due to a number of time and temperature dependent mechanisms, such as oxidation, creep, and sintering. Silica content has also been shown to affect sintering and the cyclic life of thermal barrier coatings. Thus, it is important to understand how the spraying process, the in-service thermal cycles, and the silica content can create and alter residual stresses in thermal barrier coatings.

McGrann, Roy T. R.↗
NASA NTRS1959

Analysis of Turbulent Flow and Heat Transfer in Noncircular Passages

Previous work on turbulent heat transfer and flow in tubes was generalized and applied to flow in non-circular passages of equilateral triangular and square cross section. Expressions for eddy diffusivity that had been verified for flow and heat transfer in tubes were assumed to apply in general along lines normal to a wall. Velocity distributions, wall shear-stress distributions, and friction factors, as well as wall heat-transfer distributions, wall temperature distributions, and average heat-transfer coefficients were calculated. In addition, results from a previous analysis for axial flow between rods were compared with new experimental data. For calculating wall temperature distributions, uniform heat generation in the passage wall and uniform heat transfer at the outer surface were assumed. The application of the results is restricted to moderately small peripheral wall temperature variations. Calculations were made for Reynolds numbers from 20,000 to 900,000 and Prandtl numbers from 0.73 to 300. Results show that velocities, shear stresses, and heat transfer in the region near the corner were lower than average values and were zero at the corner. Friction factors and average Nusselt numbers were lower than in a tube.

Taylor, Maynard F.↗
NASA NTRS1975

Calculated diffusion coefficients and the growth rate of olivine in a basalt magma

Concentration gradients in glass adjacent to skeletal olivines in a basalt have been examined by electron probe. The glass is depleted in Mg, Fe, and Cr and enriched in Si, Al, Na, and Ca relative to that far from olivine. Ionic diffusion coefficients for the glass compositions are calculated from temperature, ionic radius and melt viscosity, using the Stokes-Einstein relation. At 1170 C, the diffusion coefficient of Mg(2+) ions in the basalt is 4.5 billionths sq cm per sec. Comparison with measured diffusion coefficients in a mugearite suggests this value may be 16 times too small. The concentration gradient data and the diffusion coefficients are used to calculate instantaneous olivine growth rates. Growth necessarily preceded emplacement such that the composition of the crystals plus the enclosing glass need not be that of a melt. The computed olivine growth rates are compatible with the rate of crystallization deduced for the Skaegaard intrusion.

Donaldson, C. H.↗
NASA NTRS1992

A far wing line shape theory and its application to the water vibrational bands (II)

Attention is given to a far wing line shape theory based on binary collision and quasi-static approximations. The theory is applicable for both the LF and HF wings of vibrational-rotational bands. It is used to calculate the frequency and temperature dependence of the continuous absorption coefficient for frequencies up to 10,000/cm for pure water vapor. The results are compared with existing laboratory data in the 2400-2700/cm window and in the 3000-4300/cm band center region, with field measurements in the 2000-2225/cm region and with a recent experimental measurement near 9466/cm. It is concluded that both the magnitude and temperature dependence of the water vapor continuum can be accounted for by the present theory without the introduction of any adjustable parameters. Refinements of the theory and extension to foreign-broadened absorption are also discussed.

Ma, Q.↗
NASA NTRS1976

Heat transfer to a full-coverage film-cooled surface with 30 degree slant-hole injection

Heat transfer behavior was studied in a turbulent boundary layer with full coverage film cooling through an array of discrete holes and with injection 30 deg to the wall surface in the downstream direction. Stanton numbers were measured for a staggered hole pattern with pitch-to-diameter ratios of 5 and 10, an injection mass flux ratio range of 0.1 to 1.3, and a range of Reynolds number Re sub x of 150,000 to 5 million. Air was used as the working fluid, and the mainstream velocity varied from 9.8 to 34.2 m/sec (32 to 112 ft/sec). The data were taken for secondary injection temperature equal to the wall temperature and also equal to the mainstream temperature. The data may be used to obtain Stanton number as a continuous function of the injectant temperature by use of linear superposition theory. The heat transfer coefficient is defined on the basis of a mainstream-to-wall temperature difference. This definition permits direct comparison of performance between film cooling and transpiration cooling. A differential prediction method was developed to predict the film cooling data base. The method utilizes a two-dimensional boundary layer program with routines to model the injection process and turbulence augmentation. The program marches in the streamwise direction, and when a row of holes is encountered, it stops and injects fluid into the boundary layer. The turbulence level is modeled by algebraically augmenting the mixing length, with the augmentation keyed to a penetration distance for the injected fluid.

Crawford, M. E.↗
NASA NTRS1981

Survey of in-situ and remote sensing methods for soil moisture determination

General methods for determining the moisture content in the surface layers of the soil based on in situ or point measurements, soil water models and remote sensing observations are surveyed. In situ methods described include gravimetric techniques, nuclear techniques based on neutron scattering or gamma-ray attenuation, electromagnetic techniques, tensiometric techniques and hygrometric techniques. Soil water models based on column mass balance treat soil moisture contents as a result of meteorological inputs (precipitation, runoff, subsurface flow) and demands (evaporation, transpiration, percolation). The remote sensing approaches are based on measurements of the diurnal range of surface temperature and the crop canopy temperature in the thermal infrared, measurements of the radar backscattering coefficient in the microwave region, and measurements of microwave emission or brightness temperature. Advantages and disadvantages of the various methods are pointed out, and it is concluded that a successful monitoring system must incorporate all of the approaches considered.

Schmugge, T. J.↗
NASA NTRS2003

Simultaneous Temperature and Strain Sensing for Cryogenic Applications Using Dual-Wavelength Fiber Bragg Gratings

A new technique has been developed for sensing both temperature and strain simultaneously by using dual-wavelength fiber-optic Bragg gratings. Two Bragg gratings with different wavelengths were inscribed at the same location in an optical fiber to form a sensor. By measuring the wavelength shifts that resulted from the fiber being subjected to different temperatures and strains, the wavelength-dependent thermo-optic coefficients and photoelastic coefficients of the fiber were determined. This enables the simultaneous measurement of temperature and strain. In this study, measurements were made over the temperature range from room temperature down to about 10 K, addressing much of the low temperature range of cryogenic tanks. A structure transition of the optical fiber during the temperature change was found. This transition caused splitting of the waveforms characterizing the Bragg gratings, and the determination of wavelength shifts was consequently complicated. The effectiveness and sensitivities of these measurements in different temperature ranges are also discussed.

Wu, Meng-Chou↗
NASA NTRS2015

Cryogenic Refractive Indices of S-LAH55, S-LAH55V, S-LAH59, S-LAM3, S-NBM51, S-NPH2, S-PHM52, and S-TIH14 Glasses

The Transiting Exoplanet Survey Satellite (TESS) is an explorer-class planet finder, whose principal goal is to detect small planets with bright host starts in the solar neighborhood. The TESS payload consists of four identical cameras and a Data Handling Unit (DHU) fitted with CCD detectors and associated electronics. Each camera consist of a lens assembly with seven optical elements that include various types of Ohara glass substrates. The successful implementation of a panchromatic and a thermal lens assembly design for these cameras requires a fairly accurate (up to 0.000001 (1e-6)) knowledge of the temperature- and wavelength-dependent of the refractive index in the wavelength and temperature range of operation. Hence, this paper is devoted to report on measurements of the refractive index over the wavelength range of 0.42-1.15 micrometers and temperature range of 110-300 K for the following Ohara glasses: S-LAH55, S-LAH55V, S-LAH59, S-LAM3, S-NBM51, S-NPH2, S-PHM52, and S-TIH14. The measurements were performed utilizing the Cryogenic High Accuracy Refraction Measuring System (CHARMS) facility at NASA's Goddard Space Flight Center. A dense coverage of the absolute refractive index for all these substrates in the aforementioned wavelength and temperature ranges was used to determine the thermo-optic coefficient (dndT) and dispersion relation (dnd) as a function of wavelength and temperature. A comparison of the measured indices with literature values, specifically the temperature-dependent refractive indices of S-PHM52 and S-TIH14 reported by Yamamuro et al. [Yamamuro et al., Opt. Eng. 45(8), 083401 (2006)], will be presented.

cryogenic temperatures↗
NASA NTRS2017

Cryogenic Refractive Index of Heraeus Homosil Glass

This paper reports measurements of the refractive index of Homosil (Heraeus) over the wavelength range of 0.343.16 m and temperature range of 120335 K. These measurements were performed by using the Cryogenic High Accuracy Refraction Measuring System (CHARMS) facility at the NASAs Goddard Space Flight Center. These measurements were in support of an integrated Structural-Thermal-Optical-Performance (STOP) model that was developed for a field-widened Michelson interferometer that is being built and tested for the High Spectral Resolution Lidar (HSRL) project at the NASA Langley Research Center (LaRC). The cryogenic refractive index measurements were required in order to account for the highly sensitivity performance of the HSRL instrument to changes in refractive index with temperature, temperature gradients, thermal expansion, and deformation due to mounting stresses. A dense coverage of the absolute refractive index over the aforementioned wavelength and temperature ranges was used to determine the thermo-optic coefficient (dndT) and dispersion relation (dnd) as a function of wavelength and temperature. Our measurements of Homosil will be compared with measurements of other glasses from the fused silica family studied in CHARMS as well as measurements reported elsewhere in literature.

Homosil↗
NASA NTRS1994

An Algorithm to Generate Deep-Layer Temperatures from Microwave Satellite Observations for the Purpose of Monitoring Climate Change

An algorithm for generating deep-layer mean temperatures from satellite-observed microwave observations is presented. Unlike traditional temperature retrieval methods, this algorithm does not require a first guess temperature of the ambient atmosphere. By eliminating the first guess a potentially systematic source of error has been removed. The algorithm is expected to yield long-term records that are suitable for detecting small changes in climate. The atmospheric contribution to the deep-layer mean temperature is given by the averaging kernel. The algorithm computes the coefficients that will best approximate a desired averaging kernel from a linear combination of the satellite radiometer's weighting functions. The coefficients are then applied to the measurements to yield the deep-layer mean temperature. Three constraints were used in deriving the algorithm: (1) the sum of the coefficients must be one, (2) the noise of the product is minimized, and (3) the shape of the approximated averaging kernel is well-behaved. Note that a trade-off between constraints 2 and 3 is unavoidable. The algorithm can also be used to combine measurements from a future sensor (i.e., the 20-channel Advanced Microwave Sounding Unit (AMSU)) to yield the same averaging kernel as that based on an earlier sensor (i.e., the 4-channel Microwave Sounding Unit (MSU)). This will allow a time series of deep-layer mean temperatures based on MSU measurements to be continued with AMSU measurements. The AMSU is expected to replace the MSU in 1996.

Goldberg, Mitchell D.↗
DOE OSTI2021

New insights on the nebular emission, ionizing radiation, and low metallicity of Green Peas from advanced modelling

ABSTRACT Low-metallicity, compact starburst galaxies referred to as Green Peas (GPs) provide a unique window to study galactic evolution across cosmic epochs. In this work, we present new deep optical spectra for three GPs from OSIRIS at the 10-m Gran Telescopio Canarias, which are studied using a state-of-the-art methodology. A stellar population synthesis is conducted with 1098 spectral templates. The methodology succeeds at characterizing stellar populations from 0.5 Myr to 10 Gyr. The light distribution shows a large red excess from a single population with ${log}\left({age}\right) \gt 8.5\, \mathrm{yr}$ in the GP sample analysed. This points towards an incomplete characterization of the gas luminosity, whose continuum already accounts between 7.4 and $27.6{{\ \rm per\ cent}}$ in the galaxy sample. The emission spectra are fitted with the largest Bayesian chemical model consisting of an electron temperature, an electron density, the logarithmic extinction coefficient and eleven ionic species under the direct method paradigm. Additionally, building on previous work, we propose a neural networks sampler to constrain the effective temperature and ionization parameter of each source from photoionization model grids. Finally, we combine both methodologies into a 16-dimensional model, which for the first time, simultaneously explores the direct method and photoionization parameter spaces. Both techniques consistently indicate a low-metallicity gas, $7.76\lt 12+{\rm log}\left(O/H \right)\lt 8.04$, ionized by strong radiation fields, in agreement with previous works.

Fernández, V. (ORCID:0000000305315450)↗
NASA NTRS1989

Mechanical properties of several neat polymer matrix materials and unidirectional carbon fiber-reinforced composites

The mechanical and physical properties of three neat matrix materials, i.e., PEEK (polyetheretherketone) thermoplastic, Hexcel F155 rubber-toughened epoxy and Hercules 8551-7 rubber-toughened epoxy, were experimentally determined. Twelve unidirectional carbon fiber composites, incorporating matrix materials characterized in this or earlier studies (with one exception; the PISO(sub 2)-TPI matrix itself was not characterized), were also tested. These composite systems included AS4/2220-1, AS4/2220-3, T500/R914, IM6/HX1504, T300/4901A (MDA), T700/4901A (MDA), T300/4901B (MPDA), T700/4901B (MPDA), APC2 (AS4/PEEK, ICI), APC2 (AS4/PEEK, Langley Research Center), AS4/8551-7, and AS4/PISO(sub 2)-TPI. For the neat matrix materials, the tensile, shear, fracture toughness, coefficient of thermal expansion, and coefficient of moisture expansion properties were measured as a function of both temperature and moisture content. For the unidirectional composites, axial and transverse tensile, longitudinal shear, coefficient of thermal expansion, and coefficient of moisture expansion properties were determined, at room temperature and 100 C.

Coguill, Scott L.↗
NASA NTRS1947

Cooling of Gas Turbines I - Effects of Addition of Fins to Blade Tips and Rotor, Admission of Cooling Air Through Part of Nozzles, and Change in Thermal Conductivity of Turbine Components

An analysis was developed for calculating the radial temperature distribution in a gas turbine with only the temperatures of the gas and the cooling air and the surface heat-transfer coefficient known. This analysis was applied to determine the temperatures of a complete wheel of a conventional single-stage impulse exhaust-gas turbine. The temperatures were first calculated for the case of the turbine operating at design conditions of speed, gas flow, etc. and with only the customary cooling arising from exposure of the outer blade flange and one face of the rotor to the air. Calculations were next made for the case of fins applied to the outer blade flange and the rotor. Finally the effects of using part of the nozzles (from 0 to 40 percent) for supplying cooling air and the effects of varying the metal thermal conductivity from 12 to 260 Btu per hour per foot per degree Farenheit on the wheel temperatures were determined. The gas temperatures at the nozzle box used in the calculations ranged from 1600F to 2000F. The results showed that if more than a few hundred degrees of cooling of turbine blades are required other means than indirect cooling with fins on the rotor and outer blade flange would be necessary. The amount of cooling indicated for the type of finning used could produce some improvement in efficiency and a large increase in durability of the wheel. The results also showed that if a large difference is to exist between the effective temperature of the exhaust gas and that of the blade material, as must be the case with present turbine materials and the high exhaust-gas temperatures desired (2000F and above), two alternatives are suggested: (a) If metal with a thermal conductivity comparable with copper is used, then the blade temperature can be reduced by strong cooling at both the blade tip and root. The center of the blade will be less than 2000F hotter than the ends; (b) With low conductivity materials some method of direct cooling other than partial admission of cooling air is essential. From this study, it can be deduced that indirect cooling of turbine blades will not make possible large increases in gas temperature.

Brown, Byron↗
NASA NTRS1960

Heat Diffusion in Gases, Including Effects of Chemical Reaction

The diffusion of heat through gases is treated where the coefficients of thermal conductivity and diffusivity are functions of temperature. The diffusivity is taken proportional to the integral of thermal conductivity, where the gas is ideal, and is considered constant over the temperature interval in which a chemical reaction occurs. The heat diffusion equation is then solved numerically for a semi-infinite gas medium with constant initial and boundary conditions. These solutions are in a dimensionless form applicable to gases in general, and they are used, along with measured shock velocity and heat flux through a shock reflecting surface, to evaluate the integral of thermal conductivity for air up to 5000 degrees Kelvin. This integral has the properties of a heat flux potential and replaces temperature as the dependent variable for problems of heat diffusion in media with variable coefficients. Examples are given in which the heat flux at the stagnation region of blunt hypersonic bodies is expressed in terms of this potential.

Hansen, C. Frederick↗
DOE OSTI2024

Electronic Band Structure of a Superconducting Nickelate Probed by the Seebeck Coefficient in the Disordered Limit

Superconducting nickelates are a new family of strongly correlated electron materials with a phase diagram closely resembling that of superconducting cuprates. While analogy with the cuprates is natural, very little is known about the metallic state of the nickelates, making these comparisons difficult. We probe the electronic dispersion of thin-film superconducting five-layer ( n = 5 ) and metallic three-layer ( n = 3 ) nickelates by measuring the Seebeck coefficient S . We find a temperature-independent and negative S / T for both n = 5 and n = 3 nickelates. These results are in stark contrast to the strongly temperature-dependent S / T measured at similar electron filling in the cuprate La 1.36 Nd 0.4 Sr 0.24 CuO 4 . The electronic structure calculated from density-functional theory can reproduce the temperature dependence, sign, and amplitude of S / T in the nickelates using Boltzmann transport theory. This demonstrates that the electronic structure obtained from first-principles calculations provides a reliable description of the fermiology of superconducting nickelates and suggests that, despite indications of strong electronic correlations, there are well-defined quasiparticles in the metallic state. Finally, we explain the differences in the Seebeck coefficient between nickelates and cuprates as originating in strong dissimilarities in impurity concentrations. Our study demonstrates that the high elastic scattering limit of the Seebeck coefficient reflects only the underlying band structure of a metal, analogous to the high magnetic field limit of the Hall coefficient. This opens a new avenue for Seebeck measurements to probe the electronic band structures of relatively disordered quantum materials. Published by the American Physical Society 2024

Grissonnanche, G. (ORCID:0000000251153125)↗
NASA NTRS1995

Calculation of far wing of allowed spectra: The water continuum

A far-wing line shape theory based on the binary collision and quasistatic approximations that is applicable for both the low- and high-frequency wings of allowed vibrational-rotational lines has been developed. This theory has been applied in order to calculate the frequency and temperature dependence of the continuous absorption coefficient for frequencies up to 10,000 cm(exp -1) for pure H2O and for H2O-N2 mixtures. The calculations are made assuming an interaction potential consisting of an isotropic Lennard-Jones part and the leading long-range anisotropic part, and utilizing the measured line strengths and transition frequencies. The results compare well with existing data, both in magnitude and in temperature dependence. This leads us to the conclusion that although dimer and collision-induced absorptions are present, the primary mechanism responsible for the observed water continuum is the far-wing absorption of allowed lines. Recent progress on near-wing corrections to the theory and validations with recent laboratory measurements are discussed briefly.

Tipping, R. H.↗